CN105968904A - High-hardness waterproof flashy coating for photo frame - Google Patents
High-hardness waterproof flashy coating for photo frame Download PDFInfo
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- CN105968904A CN105968904A CN201610417139.5A CN201610417139A CN105968904A CN 105968904 A CN105968904 A CN 105968904A CN 201610417139 A CN201610417139 A CN 201610417139A CN 105968904 A CN105968904 A CN 105968904A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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Abstract
The invention discloses a high-hardness waterproof flashy coating for a photo frame. The high-hardness waterproof flashy coating is prepared from fluorinated polysiloxane emulsion, fluorine modified acrylate emulsion, aqueous aluminum-silver paste, cellulose acetate butyrate, modified allyl methacrylate, methyl methacrylate, butyl acrylate, hydroxyethyl acrylate, isopropanol, 2,2'-azobis(2-methylpropionitrile), sodium hydroxide, methylbenzene, acetone, anhydrous sodium sulfate, dodecafluoro dioctyl methacrylate, sodium metavanadate, diiodomethane, hydroxyethyl cellulose thickener, talcum powder, calcined kaolin, nanosilicon dioxide, magnesium hydrate, zinc oxide, superfine aluminum silicate, a silane coupling agent KH-570 and deionized water. The flashy coating is high in hardness and waterproof performance.
Description
Technical field
The present invention relates to flash coating material field, particularly relate to a kind of photo frame high-hardness water-proof flash coating material.
Background technology
At present, present in flash coating material, flakey aluminium powder forms the arranged in parallel of multilamellar in film, it is possible to
Ultraviolet, infrared ray and visible ray are effectively reflected, delay its aging damage to film, it is also possible to
Effectively stop the infiltration of water, gas and ion, because of decoration and the antiseptic effect of its this uniqueness, on photo frame surface
In film, application is more and more.
The demand when hardness of flash coating material the most of the prior art cannot meet actually used, therefore needs badly
Demand when designing the metallized coating of a kind of excellent hardness to meet actually used.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes a kind of photo frame high-hardness water-proof and dodges
Optical coating, has the hardness of excellence.
A kind of photo frame high-hardness water-proof flash coating material that the present invention proposes, its raw material includes by weight: fluorine
Silicon emulsion 35-45 part, fluorin modified crylic acid ester emulsion 5-15 part, water aluminum-silver slurry 2-9 part, acetate butyrate
Cellulose 3-6 part, modified methacrylic acid allyl ester 1-4 part, methyl methacrylate 3-9 part, propylene
Acid butyl ester 2-5 part, 2-(Acryloyloxy)ethanol 1-4 part, 2-(Acryloyloxy)ethanol 2-6 part, isopropanol 4-8 part,
Azo-bis-isobutyl cyanide 1-5 part, sodium hydroxide 2-6 part, toluene 1-4 part, acetone 3-9 part, anhydrous slufuric acid
Sodium 2-5 part, methacrylic acid ten difluoro monooctyl ester 1-4 part, sodium metavanadate 2-5 part, diiodomethane 1-4 part,
Hydroxyethylcellulose thickener 2-6 part, Pulvis Talci 1-5 part, calcined kaolin 2-6 part, nanometer titanium dioxide
Silicon 3-6 part, magnesium hydroxide 1-4 part, zinc oxide 2-5 part, superfine alumina silicate 3-6 part, silane coupler
KH-570 2-5 part, deionized water 5-15 part.
Preferably, the raw material of modified methacrylic acid allyl ester includes by weight: allyl methacrylate
5-15 part, containing hydrogen silicone oil 2-5 part, toluene 3-6 part, chloroplatinic acid 1-4 part, isopropanol 2-5 part, to benzene
Diphenol 3-9 part.
Preferably, modified methacrylic acid allyl ester is prepared by following technique: by chloroplatinic acid and isopropanol
Mix homogeneously, stands 4-6d, is subsequently adding allyl methacrylate mix homogeneously, is warming up to 65-85 DEG C,
Under the protection of nitrogen, add containing hydrogen silicone oil, toluene and hydroquinone, stir 1-2h, then heat to
90-100 DEG C, it is incubated ripening 2-4h, is cooled to room temperature after filtration and obtains modified methacrylic acid allyl ester.
Preferably, fluoro-silicone emulsion, fluorin modified crylic acid ester emulsion, water aluminum-silver slurry and acetylbutyrylcellulose
Weight ratio be 38-42:8-12:3-8:4-5.
Preferably, modified methacrylic acid allyl ester, methyl methacrylate, butyl acrylate, acrylic acid
Hydroxyl ethyl ester, 2-(Acryloyloxy)ethanol, isopropanol, azo-bis-isobutyl cyanide, sodium hydroxide, toluene, acetone, nothing
Aqueous sodium persulfate, methacrylic acid ten difluoro monooctyl ester, sodium metavanadate, diiodomethane, hydroxyethyl cellulose thickening
Agent, Pulvis Talci, calcined kaolin, nano silicon, magnesium hydroxide, zinc oxide, superfine alumina silicate,
The weight ratio of Silane coupling reagent KH-570 and deionized water is 2-3:4-8:3-4:2-3:3-5:5-7:2-4:
3-5:2-3:4-8:3-4:2-3:3-4:2-3:3-5:2-4:3-5:4-5:2-3:3-4:4-5:
3-4:8-12.
Preferably, its raw material includes by weight: fluoro-silicone emulsion 38-42 part, fluorin modified crylic acid ester emulsion
8-12 part, water aluminum-silver slurry 3-8 part, acetylbutyrylcellulose 4-5 part, modified methacrylic acid allyl ester
2-3 part, methyl methacrylate 4-8 part, butyl acrylate 3-4 part, 2-(Acryloyloxy)ethanol 2-3 part, third
Olefin(e) acid hydroxyl ethyl ester 3-5 part, isopropanol 5-7 part, azo-bis-isobutyl cyanide 2-4 part, sodium hydroxide 3-5 part,
Toluene 2-3 part, acetone 4-8 part, anhydrous sodium sulfate 3-4 part, methacrylic acid ten difluoro monooctyl ester 2-3 part,
Sodium metavanadate 3-4 part, diiodomethane 2-3 part, hydroxyethylcellulose thickener 3-5 part, Pulvis Talci 2-4
Part, calcined kaolin 3-5 part, nano silicon 4-5 part, magnesium hydroxide 2-3 part, zinc oxide 3-4
Part, superfine alumina silicate 4-5 part, Silane coupling reagent KH-570 3-4 part, deionized water 8-12 part.
Preferably, its raw material includes by weight: fluoro-silicone emulsion 40 parts, fluorin modified crylic acid ester emulsion 10
Part, water aluminum-silver slurry 5.5 parts, acetylbutyrylcellulose 4.5 parts, modified methacrylic acid allyl ester 2.5
Part, methyl methacrylate 6 parts, butyl acrylate 3.5 parts, 2-(Acryloyloxy)ethanol 2.5 parts, acrylic acid
Hydroxyl ethyl ester 4 parts, isopropanol 6 parts, azo-bis-isobutyl cyanide 3 parts, sodium hydroxide 4 parts, toluene 2.5 parts,
6 parts of acetone, anhydrous sodium sulfate 3.5 parts, methacrylic acid ten difluoro monooctyl ester 2.5 parts, sodium metavanadate 3.5
Part, diiodomethane 2.5 parts, hydroxyethylcellulose thickener 4 parts, Pulvis Talci 3 parts, calcined kaolin 4
Part, nano silicon 4.5 parts, 2.5 parts of magnesium hydroxide, zinc oxide 3.5 parts, superfine alumina silicate 4.5
Part, Silane coupling reagent KH-570 3.5 parts, deionized water 10 parts.
A kind of photo frame high-hardness water-proof flash coating material of the present invention, its raw material includes fluoro-silicone emulsion, fluorine richness
Acrylic acid ester emulsion, water aluminum-silver slurry, acetylbutyrylcellulose, modified methacrylic acid allyl ester, methyl
Acrylic acid methyl ester., butyl acrylate, 2-(Acryloyloxy)ethanol, 2-(Acryloyloxy)ethanol, isopropanol, azo two are different
Fourth cyanogen, sodium hydroxide, toluene, acetone, anhydrous sodium sulfate, methacrylic acid ten difluoro monooctyl ester, metavanadic acid
Sodium, diiodomethane, hydroxyethylcellulose thickener, Pulvis Talci, calcined kaolin, nano silicon,
Magnesium hydroxide, zinc oxide, superfine alumina silicate, Silane coupling reagent KH-570 and deionized water；With fluoro-silicone emulsion
Being base material with fluorin modified crylic acid ester emulsion, wherein with fluoro-silicone emulsion as major ingredient, auxiliary adds fluorine richness propylene
Acid esters emulsion is effectively increased the oil resistant water resistance of fluoro-silicone emulsion, and hardness have also been obtained and is effectively improved；Add
Water aluminum-silver slurry under the effect that aligns of acetylbutyrylcellulose, impart flash coating material of the present invention
Metallic luster and the flash effect of changeable colors along with angle；Add Pulvis Talci, calcined kaolin, nano silicon,
Magnesium hydroxide, zinc oxide and superfine alumina silicate are under the modification of Silane coupling reagent KH-570, it is achieved that to fluorine silicon
The enhancing of emulsion hardness, imparts the hardness that the flash coating material of the present invention is excellent；The methyl methacrylate added
Ester, butyl acrylate, 2-(Acryloyloxy)ethanol, 2-(Acryloyloxy)ethanol, isopropanol, azo-bis-isobutyl cyanide, hydrogen
Sodium oxide, toluene, acetone, anhydrous sodium sulfate, methacrylic acid ten difluoro monooctyl ester, sodium metavanadate, diiodo-
Methane and the interpolation of hydroxyethylcellulose thickener, coordinate with major ingredient fluoro-silicone emulsion, be effectively increased the present invention
The water resistance of fluoro-silicone emulsion, further increases the water resistance of flash coating material of the present invention；The modification added
Allyl methacrylate with allyl methacrylate, containing hydrogen silicone oil, toluene, chloroplatinic acid, isopropanol and
Hydroquinone is raw material, utilizes hydrosilylation, has synthesized containing hydrogen silicone oil modified methacrylic acid allyl ester
Product, is successfully grafted to organosilicon chain on propyl methacrylate monomer, is effectively increased the present invention and dodges
The tack of optical coating, toughness and water resistance.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for
The bright present invention rather than be used for limiting the invention, any made on the basis of the present invention amendment,
Equivalents etc. are the most within the scope of the present invention.
In detailed description of the invention, the weight portion of fluoro-silicone emulsion can be 35 parts, 36 parts, 37 parts, 38 parts,
39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts；The weight of fluorin modified crylic acid ester emulsion
Part can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts,
15 parts；The weight portion of water aluminum-silver slurry can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts,
5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts；Acetate butyrate fiber
The weight portion of element can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；Modified methyl
The weight portion of allyl acrylate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；
The weight portion of methyl methacrylate can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；Third
The weight portion of olefin(e) acid butyl ester can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Third
The weight portion of olefin(e) acid hydroxyl ethyl ester can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；
The weight portion of 2-(Acryloyloxy)ethanol can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The weight portion of isopropanol
It can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight portion of azo-bis-isobutyl cyanide can be 1 part, 2 parts,
3 parts, 4 parts, 5 parts；The weight portion of sodium hydroxide can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；First
The weight portion of benzene can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight of acetone
Amount part can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of anhydrous sodium sulfate can
Think 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Methacrylic acid ten difluoro monooctyl ester
Weight portion can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Sodium metavanadate
Weight portion can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight of diiodomethane
Amount part can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Hydroxyethyl cellulose increases
The weight portion of thick dose can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；Talcous weight portion can be 1
Part, 2 parts, 3 parts, 4 parts, 5 parts；The weight portion of calcined kaolin can be 2 parts, 3 parts, 4 parts, 5
Part, 6 parts；The weight portion of nano silicon can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5
Part, 6 parts；The weight portion of magnesium hydroxide can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts,
4 parts；The weight portion of zinc oxide can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；
The weight portion of superfine alumina silicate can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 6 parts；Silane coupled
The weight portion of agent KH-570 can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；
The weight portion of deionized water can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts,
13 parts, 14 parts, 15 parts.
Embodiment 1
A kind of photo frame high-hardness water-proof flash coating material that the present invention proposes, its raw material includes by weight: fluorine
Silicon emulsion 40 parts, fluorin modified crylic acid ester emulsion 10 parts, water aluminum-silver slurry 5.5 parts, acetate butyrate fiber
Element 4.5 parts, modified methacrylic acid allyl ester 2.5 parts, methyl methacrylate 6 parts, butyl acrylate
3.5 parts, 2-(Acryloyloxy)ethanol 2.5 parts, 2-(Acryloyloxy)ethanol 4 parts, isopropanol 6 parts, azo-bis-isobutyl cyanide
3 parts, sodium hydroxide 4 parts, toluene 2.5 parts, 6 parts of acetone, anhydrous sodium sulfate 3.5 parts, methacrylic acid
Ten difluoro monooctyl esters 2.5 parts, sodium metavanadate 3.5 parts, diiodomethane 2.5 parts, hydroxyethylcellulose thickener 4
Part, Pulvis Talci 3 parts, calcined kaolin 4 parts, nano silicon 4.5 parts, 2.5 parts of magnesium hydroxide,
Zinc oxide 3.5 parts, superfine alumina silicate 4.5 parts, Silane coupling reagent KH-570 3.5 parts, deionized water 10
Part.
Modified methacrylic acid allyl ester is prepared by following technique: by weight by 2.5 parts of chloroplatinic acids and
3.5 parts of isopropanol mix homogeneously, stand 5d, are subsequently adding 10 parts of allyl methacrylate mix homogeneously,
It is warming up to 75 DEG C, under the protection of nitrogen, adds 3.5 parts of containing hydrogen silicone oils, 4.5 parts of toluene and 6 parts to benzene
Diphenol, stirs 1.5h, then heats to 95 DEG C, is incubated ripening 3h, is cooled to room temperature and obtains modification after filtration
Allyl methacrylate.
Embodiment 2
A kind of photo frame high-hardness water-proof flash coating material that the present invention proposes, its raw material includes by weight: fluorine
Silicon emulsion 35 parts, fluorin modified crylic acid ester emulsion 15 parts, water aluminum-silver slurry 2 parts, acetylbutyrylcellulose 6
Part, modified methacrylic acid allyl ester 1 part, methyl methacrylate 9 parts, butyl acrylate 2 parts, third
Olefin(e) acid hydroxyl ethyl ester 4 parts, 2-(Acryloyloxy)ethanol 2 parts, isopropanol 8 parts, azo-bis-isobutyl cyanide 1 part, hydrogen-oxygen
Change 6 parts of sodium, toluene 1 part, 9 parts of acetone, anhydrous sodium sulfate 2 parts, methacrylic acid ten difluoro monooctyl ester 4
Part, sodium metavanadate 2 parts, diiodomethane 4 parts, hydroxyethylcellulose thickener 2 parts, Pulvis Talci 5 parts,
Calcined kaolin 2 parts, nano silicon 6 parts, 1 part of magnesium hydroxide, zinc oxide 5 parts, ultra-fine silicic acid
3 parts of aluminum, Silane coupling reagent KH-570 5 parts, deionized water 5 parts.
Modified methacrylic acid allyl ester is prepared by following technique: by weight by 1 part of chloroplatinic acid and 5
Part isopropanol mix homogeneously, stands 4d, is subsequently adding 15 parts of allyl methacrylate mix homogeneously, heats up
To 65 DEG C, under the protection of nitrogen, add 5 parts of containing hydrogen silicone oils, 3 parts of toluene and 9 parts of hydroquinone, stir
Mix 1h, then heat to 100 DEG C, be incubated ripening 2h, be cooled to room temperature after filtration and obtain modified methyl propylene
Allyl propionate.
Embodiment 3
A kind of photo frame high-hardness water-proof flash coating material that the present invention proposes, its raw material includes by weight: fluorine
Silicon emulsion 45 parts, fluorin modified crylic acid ester emulsion 5 parts, water aluminum-silver slurry 9 parts, acetylbutyrylcellulose 3
Part, modified methacrylic acid allyl ester 4 parts, methyl methacrylate 3 parts, butyl acrylate 5 parts, third
Olefin(e) acid hydroxyl ethyl ester 1 part, 2-(Acryloyloxy)ethanol 6 parts, isopropanol 4 parts, azo-bis-isobutyl cyanide 5 parts, hydrogen-oxygen
Change 2 parts of sodium, toluene 4 parts, 3 parts of acetone, anhydrous sodium sulfate 5 parts, methacrylic acid ten difluoro monooctyl ester 1
Part, sodium metavanadate 5 parts, diiodomethane 1 part, hydroxyethylcellulose thickener 6 parts, Pulvis Talci 1 part,
Calcined kaolin 6 parts, nano silicon 3 parts, 4 parts of magnesium hydroxide, zinc oxide 2 parts, ultra-fine silicic acid
6 parts of aluminum, Silane coupling reagent KH-570 2 parts, deionized water 15 parts.
Modified methacrylic acid allyl ester is prepared by following technique: by weight by 4 parts of chloroplatinic acids and 2
Part isopropanol mix homogeneously, stands 6d, is subsequently adding 5 parts of allyl methacrylate mix homogeneously, heats up
To 85 DEG C, under the protection of nitrogen, add 2 parts of containing hydrogen silicone oils, 6 parts of toluene and 3 parts of hydroquinone, stir
Mix 2h, then heat to 90 DEG C, be incubated ripening 4h, be cooled to room temperature after filtration and obtain modified methacrylic acid
Allyl ester.
Embodiment 4
A kind of photo frame high-hardness water-proof flash coating material that the present invention proposes, its raw material includes by weight: fluorine
Silicon emulsion 38 parts, fluorin modified crylic acid ester emulsion 12 parts, water aluminum-silver slurry 3 parts, acetylbutyrylcellulose 5
Part, modified methacrylic acid allyl ester 2 parts, methyl methacrylate 8 parts, butyl acrylate 3 parts, third
Olefin(e) acid hydroxyl ethyl ester 3 parts, 2-(Acryloyloxy)ethanol 3 parts, isopropanol 7 parts, azo-bis-isobutyl cyanide 2 parts, hydrogen-oxygen
Change 5 parts of sodium, toluene 2 parts, 8 parts of acetone, anhydrous sodium sulfate 3 parts, methacrylic acid ten difluoro monooctyl ester 3
Part, sodium metavanadate 3 parts, diiodomethane 3 parts, hydroxyethylcellulose thickener 3 parts, Pulvis Talci 4 parts,
Calcined kaolin 3 parts, nano silicon 5 parts, 2 parts of magnesium hydroxide, zinc oxide 4 parts, ultra-fine silicic acid
4 parts of aluminum, Silane coupling reagent KH-570 4 parts, deionized water 8 parts.
Modified methacrylic acid allyl ester is prepared by following technique: by weight by 2 parts of chloroplatinic acids and 4
Part isopropanol mix homogeneously, stands 4.5d, is subsequently adding 12 parts of allyl methacrylate mix homogeneously, rises
Temperature, to 68 DEG C, under the protection of nitrogen, adds 4 parts of containing hydrogen silicone oils, 4 parts of toluene and 8 parts of hydroquinone,
Stirring 1.2h, then heats to 98 DEG C, is incubated ripening 2.5h, is cooled to room temperature and obtains modified methyl after filtration
Allyl acrylate.
Embodiment 5
A kind of photo frame high-hardness water-proof flash coating material that the present invention proposes, its raw material includes by weight: fluorine
Silicon emulsion 42 parts, fluorin modified crylic acid ester emulsion 8 parts, water aluminum-silver slurry 8 parts, acetylbutyrylcellulose 4
Part, modified methacrylic acid allyl ester 3 parts, methyl methacrylate 4 parts, butyl acrylate 4 parts, third
Olefin(e) acid hydroxyl ethyl ester 2 parts, 2-(Acryloyloxy)ethanol 5 parts, isopropanol 5 parts, azo-bis-isobutyl cyanide 4 parts, hydrogen-oxygen
Change 3 parts of sodium, toluene 3 parts, 4 parts of acetone, anhydrous sodium sulfate 4 parts, methacrylic acid ten difluoro monooctyl ester 2
Part, sodium metavanadate 4 parts, diiodomethane 2 parts, hydroxyethylcellulose thickener 5 parts, Pulvis Talci 2 parts,
Calcined kaolin 5 parts, nano silicon 4 parts, 3 parts of magnesium hydroxide, zinc oxide 3 parts, ultra-fine silicic acid
5 parts of aluminum, Silane coupling reagent KH-570 3 parts, deionized water 12 parts.
Modified methacrylic acid allyl ester is prepared by following technique: by weight by 3 parts of chloroplatinic acids and 3
Part isopropanol mix homogeneously, stands 5.5d, is subsequently adding 8 parts of allyl methacrylate mix homogeneously, rises
Temperature, to 82 DEG C, under the protection of nitrogen, adds 3 parts of containing hydrogen silicone oils, 5 parts of toluene and 4 parts of hydroquinone,
Stirring 1.8h, then heats to 92 DEG C, is incubated ripening 3.5h, is cooled to room temperature and obtains modified methyl after filtration
Allyl acrylate.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office
Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this
The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention
Within the scope of.
Claims (7)
1. a photo frame high-hardness water-proof flash coating material, it is characterised in that its raw material includes by weight:
Fluoro-silicone emulsion 35-45 part, fluorin modified crylic acid ester emulsion 5-15 part, water aluminum-silver slurry 2-9 part, acetic acid fourth
Acid cellulose 3-6 part, modified methacrylic acid allyl ester 1-4 part, methyl methacrylate 3-9 part, third
Olefin(e) acid butyl ester 2-5 part, 2-(Acryloyloxy)ethanol 1-4 part, 2-(Acryloyloxy)ethanol 2-6 part, isopropanol 4-8 part,
Azo-bis-isobutyl cyanide 1-5 part, sodium hydroxide 2-6 part, toluene 1-4 part, acetone 3-9 part, anhydrous slufuric acid
Sodium 2-5 part, methacrylic acid ten difluoro monooctyl ester 1-4 part, sodium metavanadate 2-5 part, diiodomethane 1-4 part,
Hydroxyethylcellulose thickener 2-6 part, Pulvis Talci 1-5 part, calcined kaolin 2-6 part, nanometer titanium dioxide
Silicon 3-6 part, magnesium hydroxide 1-4 part, zinc oxide 2-5 part, superfine alumina silicate 3-6 part, silane coupler
KH-570 2-5 part, deionized water 5-15 part.
Photo frame high-hardness water-proof flash coating material the most according to claim 1, it is characterised in that modified
The raw material of allyl methacrylate includes by weight: allyl methacrylate 5-15 part, containing hydrogen silicone oil
2-5 part, toluene 3-6 part, chloroplatinic acid 1-4 part, isopropanol 2-5 part, hydroquinone 3-9 part.
Photo frame high-hardness water-proof flash coating material the most according to claim 1 and 2, it is characterised in that
Modified methacrylic acid allyl ester is prepared by following technique: by chloroplatinic acid and isopropanol mix homogeneously, quiet
Put 4-6d, be subsequently adding allyl methacrylate mix homogeneously, be warming up to 65-85 DEG C, the guarantor of nitrogen
Protect down, add containing hydrogen silicone oil, toluene and hydroquinone, stir 1-2h, then heat to 90-100 DEG C, protect
Temperature ripening 2-4h, is cooled to room temperature and obtains modified methacrylic acid allyl ester after filtration.
4., according to the photo frame high-hardness water-proof flash coating material described in any one of claim 1-3, its feature exists
In, fluoro-silicone emulsion, fluorin modified crylic acid ester emulsion, water aluminum-silver slurry and the weight ratio of acetylbutyrylcellulose
For 38-42:8-12:3-8:4-5.
5., according to the photo frame high-hardness water-proof flash coating material described in any one of claim 1-4, its feature exists
In, modified methacrylic acid allyl ester, methyl methacrylate, butyl acrylate, 2-(Acryloyloxy)ethanol,
2-(Acryloyloxy)ethanol, isopropanol, azo-bis-isobutyl cyanide, sodium hydroxide, toluene, acetone, anhydrous sodium sulfate,
Methacrylic acid ten difluoro monooctyl ester, sodium metavanadate, diiodomethane, hydroxyethylcellulose thickener, Pulvis Talci,
Calcined kaolin, nano silicon, magnesium hydroxide, zinc oxide, superfine alumina silicate, Silane coupling reagent KH-570
It is 2-3:4-8:3-4:2-3:3-5:5-7:2-4:3-5:2-3:4-8 with the weight ratio of deionized water:
3-4:2-3:3-4:2-3:3-5:2-4:3-5:4-5:2-3:3-4:4-5:3-4:8-12.
6., according to the photo frame high-hardness water-proof flash coating material described in any one of claim 1-5, its feature exists
In, its raw material includes by weight: fluoro-silicone emulsion 38-42 part, fluorin modified crylic acid ester emulsion 8-12 part,
Water aluminum-silver slurry 3-8 part, acetylbutyrylcellulose 4-5 part, modified methacrylic acid allyl ester 2-3 part,
Methyl methacrylate 4-8 part, butyl acrylate 3-4 part, 2-(Acryloyloxy)ethanol 2-3 part, acrylic acid hydroxyl
Ethyl ester 3-5 part, isopropanol 5-7 part, azo-bis-isobutyl cyanide 2-4 part, sodium hydroxide 3-5 part, toluene 2-3
Part, acetone 4-8 part, anhydrous sodium sulfate 3-4 part, methacrylic acid ten difluoro monooctyl ester 2-3 part, metavanadic acid
Sodium 3-4 part, diiodomethane 2-3 part, hydroxyethylcellulose thickener 3-5 part, Pulvis Talci 2-4 part, forge
Burn Kaolin 3-5 part, nano silicon 4-5 part, magnesium hydroxide 2-3 part, zinc oxide 3-4 part, surpass
Thin aluminium silicate 4-5 part, Silane coupling reagent KH-570 3-4 part, deionized water 8-12 part.
7., according to the photo frame high-hardness water-proof flash coating material described in any one of claim 1-6, its feature exists
In, its raw material includes by weight: fluoro-silicone emulsion 40 parts, fluorin modified crylic acid ester emulsion 10 parts, aqueous
Aluminum paste 5.5 parts, acetylbutyrylcellulose 4.5 parts, modified methacrylic acid allyl ester 2.5 parts, methyl
Acrylic acid methyl ester. 6 parts, butyl acrylate 3.5 parts, 2-(Acryloyloxy)ethanol 2.5 parts, 2-(Acryloyloxy)ethanol 4
Part, isopropanol 6 parts, azo-bis-isobutyl cyanide 3 parts, sodium hydroxide 4 parts, toluene 2.5 parts, 6 parts of acetone,
Anhydrous sodium sulfate 3.5 parts, methacrylic acid ten difluoro monooctyl ester 2.5 parts, sodium metavanadate 3.5 parts, diiodo-first
2.5 parts of alkane, hydroxyethylcellulose thickener 4 parts, Pulvis Talci 3 parts, calcined kaolin 4 parts, nanometer two
Silicon oxide 4.5 parts, 2.5 parts of magnesium hydroxide, zinc oxide 3.5 parts, superfine alumina silicate 4.5 parts, silane are even
Connection agent KH-570 3.5 parts, deionized water 10 parts.
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| CN101691466A (en) * | 2009-09-15 | 2010-04-07 | 中国船舶重工集团公司第七二五研究所 | Method for preparing antifouling material with surface of spherically raised microstructure |
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| CN101691466A (en) * | 2009-09-15 | 2010-04-07 | 中国船舶重工集团公司第七二五研究所 | Method for preparing antifouling material with surface of spherically raised microstructure |
| CN103936996A (en) * | 2014-04-14 | 2014-07-23 | 茂名市信龙科技有限公司 | Synthesis of photo-cured fluorosilicone polymer and preparation method of photo-cured fluorosilicone polymer coating |
| CN104178012A (en) * | 2014-09-09 | 2014-12-03 | 江苏美亿晨新材料科技有限公司 | High-property environment-friendly water-based activation nano metallic paint and preparation method |
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