CN105967828A - Zinc-rich modified-Chinese-chestnut-protein-coated slow-release fertilizer - Google Patents

Zinc-rich modified-Chinese-chestnut-protein-coated slow-release fertilizer Download PDF

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Publication number
CN105967828A
CN105967828A CN201610103224.4A CN201610103224A CN105967828A CN 105967828 A CN105967828 A CN 105967828A CN 201610103224 A CN201610103224 A CN 201610103224A CN 105967828 A CN105967828 A CN 105967828A
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CN
China
Prior art keywords
zinc
semen castaneae
fertilizer
chestnut
minute
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610103224.4A
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Chinese (zh)
Inventor
曹文柱
周承东
曹义好
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Quan Run Agricultural Science And Technology Co Ltd Of Maanshan City
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Quan Run Agricultural Science And Technology Co Ltd Of Maanshan City
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Priority to CN201610103224.4A priority Critical patent/CN105967828A/en
Publication of CN105967828A publication Critical patent/CN105967828A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C11/00Other nitrogenous fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/30Layered or coated, e.g. dust-preventing coatings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Abstract

The invention discloses a zinc-rich modified-Chinese-chestnut-protein-coated slow-release fertilizer. The fertilizer is made from the following raw materials, by weight part, 29-31 of cocopeat, 1-2 of zinc sulfate heptahydrate, 2-3 of wheat gluten powder, 95-105 of fresh Chinese chestnuts, 3-4 of zinc lignocarbonate, 6-8 of potassium sulfate, 16-18 of wheat bran, 24-26 of fruits of ficus pumila, 1.7-1.8 of a glutamine transaminase preparation and a proper amount of water. The fertilizer is scientific and reasonable in component ratio; through addition of zinc lignocarbonate and zinc sulfate heptahydrate, abundant supply of zinc is ensured; and based on a scientific ratio of nitrogen to zinc and through use of organic chelation technology, it is ensured that crops can normally absorb zinc. The fertilizer has a slow-release effect, can supplement zinc to the crops for a long time, and has a good growth promotion effect on zinc-deficient soil and crops with high demand of zinc.

Description

A kind of zinc-rich modification Semen Castaneae protein envelope slow release fertilizer
Technical field
The present invention relates to slow release fertilizer technical field, particularly relate to a kind of zinc-rich modification Semen Castaneae protein envelope slow release fertilizer.
Background technology
Along with the specialization of China's agricultural production, industrialization, the development of scale, agricultural is constantly upgraded for the requirement of fertilizer, soil fertility, and conventional fertilizers is low due to plant recovery of nutrient, constrains the sustainable development of agricultural planting.The application of coated slow release fertilizer is then the effective way solving this problem.But the coated fertilizer of current common coated slow release fertilizer is to use the non-degradable high molecular polymer of chemosynthesis, easily remain in soil and cause soil degradation and pollution, the function singleness of coated fertilizer simultaneously, generally only there is slow controlled-release effect, do not account for the effects such as water suction, antibacterial, antioxidation and the practicality for different soils environment.
The rich in nutrition content of Semen Castaneae, there are substantial amounts of starch, protein, fat etc., contain multi mineral prime element simultaneously, the most important macroelement N, P, K, Ca etc. and trace element Fe, Cu, Zn, Mn etc., Semen Castaneae also has the functional component useful to plant growing, if the polyphenol substance in Semen Castaneae is a kind of natural antioxidant, gallic acid therein, ellagic acid, elladitannin have powerful antioxidation, antibacterial characteristics.In Semen Castaneae, protein content is high simultaneously, accounts for 5%-11%, rich amino acids in Semen Castaneae albumen, and plant can absorb aminoacid, therefore can improve the trophic structure in growing process, and potentiality to be exploited is very big.
Semen Castaneae albumen has preferable dissolubility and viscosity in the pH range of 7.0-8.0, and by combining the common effect of water, hydrodynamics water and Physical entrapment water, it is allowed to that there is fabulous moisture holding capacity, the number of dropouts of moisture can be reduced, the most in the basic conditions, Semen Castaneae albumen also has preferable emulsibility, foaming characteristic and foam stability, meets the condition needed for coated fertilizer in slow release fertilizer.
Zinc is a kind of important trace element in plant, suffers from important regulating and controlling effect for the regulation of plant growing, the growth of rhizome, to zinc deficient soil and need zinc crop to supplement Zinc nutrition with greater need for by fertilizer.
Semen Castaneae all has plantation, wide material sources in various places, utilizes the slow-release fertilizer that the exploitation of Semen Castaneae albumen is novel, gives the function that slow release fertilizer is new simultaneously, and the development for slow release fertilizer opens new approach.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of zinc-rich modification Semen Castaneae protein envelope slow release fertilizer.
The present invention is achieved by the following technical solutions:
A kind of zinc-rich modification Semen Castaneae protein envelope slow release fertilizer, is prepared by the raw materials in: coconut palm bran 29-31, zinc sulphate heptahydrate 1-2, wheat gluten flour 2-3, fresh Semen Castaneae 95-105, lignin zinc carbonate 3-4, potassium sulfate 6-8, wheat bran 16-18, Receptaculum Fici Pumilae 24-26, glutamine transaminage preparation 1.7-1.8, water are appropriate.
Specifically comprising the following steps that of described zinc-rich modification Semen Castaneae protein envelope slow release fertilizer preparation method
(1) cut into slices after going bud to shell fresh Semen Castaneae, pulverize levigate after drying at 48-50 DEG C, rice-chestnut powder is joined in the water of 10 times of its quality, and use 1mol/L sodium hydroxide solution to regulate PH to 9.8-10.0, through Ultrasonic Pulverization 16-17 minute under 35-40kHz, it is heated to 40-42 DEG C afterwards, is incubated 80-90 minute, cross leaching supernatant, after vacuum lyophilization, obtain Semen Castaneae egg albumen powder;
(2) step 1 is discarded Semen Castaneae bud, chestnut shell mixing is placed in calcining furnace; it is warming up to 540-560 DEG C with 20-25 DEG C/minute; take out after calcining 120-130 minute; obtain chestnut powdered carbon standby; again by coconut palm bran, wheat bran mixing retting fermentation; post-drying for the treatment of fully to become thoroughly decomposed is pulverized and mixes with lignin zinc carbonate, chestnut powdered carbon, is placed in pelletize in comminutor;
(3) squeeze the juice clean for the Receptaculum Fici Pumilae and filter, filtrate being mixed with zinc sulphate heptahydrate, is heated to 72-75 DEG C, be cooled to 40-42 DEG C and add potassium sulfate after stirring 5 minutes, be again stirring for 10 minutes, obtain nutritional solution standby;
(4) step 1 gained Semen Castaneae egg albumen powder is added in the water of 12-15 times of its quality, and regulate PH to 7.3-7.7 with 1mol/L sodium hydroxide solution, add glutamine transaminage preparation, wheat gluten flour, be heated to 50-53 DEG C, it is incubated 3-3.5 hour, obtains modified Semen Castaneae protein liquid;
(5) step 2 gained granule is placed in bottom and has in the cylinder of heater, barrel is heated to 55-60 DEG C, rolling process sprays into by the way of spraying sprays in cylinder step 3 gained nutritional solution, continue after having sprayed to roll 10-15 minute, spray into step 4 gained modification Semen Castaneae protein liquid again, continue to roll 10-15 minute, take out and i.e. obtain coated fertilizer granule of the present invention.
The invention have the advantage that
Semen Castaneae egg albumen powder acts on modification under the conditions of glutamine transaminage and alkalescence jointly, be conducive to the expansion of protein molecule, and catalytic proteins polypeptide generation intramolecular and intermolecular generation covalent cross-linking, it is embodied in viscosity to increase, there is higher shearing force repellence and gumminess, can stably be attached to fertiliser granulates surface, the retentiveness coordinating egg albumen powder ensures being dried of fertiliser granulates, will not make moist in short time disintegrate, extend action period, during slow release, albumin layer slowly decomposes, it is alternatively arranged as plant nitrogen source, and aminoacid-cation-polyphosphoric acid complex can be formed, reduce the mobility of heavy metal in soil ion, alleviate heavy metal ion to poison.Fertilizer component proportioning of the present invention is scientific and reasonable, the addition of lignin zinc carbonate, zinc sulphate heptahydrate etc. ensure that enough supplies of zinc, the nitrogen zinc ratio of science and the use of organic chelated technique simultaneously, ensure that the crop normal absorption to zinc, and the purpose of the long-term zinc supplement of crop it is issued at slow release effect, need zinc crop to have good growth-promoting effect zinc deficient soil and height.
Detailed description of the invention
A kind of zinc-rich modification Semen Castaneae protein envelope slow release fertilizer, is made up of the raw material of following weight portion (kg): coconut palm bran 29, zinc sulphate heptahydrate 1, wheat gluten flour 2, fresh Semen Castaneae 95, lignin zinc carbonate 3, potassium sulfate 6, wheat bran 16, the Receptaculum Fici Pumilae 24, glutamine transaminage preparation 1.7, water are appropriate.
Specifically comprising the following steps that of described zinc-rich modification Semen Castaneae protein envelope slow release fertilizer preparation method
(1) cut into slices after going bud to shell fresh Semen Castaneae, pulverize levigate after drying at 48 DEG C, rice-chestnut powder is joined in the water of 10 times of its quality, and use 1mol/L sodium hydroxide solution to regulate PH to 9.8, through Ultrasonic Pulverization 16 minutes under 35kHz, it is heated to 40 DEG C afterwards, is incubated 80 minutes, cross leaching supernatant, after vacuum lyophilization, obtain Semen Castaneae egg albumen powder;
(2) step 1 is discarded Semen Castaneae bud, chestnut shell mixing is placed in calcining furnace; it is warming up to 540 DEG C with 20 DEG C/minute; take out after calcining 120 minutes; obtain chestnut powdered carbon standby; again by coconut palm bran, wheat bran mixing retting fermentation; post-drying for the treatment of fully to become thoroughly decomposed is pulverized and mixes with lignin zinc carbonate, chestnut powdered carbon, is placed in pelletize in comminutor;
(3) squeeze the juice clean for the Receptaculum Fici Pumilae and filter, filtrate being mixed with zinc sulphate heptahydrate, is heated to 72 DEG C, be cooled to 40 DEG C after stirring 5 minutes and add potassium sulfate, being again stirring for 10 minutes, obtain nutritional solution standby;
(4) step 1 gained Semen Castaneae egg albumen powder is added in the water of 12 times of its quality, and regulate PH to 7.3 with 1mol/L sodium hydroxide solution, add glutamine transaminage preparation, wheat gluten flour, be heated to 50 DEG C, be incubated 3 hours, obtain modified Semen Castaneae protein liquid;
(5) step 2 gained granule is placed in bottom and has in the cylinder of heater, barrel is heated to 55 DEG C, rolling process sprays into by the way of spraying sprays in cylinder step 3 gained nutritional solution, continue after having sprayed to roll 10 minutes, spray into step 4 gained modification Semen Castaneae protein liquid again, continue to roll 10 minutes, take out and i.e. obtain coated fertilizer granule of the present invention.
In order to further illustrate the using value of the present invention, inventor chooses two pieces of areas and is the Oryza sativa L. experiment field of 10 mu, and is divided into matched group and experimental group, matched group uses common fertilizer, experimental group uses slow-release fertilizer of the present invention, and every mu is 70kg with fertilizer, and during plantation, field management pattern is the most identical, results statistics after maturation, matched group per mu yield 479kg, experimental group per mu yield 521kg, the average relatively matched group of experimental group Zn For Rice content improves 70%, and experimental group rice grain is relatively big, condition is preferable.

Claims (2)

1. a zinc-rich modification Semen Castaneae protein envelope slow release fertilizer, it is characterized in that, be prepared by the raw materials in: coconut palm bran 29-31, zinc sulphate heptahydrate 1-2, wheat gluten flour 2-3, fresh Semen Castaneae 95-105, lignin zinc carbonate 3-4, potassium sulfate 6-8, wheat bran 16-18, Receptaculum Fici Pumilae 24-26, glutamine transaminage preparation 1.7-1.8, water are appropriate.
2. according to the zinc-rich modification Semen Castaneae protein envelope slow release fertilizer described in claims 1, it is characterised in that specifically comprising the following steps that of preparation method
(1) cut into slices after going bud to shell fresh Semen Castaneae, pulverize levigate after drying at 48-50 DEG C, rice-chestnut powder is joined in the water of 10 times of its quality, and use 1mol/L sodium hydroxide solution to regulate PH to 9.8-10.0, through Ultrasonic Pulverization 16-17 minute under 35-40kHz, it is heated to 40-42 DEG C afterwards, is incubated 80-90 minute, cross leaching supernatant, after vacuum lyophilization, obtain Semen Castaneae egg albumen powder;
(2) step 1 is discarded Semen Castaneae bud, chestnut shell mixing is placed in calcining furnace; it is warming up to 540-560 DEG C with 20-25 DEG C/minute; take out after calcining 120-130 minute; obtain chestnut powdered carbon standby; again by coconut palm bran, wheat bran mixing retting fermentation; post-drying for the treatment of fully to become thoroughly decomposed is pulverized and mixes with lignin zinc carbonate, chestnut powdered carbon, is placed in pelletize in comminutor;
(3) squeeze the juice clean for the Receptaculum Fici Pumilae and filter, filtrate being mixed with zinc sulphate heptahydrate, is heated to 72-75 DEG C, be cooled to 40-42 DEG C and add potassium sulfate after stirring 5 minutes, be again stirring for 10 minutes, obtain nutritional solution standby;
(4) step 1 gained Semen Castaneae egg albumen powder is added in the water of 12-15 times of its quality, and regulate PH to 7.3-7.7 with 1mol/L sodium hydroxide solution, add glutamine transaminage preparation, wheat gluten flour, be heated to 50-53 DEG C, it is incubated 3-3.5 hour, obtains modified Semen Castaneae protein liquid;
(5) step 2 gained granule is placed in bottom and has in the cylinder of heater, barrel is heated to 55-60 DEG C, rolling process sprays into by the way of spraying sprays in cylinder step 3 gained nutritional solution, continue after having sprayed to roll 10-15 minute, spray into step 4 gained modification Semen Castaneae protein liquid again, continue to roll 10-15 minute, take out and i.e. obtain coated fertilizer granule of the present invention.
CN201610103224.4A 2016-02-25 2016-02-25 Zinc-rich modified-Chinese-chestnut-protein-coated slow-release fertilizer Pending CN105967828A (en)

Priority Applications (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106518288A (en) * 2016-10-09 2017-03-22 胡宁 Zinc-rich organic fertilizer capable of improving plant heat resistance

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CN104086318A (en) * 2014-07-30 2014-10-08 河南力浮科技有限公司 Production method of biomass coated controlled-release fertilizer
CN105175132A (en) * 2015-09-16 2015-12-23 安徽省陆虎生物科技有限公司 Functional residue-free slow-release protein peptide fertilizer

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104086318A (en) * 2014-07-30 2014-10-08 河南力浮科技有限公司 Production method of biomass coated controlled-release fertilizer
CN105175132A (en) * 2015-09-16 2015-12-23 安徽省陆虎生物科技有限公司 Functional residue-free slow-release protein peptide fertilizer

Non-Patent Citations (4)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106518288A (en) * 2016-10-09 2017-03-22 胡宁 Zinc-rich organic fertilizer capable of improving plant heat resistance

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Application publication date: 20160928