CN1059649C - Thermal insulation (organic silicon) wall composite material and its producing method - Google Patents

Thermal insulation (organic silicon) wall composite material and its producing method Download PDF

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Publication number
CN1059649C
CN1059649C CN97120146A CN97120146A CN1059649C CN 1059649 C CN1059649 C CN 1059649C CN 97120146 A CN97120146 A CN 97120146A CN 97120146 A CN97120146 A CN 97120146A CN 1059649 C CN1059649 C CN 1059649C
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thermal insulation
composite material
organic silicon
glass fibre
hours
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Expired - Fee Related
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CN97120146A
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CN1183392A (en
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徐虎林
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/2023—Resistance against alkali-aggregate reaction
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52—Sound-insulating materials

Abstract

The present invention belongs to the field of building materials and an energy-saving technology. A fibroid and loosely granulated material is formed by using a chemical industry auxiliary agent and composite technique. An inner netted tension structure formed by the material is loose and lacunose and has good heat-insulating performance which is controlled below 0.10 W/MK under the condition of 298K. The product has the advantages of light weight, acoustic insulation, non-inflammable performance, alkali resistance, strong cohesive force and low integral manufacturing cost and is mainly used for industrial and civil buildings, the problems of indoor dew condensation, moisture and mildew of old buildings are thoroughly solved, the room temperature is increased by 2 to 3 DEG C in winter, and the product is a novel walling energy saving material.

Description

(organosilicon) body of wall thermal insulation composite material and production method
The invention belongs to building material technical field.Be applicable to heat insulation, insulation, the sound insulation of the civilian house of building, electric power, chemical industry, metallurgy, weaving, medicine, oil etc. and industrial occupancy.
Chinese patent is in open (CN1066700A on December 2nd, 1992, application number is 92104378.8) plant stem---the especially invention of sunflower bar infill panel light composite wall, this invention complex structure, need the plank framework to be connected with screw, insulation and fire prevention need double-layer structure, make troubles to construction, and the expense material of taking a lot of work, thermal conductivity height, than great, cohesive force is poor, the cost height, be unfavorable for promotion and application.Mostly to be concrete, heat insulation, insulation, sound-proofing properties poor and traditional indoor wall whitewashes.From whitewashing the tired lock of decoration process.In the season and the area of cold, be subjected to climatic influences especially, restricted construction; In the season and the area of hot summer weather, the nursing trouble, the labor intensive material resources, and also easily dry and cracked, easily come off.
In producing cement, also to consume a large amount of energy because concrete is than great, ship bulky, stir bothersome, serious environment pollution, building brick considerable damage land resources simultaneously again in the city.
In order to address the above problem, the invention provides a kind of glass fibre that utilizes the sepiolite in the building materials, pearlstone, aluminosilicate fiber cotton, wilkinite, by amylan and epoxy resin glue carboxymethyl cellulose, the physical treatment of gelatine, caustic soda, szaibelyite, hydrogen peroxide, methyl silicon sodium alcoholate, anionic surfactant (the fast T of permeate agent) and chemical reaction add organic silicon emulsion (GP), according to certain proportioning and processing step, make building materials and chemical industry, organism and inorganics in conjunction with and a kind of organosilicon body of wall thermal insulation composite material of making.The present invention combines heat insulation, insulation, sound insulation together, has that thermal conductivity is low, lightweight, cost be low, and local damage has prevention and remedies to buildings.It is extremely hot not to be afraid of severe cold, is not afraid of corrosion and radiation, and reacts with building surface, forms a kind of compound, so the cohesive force extra-heavy.
Our invention main points realize by following proposal.Major ingredient (kg/M of the present invention 3): aluminosilicate fiber cotton 7-9 (1); Wilkinite 9-10 (2); Sepiolite 5-7 (3); Glass fibre 15-20 (4); Epoxy resin glue 4-6 (5); Carboxymethyl cellulose 1-2 (6); Starch 4-6 (7); Gelatine 1-2 (8); Perlite 10-12 (9); Water 620-650 (10); Organic silicon emulsion 2-3 (11); Caustic soda 1-2 (12); Szaibelyite 1-2 (13); Permeate agent 2-4 (14); Hydrogen peroxide 1-2 (15); Methyl silicon sodium alcoholate 2-3 (16) and form.10-15mm soaks with methyl silicon sodium alcoholate the chopped glass fiber,, insulation heat insulation with being combined to form of pearlstone in the building materials, wilkinite, sepiolite, sound insulation, lightweight, materials for wall cheaply.By adding glass fibre, aluminosilicate fiber cotton and form the netted tension structure of material internal makes body of wall mix right one, does not dry and crackedly come off again.With scaleization, add starch and be warmed up to 100 ℃, do not stop to stir, add the fast T of permeate agent, hydrogen peroxide etc. leave standstill 4 hours, and have formed amylan of the present invention.Amylan of the present invention and epoxy resin glue add organosilicon and add emulsion (GP) carboxymethyl cellulose through chemical treatment, make adhesion glue infiltrate the building body, and form a kind of compound at building surface.Not only cohesive force is strong, and high temperature resistant low temperature resistant again, at cold district be not subjected to the weather condition effect season.
The processing step of producing the production method of (organosilicon) body of wall thermal insulation composite material is such: at first scaleization, add starch, be heated to 100 ℃, constantly stir, add permeate agent alkynes T.Hydrogen peroxide etc. leave standstill 4 hours to form amylan of the present invention, then the glass fibre that prescinds are soaked with methyl silicon sodium alcoholate, make the fiber reinforcement alkali resistant and stop water-swelling property.In epoxy resin glue, the adding organosilicon adds emulsion (GP) carboxymethyl cellulose and constantly stirs, and adds aluminosilicate fiber cotton, and disconnected with stainless steel instrument hand hay cutter, fully immersion.In big steel basin, add water, put into the glass fibre and the aluminosilicate fiber cotton of immersion then, and remaining all raw material is also put into big stirrer, fully stir, put at last hopper ferment 4 hours standby.
The paste that materials for wall of the present invention can be made into the clay shape directly smears use, also can be made into decorating film, makes hollow brick, and ash wall body plate etc. become finished product and use.
(organosilicon) of the present invention body of wall thermal insulation composite material can replace the concrete material that whitewashes of construction industry indoor wall, saves building materials simultaneously and enlarges the room area occupied.For example: adopt materials for wall 1cm of the present invention to compare than 240 traditional walls on 120 walls, heat insulation, insulation, soundproof effect are even more ideal, save the cost of 50%-80% on upholstery, keep the attractive in appearance and practical function of art simultaneously.Decorate than traditional method from constructing to and to have lacked three process.Materials for wall of the present invention, 8-10 unit/m 2, thickness is 8-10mm.Utilize the glue class of processing such as starch and add organic silicon emulsion, not only cohesive force is strong, weatherproof in construction, but also normal construction has in the winter time reduced drying cycle.Dried simultaneously light specific gravity 188kg/m 3, the expense that has reduced transportation and stirred has substituted the heavy thing of concrete water, mud, sand, ash, has saved material, has reduced the loss of the energy, and protection plays a role to The Surroundings in Cities.It is destroyed effectively to have reduced land resources.
Below by embodiment and process flow sheet invention is further described:
Fig. 1 is the synoptic diagram that the paste of clay shape directly spreads upon body of wall for (organosilicon) body of wall thermal insulation composite material; Piece number 1 is a brick wall, and piece number 2 is a materials for wall of the present invention.
Fig. 2 is the synoptic diagram of the made hollow brick of decorating film for (organosilicon) body of wall thermal insulation composite material; Piece number 1 is decorating film of the present invention; Piece number 2 is the decorating film hollow parts, also can make hollow brick to have the structure 1 of arranging aperture.
Fig. 3 is the synoptic diagram of the sheet material made for (organosilicon) body of wall thermal insulation composite material; Piece number 1 is a decorating film of the present invention.
Fig. 4 is the process flow sheet of (organosilicon) body of wall thermal insulation composite material.
1, in 1 groove, add entry, starch (7), caustic soda (12), permeate agent (14), hydrogen peroxide (15), heat 100 ℃, fully stir, leave standstill then 4 hours standby;
2, adding water, methyl silicon sodium alcoholate (16), glass fibre (4) in the II groove soaked 2 hours;
3, adding epoxy resin glue (5), carboxymethyl cellulose (6), organic silicon emulsion (GP) (11) at the III groove puts into aluminosilicate fiber cotton (1) then and soaks;
4, water is added in the stirrer position line, puts the I groove then, II groove, III groove and the starting material wilkinite (2) that is left, sepiolite (3), gelatine (8), perlite (9), szaibelyite (13);
5, put into the material pond at last, fermented 4 hours,, just can use by quality inspection.
(organosilicon) of the present invention body of wall thermal insulation composite material and production method, alternative traditional materials for wall.Cost is low, operation is simple, heat insulation, insulation, soundproof effect are splendid, is a kind of practical ideal materials for wall, also is the Gospel of human house.

Claims (3)

1. organosilicon body of wall thermal insulation composite material is characterized in that: raw materials used proportioning is (KG/M 3): aluminosilicate fiber cotton 7-9; (1).Perlite 10-12; (9).Wilkinite 9-10; (2).Water 620-650; (10).Sepiolite 5-7; (3).Organic silicon emulsion 2-3; (11).Glass fibre 15-20; (4).Caustic soda 1-2; (12).Resins, epoxy 4-6; (5).Szaibelyite 1-2; (13).Carboxymethyl cellulose 1-2; (6).The hot fat sodium sulfonate of maleic acid di-secondary,
Trade(brand)name; The fast T 2-4 of permeate agent; (14).Starch 4-6; (7).Hydrogen peroxide 1-2; (15).Gelatine 1-2; (8).Methyl silicon sodium alcoholate 2-3; (16).
2. the production method of an organosilicon body of wall thermal insulation composite material, it is characterized in that: 2.1 all material fiting ratios are (KG/M 3): aluminosilicate fiber cotton 7-9; (1).Perlite 10-12; (9).Wilkinite 9-10; (2).Water 620-660; (10).Sea bubble 5-7; (3).Organic silicon emulsion 2-3; (11).Glass fibre 15-20; (4).Caustic soda 1-2; (12).Resins, epoxy 4-6; (5).Szaibelyite 1-2; (13).Carboxymethyl cellulose 1-2; (6).The hot fat sodium sulfonate of maleic acid di-secondary,
Trade(brand)name: the fast T 2-4 of permeate agent; (14).Starch 4-6; (7).Hydrogen peroxide 1-2; (15).Gelatine 1-2; (8).Methyl silicon sodium alcoholate 2-3; (16) 2.2 these methods comprise following processing step:
2.2.1, put into a part of water (10) with caustic soda (12), add starch (7), be warmed to 100 ℃ of continuously stirring, put into the hot fat sodium sulfonate of maleic acid di-secondary, trade(brand)name: fast T of permeate agent (14) and hydrogen peroxide (15).Left standstill 4 hours, and formed amylan.
2.2.2 glass fibre (4) is cut into the short silk of 10-15MM, soaked 2 hours with methyl silicon sodium alcoholate (16).
2.2.3 in Resins, epoxy (5), add organic silicon emulsion (11) and carboxymethyl cellulose (6), and stir, put into aluminosilicate fiber cotton (1) then and soak.
2.2.4 all material is put into big stirrer, fully stir, put into hopper then static 4 hours, dress bag metering warehouse-in.
3. organosilicon body of wall thermal insulation composite material according to claim 1 is characterized in that: this material further is processed as paste and decorating film.
CN97120146A 1997-11-12 1997-11-12 Thermal insulation (organic silicon) wall composite material and its producing method Expired - Fee Related CN1059649C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN97120146A CN1059649C (en) 1997-11-12 1997-11-12 Thermal insulation (organic silicon) wall composite material and its producing method

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Application Number Priority Date Filing Date Title
CN97120146A CN1059649C (en) 1997-11-12 1997-11-12 Thermal insulation (organic silicon) wall composite material and its producing method

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CN1183392A CN1183392A (en) 1998-06-03
CN1059649C true CN1059649C (en) 2000-12-20

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1068859C (en) * 1998-10-29 2001-07-25 陈占魁 Composite thermal insulating material
CN100425564C (en) * 2006-11-03 2008-10-15 北京大津建筑材料有限责任公司 Inner wall surface decoration material and its preparation method
CN101798195B (en) * 2010-03-18 2012-06-20 北京联合大学生物化学工程学院 Thermosetting resin base fire retardant module
CN104557082B (en) * 2014-12-18 2016-06-01 济南海川投资集团有限公司 The making method of a kind of carbon anode roasting furnace fire road vision slit sealing cover
CN108996958A (en) * 2017-06-07 2018-12-14 深圳市元亨环保产业新技术有限公司 It is a kind of using building waste be raw material for quickly squeeze out wallboard product material prescription

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87102864A (en) * 1987-04-15 1987-11-18 王吉宇 Composite silicate thermal insulation paint and production method thereof
CN87101962A (en) * 1987-03-13 1988-03-30 四川省涪陵地区垫江县三峡节能产品厂 Composite silicate heat insulation material and method for making
CN1030069A (en) * 1988-02-02 1989-01-04 夏杏雪 Novel composite thermal insulating material
CN1058419A (en) * 1990-07-21 1992-02-05 田后德 Composite heat-insulated material
CN1107815A (en) * 1994-03-04 1995-09-06 徐虎林 Composite, insulating, light organosilicon wall material and its production process
CN1124750A (en) * 1994-02-09 1996-06-19 曲中辉 Non-toxic compounded insulation paint

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87101962A (en) * 1987-03-13 1988-03-30 四川省涪陵地区垫江县三峡节能产品厂 Composite silicate heat insulation material and method for making
CN87102864A (en) * 1987-04-15 1987-11-18 王吉宇 Composite silicate thermal insulation paint and production method thereof
CN1030069A (en) * 1988-02-02 1989-01-04 夏杏雪 Novel composite thermal insulating material
CN1058419A (en) * 1990-07-21 1992-02-05 田后德 Composite heat-insulated material
CN1124750A (en) * 1994-02-09 1996-06-19 曲中辉 Non-toxic compounded insulation paint
CN1107815A (en) * 1994-03-04 1995-09-06 徐虎林 Composite, insulating, light organosilicon wall material and its production process

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