CN105952425A - Method for improving ordinary heavy oil reservoir recovery ratio by adopting chemical agents to assist CO2 huff and puff - Google Patents

Method for improving ordinary heavy oil reservoir recovery ratio by adopting chemical agents to assist CO2 huff and puff Download PDF

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Publication number
CN105952425A
CN105952425A CN201610541936.4A CN201610541936A CN105952425A CN 105952425 A CN105952425 A CN 105952425A CN 201610541936 A CN201610541936 A CN 201610541936A CN 105952425 A CN105952425 A CN 105952425A
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chemical agent
volume
oil
thinner
well
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CN105952425B (en
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李松岩
李兆敏
张启亮
吴明轩
李宾飞
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China University of Petroleum East China
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China University of Petroleum East China
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    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/164Injecting CO2 or carbonated water
    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons

Abstract

The invention relates to a method for improving the ordinary heavy oil reservoir recovery ratio by adopting chemical agents to assist CO2 huff and puff. The method is characterized by combining the chemical agents with CO2 huff and puff, firstly injecting a viscosity reducer or foaming agent type chemical agent solution slug into an oil well undergoing multiple rounds of CO2 huff and puff, later injecting a high pressure CO2 slug into the well and carrying out soaking after injection is completed. The method has the advantages that during soaking, the viscosity reducer type chemical agents and the ordinary heavy oil form oil-in-water type emulsion, thus substantially reducing the oil-water interfacial tension and reducing the crude oil flow resistance during exploitation; the CO2 gas phase mobility can be controlled and CO2 can be effectively prevented from gas channeling through addition of the foaming agent type chemical agents, so that CO2 diffuses toward the depth of the stratum and the CO2 wave and volume are increased; and due to synergy of the chemical agents and CO2, the oil well can still maintain higher oil production after multiple rounds of huff and puff.

Description

A kind of chemical agent auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up
Technical field
The present invention relates to a kind of chemical agent auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, belongs to oil-gas field development The technical field of engineering.
Background technology
Growing along with global economy, the demand of oil is rapidly increased by the world, through eighties of last century to conventional oil resource Large-scale exploitation after, viscous crude resource has attracted the attention of common people with its abundant reserves, thus the development technique of heavy crude reservoir Also receive much concern.Viscous crude is also known as heavy crude or high viscosity oil, by viscosity classification, viscosity under reservoir temperature is higher than The degassed crude of 100mPa.s is referred to as viscous crude.According to relevant information, the reserves of China's viscous crude occupy the 7th in the world, so far Have been found that 9 big-and-middle-sized oil basins and large number of heavy crude reservoir block.Countries in the world are in the evolution of petroleum industry In, it is all that first exploitation is easier to exploitation, lighter crude oil.The country that foreign oil reserves are big, because of its aboundresources and exploit thick Oil cost is high, risk is big.Along with gradually decreasing of relatively light crude resource, it has to start to exploit the mink cell focus of some more difficult exploitations, In the most alive boundary stone oil yield, the share of mink cell focus is gradually increased.
At present, the Technology of Heavy Oil Recovery is broadly divided into and cold adopts technology and thermal recovery technology.Heavy crude heat extraction technical matters is complicated, relatively costly; Heavy oil cold flow production technology mainly includes CO2Handle up, CO2Drive, N2Handle up, chemical flooding etc., wherein CO2Handling up is heavy oil cold flow production One of topmost mode.
In foreign language literature " Fuel " 03 phase in 2015, " Enhanced oil recovery from tight formations through CO2 Huff ' n ' puff processes " literary composition is mentioned, CO2The purpose of production of heavy oil reservoir of handling up is to pass through CO2Dissolving in viscous crude, Make viscous crude volumetric expansion, reduce the light components in viscosity of thickened oil and extraction viscous crude, and there is the effect of dissolved gas drive.Its In substantial amounts of desk research and on-the-spot test show, common heavy oil CO2The raising single well production dose-effect fruit that handles up is notable, CO2Handle up and adopt Oil can make stripper well strengthening volume increase.But common heavy oil oil well carries out many rounds CO2After handling up, owing to oil gas mobility difference is big, Cause CO2Has channeling is serious, and swept volume is little, and cycle oil production, oil-gas ratio all can decline along with the increase of round of handling up.As What improves many rounds CO2The oil recovery of the common heavy oil oil well handled up is a current difficult problem.
Summary of the invention
For existing CO2The deficiency of technology of handling up, the present invention provides a kind of chemical agent auxiliary CO2Handle up raising common heavy oil reservoir The method of recovery ratio.
Summary of the invention:
The method of the present invention is by chemical agent and CO2Handle up and combine, to carrying out too much round CO2The oil well handled up is initially injected Thinner or foaming agent class chemical solution slug, backward well in inject high pressure CO2Slug, carries out stewing well after having injected. During stewing well, thinner class chemical agent forms oil-in-water emulsion with common heavy oil, thus viscosity of crude is greatly reduced, and reduces Crude oil flow resistance during exploitation.And the addition of foaming agent class chemical agent can improve displacement efficiency, control CO2Gas phase mobility, has Prevent CO to effect2There is has channeling, increase CO2Gas swept volume.Chemical agent and CO2Synergism many rounds are handled up After, oil well still is able to keep higher oil production.
Explanation of nouns:
Common heavy oil: under reservoir condition, viscosity of crude is the viscous crude of 50~1000mPa.s, this type of flooding for heavy oil development effectiveness is poor, Currently mainly with CO2Handle up, steam soak and steam drive etc., and development scheme is main.
Chemical agent: be divided into thinner class and foaming agent class.Wherein, thinner class chemical agent can be effectively reduced oil-water interfaces and opens Power, forms oil-in-water emulsion, thus viscosity of crude is greatly reduced;Foaming agent class chemical agent can make CO2Gas involves body Long-pending increase, effectively controls CO2Gas phase mobility, forming part foam oil.Due to CO2Synergism with chemical agent so that oil Well, after high round is handled up, still is able to keep higher oil production.
Technical scheme is as follows:
A kind of chemical agent auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, comprises the following steps that
(1) chemical solution slug injects: chemical agent is configured to chemical agent aqueous solution, pit shaft injects stratum, chemical agent water The mass concentration of solution is 0.1~2.0%, and the volume injecting chemical agent aqueous solution is 8m3~20m3
(2)CO2Slug injects: by CO2Slug injects in stratum by pit shaft, CO under the reservoir condition of injection2Volume with The volume ratio of the chemical agent aqueous solution injected is 0.5:1~5:1;
(3) stewing well diffusion: by CO2After injecting oil reservoir, closing well carries out stewing well, stewing well time 7d~14d, during stewing well, changes Learn agent and viscosity of crude, CO are greatly reduced2Extract with crude oil, volumetric expansion, the effect such as dissolving viscosity reduction;
(4) opening well and making production: stewing well terminates rear opening well and making production, during stratum filtration, CO2Mix with chemical agent, CO2Gas Body displacement crude oil and emulsion, from formation flow to pit shaft, are finally adopted to ground;
Currently preferred, treat the chemical agent auxiliary CO of a round2Handle up after end, repeat step (1)~step (4), Carry out 2-5 round to handle up, improve many rounds CO2The oil production of oil well after handling up.
Currently preferred, described chemical agent is thinner and/or foaming agent.
Currently preferred, when described chemical agent is water solublity thinner, the mass concentration of step (1) thinner aqueous solution Being 0.2~1.0%, the volume injecting thinner aqueous solution is 10m3~20m3;CO under the reservoir condition that step (2) is injected2's Volume is 1:1~5:1 with the ratio of the volume of the thinner solution of injection;During the stewing well of step (3), thinner and common heavy oil Form oil-in-water emulsion, viscosity of crude, CO are greatly reduced2Extract with crude oil, volumetric expansion, dissolving viscosity reduction etc. are made With;The stewing well of step (4) terminates rear opening well and making production, during stratum filtration, CO2Mix with water-oil emulsion, CO2Gas Displacement crude oil and emulsion, from formation flow to pit shaft, are finally adopted to ground.
It is further preferred that the mass concentration of thinner aqueous solution is 1.0%, the volume injecting thinner aqueous solution is 12m3, note CO under the reservoir condition entered2The ratio of volume and the volume of the thinner solution of injection be 1:1.
Currently preferred, when described chemical agent is foaming agent, the mass concentration of step (1) foaming agent is 0.2~0.5%, The volume injecting foaming agent aqueous solution is 15m3~20m3;CO under the reservoir condition that step (2) is injected2The rising of volume and injection The ratio of the volume of infusion solution is 2:1~5:1;During the stewing well of step (3), foaming agent solution can improve displacement efficiency, increases Add CO2Swept volume, CO2Can extract with crude oil, volumetric expansion, the effect such as dissolving viscosity reduction;Step (4) stewing well knot Opening well and making production after bundle, during stratum filtration, CO2Mix with foaming agent solution, can effectively control CO2Mobility, CO2Gas Body displacement crude oil and mixed liquor, from formation flow to pit shaft, are finally adopted to ground.
It is further preferred that the mass concentration of foaming agent is 0.5%, the volume injecting foaming agent aqueous solution is 15m3;The oil injected CO under the conditions of Tibetan2The ratio of volume and the volume of the foaming agent solution of injection be 2:1.
Currently preferred, described water solublity thinner is the thinner that viscosity of crude can be made to reduce 90-98%, it is preferred that Water solublity thinner is alkyl sulfonates, alkyl benzene sulfonate, polyoxyethylated alkyl alcohol class thinner.
Alkyl sulfonates, alkyl benzene sulfonate, polyoxyethylated alkyl alcohol class thinner is prior art, conventional commercial product Product.
Currently preferred, described foaming agent is two-(2-ethylhexyl)-sulfonic acid sodium succinate (AOT) and/or fatty acid polyoxy Ethylene polyethenoxy ether (C12E9P3)。
It is an advantage of the current invention that:
Chemical agent the most of the present invention auxiliary CO2The process of raising common heavy oil reservoir recovery ratio of handling up can solve effectively Certainly high round CO2The problem that huff and puff oil recovery amount declines rapidly.The chemical agent injected can make CO2Spread to depths, stratum, improve CO2Gas swept volume so that distance well head in-place oil remotely is plucked out of, thus improves high round CO2Handle up Oil production.
2. the present invention assists CO at chemical agent2Handling up during stewing well, the thinner class chemical agent of use can be with common heavy oil shape Become oil-in-water emulsion, interfacial tension is greatly reduced, reduces viscous crude flow resistance;During opening well and making production, use Foaming agent class chemical agent can control CO2Gas phase mobility, is effectively prevented CO2There is has channeling, thus improve high round CO2 The oil production handled up.
Accompanying drawing explanation
Fig. 1 is that chemical agent assists CO2The schematic diagram of the process improving common heavy oil reservoir recovery ratio of handling up;
In figure, 1, high pressure CO2Storage tank;2, ground supercharging injection device;3, well is injected;4, chemical agent aqueous solution storage tank;5、 Straight well;6, common heavy oil reservoir.
Fig. 2 is that chemical agent assists CO2Handle up and CO2Handle up respectively handle up round recovery percent of reserves contrast block diagram.
Detailed description of the invention
Below in conjunction with embodiment and Figure of description, the present invention is described further, but is not limited to this.
Embodiment 1
A kind of chemical agent auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, flow process is as it is shown in figure 1, pass through pressure Pipeline is by high pressure CO2Storage tank 1 exit is connected with ground injection device 2, connects ground injection device 2 by pipeline and injects Well 3, foaming agent aqueous solution storage tank 4 is connected with ground injection device 2 by pipeline, connects ground injection device 2 by pipeline With injection well 3.
Specifically include step as follows:
(1) foaming agent solution slug injection process: two-(2-ethylhexyl)-sulfonic acid sodium succinate foaming agent is configured to foaming agent water Solution, is injected stratum by pit shaft, and the mass concentration of foaming agent aqueous solution is 0.5%, and the volume injecting foaming agent aqueous solution is 15m3
(2) high pressure CO2Slug injection process: by CO2Slug passes through ground supercharging equipment supercharging, pit shaft inject reservoir, note CO under the reservoir condition entered2The volume ratio of chemical agent aqueous solution of volume and injection be 2:1;
(3) stewing well diffusion: by CO2After injecting oil reservoir, closing well carries out stewing well, stewing well time 7d, pressure during the stewing well of record Change.CO during stewing well2Extract with crude oil, volumetric expansion, the effect such as dissolving viscosity reduction;
After (4) one weeks, opening well and making production.The addition of foaming agent solution, can increase CO2Gas swept volume, controls CO2Stream Degree, is effectively prevented CO2There is has channeling.CO2Gas displacement crude oil etc. flow to pit shaft from oil reservoir, finally adopts to ground;
(5) the foaming agent auxiliary CO of a round is treated2Handle up after end, repeat step (1)~step (4) 3 times, it is achieved The foaming agent auxiliary CO of many rounds2Handle up, improve many rounds CO2Huff and puff oil recovery amount.
Embodiment 2
A kind of chemical agent auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, specifically includes step as follows:
(1) thinner solution slug injection process: alkyl sulfonates thinner is configured to thinner aqueous solution, pit shaft notes Entering stratum, the mass concentration of thinner aqueous solution is 1.0%, and the volume injecting thinner aqueous solution is 12m3
(2) high pressure CO2Slug injection process: by CO2Slug passes through ground supercharging equipment supercharging, pit shaft inject reservoir, note CO under the reservoir condition entered2The volume ratio of chemical agent aqueous solution of volume and injection be 1:1;
(3) stewing well diffusion: by CO2After injecting oil reservoir, closing well carries out stewing well, stewing well time 10d, presses during the stewing well of record The change of power.During stewing well, thinner forms oil-in-water emulsion with common heavy oil, and viscosity of crude, CO are greatly reduced2 Extract with crude oil, volumetric expansion, the effect such as dissolving viscosity reduction;
(4) stewing well terminates rear opening well and making production, during stratum filtration, CO2Mix with water-oil emulsion, CO2Gas displacement Crude oil and emulsion, from formation flow to pit shaft, are finally adopted to ground.
(5) the thinner auxiliary CO of a round is treated2Handle up after end, repeat step (1)~step (4) 4 times, it is achieved The thinner auxiliary CO of many rounds2Handle up, improve many rounds CO2Huff and puff oil recovery amount.
Embodiment 3
Simulation chemical agent auxiliary CO2Handle up and exploit the experimental provision of common heavy oil reservoir mainly by the double plunger metering of displacement liquid The compositions such as the control of pump, the double plunger dosing pump of displacing gases, pressure transmitter, balance, fill out sand tube, temperature and pressure and record system, Experiment is carried out, to simulate reservoir media under stationary temperature, pressure.
Concretely comprise the following steps:
(1) utilize fill out sand tube to fill and present the rock core of certain permeability, weigh dry weight, evacuation, saturation water, weigh weight in wet base, calculate Porosity, measures rock core water phase permeability;
(2) rock core is adjusted to formation temperature 60 DEG C and strata pressure;
(3) with the speed saturated oils of 0.5ml/min, until port of export product fluid is the most aqueous, closes the rock core port of export and stablize A period of time;
(4) CO is injected from injection end with the speed of 0.5ml/min2, work as CO2When amount injection reaches 24ml, stop gas injection, Close injection end stewing well 12h;
(5) open injection end valve, make oil gas spue under the pressure drop gradient of 1MPa/min, record oil production;
(6) repeat step (4)~step (5), carry out the CO of next one2Handle up experiment;
(7) by foaming agent aliphatic acid polyethenoxy polyethenoxy ether (C12E9P3) be dissolved in formation water and be configured to mass concentration and be The solution of 0.5%, pours in intermediate receptacle;
(8) foaming agent solution slug is injected, when aliphatic acid polyethenoxy polyethenoxy ether from injection end with the speed of 1ml/min (C12E9P3) foaming agent solution injection rate is when reaching 12ml, stop injecting, be then injected into the high pressure CO of 24ml2Slug, closes Close injection end stewing well certain time;
(9) open injection end valve after stewing well 12h, make oil, gas, foaming agent solution tell under the pressure drop gradient of 1MPa/min Go out, record oil production;
The foaming agent auxiliary CO of (10) rounds2Handle up after end, repeat step (8)~step (9) three times, it is achieved 4 The foaming agent auxiliary CO of individual round2Handle up.
(11) contrast CO2Handle up displacement crude oil, inject the high pressure CO of 24ml2, it is not injected into foaming agent solution, closes injection end Valve carries out 12h and boils in a covered pot over a slow fire opening well and making production after well, the cycle oil production of record opening well and making production, carries out the CO of 6 rounds2Handle up.
Experimental result is as in figure 2 it is shown, contrast chemical agent assists CO2Handle up and CO2Handle up, chemical agent auxiliary CO2Handle up and have Higher recovery ratio, after 6 rounds of handling up, overall recovery factor has reached 41.96%, achieves preferable exploitation effect.

Claims (9)

1. a chemical agent auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, comprises the following steps that
(1) chemical solution slug injects: chemical agent being configured to chemical agent aqueous solution, pit shaft injects stratum, the mass concentration of chemical agent aqueous solution is 0.1~2.0%, and the volume injecting chemical agent aqueous solution is 8m3~20m3
(2)CO2Slug injects: by CO2Slug injects in stratum by pit shaft, CO under the reservoir condition of injection2The volume ratio of chemical agent aqueous solution of volume and injection be 0.5:1~5:1;
(3) stewing well diffusion: by CO2After injecting oil reservoir, closing well carries out stewing well, stewing well time 7d~14d, and during stewing well, chemical agent is greatly reduced viscosity of crude, CO2Extract with crude oil, volumetric expansion, the effect such as dissolving viscosity reduction;
(4) opening well and making production: stewing well terminates rear opening well and making production, during stratum filtration, CO2Mix with chemical agent, CO2Gas displacement crude oil and emulsion, from formation flow to pit shaft, are finally adopted to ground.
Chemical agent the most according to claim 1 auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, it is characterised in that treat the chemical agent auxiliary CO of a round2Handle up after end, repeat step (1)~step (4), carry out 2-5 round and handle up, improve many rounds CO2The oil production of oil well after handling up.
Chemical agent the most according to claim 1 auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, it is characterised in that described chemical agent is thinner and/or foaming agent.
Chemical agent the most according to claim 3 auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, it is characterised in that when described chemical agent is water solublity thinner, the mass concentration of step (1) thinner aqueous solution is 0.2~1.0%, the volume injecting thinner aqueous solution is 10m3~20m3;CO under the reservoir condition that step (2) is injected2The ratio of volume and the volume of the thinner solution of injection be 1:1~5:1;During the stewing well of step (3), thinner forms oil-in-water emulsion with common heavy oil, and viscosity of crude, CO are greatly reduced2Extract with crude oil, volumetric expansion, the effect such as dissolving viscosity reduction;The stewing well of step (4) terminates rear opening well and making production, during stratum filtration, CO2Mix with water-oil emulsion, CO2Gas displacement crude oil and emulsion, from formation flow to pit shaft, are finally adopted to ground.
Chemical agent the most according to claim 4 auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, it is characterised in that the mass concentration of thinner aqueous solution is 1.0%, the volume injecting thinner aqueous solution is 12m3, CO under the reservoir condition of injection2The ratio of volume and the volume of the thinner solution of injection be 1:1.
Chemical agent the most according to claim 3 auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, it is characterised in that when described chemical agent is foaming agent, the mass concentration of step (1) foaming agent is 0.2~0.5%, the volume injecting foaming agent aqueous solution is 15m3~20m3;CO under the reservoir condition that step (2) is injected2The ratio of volume and the volume of the foaming agent solution of injection be 2:1~5:1;During the stewing well of step (3), foaming agent solution can improve displacement efficiency, increases CO2Swept volume, CO2Can extract with crude oil, volumetric expansion, the effect such as dissolving viscosity reduction;The stewing well of step (4) terminates rear opening well and making production, during stratum filtration, CO2Mix with foaming agent solution, can effectively control CO2Mobility, CO2Gas displacement crude oil and mixed liquor, from formation flow to pit shaft, are finally adopted to ground.
Chemical agent the most according to claim 6 auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, it is characterised in that the mass concentration of foaming agent is 0.5%, the volume injecting foaming agent aqueous solution is 15m3;CO under the reservoir condition injected2The ratio of volume and the volume of the foaming agent solution of injection be 2:1.
Chemical agent the most according to claim 3 auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, it is characterised in that described water solublity thinner is the thinner that viscosity of crude can be made to reduce 90-98%, preferably, water solublity thinner is alkyl sulfonates, alkyl benzene sulfonate, polyoxyethylated alkyl alcohol class thinner.
Chemical agent the most according to claim 3 auxiliary CO2The method of raising common heavy oil reservoir recovery ratio of handling up, it is characterised in that described foaming agent is two-(2-ethylhexyl)-sulfonic acid sodium succinate (AOT) and/or aliphatic acid polyethenoxy polyethenoxy ether (C12E9P3)。
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