CN105950802B - A kind of leather care products of oil rub resistance anti-static dust-proof and preparation method and application - Google Patents
A kind of leather care products of oil rub resistance anti-static dust-proof and preparation method and application Download PDFInfo
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- CN105950802B CN105950802B CN201610539181.4A CN201610539181A CN105950802B CN 105950802 B CN105950802 B CN 105950802B CN 201610539181 A CN201610539181 A CN 201610539181A CN 105950802 B CN105950802 B CN 105950802B
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- leather
- care products
- leather care
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- dimethicone
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
The invention discloses a kind of leather care products of oil rub resistance anti-static dust-proof and preparation method and application, which be made by N dodecyls N.N bis- (2 hydroxyethyl) benzyl ammonium chloride, dimethicone, amido silicon oil, high molecular polymer, organic acid, nonionic surfactant, essence and water.The intermiscibility of the raw materials such as bis- (2 hydroxyethyl) benzyl ammonium chlorides of dimethicone, amido silicon oil and high molecular polymer, N dodecyls N.N in inventive formulation is good, has good synergistic effect.Obtained leather care products can form protective film on leather and fur products surface, play barrier ultraviolet light, leather and fur products is delayed to generate cracking due to illumination, extend leather usage time.The care agent of the present invention can assign the superior feel of leather and fur products and perception, have with the processed leather of the care agent and refuse oily water repellent effect well.
Description
Technical field
The invention belongs to field of fine chemical, and in particular to a kind of leather care products and its system of oil rub resistance anti-static dust-proof
Preparation Method and application.
Background technology
With the development of the social economy, promotion of the people to material pursuits, more and more leathercrafts have obtained widely
It uses.High-grade leathercraft is always linked together with fashion fleshpots.With social city, the development of technicalization,
Leather industry has obtained vigorous growth, and more and more consumers select leather and fur products to show oneself makings, the thing followed
Be leather care products usage amount increase and leather nursing after it is easy to produce static electricity, easily be stained with ash, not oil resistant the problems such as show.
And the leather care products of a oil rub resistance anti-static dust-proof, protective separation film can be formed on leather, it is ensured that leather
On not viscous ash, oil rub resistance, this is very crucial.
Existing leather nursing glazing agent, mainly using addition softening agent, mould inhibitor or wax emulsion etc. in resin, but
This can not meet current requirement, does not play the role of oil rub resistance anti-static dust-proof, and polishing effect unobvious, exists not
Foot.
Invention content
In order to overcome existing leather care products be easily stained with dirt, it is not antistatic, intolerant to greasy dirt, gloss is dark, is easily produced after use
The defects of raw cracking, primary and foremost purpose of the invention is to provide a kind of leather care products of oil rub resistance anti-static dust-proof.
Another object of the present invention is to provide the preparation method of above-mentioned leather care products.
It is still another object of the present invention to provide the purposes of above-mentioned leather care products.
The purpose of the present invention is achieved through the following technical solutions：
A kind of leather care products are made by the raw material of following mass percent：
Preferably, the leather care products are made by the raw material of following mass percent：
Bis- (2- hydroxyethyls) benzyl ammonium chlorides of N- dodecyls-N.N- in formula are the production of Qing Te companies of the U.S.
Other compositions compounding in antistatic agent, with formula is preferable, and antistatic effect is superior, and it is dust-proof to show antistatic, non-sticky ash
Characteristic.
Preferably, the viscosity of dimethicone is 500,000, and the ammonia value of amido silicon oil is 0.27；The two ingredients are used to be formulated
Afterwards, the leather care products glazing good film-forming property of gained has oil rub resistance characteristic.
The preferred polyacrylamide of the high molecular polymer, polyacrylic acid or polyurethane；
The polyacrylamide preferred cationic polyacrylamide or non-ionic polyacrylamide, preferably 200,000 monomers gather
Synthesis；
The preferred glacial acetic acid of the organic acid or citric acid；
The preferred isomery C13 alcohol ether -5EO of the nonionic surfactant and/or isomery C13 alcohol ether -7EO, are bar
Si Fu companies produce；
The preferred deionized water of the water.
The preparation method of above-mentioned leather care products includes the following steps：
(1) dimethicone, amido silicon oil, nonionic surfactant, organic acid and water are mixed, stirring is allowed to disperse
Uniformly, latex A is made；
(2) N- dodecyls-N.N- bis- (2- hydroxyethyls) benzyl ammonium chloride, high molecular polymer and essence are mixed
It closes, stirring is allowed to be uniformly dispersed, and lotion B is made；
(3) latex A and lotion B are mixed, leather care products is made after stirring evenly；
20-40min is stirred under the preferred 800-1200rpm of stirring described in step (1)；
4-8min is stirred under the preferred 500-800rpm of stirring described in step (2) and (3).
The leather care products of the present invention can be applied to shoes, clothing, suitcase and sand made of animal's leather or dermatine
On hair；
In use, after leather and fur products is cleaned up, the leather care products 1-2 of the present invention is sprayed at distance 20-25cm
It is secondary, it is then wiped with dry towel uniform.
The present invention is had the following advantages relative to the prior art and effect：
1st, the dimethicone in inventive formulation, amido silicon oil and high molecular polymer, N- dodecyls-N.N- are double
The intermiscibility of the raw materials such as (2- hydroxyethyls) benzyl ammonium chloride is good, has good synergistic effect.
2nd, leather care products of the invention can form protective film on leather and fur products surface, play barrier ultraviolet light, delay skin
Leather goods generate cracking due to illumination, extend leather usage time.
3rd, care agent of the invention can assign the superior feel of leather and fur products and perception, with the processed leather of the care agent
With refusing oily water repellent effect well.
4th, 2500 volts on leather of electrostatic potential can be reduced to 0 by care agent of the invention, formed protective separation film, made leather
Non-sticky ash, dosage is few, and effect is good.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, but the implementation of the present invention is not limited to this.
Embodiment 1
A kind of leather care products are made by the raw material of following mass percent：
Preparation method includes the following steps：
(1) dimethicone, amido silicon oil, nonionic surfactant, organic acid and deionized water are added in into reaction kettle
In, 20-40min is stirred under 800-1200rpm and is allowed to be uniformly dispersed, latex A is made；
(2) bis- (2- hydroxyethyls) benzyl ammonium chlorides of N- dodecyls-N.N-, high molecular polymer and essence are added in
4-8min is stirred in reaction kettle, under 500-800rpm to be allowed to be uniformly dispersed, and lotion B is made；
(3) latex A and lotion B are mixed, leather care products is made after stirring 4-8min under 500-800rpm.
Embodiment 2
A kind of leather care products are made by the raw material of following mass percent：
The preparation method is the same as that of Example 1.
Embodiment 3
A kind of leather care products are made by the raw material of following mass percent：
The preparation method is the same as that of Example 1.
Embodiment 4
A kind of leather care products are made by the raw material of following mass percent：
The preparation method is the same as that of Example 1.
Leather care products made from the embodiment of the present invention are milky, there is sweet osmanthus taste, and viscosity is 2000 or so.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (8)
1. a kind of leather care products, it is characterised in that be made by the raw material of following mass percent：
The viscosity of the dimethicone is 500,000, and the ammonia value of amido silicon oil is 0.27.
2. leather care products according to claim 1, it is characterised in that：The high molecular polymer is polyacrylamide
Amine, polyacrylic acid or polyurethane.
3. leather care products according to claim 1, it is characterised in that：The organic acid is glacial acetic acid or citric acid.
4. leather care products according to claim 1, it is characterised in that：The nonionic surfactant is isomery
C13 alcohol ether -5EO and/or isomery C13 alcohol ethers -7EO.
5. the preparation method of claim 1-4 any one of them leather care products, it is characterised in that include the following steps：
(1) dimethicone, amido silicon oil, nonionic surfactant, organic acid and water are mixed, it is equal that stirring is allowed to dispersion
It is even, latex A is made；
(2) bis- (2- hydroxyethyls) benzyl ammonium chlorides of N- dodecyls-N, N-, high molecular polymer and essence are mixed, stirred
It mixes and is allowed to be uniformly dispersed, lotion B is made；
(3) latex A and lotion B are mixed, leather care products is made after stirring evenly.
6. the preparation method of leather care products according to claim 5, it is characterised in that：
Stirring described in step (1) is to stir 20-40min under 800-1200rpm；
Stirring described in step (2) and (3) is to stir 4-8min under 500-800rpm.
7. claim 1-4 any one of them leather care products answering in animal's leather product or the nursing of dermatine product
With.
8. application of the leather care products according to claim 7 in animal's leather product or the nursing of dermatine product,
It is characterized in that：In use, after leather and fur products is cleaned up, any one of claim 1-4 institutes are sprayed at distance 20-25cm
Then the leather care products stated 1-2 times are wiped uniform with dry towel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610539181.4A CN105950802B (en) | 2016-07-08 | 2016-07-08 | A kind of leather care products of oil rub resistance anti-static dust-proof and preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610539181.4A CN105950802B (en) | 2016-07-08 | 2016-07-08 | A kind of leather care products of oil rub resistance anti-static dust-proof and preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105950802A CN105950802A (en) | 2016-09-21 |
| CN105950802B true CN105950802B (en) | 2018-06-19 |
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ID=56901245
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610539181.4A Active CN105950802B (en) | 2016-07-08 | 2016-07-08 | A kind of leather care products of oil rub resistance anti-static dust-proof and preparation method and application |
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| Country | Link |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4940757A (en) * | 1989-04-20 | 1990-07-10 | Peach State Labs, Inc. | Stain resistant polymeric composition |
| CN101284972A (en) * | 2008-06-13 | 2008-10-15 | 魏永红 | Multifunctional care agent and method for making same |
| CN102634285A (en) * | 2012-03-27 | 2012-08-15 | 河北永泰柯瑞特化工有限公司 | Fur brightener composition and preparation method and application thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6354477A (en) * | 1986-08-22 | 1988-03-08 | Yuji Kato | Lustering agent composition |
-
2016
- 2016-07-08 CN CN201610539181.4A patent/CN105950802B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4940757A (en) * | 1989-04-20 | 1990-07-10 | Peach State Labs, Inc. | Stain resistant polymeric composition |
| CN101284972A (en) * | 2008-06-13 | 2008-10-15 | 魏永红 | Multifunctional care agent and method for making same |
| CN102634285A (en) * | 2012-03-27 | 2012-08-15 | 河北永泰柯瑞特化工有限公司 | Fur brightener composition and preparation method and application thereof |
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| Publication number | Publication date |
|---|---|
| CN105950802A (en) | 2016-09-21 |
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