CN104593163B - A kind of concentration liquid detergent - Google Patents

A kind of concentration liquid detergent Download PDF

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Publication number
CN104593163B
CN104593163B CN201410750606.7A CN201410750606A CN104593163B CN 104593163 B CN104593163 B CN 104593163B CN 201410750606 A CN201410750606 A CN 201410750606A CN 104593163 B CN104593163 B CN 104593163B
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liquid detergent
concentration
surfactant
thickener
fatty alcohol
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CN104593163A (en
Inventor
刘保
陈建斌
陈树旭
陈文�
赵建红
卢志敏
王志刚
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Guangzhou Langqi Daily Necessities Co ltd
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LANGQI INDUSTRY Co Ltd GUANGZHOU
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Abstract

The invention discloses a kind of concentration liquid detergents, its component includes surfactant, thickener and deionized water, wherein, it is sodium chloride that surfactant, which includes sodium sulfate of polyethenoxy ether of fatty alcohol, modified thickening type fatty alcohol polyoxyethylene ether, dodecanamide propyl amine oxide and cocoanut fatty acid diethanolamide, the thickener,.The concentration laundry liquid formulation is mild, strong detergency, even and if higher before ratio of viscosities dilution after being diluted with twice of water, have the direct feel of concentrated product to consumer, so as to reduce usage amount, avoid wasting, can also achieve the purpose that environmental protection.

Description

A kind of concentration liquid detergent
Technical field
The present invention relates to a kind of detergent more particularly to a kind of concentration liquid detergents.
Background technology
Liquid detergent is common daily necessities in daily life, a concentration of 15-20% of common liquid detergent.With life Horizontal raising, the energy conservation and environmental awareness of consumer also slowly enhance, and the requirement to liquid detergent is also gradually increased.Therefore, it develops Both packing cost, transportation cost can be saved, reduces the concentration liquid detergent of plastic bottle pollution problem also into a kind of trend.It is existing All it is twice or so of ordinary liquid laundry detergent in the concentration liquid detergent active matter content of most of kind on the market, though concentration improves , it can be still diluter liquid in terms of Product Status, the feeling that consumer is concentrated product can not be given on sense organ, thus it is big The problem of some consumers are because of use habit, still can be used according to the dosage of ordinary liquid laundry detergent, not reduced deliberately Dosage uses, and causes very big waste, and there is no realize really environmental protection.
At present, why the concentration of present concentration liquid detergent can only be common twice or so, mainly by it is following two because Element influences.First is cost factor, if cycles of concentration higher, the cost of liquid detergent is also even higher by multiple increase, then adds Upper packaging, sale price is higher, and consumer's difficulty receives.Second is technical factor, if cycles of concentration higher, needs solubilization technique, It needs to add in the solubilizer such as toluenesulfonic acid sodium salt, cumene sodium sulfonate, ethyl alcohol, isopropanol to reduce viscosity and improve mobility, but It is to add these solubilizer not having detergency much help, causes to waste.
Invention content
The purpose of the present invention is to provide a kind of concentration liquid detergents, and the concentration laundry liquid formulation is mild, strong detergency, and i.e. Just higher before ratio of viscosities dilution after being diluted with twice of water has the direct feel of concentrated product to consumer, so as to reduce usage amount, It avoids wasting, can also achieve the purpose that environmental protection.
The purpose of the present invention is achieved through the following technical solutions:A kind of concentration liquid detergent, component are lived including surface Property agent, thickener and deionized water, wherein, surfactant includes sodium sulfate of polyethenoxy ether of fatty alcohol, modified thickening type fat Fat alcohol polyoxyethylene ether, dodecanamide propyl amine oxide and cocoanut fatty acid diethanolamide;The thickener is sodium chloride.
Surfactant in the component of the present invention is mainly using modified thickening type fatty alcohol polyoxyethylene ether and lauroyl The compounding of amine propyl amine oxide, cocoanut fatty acid diethanolamide.Sodium sulfate of polyethenoxy ether of fatty alcohol, modified thickening type fat Fat alcohol polyoxyethylene ether, dodecanamide propyl amine oxide and cocoanut fatty acid diethanolamide are mild surfactant, Strong detergency and do not injure skin.These four surfactants are in high salinity(That is high concentration sodium chloride)In the case of, it shows The effect of viscosity reduction is cooperateed with, after twice of water dilution, salinity(Sodium chloride)Concentration reduces, in low salt(Low concentration sodium chloride)Situation Under, these surfactants then show the effect of synergistic thickening.It therefore, can not only using sodium chloride as thickener in the present invention The enough viscosity for reducing concentration liquid detergent, moreover it is possible to realize that viscosity is more before the ratio of viscosities dilution of the liquid detergent after being diluted with twice of water Height can allow consumer in the concentration for intuitively experiencing product.By product produced by the present invention, polybag may be used Packaging, as long as being cut off during use in the liquid detergent empty bottle for pouring into and having used, adds twice of tap water, and oscillation shakes up, Mill run can be regarded to use, the liquid detergent after dilution still maintains stronger detergency and higher viscosity, completely full Sufficient consumer demand.By concentration liquid detergent produced by the present invention, subtracting for transportation cost and packing material cost is greatly realized It is few, and consumer can use same liquid detergent bottle always, and without throwing away waste, modeling is reduced so as to be realized into next step Ordinary liquid laundry detergent is lower, has higher economic value than using for the environmentally friendly purpose and the use cost of consumer that material is packed And social value.
As an embodiment of the invention, quality hundred of each component in liquid detergent is concentrated in the surfactant Divide than content and be:
Sodium sulfate of polyethenoxy ether of fatty alcohol 27 ~ 32%
Modified thickening type fatty alcohol polyoxyethylene ether 9 ~ 11%
Dodecanamide propyl amine oxide 6 ~ 8%
Cocoanut fatty acid diethanolamide 5 ~ 6%.
Mass percentage content of the heretofore described thickener in liquid detergent is concentrated is 5 ~ 6%.
In liquid detergent, addition solubilizer is generally required, such as sodium xylene sulfonate, cumene sodium sulfonate, ethyl alcohol, isopropanol Etc. come reduce viscosity and improve mobility.In the present invention, can add these solubilizer improves mobility, but adds these Solubilizer can increase cost, therefore as a modification of the present invention, add methyl hexadecanoate polyoxyethylene ether in formula.Palm fibre Palmitic acid acid methyl esters polyoxyethylene ether is nonionic surfactant, and addition in formula can enhance detergency, and moreover it goes back It can make concentration liquid detergent that there is splendid high low temperature flow, so in formula just without additionally adding solubilizer, drop again Low cost has higher economic value.As one embodiment of the present of invention, the methyl hexadecanoate polyoxyethylene ether is dense Mass percentage content is 9 ~ 12% in contracting liquid detergent.
Compared with the prior art, the present invention has the following advantages:
(1) more than twice of a concentration of ordinary liquid laundry detergent of surfactant in the present invention, wherein modified thickening type fat The surfactant of alcohol polyoxyethylene ether, dodecanamide propyl amine oxide and cocoanut fatty acid diethanolamide compounding, cooperation Thickener sodium chloride is realized with after twice of water dilution, and viscosity higher before the ratio of viscosities dilution of liquid detergent can allow consumer to exist The concentration of product is intuitively experienced, dosage can be reduced when in use.And the concentration liquid detergent concentration of the present invention is high and viscous It is thick, plastic bag packaging may be used.As long as cutting off packaging bag when in use, pour into the liquid detergent empty bottle used, then Twice of tap water is added in, oscillation shakes up, it is possible to use as ordinary liquid laundry detergent.Liquid detergent after dilution still maintains relatively strong Detergency and higher viscosity, fully meet consumer demand.
(2) methyl hexadecanoate polyoxyethylene ether is added in the present invention with regard to that can make concentration liquid detergent that there is splendid low temperature stream Dynamic property without adding solubilizer again, reduces cost, has higher economic value.
(3) surfactant that the present invention uses has strong detergency, and mild, will not injure skin.
(4) concentration liquid detergent provided by the invention is sticky, greatly realizes the reduction of transportation cost and packing material cost. And consumer can use same liquid detergent bottle always, and without throwing away waste, plastic bag is reduced so as to further realize The environmentally friendly purpose of dress, and the use cost ratio of consumer is lower using ordinary liquid laundry detergent, has higher economic value and society It can be worth.
Specific embodiment
By taking embodiment 1 ~ 4 as an example, each component be can be made into concentration liquid detergent by mixing.The concentration of Example 1 ~ 4 After liquid detergent twice of water of addition is converted out, the detergency measure side in agent standard is washed by liquid with QB/T 1224-2012 dress materials Method carries out detergency measure, as a result as follows:
From the results, it was seen that plus the liquid detergent detergency after the dilution of twice water be all higher than the liquid detergent decontamination of national standard Power.
After concentration liquid detergent twice of the water of addition of Example 1 ~ 4 is converted out, viscosity test is carried out with NDJ-1 types viscosimeter, As a result it is as follows:
From the results, it was seen that the liquid detergent ratio of viscosities after diluting twice is high before diluting, consumer can be allowed intuitively Experience the concentration of product.And market concentration liquid detergent dilutes twice of rear viscosity and the viscosity of water is similar.
The present invention can be summarized with others without prejudice to the concrete form of the spirit or essential characteristics of the present invention.The present invention's The embodiment above can only all be considered the description of the invention rather than limitation, as that can not add essence in the present invention and prevent Rotten agent.Therefore every substantial technological according to the present invention makees above example any trickle amendment, equivalent variations are with repairing Decorations, belong in the range of technical solution of the present invention.

Claims (2)

1. a kind of concentration liquid detergent, which is characterized in that it is by surfactant, thickener and deionized water, essence, preservative group Into, wherein, surfactant is by sodium sulfate of polyethenoxy ether of fatty alcohol, modified thickening type fatty alcohol polyoxyethylene ether, lauroyl Amine propyl amine oxide, cocoanut fatty acid diethanolamide and methyl hexadecanoate polyoxyethylene ether composition, the thickener are chlorine Change sodium;Wherein described each surfactant, mass percentage content of the component in liquid detergent is concentrated are:
Sodium sulfate of polyethenoxy ether of fatty alcohol 27 ~ 32%
Modified thickening type fatty alcohol polyoxyethylene ether 9 ~ 11%
Dodecanamide propyl amine oxide 6 ~ 8%
Cocoanut fatty acid diethanolamide 5 ~ 6%
Methyl hexadecanoate polyoxyethylene ether 9 ~ 12%.
2. concentration liquid detergent according to claim 1, which is characterized in that quality of the thickener in liquid detergent is concentrated Degree is 5 ~ 6%.
CN201410750606.7A 2014-12-10 2014-12-10 A kind of concentration liquid detergent Active CN104593163B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107460061A (en) * 2017-08-31 2017-12-12 重庆尚洁日化用品有限公司 One kind concentration liquid detergent

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104962401A (en) * 2015-07-15 2015-10-07 广州市拓瑞化工科技有限公司 Waterless nano laundry detergent and manufacturing technique thereof
CN108034521A (en) * 2017-12-29 2018-05-15 广州慈康生物科技有限公司 A kind of concentration liquid detergent with long-acting bacteriostatic
CN111849201A (en) * 2020-07-30 2020-10-30 江苏华彩化学科技有限公司 Macromolecular dye and application thereof in super-concentrated efficient antibacterial laundry gel bead
CN115368978B (en) * 2022-06-30 2023-09-12 纳爱斯浙江科技有限公司 Concentrated detergent with high-power dilution and thickening performance and preparation method thereof

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN102010802A (en) * 2010-12-13 2011-04-13 陈继峰 Concentrated multienzyme cleaning solution and preparation method thereof
CN103540444A (en) * 2013-09-27 2014-01-29 安徽华印机电股份有限公司 Mild non-irritating detergent for skin
CN103540436A (en) * 2013-09-27 2014-01-29 安徽华印机电股份有限公司 Pesticide residue removing liquid detergent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102010802A (en) * 2010-12-13 2011-04-13 陈继峰 Concentrated multienzyme cleaning solution and preparation method thereof
CN103540444A (en) * 2013-09-27 2014-01-29 安徽华印机电股份有限公司 Mild non-irritating detergent for skin
CN103540436A (en) * 2013-09-27 2014-01-29 安徽华印机电股份有限公司 Pesticide residue removing liquid detergent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107460061A (en) * 2017-08-31 2017-12-12 重庆尚洁日化用品有限公司 One kind concentration liquid detergent

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Address after: 511455 No. 8 Xiaohu South Third Road, Xiaohu Island, Huangge Town, Nansha District, Guangzhou City, Guangdong Province

Patentee after: GUANGZHOU LANGQI DAILY NECESSITIES CO.,LTD.

Address before: No. 128, Huangpu Avenue East, Tianhe District, Guangzhou, Guangdong 510660

Patentee before: GUANGZHOU LONKEY INDUSTRIAL Co.,Ltd.

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