CN105950094A - Unsaturated polyester resin used for quartzite bonding and preparation method thereof - Google Patents
Unsaturated polyester resin used for quartzite bonding and preparation method thereof Download PDFInfo
- Publication number
- CN105950094A CN105950094A CN201610502080.XA CN201610502080A CN105950094A CN 105950094 A CN105950094 A CN 105950094A CN 201610502080 A CN201610502080 A CN 201610502080A CN 105950094 A CN105950094 A CN 105950094A
- Authority
- CN
- China
- Prior art keywords
- parts
- resin
- preparation
- unsaturated polyester
- polyester resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
- C09J171/02—Polyalkylene oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Epoxy Resins (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to unsaturated polyester resin used for quartzite bonding, and a preparation method thereof. The unsaturated polyester resin comprises ingredients in parts by weight as follows: 25-30 parts of dimethylacetamide, 20 30 parts of phenolic resin, 10-15 parts of tung oil anhydride, 20-28 parts of maleic anhydride, 20-25 parts of propane-trione, 15-30 parts of polyethylene glycol, 17-26 parts of alkyd resin, 10-15 parts of dipropylene glycol, 20-30 parts of epoxy hardener, 5-10 parts of xylene and 10-20 parts of polyethyleneimine. According to the invention, the preparation technological process is short, steps are simple, the operation is convenient, the production cost for the unsaturated polyester resin is lowered while performance of the unsaturated polyester resin is improved, corporate profits are improved, and the unsaturated polyester resin has the advantages of being low in production cost, good in bonding effect, high in economy and the like.
Description
Technical field
The invention belongs to technical field of polymer composite materials, be specifically related to a kind of unsaturated-resin for quartz bonding and preparation method thereof.
Background technology
nullArtificial quartz in lump is that a kind of quartz crystal by more than 90% adds resin and a kind of Novel stone of other trace element synthetic，This stone material is at certain physics、The large-sized plates material suppressed under electrochemical conditions，Due to quartz as main material，Quartz quality is hard、Fine and close，Compared with artificial marble，There is high surface hardness、Anti scuffing、Wear-resisting characteristic，Shock resistance、Bending resistance、Resistance to compression、High temperature resistant、Anticorrosive、The performance such as impermeable is also more excellent than artificial marble，Also have indeformable、Do not ftracture、Invariant color、Do not fade、Durable in use、Safeguard simple advantage，Quartz table top color is various，Can be widely applied to such as hotel、Dining room、Bank、Hospital、Exhibition、The public buildings such as laboratory and kitchen countertop、Commode、Kitchen guarding's metope、Dining table、Tea table、Windowsill、The house decoration fields such as door pocket，It it is a kind of "dead" pollution、The environmental protection of repeatable utilization、Green novel building house decorative material，Without any polluter and radiation source，Environmental protection，Owing to quartz crystal relies primarily on resin-bonded，The quality of resin determines the quality of artificial quartz in lump，The problem that quartz resin exists in process of production at present has: one is that in producing, product is cracking、Deformation；Two is resin and quartz sand dispersibility, bad adhesion；In order to overcome the problems referred to above, improve the bond effect of quartz, it is necessary to research and develop a kind of unsaturated-resin for quartz bonding and preparation method thereof.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, and unsaturated-resin for quartz bonding that a kind of production cost is low, bond effect good, economy is high and preparation method thereof is provided.
The object of the present invention is achieved like this: a kind of unsaturated-resin and preparation method thereof for quartz bonding, and it includes following parts by weight ingredient: dimethyl acetylamide 25-30, phenolic resin 20-30, tung oil acid anhydride 10-15, maleic anhydride 20-28, the third triketone 20-25, Polyethylene Glycol 15-30, alkyd resin 17-26, dipropylene glycol 10-15, epoxy hardener 20-30, dimethylbenzene 5-10, polymine 10-20.
The present invention is preferably composed of the following components in parts by weight: dimethyl acetylamide 25, phenolic resin 22, tung oil acid anhydride 14, maleic anhydride the 26, third triketone 24, Polyethylene Glycol 21, alkyd resin 23, dipropylene glycol 13, epoxy hardener 25, dimethylbenzene 7, polymine 16.
A kind of unsaturated-resin for quartz bonding and preparation method thereof, described preparation technology comprises the steps:
Step one: take raw material；
Step 2: first add dimethyl acetylamide, phenolic resin and tung oil acid anhydride in a kettle. and be heated to 160 DEG C, maintains 30min；
Step 3: add maleic anhydride, the third triketone, Polyethylene Glycol and alkyd resin the most in a kettle. and be warming up to 195 DEG C, maintains 20min；
Step 4: add dipropylene glycol, epoxy hardener, dimethylbenzene and polymine after being cooled to 60 DEG C in a kettle., maintains 50min；
Step 5: be cooled to room temperature.
Beneficial effects of the present invention: proportioning raw materials and the technological process of the present invention are got by the practice of thousands of times, and the preparation technology flow process of the present invention is short, step is simple and convenient to operate；The present invention improves its performance while reducing unsaturated-resin production cost, improves the profit of enterprise, has the advantage that production cost is low, bond effect good, economy is high.
Detailed description of the invention
Being described principle and the feature of the present invention below in conjunction with specific embodiment, illustrated embodiment is only intended to explain the present invention, and non-limiting the scope of the present invention.
Embodiment 1
The present invention is composed of the following components in parts by weight: dimethyl acetylamide 25, phenolic resin 22, tung oil acid anhydride 14, maleic anhydride the 26, third triketone 24, Polyethylene Glycol 21, alkyd resin 23, dipropylene glycol 13, epoxy hardener 25, dimethylbenzene 7, polymine 16.
The preparation technology of the present invention comprises the steps:
Step one: take raw material；
Step 2: first add dimethyl acetylamide, phenolic resin and tung oil acid anhydride in a kettle. and be heated to 160 DEG C, maintains 30min；
Step 3: add maleic anhydride, the third triketone, Polyethylene Glycol and alkyd resin the most in a kettle. and be warming up to 195 DEG C, maintains 20min；
Step 4: add dipropylene glycol, epoxy hardener, dimethylbenzene and polymine after being cooled to 60 DEG C in a kettle., maintains 50min；
Step 5: be cooled to room temperature.
Proportioning raw materials and the technological process of the present invention are got by the practice of thousands of times, and the preparation technology flow process of the present invention is short, step is simple and convenient to operate；The present invention improves its performance while reducing unsaturated-resin production cost, improves the profit of enterprise, has the advantage that production cost is low, bond effect good, economy is high.
Embodiment 2
The present invention is composed of the following components in parts by weight: dimethyl acetylamide 28, phenolic resin 25, tung oil acid anhydride 13, maleic anhydride the 25, third triketone 21, Polyethylene Glycol 28, alkyd resin 20, dipropylene glycol 15, epoxy hardener 22, dimethylbenzene 8, polymine 17.
The preparation technology of the present invention comprises the steps:
Step one: take raw material；
Step 2: first add dimethyl acetylamide, phenolic resin and tung oil acid anhydride in a kettle. and be heated to 160 DEG C, maintains 30min；
Step 3: add maleic anhydride, the third triketone, Polyethylene Glycol and alkyd resin the most in a kettle. and be warming up to 195 DEG C, maintains 20min；
Step 4: add dipropylene glycol, epoxy hardener, dimethylbenzene and polymine after being cooled to 60 DEG C in a kettle., maintains 50min；
Step 5: be cooled to room temperature.
Proportioning raw materials and the technological process of the present invention are got by the practice of thousands of times, and the preparation technology flow process of the present invention is short, step is simple and convenient to operate；The present invention improves its performance while reducing unsaturated-resin production cost, improves the profit of enterprise, has the advantage that production cost is low, bond effect good, economy is high.
Claims (3)
1. unsaturated-resin and preparation method thereof for quartz bonding, it is characterised in that: it includes following parts by weight ingredient: dimethyl acetylamide 25-30, phenolic resin 20-30, tung oil acid anhydride 10-15, maleic anhydride 20-28, the third triketone 20-25, Polyethylene Glycol 15-30, alkyd resin 17-26, dipropylene glycol 10-15, epoxy hardener 20-30, dimethylbenzene 5-10, polymine 10-20.
A kind of unsaturated-resin and preparation method thereof for quartz bonding the most according to claim 1, it is characterised in that: it includes following parts by weight ingredient: dimethyl acetylamide 25, phenolic resin 22, tung oil acid anhydride 14, maleic anhydride the 26, third triketone 24, Polyethylene Glycol 21, alkyd resin 23, dipropylene glycol 13, epoxy hardener 25, dimethylbenzene 7, polymine 16.
A kind of unsaturated-resin for quartz bonding the most according to claim 1 and 2 and preparation method thereof, it is characterised in that: described preparation technology comprises the steps:
Step one: take raw material；
Step 2: first add dimethyl acetylamide, phenolic resin and tung oil acid anhydride in a kettle. and be heated to 160 DEG C, maintains 30min；
Step 3: add maleic anhydride, the third triketone, Polyethylene Glycol and alkyd resin the most in a kettle. and be warming up to 195 DEG C, maintains 20min；
Step 4: add dipropylene glycol, epoxy hardener, dimethylbenzene and polymine after being cooled to 60 DEG C in a kettle., maintains 50min；
Step 5: be cooled to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610502080.XA CN105950094A (en) | 2016-06-30 | 2016-06-30 | Unsaturated polyester resin used for quartzite bonding and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610502080.XA CN105950094A (en) | 2016-06-30 | 2016-06-30 | Unsaturated polyester resin used for quartzite bonding and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105950094A true CN105950094A (en) | 2016-09-21 |
Family
ID=56901987
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610502080.XA Pending CN105950094A (en) | 2016-06-30 | 2016-06-30 | Unsaturated polyester resin used for quartzite bonding and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105950094A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109705782A (en) * | 2018-12-29 | 2019-05-03 | 广西六万山林业有限公司 | A kind of adhesive and preparation method thereof of container veneer |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
| CN102686691A (en) * | 2009-12-28 | 2012-09-19 | 日东电工株式会社 | Polyester adhesive composition |
| CN102825868A (en) * | 2012-08-20 | 2012-12-19 | 广东中旗新材料科技有限公司 | Silicon crystal composite panel |
| CN103204658A (en) * | 2013-03-20 | 2013-07-17 | 安徽瑞翔石英制品有限公司 | High-wear-resistance artificial quartz stone plate and production process thereof |
| CN103468104A (en) * | 2012-06-09 | 2013-12-25 | 上海东沈电子科技有限公司 | Synthetic method for tung oil modified unsaturated polyester coating |
-
2016
- 2016-06-30 CN CN201610502080.XA patent/CN105950094A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
| CN102686691A (en) * | 2009-12-28 | 2012-09-19 | 日东电工株式会社 | Polyester adhesive composition |
| CN103468104A (en) * | 2012-06-09 | 2013-12-25 | 上海东沈电子科技有限公司 | Synthetic method for tung oil modified unsaturated polyester coating |
| CN102825868A (en) * | 2012-08-20 | 2012-12-19 | 广东中旗新材料科技有限公司 | Silicon crystal composite panel |
| CN103204658A (en) * | 2013-03-20 | 2013-07-17 | 安徽瑞翔石英制品有限公司 | High-wear-resistance artificial quartz stone plate and production process thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109705782A (en) * | 2018-12-29 | 2019-05-03 | 广西六万山林业有限公司 | A kind of adhesive and preparation method thereof of container veneer |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104725626B (en) | A kind of preparation method of the unsaturated-resin suitable in artificial quartz in lump | |
| WO2016041324A1 (en) | Method for the preparation of a high-gloss, high-transparency artificial colored silica stone slab | |
| WO2016041323A1 (en) | Method using colored silica sand for the production of colored synthetic silica stone | |
| CN104446142A (en) | Potassium titanate crystal whisker composite quartz plate product and preparation method of composite quartz plate product | |
| CN104087135A (en) | Spraying powder used for household appliance evaporator and preparation method thereof | |
| CN105505115A (en) | Powder coating with high weather resistance and good decorative effect | |
| CN105950094A (en) | Unsaturated polyester resin used for quartzite bonding and preparation method thereof | |
| CN104478297A (en) | Lightweight artificial quartz stone and preparation method thereof | |
| CN104478298A (en) | Lightweighted artificial quartz stone decorative surface material and preparation method thereof | |
| CN103482900A (en) | Stone-imitated coating material | |
| CN106186818A (en) | A kind of superhard quartz and preparation method thereof | |
| CN113200710A (en) | Stain-resistant artificial quartz stone and manufacturing method thereof | |
| CN106190025A (en) | A kind of crystal face agent for quartz polishing and preparation technology thereof | |
| CN107827395A (en) | A kind of cracking resistance artificial quartz stone plate | |
| CN103937397A (en) | Dermatoglyph powder coating | |
| CN105924034A (en) | High-temperature-resistant quartzite and preparation process thereof | |
| CN102936448B (en) | Stain-resistant artificial stone basin surface protection material | |
| CN209194921U (en) | A kind of high intensity solid wooden compound floor | |
| CN106186822A (en) | A kind of wear-resisting quartzite slate and preparation technology thereof | |
| CN102977751B (en) | Antiquing and colour-retouching decorative paint | |
| CN107698196A (en) | A kind of preparation method of high-performance artificial quartz stone plate | |
| CN106186804A (en) | A kind of antiseptical artificial quartz stone plate and preparation technology thereof | |
| CN105036662A (en) | Composite-material floor tile | |
| CN106118911A (en) | A kind of quartz cleaning agent and preparation technology thereof | |
| CN102417785A (en) | Preparation method for epoxy corrosion-resistant coating for pipeline |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160921 |