CN105948399B - The biochemical preparation and preparation method thereof of xanthan gum production waste water - Google Patents
The biochemical preparation and preparation method thereof of xanthan gum production waste water Download PDFInfo
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- CN105948399B CN105948399B CN201610455513.0A CN201610455513A CN105948399B CN 105948399 B CN105948399 B CN 105948399B CN 201610455513 A CN201610455513 A CN 201610455513A CN 105948399 B CN105948399 B CN 105948399B
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
- C02F1/004—Processes for the treatment of water whereby the filtration technique is of importance using large scale industrial sized filters
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/286—Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
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Abstract
The present invention relates to a kind of biochemical preparations of processing xanthan gum production waste water, the preparation includes physical preparation and composite bacteria agent, and the composite bacteria agent includes the raw material of following volume ratio: 4 parts of pseudomonas aeruginosa, 4 parts of green ochre mould, 3 parts of Acidithiobacillus ferrooxidans strain GF, 3 parts of bacillus amyloliquefaciens, 2 parts of Clostridium papyrosolvens, 2 parts of scenedesmus obliquus.The biochemical preparation has the microorganism of excellent degradation capability containing there are many to Recalcitrant chemicals, and reasonable compatibility between each strain has good degradation effect, has broad application prospects.
Description
Technical field
The present invention relates to biofermentation industry xanthan gum clean manufacturing field, a kind of xanthan gum production waste water is specifically provided
Biochemical preparation and preparation method thereof.
Background technique
Xanthan gum (xanthan gum) is the northern research department (Northern of United States Department of Agriculture's the 1950s
Regional Research Laboratories, NRRL) from sarson Huang sporangium (Xanthom onas cam
Pestris) NRRLB21459 has found the neutral water soluble polysaccharide of secretion, also known as xanthan gum.It is by glucose, mannose
The outer heteroglycan of a kind of extracellular microbial formed with glucuronic acid with 218: 2: 2 molar ratio, " pentasaccharides repetitive unit " main chain
It is formed by 2 D-Glucose molecules through β-Isosorbide-5-Nitrae glucosides key connection, the skeleton structure with like fibrous element, in every 2 glucose
A carbon key on be connected with three carbohydrate side chains being made of 2 sweet glycan and 1 glucuronic acid.Unique point of xanthan gum
Minor structure imparts the physicochemical property of its numerous brilliance, such as good thickening property, thixotropy, emulsibility, pseudoplastic behavior.It is also
One important characteristic is can to generate reciprocation with other polysaccharides viscosity be caused to increase, meanwhile or a kind of through repeatedly
The green matter of the non-toxic and safe of confirmation, therefore become in food industry widely used a kind of bacterial polysaccharides and at present in the world
One of the biogum that best performance is got over.Since early 1960s U.S. Kelco company puts into industrialized production, xanthan gum
Product has been widely used in fields such as food, light industry, medicine, weaving, cosmetics, oil exploitation and fire-fightings.
Currently, the production method of xanthan gum mainly has fermentation method, protein Hydrolyze method and three kinds of chemical synthesis, wherein micro-
Biological fermentation process has become the main stream approach of production xanthan gum.Fermentation method produces xanthan gum need to be through everfermentation, film filtering, concentration
The technological operations such as crystallization, centrifuge separation, ion exchange, drying, screening, packaging will generate a large amount of after concentrate centrifuge separation
Impurity amino acid, protein, residual sugar, inorganic salt and other material.
As the demand to xanthan gum surges, China has become the maximum xanthan gum producing country in the whole world.Because xanthan gum is
Biofermentation polysaccharide, the problem of fermented waste fluid will necessarily being brought to pollute, since xanthan gum has insoluble machine agent, spy soluble easily in water
It selects so need to add a large amount of organic solvents into fermentation liquid in production, xanthan gum is precipitated out from fermentation liquid, then with
Distillation side obtain product, extract generate waste water characteristic be containing a large amount of thallus and with organic matter (COD), there are also rectifying column recycling
Efflux wastewater and equipment cleaning after drinking, major pollutants are the organic matters such as unused starch, protein.Xanthan Gum Wastewater is also
Having an evident characteristic is exactly containing gelatin substance, it is difficult to which degradation treatment mainly contains part containing a large amount of fermentation pollutant
The inorganic salts such as sodium chloride, sodium nitrate, calcium chloride and a large amount of carbohydrate and organic molecular species such as residual sugar, acetic acid, pyruvic acid etc.,
CODcr is in 4000mg/L or more.If processing is bad, not only pollute the environment, can also waste biological substance therein, while right
The water resource in China constitutes a threat to, by the serious development for restricting enterprise.
Waste water caused by the link of entire production threonine contains the pollutants such as the industrial COD of high concentration, ammonia nitrogen, handles
Higher cost constrains the development of xanthan gum industry.Although manufacturing enterprise, scientific research institution and related universities and colleges are all to improvement
A large amount of research is carried out.But all there are no mature complete set technologys to be applied to production practices both at home and abroad at present.It is main to ask
Topic is that one-time investment is excessive or day-to-day operation expense is excessively high, and most producers are unbearable, it has to maintain exceeded row for a long time
The status put.
Have nothing in common with each other at present to the processing method of Xanthan Gum Wastewater, physical method can faster removal waste water in object
Matter, but its disadvantage also can not be ignored, such as equipment will be cleaned often, prevent the extensive use of the method in the treatment of waste water.It is existing
There are also wastewater treatment is used for using physical absorption in technology, absorption method depends on the huge specific surface area of adsorbent, passes through
Physical absorption or chemisorption remove the pollutant in water.Active carbon is because having pore structure abundant and huge specific surface
Product, and its chemical stability is good, and adsorption capacity is strong, is often widely used as a kind of important sorbent material, but its at
This is higher.There are also being adsorbed using the nonmetallic ions mineral such as attapulgite, but natural non-metallic mineral have as adsorbent
Following limitation: natural non-metallic mineral density is larger and specific surface area is limited, and natural non-metallic mineral surfaces mostly band is negative
Electricity, and natural non-metallic fine ore such as clay minerals are directlyed adopt as adsorbent, solid-liquid is difficult to separate after having absorption
Problem.
Chemical method degradation process is then simple but random.Xanthan gum at high operating temperatures, can occur with oxidizing substance
Thermal degradation, but this method needs a large amount of heat.And current bioremediation is required to pre-process such as flocculation, air bearing.With
Physical method, chemistry are compared, and micro- raw processing waste water has the distinguishing features such as economical and efficient and can realize the recycling of wastewater treatment, nothing
Evil, so that microbial method occupies critical positions in always.
Summary of the invention
The purpose of the present invention is being directed to the deficiency of traditional handicraft, a kind of biochemical system of processing xanthan gum production waste water is provided
Agent and preparation method thereof significantly reduces production cost, and production process is easy to operate, stable and reliable product quality.Meet money
Source comprehensive utilization, energy-saving and emission-reduction requirement, while reducing discharging of waste liquid, alleviate sewage treatment burden, bring huge
Economic benefit and environmental benefit.In order to achieve the object of the present invention, it adopts the following technical scheme that
The biochemical preparation of xanthan gum production waste water is handled, the preparation includes physical preparation and composite bacteria agent；
Include: using the method that the biochemical preparation handles Xanthan Gum Wastewater
(1) by Xanthan Gum Wastewater after grid, into setting pot, enter primary deposition by the sewage of girt-water separation
Pond promotes the buoyance lift of grease in waste water, reduces the content of suspended matter by primary sedimentation tank；
(2) physical absorbent is prepared
It is mixed according to forsterite powder, conch meal, kaolin, chitosan, the mass ratio that pore creating material mass ratio is 3:2:3:1:5
Close, stir evenly and be placed in pelletizer, mixture 22-25%(weight is added) water, be granulated, obtaining partial size is 3~5mm
Spherical green compact；Dry 20h, calcines 1h under the conditions of 1050 DEG C, obtains physical absorbent under the conditions of 95 DEG C.
(3) waste water by primary sedimentation tank processing enters aeration tank, adds the addition of 0.4kg in aeration tank according to sewage per ton
Physical absorbent is added in sewage by amount；
After physical absorbent is handled, part NH3- N, sulfate radical, phosphorus are removed；
(4) enter sedimentation basin by the waste water of Air Exposure, adjusting pH is 6.5-7.0, and waste water per ton adds compound every time
10 grams of microbial inoculum, sewage residence time control in sedimentation basin is to be discharged after 24 hours.
The composite bacteria agent is prepared by microbial bacterial agent, algae microbial inoculum；
Preferably, the active constituent of the composite bacteria agent includes the raw material of following volume ratio:
4 parts of pseudomonas aeruginosa, 4 parts of green ochre mould, 3 parts of Acidithiobacillus ferrooxidans strain GF, 3 parts of bacillus amyloliquefaciens,
2 parts of Clostridium papyrosolvens, 2 parts of scenedesmus obliquus；
The pseudomonas aeruginosa is pseudomonas aeruginosa (Pseudomonas aeruginosa) ATCC15442；
The green ochre mould is (penicillium ochrochlorron) CGMCC NO.4390(CN102174411)；
The Acidithiobacillus ferrooxidans strain GF is Acidithiobacillus ferrooxidans strain GF (Acidithiobacillus
Ferrooxidans) 53993 ATCC；
The bacillus amyloliquefaciens be (Bacillus amyloliquefaciens) ATCC 23843；
The Clostridium papyrosolvens be (Clostridium papyrosolvens) ATCC 700395；
The scenedesmus obliquus is (Scenedesmus obliquus) CGMCC No.8015(CN103484374A).
By the above pseudomonas aeruginosa, green ochre mould, Acidithiobacillus ferrooxidans strain GF, bacillus amyloliquefaciens, molten paper shuttle
Bacterium, scenedesmus obliquus control 1 × 10 according to routine culture concentration8A/gram, it is 1 × 10 by scenedesmus obliquus culture to concentration5
The algae solution of a/ml, by above-mentioned pseudomonas aeruginosa, green ochre mould, Acidithiobacillus ferrooxidans strain GF, bacillus amyloliquefaciens, molten
Paper clostridium, scenedesmus obliquus bacterium solution are mixed according to volume ratio, are stood 6 hours, are obtained mixing liquid；
Mixing liquid and carrier are mixed according to weight ratio for 1:2 up to composite bacteria agent
The adsorbing agent carrier is made of the raw material that following weight matches: 4 parts of attapulgite, 3 parts of montmorillonite, straw powder 3
Part, 2 parts of kaolin, above-mentioned attapulgite, montmorillonite, straw powder, kaolin are 100 mesh.
After mixing liquid and carrier are mixed by weight, mixed material is dried, drying temperature is 20-50 DEG C,
Water content is 20-30% after drying；It examines, packaging: being examined by quality standard, finished product is packed by weight to get compound bacteria
Agent.
Carrier provided by the invention can not only expand the specific surface area of carrier, and, distribution big with tensile strength is
The features such as even, large specific surface area, long service life；
Carrier provided by the invention can greatly improve the adhesion amount of microorganism, increase the biofilm biomass integrally adhered to, instead
It answers the microorganism concn in slot to be improved, and sludge yield can be reduced；
It is that the present invention obtains the utility model has the advantages that
1 forsterite is commonly used for refractory material: manufacturing forsterite brick, is used for ladle, goes out in glass melter as electric furnace
Steel mouth filler material primary raw material etc., but it is relatively simple to its development and application, and the above-mentioned refractory material purposes of forsterite is to grain
Degree requires stringent, it is only necessary to which coarseness and middle granularity cause developing along with forsterite is brittle so that fine powder does not have purposes
Middle to generate a large amount of fine powders, above-mentioned forsterite fine powder causes the wasting of resources for filling out ditch.And the fine powder that wet production line generates
Part is drifted away with river water, causes serious environmental pollution.
After the present invention uses physical absorption, not only waste utilization forsterite fine powder, but also pass through physical absorption, part
NH3- N, sulfate radical, phosphorus are removed, and are greatly reduced the time of subsequent biological treatment and the dosage of biological treatment microbial inoculum, are also dropped
Low processing cost.
Specifically for physical absorption is passed through, the sewage after removing most ammonia-nitrogen sulfate radical is designed 2 composite bacteria agents, will
The various strains that can form dominant microflora, are configured to high-efficiency microorganism preparation, are added in waste water treatment system, add by a certain amount of
The degradation of fast microbe guarantees system stable operation to improve the biological treatment efficiency of system.It is containing there are many right
Recalcitrant chemicals have a microorganism of excellent degradation capability, reasonable compatibility between each strain, and symbiosis is coordinated, mutually not antagonism, activity
Height, biomass is big, and breeding is fast, adds in waste water treatment system, has good degradation effect to macromolecular, hard-degraded substance,
There is unique treatment effect to traditional propylhomoserin process discharge waste water.Discharge of wastewater processing is generated suitable for the application preparation method,
Processing water and water quality treatment can be improved, reduce operating cost, promote qualified discharge.
3 adsorbents are to make it water-soluble containing a certain number of sticking grains containing the natural material based on attapulgite
There is different degrees of electronegativity in liquid, metastable suspended particulate is presented in the variation of this electronegativity and raw wastewater, electricity occurs
The processes such as neutralization, absorption, destroy the potential balance of raw wastewater, aggravate the collision between suspended particulate, so that the effect of flocculation decline
Fruit enhancing.And above-mentioned attapulgite, montmorillonite, stalk, contain a certain amount of minerals in chitin carrier, it is effectively scattered in useless
When water, its own cation exchange capacity (CEC) having plays positive booster action in flocculation process, kaolin be macromolecule sun from
Sub- flocculant, plays that its net is caught and bridge formation function, adsorption effect are improved in the treatment of waste water.
Specific embodiment
Embodiment 1
The biochemical preparation of xanthan gum production waste water is handled, the preparation includes physical preparation and composite bacteria agent；
Include: using the method that the biochemical preparation handles Xanthan Gum Wastewater
(1) by Xanthan Gum Wastewater after grid, into setting pot, enter primary deposition by the sewage of girt-water separation
Pond promotes the buoyance lift of grease in waste water, reduces the content of suspended matter by primary sedimentation tank；
(2) physical absorbent is prepared
It is mixed according to forsterite powder, conch meal, kaolin, chitosan, the mass ratio that pore creating material mass ratio is 3:2:3:1:5
Close, stir evenly and be placed in pelletizer, mixture 22-25%(weight is added) water, be granulated, obtaining partial size is 3~5mm
Spherical green compact；Dry 20h, calcines 1h under the conditions of 1050 DEG C, obtains physical absorbent under the conditions of 95 DEG C.
(3) waste water by primary sedimentation tank processing enters aeration tank, adds the addition of 0.4kg in aeration tank according to sewage per ton
Physical absorbent is added in sewage by amount；
After physical absorbent is handled, part NH3- N, sulfate radical, phosphorus are removed；
(4) enter sedimentation basin by the waste water of Air Exposure, adjusting pH is 6.5-7.0, and waste water per ton adds compound every time
10 grams of microbial inoculum, sewage residence time control in sedimentation basin is to be discharged after 24 hours.
The composite bacteria agent is prepared by microbial bacterial agent, algae microbial inoculum；
Preferably, the active constituent of the composite bacteria agent includes the raw material of following volume ratio:
4 parts of pseudomonas aeruginosa, 4 parts of green ochre mould, 3 parts of Acidithiobacillus ferrooxidans strain GF, 3 parts of bacillus amyloliquefaciens,
2 parts of Clostridium papyrosolvens, 2 parts of scenedesmus obliquus；
The pseudomonas aeruginosa is pseudomonas aeruginosa (Pseudomonas aeruginosa) ATCC15442;
The green ochre mould is (penicillium ochrochlorron) CGMCC NO.4390；
The Acidithiobacillus ferrooxidans strain GF is Acidithiobacillus ferrooxidans strain GF (Acidithiobacillus
Ferrooxidans) 53993 ATCC；
The bacillus amyloliquefaciens be (Bacillus amyloliquefaciens) ATCC 23843；
The Clostridium papyrosolvens be (Clostridium papyrosolvens) ATCC 700395；
The scenedesmus obliquus is (Scenedesmus obliquus) CGMCC No.8015(CN103484374A)
By the above pseudomonas aeruginosa, green ochre mould, Acidithiobacillus ferrooxidans strain GF, bacillus amyloliquefaciens, molten paper shuttle
Bacterium, scenedesmus obliquus control 1 × 10 according to routine culture concentration8A/gram, it is 1 × 10 by scenedesmus obliquus culture to concentration5
The algae solution of a/ml, by above-mentioned pseudomonas aeruginosa, green ochre mould, Acidithiobacillus ferrooxidans strain GF, bacillus amyloliquefaciens, molten
Paper clostridium, scenedesmus obliquus bacterium solution are mixed according to volume ratio, are stood 6 hours, are obtained mixing liquid；
Mixing liquid and carrier are mixed according to weight ratio for 1:2 up to composite bacteria agent
The adsorbing agent carrier is made of the raw material that following weight matches: 4 parts of attapulgite, 3 parts of montmorillonite, straw powder 3
Part, 2 parts of kaolin, above-mentioned attapulgite, montmorillonite, straw powder, kaolin are 100 mesh.
After mixing liquid and carrier are mixed by weight, mixed material is dried, drying temperature is 20-50 DEG C,
Water content is 20-30% after drying；It examines, packaging: being examined by quality standard, finished product is packed by weight to get compound bacteria
Agent.
Embodiment 2
The biochemical preparation of xanthan gum production waste water is handled, the preparation includes physical preparation and composite bacteria agent；
Include: using the method that the biochemical preparation handles Xanthan Gum Wastewater
(1) by Xanthan Gum Wastewater after grid, into setting pot, enter primary deposition by the sewage of girt-water separation
Pond promotes the buoyance lift of grease in waste water, reduces the content of suspended matter by primary sedimentation tank；
(2) physical absorbent is prepared
It is mixed according to forsterite powder, conch meal, kaolin, chitosan, the mass ratio that pore creating material mass ratio is 3:2:3:1:5
Close, stir evenly and be placed in pelletizer, mixture 22-25%(weight is added) water, be granulated, obtaining partial size is 3~5mm
Spherical green compact；Dry 20h, calcines 1h under the conditions of 1050 DEG C, obtains physical absorbent under the conditions of 95 DEG C.
(3) waste water by primary sedimentation tank processing enters aeration tank, adds the addition of 0.4kg in aeration tank according to sewage per ton
Physical absorbent is added in sewage by amount；
After physical absorbent is handled, part NH3- N, sulfate radical, phosphorus are removed；
(4) enter sedimentation basin by the waste water of Air Exposure, adjusting pH is 6.5-7.0, and waste water per ton adds compound every time
10 grams of microbial inoculum, sewage residence time control in sedimentation basin is to be discharged after 24 hours.
The composite bacteria agent is prepared by microbial bacterial agent, algae microbial inoculum；
Preferably, the active constituent of the composite bacteria agent includes the raw material of following volume ratio:
5 parts of pseudomonas aeruginosa, 5 parts of green ochre mould, 4 parts of Acidithiobacillus ferrooxidans strain GF, 4 parts of bacillus amyloliquefaciens,
3 parts of Clostridium papyrosolvens, 3 parts of scenedesmus obliquus；
The pseudomonas aeruginosa is pseudomonas aeruginosa (Pseudomonas aeruginosa) ATCC15442;
The green ochre mould is (penicillium ochrochlorron) CGMCC NO.4390；
The Acidithiobacillus ferrooxidans strain GF is Acidithiobacillus ferrooxidans strain GF (Acidithiobacillus
Ferrooxidans) 53993 ATCC；
The bacillus amyloliquefaciens be (Bacillus amyloliquefaciens) ATCC 23843；
The Clostridium papyrosolvens be (Clostridium papyrosolvens) ATCC 700395；
The scenedesmus obliquus is (Scenedesmus obliquus) CGMCC No.8015(CN103484374A)
By the above pseudomonas aeruginosa, green ochre mould, Acidithiobacillus ferrooxidans strain GF, bacillus amyloliquefaciens, molten paper shuttle
Bacterium, scenedesmus obliquus control 1 × 10 according to routine culture concentration8A/gram, it is 1 × 10 by scenedesmus obliquus culture to concentration5
The algae solution of a/ml, by above-mentioned pseudomonas aeruginosa, green ochre mould, Acidithiobacillus ferrooxidans strain GF, bacillus amyloliquefaciens, molten
Paper clostridium, scenedesmus obliquus bacterium solution are mixed according to volume ratio, are stood 6 hours, are obtained mixing liquid；
Mixing liquid and carrier are mixed according to weight ratio for 1:2 up to composite bacteria agent
The adsorbing agent carrier is made of the raw material that following weight matches: 4 parts of attapulgite, 3 parts of montmorillonite, straw powder 3
Part, 2 parts of kaolin, above-mentioned attapulgite, montmorillonite, straw powder, kaolin are 100 mesh.
After mixing liquid and carrier are mixed by weight, mixed material is dried, drying temperature is 20-50 DEG C,
Water content is 20-30% after drying；It examines, packaging: being examined by quality standard, finished product is packed by weight to get compound bacteria
Agent.
Embodiment 3 handles waste water example effects
Abundant rich workshop xanthan gum fermentation waste water is taken, enters sewage treatment according to embodiment 1-2 method bottom material respectively
COD, ammonia nitrogen, total nitrogen data is measured by sampling in system；
Control group 1 compared with Example 1, does not add physical absorbent；Compare 2 groups do not add compared with Example 1 it is compound
Microbial inoculum.COD, ammonia nitrogen, SS, water outlet phosphorus content and clarity test data such as the following table 1 is measured by sampling:
Table 1
| COD removal rate | Ammonia nitrogen removal frank | Tp removal rate | It is discharged phosphorus content | Clarity | |
| Compare 1 group | 50.7% | 43.3% | 51.5% | > 0.5mg/L | 11cm |
| Compare 2 groups | 49.5% | 61.7% | 62.4% | > 0.5mg/L | 10cm |
| Example 1 group | 99.9% | 99.5% | 99.6% | < 0.5mg/L | 27cm |
| 2 groups of embodiment | 99.7% | 99.5% | 99.5% | < 0.5mg/L | 27cm |
Listed above is only best specific embodiment of the invention.It is clear that the invention is not restricted to which above embodiments, may be used also
With there are many deformations.All changes that those skilled in the art directly can export or associate from present disclosure
Shape is considered as protection scope of the present invention.
Claims (5)
1. a kind of biochemical preparation of processing xanthan gum production waste water, the preparation includes physical preparation and composite bacteria agent;
The physical preparation are as follows: according to forsterite powder, conch meal, kaolin, chitosan, pore creating material mass ratio be 3:2:3:1:
5 mass ratio mixing, stirs evenly and is placed in pelletizer, the water for accounting for mixture 22-25%w/w is added, be granulated, obtain partial size
For the green compact of 3~5mm；Dry 20h under the conditions of 95 DEG C, then calcined under the conditions of 1050 DEG C 1h to get;
The composite bacteria agent is prepared by microbial bacterial agent, algae microbial inoculum;
The composite bacteria agent includes the raw material of following volume ratio:
4 parts of pseudomonas aeruginosa, 4 parts of green ochre mould, 3 parts of Acidithiobacillus ferrooxidans strain GF, 3 parts of bacillus amyloliquefaciens, molten paper
2 parts of clostridium, 2 parts of scenedesmus obliquus.
2. preparation according to claim 1, which is characterized in that
The pseudomonas aeruginosa is (Pseudomonas aeruginosa) ATCC 15442;
The green ochre mould is (penicillium ochrochlorron) CGMCC NO.4390；
The Acidithiobacillus ferrooxidans strain GF is (Acidithiobacillus ferrooxidans) ATCC 53993；
The bacillus amyloliquefaciens are (Bacillus amyloliquefaciens) ATCC 23843；
The Clostridium papyrosolvens are (Clostridium papyrosolvens) ATCC 700395；
The scenedesmus obliquus is (Scenedesmus obliquus) CGMCC No.8015.
3. preparation according to claim 1, which is characterized in that the composite bacteria agent the preparation method comprises the following steps: verdigris is false single
Spore bacterium, green ochre mould, Acidithiobacillus ferrooxidans strain GF, bacillus amyloliquefaciens, Clostridium papyrosolvens, are controlled according to routine culture concentration
System is 1 × 108A/gram, it is 1 × 10 by scenedesmus obliquus culture to concentration5The algae solution of a/ml, then mixes according to volume ratio, quiet
It sets 6 hours, obtains mixing liquid, mixing liquid and carrier are mixed according to weight ratio for 1:2 up to composite bacteria agent.
4. preparation according to claim 3, which is characterized in that the carrier is made of the raw material that following weight matches: recessed
Convex stick native 4 parts, 3 parts of montmorillonite, 3 parts of straw powder, 2 parts of kaolin.
5. the purposes that preparation described in claim 1-4 any one is used for xanthan gum production wastewater treatment.
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| CN107381675A (en) * | 2017-08-31 | 2017-11-24 | 太仓雄鹰皮具有限公司 | Inexpensive sewage-treating agent of garment material production environmental protection and preparation method thereof |
| CN109775919B (en) * | 2017-11-10 | 2022-04-15 | 内蒙古阜丰生物科技有限公司 | Biochemical environment-friendly process for effectively treating xanthan gum industrial wastewater |
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| CN104261636B (en) * | 2014-10-20 | 2016-02-24 | 内蒙古阜丰生物科技有限公司 | A kind of method for administering xanthan gum production waste |
| CN105000676B (en) * | 2015-08-04 | 2017-09-19 | 呼伦贝尔东北阜丰生物科技有限公司 | A kind of processing method of amylum wastewater |
| CN105254034A (en) * | 2015-11-23 | 2016-01-20 | 济南昊泽环保科技有限公司 | Monosodium glutamate production wastewater treating agent and wastewater treatment method |
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