CN105254034A - Monosodium glutamate production wastewater treating agent and wastewater treatment method - Google Patents

Monosodium glutamate production wastewater treating agent and wastewater treatment method Download PDF

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Publication number
CN105254034A
CN105254034A CN201510818925.1A CN201510818925A CN105254034A CN 105254034 A CN105254034 A CN 105254034A CN 201510818925 A CN201510818925 A CN 201510818925A CN 105254034 A CN105254034 A CN 105254034A
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bacterium powder
waste water
wastewater treatment
wastewater
powder
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冉德焕
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Jinan Haoze Environmental Protection Science & Technology Co Ltd
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Jinan Haoze Environmental Protection Science & Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Micro-Organisms Or Cultivation Processes Thereof (AREA)

Abstract

The invention belongs to the field of treatment of wastewater in food enterprises and in particular relates to a treating agent of wastewater in monosodium glutamate production enterprises and also relates to a monosodium glutamate production wastewater treatment method. The monosodium glutamate production wastewater treating agent comprises the following components in parts by weight: a physical water purifying agent, a compound microbial agent and an enzymic preparation, wherein the physical water purifying agent comprises 1-5 parts of activated carbon, 1-5 parts of organically modified zeolite and 1-5 parts of polyacrylamide; the compound microbial agent comprises 0.02-0.1 part of konjac acidovorax powder, 0.05-0.2 part of arthrobacter powder, 0.05-0.2 part of bacillus laterosporus powder and 0.04-0.2 part of moraxella powder; and the enzymic preparation comprises 0.05-0.1 part of xylanase, 0.04-0.09 part of glutaminase and 0.01-0.06 part of acid proteinase. By adopting the wastewater treating agent and the wastewater treatment method, complex large-particle organic matters difficult to degrade are hydrolyzed into simple organic matters easy to degrade, thus greatly reducing the content of SS (suspended substance) in the wastewater, and the treated wastewater has high BOD (biochemical oxygen demand) and COD (chemical oxygen demand) removal rates and reaches the specified discharge standard.

Description

Gustatory production wastewater treatment agent and method of wastewater treatment
Technical field
The invention belongs to food enterprise field of waste water treatment, be specifically related to a kind of gustatory production wastewater treatment agent, also relate to above-mentioned gustatory production wastewater treatment process.
Background technology
Monosodium glutamate is a kind of food freshener be widely used, produce monosodium glutamate and will produce a large amount of high concentrated organic wastewaters, the gourmet powder waste water water yield is large, organic content is high, COD reaches 20-80g/L, suspended substance and ammonia-nitrogen content high, pH value is low, intractability is very big, processing cost is high, therefore a lot of glutamate production producers fails effectively to process gourmet powder waste water, great harm is brought to environment and social development, monosodium glutamate industry factory effluent pollution on the environment problem is on the rise, in well-known Basin of Huaihe River pollution problem, it is the second largest source of pollution being only second to paper waste, the improvement of gourmet powder waste water has become the great difficult problem of restriction glutamate production enterprise development.
China just to begin one's study the treatment process of gourmet powder waste water from late 1970s, but not yet there is very big breakthrough so far, the key of its problem is just that in gourmet powder waste water, chlorine ion concentration is high, general freezing isoelectric point method produces the content of chlorion in the waste water of monosodium glutamate discharge up to 10-30g/L, restraining effect is created to anaerobic treatment process, but result of study shows, when chlorine ion concentration is less than 6g/L, chlorion to the restraining effect of anaerobic process by not obvious.
The main source of gourmet powder waste water is:
(1) waste liquor after fermentation liquor extraction L-glutamic acid or ion-exchange tail washings;
(2) washes of various equipment in production process (tank etc. of tank of sizing mixing, liquefied pot, saccharifying tank, fermentor tank, extractor, neutralization decolouring);
(3) ion exchange resin washing and regenerative wastewater;
(4) (95 DEG C) are liquefied to saccharification, saccharification to the water coolant in each stage such as fermentation;
(5) various water of condensation (liquefaction, saccharification, the technique such as concentrated)
The feature of Some Domestic Gourmet Powder Factory factory effluent water quality and subject matter
From emission concentration, gourmet powder waste water belongs to high concentrated organic wastewater;
Useless Organic substance in water and suspended substance mycelium content high, acidity is large;
High ammonia nitrogen and sulphate content, have directly anaerobic and aerobic biology and indirectly toxic action;
The subject matter existed in monosodium glutamate wastewater treatment be process investment and working cost too high;
Also there is no suitable effective administering method now, though the anaerobic process process that expense can be adopted lower, but still the problem of high-sulfate cannot be solved.
Treatment process for gourmet powder waste water mainly contains Physical, as flocculent precipitation, and chemical method, biomembrance process etc., but its effect is unobvious especially, therefore, needs to design the high method of wastewater treatment of a kind of BOD and COD clearance for above-mentioned gourmet powder waste water.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides the gustatory production wastewater treatment agent that a kind of COD clearance is high, present invention also offers above-mentioned gustatory production wastewater treatment process.
The present invention is realized by following technical scheme:
Gustatory production wastewater treatment agent, comprises the component of following portions by weight:
Physics water purification agent is: gac is 1-5, and organic modified zeolite is 1-5 and polyacrylamide 1-5;
Complex micro organism fungicide is: konjaku acidovorax facilis bacterium powder 0.02-0.1, Arthrobacter bacterium powder 0.05-0.2, bacillus laterosporus bacterium powder 0.05-0.2 and catarrhalis bacterium powder 0.04-0.2;
Zymin is: zytase 0.05-0.1, L-Glutamine deaminase 0.04-0.09, aspartic protease 0.01-0.06.
Preferably, in above-mentioned complex micro organism fungicide, konjaku acidovorax facilis bacterium powder 0.06, Arthrobacter bacterium powder 0.12, bacillus laterosporus bacterium powder 0.14 and catarrhalis bacterium powder 0.12.
In above-mentioned zymin, zytase 0.08, L-Glutamine deaminase 0.07, aspartic protease 0.04.
Gustatory production wastewater treatment process of the present invention, comprises following step:
(1) filter: adopt grid sieving;
(2) precipitate: in settling step, add the physics water purification agent of following parts by weight, gac is 1-5, and organic modified zeolite is 1-5 and polyacrylamide 1-5; Limit edged stirs, and mixing speed is 10-20r/min; 1-4 hour is left standstill after stirring; Described physics water purification agent is the 0.005-0.02% of waste water gross weight;
(3) waste water in Wastewater Treated by Activated Sludge Process step (2), puts into aeration tank by the waste water in step (2), adds the active sludge containing complex micro organism fungicide in aeration tank, then be fed in aeration tank by active sludge;
In active sludge, complex micro organism fungicide is: konjaku acidovorax facilis bacterium powder 0.02-0.1, Arthrobacter bacterium powder 0.05-0.2, bacillus laterosporus bacterium powder 0.05-0.2 and catarrhalis bacterium powder 0.04-0.2;
The gross weight of complex micro organism fungicide is the 0.005-0.02% that waste water is heavy;
(4) waste water in step (3) is put into settling tank, add zymin again, be specially: zytase 0.05-0.1, L-Glutamine deaminase 0.04-0.09, aspartic protease 0.01-0.06, the add-on of described zymin is the 0.002-0.008 that waste water is heavy.
The particle diameter of above-mentioned active sludge is 200-1000 μm.
In above-mentioned step (2), in settling step, add the physics water purification agent of following parts by weight, gac is 3, and organic modified zeolite is 3 and polyacrylamide 3; Limit edged stirs, and mixing speed is 15r/min; 2.5 hours are left standstill after stirring; Described physics water purification agent is 0.008% of waste water gross weight.
In above-mentioned step (3), konjaku acidovorax facilis bacterium powder 0.06, Arthrobacter bacterium powder 0.12, bacillus laterosporus bacterium powder 0.14 and catarrhalis bacterium powder 0.12, the gross weight of complex micro organism fungicide be waste water heavy 0.008%.
In above-mentioned step (4), zytase 0.08, L-Glutamine deaminase 0.07, aspartic protease 0.04, the add-on of zymin be waste water heavy 0.006%.
Beneficial effect of the present invention is, adopt waste water conditioner of the present invention and method of wastewater treatment, complicated and difficult degradation, the easy degraded of oarse-grained hydrolysis of organic matter one-tenth simple organic, greatly reduce the SS content in waste water, waste water BOD after process and COD clearance high, reach the emission standard of regulation.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Embodiment 1
Gather the waste water of certain monosodium glutamate enterprise, after testing, the waste water of this enterprise does not reach emission standard, and discharge after needs process, adopt waste water conditioner of the present invention and the waste water of method of wastewater treatment to above-mentioned enterprise to process, concrete steps are as follows again:
Gustatory production wastewater treatment process, comprises following step:
(1) filter: adopt grid sieving;
(2) precipitate: in settling step, add the physics water purification agent of following parts by weight, gac is 3, organic modified zeolite is 3 and polyacrylamide 3; Limit edged stirs, and mixing speed is 15r/min; 2.5 hours are left standstill after stirring; Described physics water purification agent is 0.008% of waste water gross weight;
(3) waste water in Wastewater Treated by Activated Sludge Process step (2), puts into aeration tank by the waste water in step (2), adds the active sludge containing complex micro organism fungicide in aeration tank, then be fed in aeration tank by active sludge;
In active sludge, complex micro organism fungicide is: konjaku acidovorax facilis bacterium powder 0.06, Arthrobacter bacterium powder 0.12, bacillus laterosporus bacterium powder 0.14 and catarrhalis bacterium powder 0.12, the gross weight of complex micro organism fungicide be waste water heavy 0.008%;
(4) waste water in step (3) is put into settling tank, then adds zymin, be specially: zytase 0.08, L-Glutamine deaminase 0.07, aspartic protease 0.04, the add-on of zymin be waste water heavy 0.006%.
The particle diameter of above-mentioned active sludge is 200-1000 μm.
SS clearance is 99.4%.
BOD clearance is 98.3%.
COD clearance is 98.9%.
Embodiment 2
Gustatory production wastewater treatment process, comprises following step:
(1) filter: adopt grid sieving;
(2) precipitate: in settling step, add the physics water purification agent of following parts by weight, gac is 1, organic modified zeolite is 1 and polyacrylamide 1; Limit edged stirs, and mixing speed is 10r/min; 1 hour is left standstill after stirring; Described physics water purification agent is 0.005% of waste water gross weight;
(3) waste water in Wastewater Treated by Activated Sludge Process step (2), puts into aeration tank by the waste water in step (2), adds the active sludge containing complex micro organism fungicide in aeration tank, then be fed in aeration tank by active sludge;
In active sludge, complex micro organism fungicide is: konjaku acidovorax facilis bacterium powder 0.02, Arthrobacter bacterium powder 0.05, bacillus laterosporus bacterium powder 0.05 and catarrhalis bacterium powder 0.04, the gross weight of complex micro organism fungicide be waste water heavy 0.005%;
(4) waste water in step (3) is put into settling tank, then adds zymin, be specially: zytase 0.05, L-Glutamine deaminase 0.04, aspartic protease 0.01, the add-on of zymin be waste water heavy 0.002%.
Embodiment 3
Gustatory production wastewater treatment process, comprises following step:
(1) filter: adopt grid sieving;
(2) precipitate: in settling step, add the physics water purification agent of following parts by weight, gac is 5, organic modified zeolite is 5 and polyacrylamide 5; Limit edged stirs, and mixing speed is 20r/min; 4 hours are left standstill after stirring; Described physics water purification agent is 0.02% of waste water gross weight;
(3) waste water in Wastewater Treated by Activated Sludge Process step (2), puts into aeration tank by the waste water in step (2), adds the active sludge containing complex micro organism fungicide in aeration tank, then be fed in aeration tank by active sludge;
In active sludge, complex micro organism fungicide is: konjaku acidovorax facilis bacterium powder 0.1, Arthrobacter bacterium powder 0.2, bacillus laterosporus bacterium powder 0.2 and catarrhalis bacterium powder 0.2, the gross weight of complex micro organism fungicide be waste water heavy 0.005%;
(4) waste water in step (3) is put into settling tank, then adds zymin, be specially: zytase 0.1, L-Glutamine deaminase 0.09, aspartic protease 0.06, the add-on of zymin be waste water heavy 0.008%.

Claims (8)

1. gustatory production wastewater treatment agent, comprises the component of following portions by weight:
Physics water purification agent is: gac is 1-5, and organic modified zeolite is 1-5 and polyacrylamide 1-5;
Complex micro organism fungicide is: konjaku acidovorax facilis bacterium powder 0.02-0.1, Arthrobacter bacterium powder 0.05-0.2, bacillus laterosporus bacterium powder 0.05-0.2 and catarrhalis bacterium powder 0.04-0.2;
Zymin is: zytase 0.05-0.1, L-Glutamine deaminase 0.04-0.09, aspartic protease 0.01-0.06.
2. gustatory production wastewater treatment agent as claimed in claim 1, is characterized in that, in described complex micro organism fungicide, and konjaku acidovorax facilis bacterium powder 0.06, Arthrobacter bacterium powder 0.12, bacillus laterosporus bacterium powder 0.14 and catarrhalis bacterium powder 0.12.
3. gustatory production wastewater treatment agent as claimed in claim 1, is characterized in that, in described zymin,
Zytase 0.08, L-Glutamine deaminase 0.07, aspartic protease 0.04.
4. gustatory production wastewater treatment process as claimed in claim 1, comprises following step:
(1) filter: adopt grid sieving;
(2) precipitate: in settling step, add the physics water purification agent of following parts by weight, gac is 1-5, and organic modified zeolite is 1-5 and polyacrylamide 1-5; Limit edged stirs, and mixing speed is 10-20r/min; 1-4 hour is left standstill after stirring; Described physics water purification agent is the 0.005-0.02% of waste water gross weight;
(3) waste water in Wastewater Treated by Activated Sludge Process step (2), puts into aeration tank by the waste water in step (2), adds the active sludge containing complex micro organism fungicide in aeration tank, then be fed in aeration tank by active sludge;
In described active sludge, complex micro organism fungicide is: konjaku acidovorax facilis bacterium powder 0.02-0.1, Arthrobacter bacterium powder 0.05-0.2, bacillus laterosporus bacterium powder 0.05-0.2 and catarrhalis bacterium powder 0.04-0.2;
The gross weight of complex micro organism fungicide is the 0.005-0.02% that waste water is heavy;
(4) waste water in step (3) is put into settling tank, add zymin again, be specially: zytase 0.05-0.1, L-Glutamine deaminase 0.04-0.09, aspartic protease 0.01-0.06, the add-on of described zymin is the 0.002-0.008% that waste water is heavy.
5. gustatory production wastewater treatment process as claimed in claim 4, it is characterized in that, the particle diameter of described active sludge is 200-1000 μm.
6. gustatory production wastewater treatment process as claimed in claim 4, it is characterized in that, in described step (2), in settling step, add the physics water purification agent of following parts by weight, gac is 3, and organic modified zeolite is 3 and polyacrylamide 3; Limit edged stirs, and mixing speed is 15r/min; 2.5 hours are left standstill after stirring; Described physics water purification agent is 0.008% of waste water gross weight.
7. gustatory production wastewater treatment process as claimed in claim 4, it is characterized in that, in described step (3), konjaku acidovorax facilis bacterium powder 0.06, Arthrobacter bacterium powder 0.12, bacillus laterosporus bacterium powder 0.14 and catarrhalis bacterium powder 0.12, the gross weight of complex micro organism fungicide be waste water heavy 0.008%.
8. gustatory production wastewater treatment process as claimed in claim 4, is characterized in that, described step (4) zytase 0.08, L-Glutamine deaminase 0.07, aspartic protease 0.04, the add-on of zymin be waste water heavy 0.006%.
CN201510818925.1A 2015-11-23 2015-11-23 Monosodium glutamate production wastewater treating agent and wastewater treatment method Pending CN105254034A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105833832A (en) * 2016-06-22 2016-08-10 内蒙古阜丰生物科技有限公司 Biochemical preparation for treating glutamic acid fermentation sewage
CN105906169A (en) * 2016-06-30 2016-08-31 内蒙古阜丰生物科技有限公司 Biological preparation for treating sodium glutamate fermentation sewage
CN105923921A (en) * 2016-06-22 2016-09-07 内蒙古阜丰生物科技有限公司 Treatment process of monosodium glutamate fermentation wastewater
CN105921099A (en) * 2016-06-22 2016-09-07 内蒙古阜丰生物科技有限公司 Biochemical preparation for treating threonine fermentation sewage
CN105948400A (en) * 2016-06-22 2016-09-21 内蒙古阜丰生物科技有限公司 Environment-friendly technique for restoring L-threonine fermentation wastewater
CN105948399A (en) * 2016-06-22 2016-09-21 内蒙古阜丰生物科技有限公司 Biochemical agent for xanthan gum production wastewater and preparation method thereof
CN106045201A (en) * 2016-06-30 2016-10-26 内蒙古阜丰生物科技有限公司 Biological treatment process of xanthan gum fermentation waste
CN106082532A (en) * 2016-06-22 2016-11-09 内蒙古阜丰生物科技有限公司 For processing the preparation method of the biochemical preparation of Threonine Fermentation waste water
CN106915873A (en) * 2017-04-11 2017-07-04 内蒙古阜丰生物科技有限公司 Administer the environment-protective process of waste gourmet powder fermenting liquor

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CN104529052A (en) * 2014-11-26 2015-04-22 山东永泰化工有限公司 Tire production enterprise wastewater treatment method
CN104556552A (en) * 2014-11-26 2015-04-29 山东永泰化工有限公司 Treatment method of rubber accelerator production wastewater
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CN105923921B (en) * 2016-06-22 2018-09-07 内蒙古阜丰生物科技有限公司 The treatment process of gourmet powder fermenting waste water
CN105921099B (en) * 2016-06-22 2018-09-07 内蒙古阜丰生物科技有限公司 Biochemical preparation for administering Threonine Fermentation sewage
CN105923921A (en) * 2016-06-22 2016-09-07 内蒙古阜丰生物科技有限公司 Treatment process of monosodium glutamate fermentation wastewater
CN105921099A (en) * 2016-06-22 2016-09-07 内蒙古阜丰生物科技有限公司 Biochemical preparation for treating threonine fermentation sewage
CN105948400A (en) * 2016-06-22 2016-09-21 内蒙古阜丰生物科技有限公司 Environment-friendly technique for restoring L-threonine fermentation wastewater
CN105948399A (en) * 2016-06-22 2016-09-21 内蒙古阜丰生物科技有限公司 Biochemical agent for xanthan gum production wastewater and preparation method thereof
CN106082532B (en) * 2016-06-22 2018-12-07 内蒙古阜丰生物科技有限公司 For handling the preparation method of the biochemical preparation of Threonine Fermentation waste water
CN105948400B (en) * 2016-06-22 2018-11-16 内蒙古阜丰生物科技有限公司 A kind of environment-protective process for repairing L-threonine fermentation waste water
CN106082532A (en) * 2016-06-22 2016-11-09 内蒙古阜丰生物科技有限公司 For processing the preparation method of the biochemical preparation of Threonine Fermentation waste water
CN105833832A (en) * 2016-06-22 2016-08-10 内蒙古阜丰生物科技有限公司 Biochemical preparation for treating glutamic acid fermentation sewage
CN106045201A (en) * 2016-06-30 2016-10-26 内蒙古阜丰生物科技有限公司 Biological treatment process of xanthan gum fermentation waste
CN105906169A (en) * 2016-06-30 2016-08-31 内蒙古阜丰生物科技有限公司 Biological preparation for treating sodium glutamate fermentation sewage
CN106045201B (en) * 2016-06-30 2019-02-05 内蒙古阜丰生物科技有限公司 The biological treatment of xanthan gum fermentation waste
CN106915873A (en) * 2017-04-11 2017-07-04 内蒙古阜丰生物科技有限公司 Administer the environment-protective process of waste gourmet powder fermenting liquor
CN106915873B (en) * 2017-04-11 2020-06-26 内蒙古阜丰生物科技有限公司 Environment protection process for treating waste liquid of monosodium glutamate fermentation

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