CN103739142A - Chinese patent medicine production wastewater treatment technology - Google Patents
Chinese patent medicine production wastewater treatment technology Download PDFInfo
- Publication number
- CN103739142A CN103739142A CN201310568528.4A CN201310568528A CN103739142A CN 103739142 A CN103739142 A CN 103739142A CN 201310568528 A CN201310568528 A CN 201310568528A CN 103739142 A CN103739142 A CN 103739142A
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- CN
- China
- Prior art keywords
- treatment
- water outlet
- tank
- coagulative precipitation
- precipitation tank
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- 239000003814 drug Substances 0.000 title claims abstract description 15
- 238000004065 wastewater treatment Methods 0.000 title abstract description 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000002351 wastewater Substances 0.000 claims abstract description 26
- 238000001556 precipitation Methods 0.000 claims abstract description 20
- 239000000126 substance Substances 0.000 claims abstract description 11
- 239000010802 sludge Substances 0.000 claims abstract description 7
- 238000001914 filtration Methods 0.000 claims abstract description 6
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 230000001112 coagulating effect Effects 0.000 claims description 21
- 230000007062 hydrolysis Effects 0.000 claims description 9
- 238000006460 hydrolysis reaction Methods 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 230000020477 pH reduction Effects 0.000 claims description 9
- 238000004062 sedimentation Methods 0.000 claims description 9
- 238000009280 upflow anaerobic sludge blanket technology Methods 0.000 claims description 9
- 238000005868 electrolysis reaction Methods 0.000 claims description 7
- QMQXDJATSGGYDR-UHFFFAOYSA-N methylidyneiron Chemical compound [C].[Fe] QMQXDJATSGGYDR-UHFFFAOYSA-N 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 3
- 230000002906 microbiologic effect Effects 0.000 claims description 3
- 238000002203 pretreatment Methods 0.000 claims description 3
- 239000002562 thickening agent Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 abstract description 3
- 239000001301 oxygen Substances 0.000 abstract description 3
- 239000000725 suspension Substances 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 2
- 230000015271 coagulation Effects 0.000 abstract 2
- 238000005345 coagulation Methods 0.000 abstract 2
- 239000008187 granular material Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000019600 saltiness Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Landscapes
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The invention discloses a Chinese patent medicine production wastewater treatment technology, and belongs to the technical field of wastewater treatment. The technology comprises the steps of (1) pretreatment, (2) coagulation precipitation treatment, (3) anaerobic treatment, (4) aerobic treatment, (5) filtering treatment, and (6) sludge treatment. Chinese patent medicine wastewater undergoes pretreatment, coagulation precipitation, anaerobic treatment, aerobic treatment and the like, so the chemical oxygen demand (COD), the biochemical oxygen demand (BOD), the concentration of solid suspension (SS) and the content of ammonia nitrogen (NH3-N) in the wastewater are greatly reduced, and the influences on the environment are reduced.
Description
Technical field
The present invention relates to the processing of pharmacy field waste water, the treatment process of especially a kind of capsule, tablet, granule Chinese patent medicine factory effluent.
Background technology
Chinese patent medicine waste water of pharmaceutical industry is the high concentrated organic wastewater that a class contains hard-degraded substance and bio-toxicity material, and domestic Chinese patent medicine waste water of pharmaceutical industry quantity discharged is large, and water pollution is serious.The feature of its waste water is that complicated component, organic content are high, toxicity is large, colourity is dark and saltiness is high, and particularly biochemical is very poor, and intermittently discharged, belongs to unmanageable trade effluent.Along with the development of China's medicine industry, Chinese patent medicine pharmacy waste water becomes one of important source of pollution gradually, and how processing such waste water is a difficult problem of current environment protection.
The processing of herbal pharmaceutical industry waste water has become problem demanding prompt solution, so the effective pharmacy waste water treatment technology of exploiting economy has important theory significance and realistic meaning.Chinese patent medicine wastewater processing technology is at home and abroad studied seldom.
Summary of the invention
The object of the present invention is to provide a kind for the treatment of process of Chinese patent medicine factory effluent.
Object of the present invention can be achieved through the following technical solutions:
A treatment process for Chinese patent medicine factory effluent, is characterized in that, comprises the following steps:
(1) pre-treatment: high-concentration waste water is removed large impurity through grille well, after enter preliminary sedimentation tank, remove after large suspended substance from flowing to equalizing tank even water quality in equalizing tank;
(2) coagulating sedimentation is processed: equalizing tank water outlet is promoted to coagulative precipitation tank I through pump, the water outlet of coagulative precipitation tank I is from flowing to iron-carbon micro-electrolysis reactor, larger molecular organics is converted into small organic molecule, the water outlet of iron-carbon micro-electrolysis reactor flow to coagulative precipitation tank II, removes suspended substance, organism;
(3) anaerobic treatment: the water outlet of coagulative precipitation tank II is mixed into hydrolysis acidification pool with low concentration wastewater, and hydrolysis acidification pool water outlet is promoted to UASB anaerobic reactor through pump, the water outlet of UASB anaerobic reactor enters backflow pond;
(4) aerobic treatment: the water outlet of backflow pond flow to SBR pond, by the effect of aerobic microbiological, removes organism and ammonia nitrogen, and the water outlet of SBR pond flow to blowoff basin;
(5) filtration treatment: blowoff basin water outlet after medium filter filters by standardization discharge outlet qualified discharge;
(6) sludge treatment: the mud that preliminary sedimentation tank, hydrolysis acidification pool, UASB anaerobic reactor, SBR pond, coagulative precipitation tank I, coagulative precipitation tank II produce enters sludge thickener, through folded spiral shell pressure filter press filtration, dry mud outward transport is disposed.
Beneficial effect of the present invention: the present invention combines Chinese patent medicine waste water through steps such as pre-treatment, coagulating sedimentation, anaerobic treatment and aerobic treatment, significantly reduce the chemical oxygen demand cod in waste water, biochemical requirement BOD, solid suspension substrate concentration SS, ammonia-nitrogen content NH3-N, reduce the impact on environment.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
Table 1 is the waste water quality index of certain wafer, tablet, the discharge of granule Chinese patent medicine enterprise:
| Waste water type | pH | COD | BOD | NH3-N | SS |
| High-concentration waste water | — | ≤16000 | ≤4500 | ≤50 | ≤1500 |
| Low concentration wastewater | 6-9 | ≤500 | ≤250 | ≤30 | ≤250 |
Treatment process of the present invention is: first high-concentration waste water removes large impurity through grille well, after enter preliminary sedimentation tank, remove after most suspended substances from flowing to equalizing tank even water quality in equalizing tank; Through pump, be promoted to coagulative precipitation tank I again, control into iron-carbon micro-electrolysis suspended substance; The water outlet of coagulative precipitation tank I flow to iron-carbon micro-electrolysis, and larger molecular organics is converted into small organic molecule, improves the biodegradability of waste water; Iron-carbon micro-electrolysis water outlet flow to coagulative precipitation tank II, removes suspended substance, organism and regulates wastewater pH; The water outlet of coagulative precipitation tank II is mixed into hydrolysis acidification pool with low concentration wastewater, further reduces the biodegradability of organism and raising waste water; Hydrolysis acidification pool water outlet is promoted to UASB anaerobic reactor through pump, by anaerobic reaction, removes most organic; The water outlet of UASB anaerobic reactor enters backflow pond, then flow to SBR pond, by aerobic microbiological effect, removes residual organic substances and ammonia nitrogen; SBR water outlet flow to blowoff basin, then after more medium filter filters by standardization discharge outlet qualified discharge.
The excess sludge that preliminary sedimentation tank, hydrolysis acidification pool, UASB, SBR pond, coagulative precipitation tank I, coagulative precipitation tank II produce enters sludge thickener, and through folded spiral shell pressure filter press filtration, dry mud outward transport is disposed.
Table 2 is the effluent qualities after the present invention processes:
| Control project | pH | COD | BOD | NH3-N |
| Emission standard | 6-9 | ≤100 | ≤20 | ≤8 |
Table 3 is each section of effluent quality index of the present invention (unit is all with mg/L)
Above content is only to technique example of the present invention and explanation; affiliated those skilled in the art make various modifications to described specific embodiment or supplement or adopt similar mode to substitute; only otherwise depart from the technique of invention or surmount this scope as defined in the claims, all should belong to protection scope of the present invention.
Claims (1)
1. a treatment process for Chinese patent medicine factory effluent, is characterized in that, comprises the following steps:
(1) pre-treatment: high-concentration waste water is removed large impurity through grille well, after enter preliminary sedimentation tank, remove after large suspended substance from flowing to equalizing tank even water quality in equalizing tank;
(2) coagulating sedimentation is processed: equalizing tank water outlet is promoted to coagulative precipitation tank I through pump, the water outlet of coagulative precipitation tank I is from flowing to iron-carbon micro-electrolysis reactor, larger molecular organics is converted into small organic molecule, the water outlet of iron-carbon micro-electrolysis reactor flow to coagulative precipitation tank II, removes suspended substance, organism;
(3) anaerobic treatment: the water outlet of coagulative precipitation tank II is mixed into hydrolysis acidification pool with low concentration wastewater, and hydrolysis acidification pool water outlet is promoted to UASB anaerobic reactor through pump, the water outlet of UASB anaerobic reactor enters backflow pond;
(4) aerobic treatment: the water outlet of backflow pond flow to SBR pond, by the effect of aerobic microbiological, removes organism and ammonia nitrogen, and the water outlet of SBR pond flow to blowoff basin;
(5) filtration treatment: blowoff basin water outlet after medium filter filters by standardization discharge outlet qualified discharge;
(6) sludge treatment: the mud that preliminary sedimentation tank, hydrolysis acidification pool, UASB anaerobic reactor, SBR pond, coagulative precipitation tank I, coagulative precipitation tank II produce enters sludge thickener, through folded spiral shell pressure filter press filtration, dry mud outward transport is disposed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310568528.4A CN103739142A (en) | 2013-11-15 | 2013-11-15 | Chinese patent medicine production wastewater treatment technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310568528.4A CN103739142A (en) | 2013-11-15 | 2013-11-15 | Chinese patent medicine production wastewater treatment technology |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103739142A true CN103739142A (en) | 2014-04-23 |
Family
ID=50496234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310568528.4A Pending CN103739142A (en) | 2013-11-15 | 2013-11-15 | Chinese patent medicine production wastewater treatment technology |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103739142A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104016552A (en) * | 2014-06-20 | 2014-09-03 | 太仓远德环保科技有限公司 | Wastewater treatment equipment and method |
| CN104445814A (en) * | 2014-11-19 | 2015-03-25 | 山东大学 | Process and device for treating tetracycline antibiotic wastewater |
| CN106587510A (en) * | 2016-12-30 | 2017-04-26 | 四川师范大学 | Method for treating chemical organic wastewater |
| CN111892252A (en) * | 2020-04-09 | 2020-11-06 | 朱宇浩 | Traditional Chinese medicine wastewater treatment method |
| CN111925062A (en) * | 2020-08-14 | 2020-11-13 | 天津城建大学 | A kind of combined treatment process of pharmaceutical intermediate production wastewater |
| CN111943426A (en) * | 2020-07-10 | 2020-11-17 | 同济大学 | A kind of treatment method of high-salt pharmaceutical wastewater |
| CN112062402A (en) * | 2020-09-08 | 2020-12-11 | 江苏众志新禹环境科技有限公司 | Biomembrane reaction type pharmaceutical wastewater treatment method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102807303A (en) * | 2012-09-06 | 2012-12-05 | 唐国民 | Traditional Chinese medicine wastewater advanced treatment technology |
-
2013
- 2013-11-15 CN CN201310568528.4A patent/CN103739142A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102807303A (en) * | 2012-09-06 | 2012-12-05 | 唐国民 | Traditional Chinese medicine wastewater advanced treatment technology |
Non-Patent Citations (2)
| Title |
|---|
| 吕开雷等: "水解酸化―UASB―SBR处理制药废水", 《给水排水》 * |
| 沈扬等: "铁屑还原法在中药提取物废水处理中的设计应用", 《化工设计通讯》 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104016552A (en) * | 2014-06-20 | 2014-09-03 | 太仓远德环保科技有限公司 | Wastewater treatment equipment and method |
| CN104016552B (en) * | 2014-06-20 | 2015-08-26 | 太仓远德环保科技有限公司 | A kind of sewage treatment equipment and method thereof |
| CN104445814A (en) * | 2014-11-19 | 2015-03-25 | 山东大学 | Process and device for treating tetracycline antibiotic wastewater |
| CN104445814B (en) * | 2014-11-19 | 2016-02-17 | 山东大学 | A kind of technique for the treatment of tetracycline antibiotics waste water and device |
| CN106587510A (en) * | 2016-12-30 | 2017-04-26 | 四川师范大学 | Method for treating chemical organic wastewater |
| CN111892252A (en) * | 2020-04-09 | 2020-11-06 | 朱宇浩 | Traditional Chinese medicine wastewater treatment method |
| CN111943426A (en) * | 2020-07-10 | 2020-11-17 | 同济大学 | A kind of treatment method of high-salt pharmaceutical wastewater |
| CN111943426B (en) * | 2020-07-10 | 2022-11-04 | 同济大学 | A kind of treatment method of high-salt pharmaceutical wastewater |
| CN111925062A (en) * | 2020-08-14 | 2020-11-13 | 天津城建大学 | A kind of combined treatment process of pharmaceutical intermediate production wastewater |
| CN112062402A (en) * | 2020-09-08 | 2020-12-11 | 江苏众志新禹环境科技有限公司 | Biomembrane reaction type pharmaceutical wastewater treatment method |
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Application publication date: 20140423 |