CN112062402A - Biomembrane reaction type pharmaceutical wastewater treatment method - Google Patents
Biomembrane reaction type pharmaceutical wastewater treatment method Download PDFInfo
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- CN112062402A CN112062402A CN202010935053.8A CN202010935053A CN112062402A CN 112062402 A CN112062402 A CN 112062402A CN 202010935053 A CN202010935053 A CN 202010935053A CN 112062402 A CN112062402 A CN 112062402A
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- wastewater
- coagulating sedimentation
- sedimentation tank
- treatment
- sequencing batch
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
- C02F1/36—Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/343—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the pharmaceutical industry, e.g. containing antibiotics
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
The invention relates to the technical field of wastewater treatment, in particular to a biomembrane reaction type pharmaceutical wastewater treatment method. The method comprises the following steps: a) the pharmaceutical wastewater enters an adjusting tank for stirring and pre-aeration treatment, and the treated wastewater is sent into a coagulating sedimentation tank; b) a flocculating agent is added into the coagulating sedimentation tank, after suspended matters in the wastewater are removed by the coagulating sedimentation tank, the wastewater enters the sequencing batch biofilm reactor, and sludge discharged from the coagulating sedimentation tank is transported outside for treatment; c) after microorganisms in the wastewater are removed by the sequencing batch biofilm reactor, the wastewater is sent into a filter tank for ultrasonic disinfection, and water which reaches the discharge standard is obtained after disinfection. The invention carries out anaerobic, anoxic and aerobic processes by using the sequencing batch biofilm reactor to treat aerobic, attached facultative and attached anaerobic microorganisms. Through ultrasonic disinfection, avoid throwing into medicine to the aquatic to can not influence quality of water. This application has improved the waste water treatment effect, has practiced thrift the cost.
Description
Technical Field
The invention relates to the technical field of wastewater treatment, in particular to a biomembrane reaction type pharmaceutical wastewater treatment method.
Background
The pharmaceutical industry wastewater mainly comprises four types of antibiotic production wastewater, synthetic drug production wastewater, Chinese patent drug production wastewater, and washing water and flushing wastewater in the production process of various preparations. The waste water has the characteristics of complex components, high organic matter content, high toxicity, deep chromaticity, high salt content, particularly poor biodegradability, and intermittent discharge, and belongs to industrial waste water which is difficult to treat. With the development of the pharmaceutical industry in China, pharmaceutical wastewater gradually becomes one of important pollution sources, and how to treat the wastewater is a difficult problem of environmental protection at present. The prior art usually ignores the unique characteristics of pharmaceutical wastewater, and generally adopts a general process flow of pretreatment and biochemical treatment reinforcement liquid separation. The process occupies a large area and consumes much energy.
Disclosure of Invention
In order to solve the technical problems described in the background art, the invention provides a biomembrane reaction type pharmaceutical wastewater treatment method, which carries out anaerobic, anoxic and aerobic processes through a sequencing batch biomembrane reactor to treat aerobic, attached facultative and attached anaerobic microorganisms. Through ultrasonic disinfection, avoid throwing into medicine to the aquatic to can not influence quality of water. This application has improved the waste water treatment effect, has practiced thrift the cost.
The technical scheme adopted by the invention for solving the technical problems is as follows:
a biomembrane reaction type pharmaceutical wastewater treatment method comprises the following steps:
a) the pharmaceutical wastewater enters an adjusting tank for stirring and pre-aeration treatment, and the treated wastewater is sent into a coagulating sedimentation tank;
b) a flocculating agent is added into the coagulating sedimentation tank, after suspended matters in the wastewater are removed by the coagulating sedimentation tank, the wastewater enters the sequencing batch biofilm reactor, and sludge discharged from the coagulating sedimentation tank is transported outside for treatment;
c) after microorganisms in the wastewater are removed by the sequencing batch biofilm reactor, the wastewater is sent into a filter tank for ultrasonic disinfection, and water which reaches the discharge standard is obtained after disinfection.
Specifically, the flocculant is polyacrylamide.
The invention has the beneficial effects that: the invention provides a biomembrane reaction type pharmaceutical wastewater treatment method, which carries out anaerobic, anoxic and aerobic processes through a sequencing batch biomembrane reactor to treat aerobic, attached facultative and attached anaerobic microorganisms. Through ultrasonic disinfection, avoid throwing into medicine to the aquatic to can not influence quality of water. This application has improved the waste water treatment effect, has practiced thrift the cost.
Drawings
The invention is further described with reference to the following figures and examples.
FIG. 1 is a schematic diagram of the framework of the present invention;
Detailed Description
The invention will now be described in further detail with reference to the accompanying drawings. These drawings are simplified schematic diagrams illustrating only the basic structure of the invention in a schematic manner, and thus show only the constitution related to the invention.
Fig. 1 is a schematic diagram of the framework of the present invention.
As shown in the attached figure 1, a biomembrane reaction type pharmaceutical wastewater treatment method comprises the following steps:
a) the pharmaceutical wastewater enters an adjusting tank for stirring and pre-aeration treatment, and the treated wastewater is sent into a coagulating sedimentation tank;
b) a flocculating agent is added into the coagulating sedimentation tank, after suspended matters in the wastewater are removed by the coagulating sedimentation tank, the wastewater enters the sequencing batch biofilm reactor, and sludge discharged from the coagulating sedimentation tank is transported outside for treatment;
c) after microorganisms in the wastewater are removed by the sequencing batch biofilm reactor, the wastewater is sent into a filter tank for ultrasonic disinfection, and water which reaches the discharge standard is obtained after disinfection.
The flocculating agent is polyacrylamide.
The coagulating sedimentation tank is one of sedimentation tanks in water supply and drainage. The coagulation process is the most basic and very important treatment process in the treatment of industrial water and domestic sewage, and by adding some medicaments (generally called coagulant and coagulant aid) into water, particles which are difficult to precipitate in the water can be polymerized with each other to form colloid, and then are combined with impurities in the water body to form larger floccules. The flocculating constituent has strong adsorption capacity, can adsorb suspended matters, and can adsorb partial bacteria and soluble substances. The flocs sink down by increasing their volume through adsorption.
A Sequencing Batch Biofilm Reactor (Sequencing Biofilm Batch Reactor), also known as a membrane SBR (BABR), is a new biological sewage treatment process which is researched and applied at home and abroad. The sequencing batch biofilm reactor is a novel composite biofilm reactor developed by filling different fillers (such as fiber fillers, activated carbon, ceramsite and the like) in an SBR reactor, and the intervention of the fillers provides a more favorable living environment for microorganisms. The microorganisms form a complex ecosystem consisting of a plurality of nutrition levels such as bacteria, fungi, algae, protozoa, metazoan and the like in the longitudinal direction, and form a suspended aerobic type, attached facultative type and attached anaerobic type microorganism system with various different activities, breathing types and nutrition types in the transverse direction along the direction of water flowing to the carrier, thereby greatly improving the processing capacity and stability of the reactor, and the advantages of stable reaction process, more and complex biomass, less residual sludge, less power consumption and small occupied area of the sequencing batch biofilm reactor are achieved.
The sterilization and disinfection mechanism of the ultrasonic wave is that the ultrasonic wave can perform ultrasonic cavitation in liquid to instantly generate hundreds of millions of cavitation micro bubbles, a plurality of cavitation bubbles are instantly generated and instantly exploded, meanwhile, the temperature of the liquid is continuously increased along with high temperature and high pressure, a hand is stretched into the liquid to feel pinprick, the cavitation generates strong mechanical shearing action, and the cell walls of microorganisms can be broken, so that the cell contents overflow out of the cell walls, and thus, certain components in the cells, such as DNA, RNA, amino acid, alkaloid, protein and the like can be extracted. The adoption of ultrasonic wave sterilization avoids the generation of harmful byproducts and the irreversible influence on human bodies and the environment. In addition, the characteristic of large water volume of the papermaking wastewater is that the cost of the medicament is obviously increased if chlorine adding disinfection is continuously adopted, and the ultrasonic disinfection mode does not need to add any substance into water, so that the cost is superior to that of the chlorine adding disinfection firstly, and other substances do not need to be added, so that the water quality is not affected by adopting the ultrasonic disinfection.
In light of the foregoing description of preferred embodiments according to the invention, many modifications and variations can be made by the worker skilled in the art without departing from the scope of the invention. The technical scope of the present invention is not limited to the content of the specification, and must be determined according to the scope of the claims.
Claims (2)
1. A biomembrane reaction type pharmaceutical wastewater treatment method is characterized in that: the method comprises the following steps:
a) the pharmaceutical wastewater enters an adjusting tank for stirring and pre-aeration treatment, and the treated wastewater is sent into a coagulating sedimentation tank;
b) a flocculating agent is added into the coagulating sedimentation tank, after suspended matters in the wastewater are removed by the coagulating sedimentation tank, the wastewater enters the sequencing batch biofilm reactor, and sludge discharged from the coagulating sedimentation tank is transported outside for treatment;
c) after microorganisms in the wastewater are removed by the sequencing batch biofilm reactor, the wastewater is sent into a filter tank for ultrasonic disinfection, and water which reaches the discharge standard is obtained after disinfection.
2. The method of claim 1, wherein the step of treating the wastewater comprises: the flocculant is polyacrylamide.
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CN202010935053.8A CN112062402A (en) | 2020-09-08 | 2020-09-08 | Biomembrane reaction type pharmaceutical wastewater treatment method |
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CN202010935053.8A CN112062402A (en) | 2020-09-08 | 2020-09-08 | Biomembrane reaction type pharmaceutical wastewater treatment method |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103739142A (en) * | 2013-11-15 | 2014-04-23 | 安徽省绿巨人环境技术有限公司 | Chinese patent medicine production wastewater treatment technology |
CN110526526A (en) * | 2019-09-25 | 2019-12-03 | 江苏众志新禹环境科技有限公司 | The method of Pharmaceutical Wastewater Treatment |
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- 2020-09-08 CN CN202010935053.8A patent/CN112062402A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103739142A (en) * | 2013-11-15 | 2014-04-23 | 安徽省绿巨人环境技术有限公司 | Chinese patent medicine production wastewater treatment technology |
CN110526526A (en) * | 2019-09-25 | 2019-12-03 | 江苏众志新禹环境科技有限公司 | The method of Pharmaceutical Wastewater Treatment |
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Application publication date: 20201211 |
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