CN107473546A - A kind of special repair materials of mercury and its preparation technology - Google Patents

A kind of special repair materials of mercury and its preparation technology Download PDF

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Publication number
CN107473546A
CN107473546A CN201710977593.0A CN201710977593A CN107473546A CN 107473546 A CN107473546 A CN 107473546A CN 201710977593 A CN201710977593 A CN 201710977593A CN 107473546 A CN107473546 A CN 107473546A
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China
Prior art keywords
parts
preparation technology
mercury
repair materials
medical stone
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Withdrawn
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CN201710977593.0A
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Chinese (zh)
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方碧水
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Individual
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Individual
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Priority to CN201710977593.0A priority Critical patent/CN107473546A/en
Publication of CN107473546A publication Critical patent/CN107473546A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/06Nutrients for stimulating the growth of microorganisms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/20Sludge processing

Abstract

The present invention relates to a kind of special repair materials of mercury and its preparation technology, raw material constituent is made up of following ratio in parts by weight:20 30 parts of medical stone, 10 20 parts of zeolite powder, 6 12 parts of molecular sieve, 46 parts of sodium metasilicate, 7 11 parts of fiber-ball filter media, 20 25 parts of bentonite, 6 10 parts of 2mg/L polyacrylamide solutions, 30 40 parts of wood chip, 10 20 parts of humus, 68 parts of composite flora, 60 80 parts of deionized water.Material of the present invention is easy to get, it is nutritious in medical stone and zeolite, nutrition is discharged, improves organism in water survival rate, surface has cellular, effective absorbing heavy metal ions in water, probiotics breeding can effectively be carried out using composite flora, remove harmful substance and excessive sulfide etc. in water, and formed and be solidified on surface with other materials, from cleaning inside mud, dissolved oxygen is effectively discharged, to nutrient needed for biology offer.

Description

A kind of special repair materials of mercury and its preparation technology
Technical field
The present invention relates to a kind of special repair materials of mercury and its preparation technology.
Background technology
The pollution source of water body can be divided into endogenous and external source, will except to external source pollution during pollution administration water body Cut off or controlled, the influence of endogenous pollution equally be can not ignore.After polluter enters water body, by precipitating, adsorbing Approach is eventually deposited in bed mud and gradually accumulated.Because constantly enrichment accumulates, nitrogen phosphorus, oxygen consumption in polluted water body deposit The pollutant concentrations such as organic matter, hardly degraded organic substance are often the order of magnitude multiple of each pollutant concentration in overlying water, and bed mud has Machine material can produce the materials such as ammonia nitrogen, hydrogen sulfide, volatile organic matter under anaerobic can produce stench.So polluted-water Bed mud be pollutant " accumulation storehouse ", can aggravate water pollution under certain condition, also can be to week with caused stench The life of the side people has an impact.
At present according to the difference of control method principle, polluted water body deposit administering method can be divided into Physical, chemical method and Bioanalysis.Physical control method mainly has dredging method and cladding process, and advantage is quick, but quantities is big, and cost is high, and bottom is dwelt The ecosystem has destructiveness, and dredging method is also contemplated that bed mud placement place problem.Chemical method principle is chemical reagent and pollution The reactions such as oxidation, reduction, precipitation, polymerization occur for thing, make pollutant that low stain or pollution-free shape are separated or be converted into from bed mud State, but if the chemical reagent of selection is improper or dosage is inaccurate easily causes secondary pollution.Bioanalysis refers to biological utilisation bed mud In each pollutant carry out metabolic activity so that pollutant concentration is reduced or removed, with first two method compared with cost it is low, It is small to original ecology influence, do not produce the advantages of secondary pollution substantially, therefore be rapidly developed.
The content of the invention
The invention aims to overcome the shortcomings of the above and provide a kind of special repair materials of mercury and Its preparation technology.
Technical scheme includes:A kind of special repair materials of mercury and its preparation technology, raw material group It is made up of in parts by weight following ratio into composition:Medical stone 20-30 parts, zeolite powder 10-20 parts, molecular sieve 6-12 parts, silicic acid Sodium 4-6 parts, fiber-ball filter media 7-11 parts, bentonite 20-25 parts, 2mg/L polyacrylamide solution 6-10 parts, wood chip 30-40 parts, Humus 10-20 parts, composite flora 6-8 parts, deionized water 60-80 parts.
Further improvement of the present invention is:The composite flora includes photosynthetic bacteria group, lactobacillus, yeast flora, leather Lan Shi positives actinomycete group and thread flora.
Further improvement of the present invention is:Its preparation method is as follows:
A, under normal temperature and pressure, medical stone, zeolite powder, fiber-ball filter media and wood chip is carried out to beat powder, carry out high-temperature activation processing, temperature Degree is set to 230-280 DEG C, pressure 1.3-1.5Mpa, adds in deionized water after carrying out immersion 36-40h, under aerobic condition Composite flora is put into, oxygenic aeration is carried out, obtains mixture A;
B, molecular sieve, sodium metasilicate, bentonite are stirred, add humus and appropriate 2mg/L polyacrylamide solutions, stirring Speed is 480-600r/min, is soaked 1-2 days after stirring, add mixture A be stirred, be evenly stirred until it is thick after Obtain product, stir speed (S.S.) 230-320r/min.
Beneficial effects of the present invention:Material of the present invention is easy to get, nutritious in medical stone and zeolite, discharges nutrition, improves Organism in water survival rate, surface have cellular, effective absorbing heavy metal ions in water, benefit can be effectively carried out using composite flora Raw bacterium breeding, removes harmful substance and excessive sulfide etc. in water, and is formed and be solidified on surface with other materials, clear from inside Clean mud, effectively discharges dissolved oxygen, to nutrient needed for biology offer.
Embodiment:
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described, and the embodiment is only used In explaining the present invention, it is not intended to limit the scope of the present invention..
Embodiment 1
A kind of special repair materials of mercury and its preparation technology, raw material constituent is in parts by weight by following ratio Composition:25 parts of medical stone, 18 parts of zeolite powder, 10 parts of molecular sieve, 5 parts of sodium metasilicate, 10 parts of fiber-ball filter media, 23 parts of bentonite, 8 parts of 2mg/L polyacrylamide solutions, 36 parts of wood chip, 14 parts of humus, 7 parts of composite flora, 75 parts of deionized water.
Its preparation method is as follows:
A, under normal temperature and pressure, medical stone, zeolite powder, fiber-ball filter media and wood chip is carried out to beat powder, carry out high-temperature activation processing, temperature Degree is set to 250 DEG C, pressure 1.4Mpa, adds in deionized water after carrying out immersion 40h, compound bacteria is put under aerobic condition Group, oxygenic aeration is carried out, obtains mixture A;
B, molecular sieve, sodium metasilicate, bentonite are stirred, add humus and appropriate 2mg/L polyacrylamide solutions, stirring Speed is 560r/min, is soaked 2 days after stirring, add mixture A be stirred, be evenly stirred until it is thick after must produce Thing, stir speed (S.S.) 300r/min.
Embodiment 2
A kind of special repair materials of mercury and its preparation technology, raw material constituent is in parts by weight by following ratio Composition:20 parts of medical stone, 20 parts of zeolite powder, 6 parts of molecular sieve, 6 parts of sodium metasilicate, 7 parts of fiber-ball filter media, 25 parts of bentonite, 2mg/ 6 parts of L polyacrylamide solutions, 40 parts of wood chip, 10 parts of humus, 8 parts of composite flora, 60 parts of deionized water.
Its preparation method is as follows:
A, under normal temperature and pressure, medical stone, zeolite powder, fiber-ball filter media and wood chip is carried out to beat powder, carry out high-temperature activation processing, temperature Degree is set to 230 DEG C, pressure 1.5Mpa, adds in deionized water after carrying out immersion 36h, compound bacteria is put under aerobic condition Group, oxygenic aeration is carried out, obtains mixture A;
B, molecular sieve, sodium metasilicate, bentonite are stirred, add humus and appropriate 2mg/L polyacrylamide solutions, stirring Speed is 600r/min, is soaked 1 day after stirring, add mixture A be stirred, be evenly stirred until it is thick after must produce Thing, stir speed (S.S.) 320r/min.
Embodiment 3
A kind of special repair materials of mercury and its preparation technology, raw material constituent is in parts by weight by following ratio Composition:30 parts of medical stone, 10 parts of zeolite powder, 12 parts of molecular sieve, 4 parts of sodium metasilicate, 11 parts of fiber-ball filter media, 20 parts of bentonite, 10 parts of 2mg/L polyacrylamide solutions, 30 parts of wood chip, 20 parts of humus, 6 parts of composite flora, 80 parts of deionized water.
Its preparation method is as follows:
A, under normal temperature and pressure, medical stone, zeolite powder, fiber-ball filter media and wood chip is carried out to beat powder, carry out high-temperature activation processing, temperature Degree is set to 280 DEG C, pressure 1.3Mpa, adds in deionized water after carrying out immersion 40h, compound bacteria is put under aerobic condition Group, oxygenic aeration is carried out, obtains mixture A;
B, molecular sieve, sodium metasilicate, bentonite are stirred, add humus and appropriate 2mg/L polyacrylamide solutions, stirring Speed is 480r/min, is soaked 2 days after stirring, add mixture A be stirred, be evenly stirred until it is thick after must produce Thing, stir speed (S.S.) 230r/min.
Embodiment 4
A kind of special repair materials of mercury and its preparation technology, raw material constituent is in parts by weight by following ratio Composition:22 parts of medical stone, 18 parts of zeolite powder, 10 parts of molecular sieve, 5 parts of sodium metasilicate, 9 parts of fiber-ball filter media, 23 parts of bentonite, 9 parts of 2mg/L polyacrylamide solutions, 36 parts of wood chip, 14 parts of humus, 7 parts of composite flora, 65 parts of deionized water.
Its preparation method is as follows:
A, under normal temperature and pressure, medical stone, zeolite powder, fiber-ball filter media and wood chip is carried out to beat powder, carry out high-temperature activation processing, temperature Degree is set to 260 DEG C, pressure 1.4Mpa, adds in deionized water after carrying out immersion 38h, compound bacteria is put under aerobic condition Group, oxygenic aeration is carried out, obtains mixture A;
B, molecular sieve, sodium metasilicate, bentonite are stirred, add humus and appropriate 2mg/L polyacrylamide solutions, stirring Speed is 500r/min, is soaked 2 days after stirring, add mixture A be stirred, be evenly stirred until it is thick after must produce Thing, stir speed (S.S.) 280r/min.
In above example, composite flora includes photosynthetic bacteria group, lactobacillus, yeast flora, Gram positive actinomycetes Group and thread flora, embodiment 1 is most preferred embodiment, nutritious, effectively goes to eliminate the unusual smell, and is formed and solidified on riverway sludge top layer Layer, adsorb the nutriment in mud, effective oxygenation.
Explanation embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the technology of this area For personnel, within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., it should be included in Within protection scope of the present invention.

Claims (3)

1. a kind of special repair materials of mercury and its preparation technology, it is characterised in that:Raw material constituent is by weight Number is made up of following ratio:Medical stone 20-30 parts, zeolite powder 10-20 parts, molecular sieve 6-12 parts, sodium metasilicate 4-6 parts, fiber Ball filtering material 7-11 parts, bentonite 20-25 parts, 2mg/L polyacrylamide solution 6-10 parts, wood chip 30-40 parts, humus 10-20 Part, composite flora 6-8 parts, deionized water 60-80 parts.
2. a kind of special repair materials of mercury according to claim 1 and its preparation technology, it is characterised in that: The composite flora includes photosynthetic bacteria group, lactobacillus, yeast flora, Gram positive actinomycetes group and thread flora.
3. a kind of special repair materials of mercury according to claim 1 and its preparation technology, it is characterised in that: Its preparation method is as follows:
A, under normal temperature and pressure, medical stone, zeolite powder, fiber-ball filter media and wood chip is carried out to beat powder, carry out high-temperature activation processing, temperature Degree is set to 230-280 DEG C, pressure 1.3-1.5Mpa, adds in deionized water after carrying out immersion 36-40h, under aerobic condition Composite flora is put into, oxygenic aeration is carried out, obtains mixture A;
B, molecular sieve, sodium metasilicate, bentonite are stirred, add humus and appropriate 2mg/L polyacrylamide solutions, stirring Speed is 480-600r/min, is soaked 1-2 days after stirring, add mixture A be stirred, be evenly stirred until it is thick after Obtain product, stir speed (S.S.) 230-320r/min.
CN201710977593.0A 2017-10-19 2017-10-19 A kind of special repair materials of mercury and its preparation technology Withdrawn CN107473546A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108275785A (en) * 2018-01-23 2018-07-13 刘牧 The application method of micro- oxygen particle of in situ environment microbial acclimation is modified through EM
CN113603319A (en) * 2021-08-16 2021-11-05 中国一冶集团有限公司 Multifunctional bottom mud purifying agent and preparation method and application thereof
CN113860481A (en) * 2021-11-18 2021-12-31 陈雪文 Black and odorous river sediment in-situ repairing agent and preparation and repairing method thereof
CN114262067A (en) * 2021-12-30 2022-04-01 青岛威羽山环保科技有限公司 Point source area water body repairing material and repairing process thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108275785A (en) * 2018-01-23 2018-07-13 刘牧 The application method of micro- oxygen particle of in situ environment microbial acclimation is modified through EM
CN113603319A (en) * 2021-08-16 2021-11-05 中国一冶集团有限公司 Multifunctional bottom mud purifying agent and preparation method and application thereof
CN113860481A (en) * 2021-11-18 2021-12-31 陈雪文 Black and odorous river sediment in-situ repairing agent and preparation and repairing method thereof
CN113860481B (en) * 2021-11-18 2023-09-22 陈雪文 Black and odorous river sediment in-situ repairing agent and preparation and repairing method
CN114262067A (en) * 2021-12-30 2022-04-01 青岛威羽山环保科技有限公司 Point source area water body repairing material and repairing process thereof

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Application publication date: 20171215

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