CN105925825A - Preparation method for high-tenacity efficient Al-Sr intermediate alloy alterant - Google Patents

Preparation method for high-tenacity efficient Al-Sr intermediate alloy alterant Download PDF

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Publication number
CN105925825A
CN105925825A CN201610343391.6A CN201610343391A CN105925825A CN 105925825 A CN105925825 A CN 105925825A CN 201610343391 A CN201610343391 A CN 201610343391A CN 105925825 A CN105925825 A CN 105925825A
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China
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intermediate alloy
preparation
efficient
al4sr
high tenacity
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CN201610343391.6A
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Chinese (zh)
Inventor
李润霞
于宝义
张鹏
张文华
郑黎
任国庆
张琦
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Shenyang University of Technology
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Shenyang University of Technology
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium

Abstract

The invention discloses a preparation method for Al-Sr intermediate alloy wire rods adopting an ultrasonic melt treatment process, additional adding of new alloy elements is not required, and the preparation method is low in cost, easy to operate and practical. Cavitation bubbles are generated in a solution during the ultrasonic melt treatment process, high energy generated by the collapse of the cavitation bubbles has the crushing effect for Al4Sr phases in the Al-Sr intermediate alloy, and the bulky primary Al4Sr phases become fine in size and diffused. In addition, ultrasonic has the effects of degassing, deslagging and purification for purifying a melt. According to a hot extrusion process, the technology of large variable deformation is adopted for refining the Al4Sr phases in the Al-Sr intermediate alloy. According to the preparation method, in the process of preparing a high-tenacity efficient Al-Sr intermediate alloy alterant, the Al4Sr phases are small in size, even in distribution and diffused; and the Al-Sr intermediate alloy alterant has high tenacity and can be rolled to be the wire rods.

Description

A kind of efficient Al-Sr intermediate alloy alterant preparation method of high tenacity
Technical field
The invention belongs to materials processing field, particularly relate to the preparation technology of a kind of Al-Sr intermediate alloy alterant.
Background technology
After the sixties in 20th century is found that Sr has metamorphism, Sr Metamorphism treatment has obtained swift and violent development, and at wheel hub And have also been obtained successfully application on aluminium alloy.Owing to Sr adds scaling loss more seriously with simple substance form, so Sr is generally with Al- Sr intermediate alloy form adds.The method producing Al-Sr intermediate alloy mainly has the method for oozing, thermal reduction and fused salt electrolysis process. And thermal reduction and fused salt electrolysis process also rest on laboratory stage, it is impossible to apply and produce in factory mass, produce oozing method During the scaling loss ratio of strontium more serious, casting yield is low.
At present, it is highly brittle due to common Al-Sr intermediate alloy so that it is the production difficulty of coiled material is very big, only has in the world Very few companies has grasped the production technology of this coiled material.Domestic also do not have to produce Al-Sr intermediate alloy alterant coiled material Enterprise and production line.The Metamorphism treatment of most domestic casting Al-Si alloy product all uses batch (-type) discontinuously to add Al- Sr intermediate alloy block or the way of certain diameter pole stock, thus decrease in production automaticity.Therefore, traditional On the basis of preparation Al-Sr intermediate alloy wire rod, the Al-Sr intermediate alloy wire rod using ultrasound wave melt treatment to prepare can To improve its percentage elongation, prepare the Al-Sr intermediate alloy alterant coiled material with high tenacity, domestic aluminum processing enterprise can be made Al-Sr alloy addition manner obtain breakthrough change, improve further the automated production degree of aluminum processing enterprise, to state People's expanding economy is significant.
Both at home and abroad commercial type Al-Sr intermediate alloy alterant more or less all deposit the most not Foot, particularly stage of incubation is long, the problem that effective metamorphic epoch is short.In Al-Sr intermediate alloy, Sr is generally with intermetallic compound Presented in Al4Sr, therefore, the stability of Al4Sr phase, i.e. complexity that Sr atom separates out from Al4Sr middle reaches and expansion Dissipate speed and its modification effect will be played the important effect of producing, and the stability of Al4Sr phase and its form, size, The factors such as crystal structure are relevant, and therefore we can refine Al-by the preparation or processing technique that control Al-Sr intermediate alloy The tissue morphology of the Al4Sr phase in Sr intermediate alloy.Therefore, on the basis of traditional preparation Al-Sr intermediate alloy wire rod, adopt In the Al-Sr intermediate alloy wire rod prepared by ultrasound wave melt treatment, Al4Sr phase is tiny, disperse and being evenly distributed, and improves The Sr atom of Al-Sr intermediate alloy alterant diffusion velocity in Al-Si alloy, reduces stage of incubation, extends it the most rotten Time.
Summary of the invention
Goal of the invention: the present invention provides the preparation method of the efficient Al-Sr intermediate alloy alterant of a kind of high tenacity.Its mesh Be to obtain that a kind of Al4Sr phase size is tiny, Dispersed precipitate, and the high tenacity Al-Sr intermediate alloy alterant that percentage elongation is high.
Technical scheme:
The present invention is the efficient Al-Sr intermediate alloy alterant preparation method of a kind of high tenacity, and the method includes the steps of:
(1) preparation 3.6kg commercial-purity aluminium, 0.4kg technical pure strontium;
(2) graphite crucible of 5kg capacity is dried, then the commercial-purity aluminium prepared is put into graphite crucible carry out melting, melting Temperature is 790 DEG C, adds technical pure strontium after commercial-purity aluminium is completely melt as aluminum liquid;
(3) after technical pure strontium is completely melt, ultrasound wave melt treatment is used;
(4) stand after, stainless steel tube is inserted aluminum liquid 2/3rds depths lead to argon and slowly do surrounding motion, ventilation 2 ~ 3min, is poured in the mould of preheating after standing certain time, and mould is diameter 128mm, the metal die of high 40mm, and room temperature is cold But molding;
(5) the extruding pad preheating of needs when Al-Sr intermediate alloy ingot step (4) prepared and extruding, by horizontal extruder Pressurizing unit preheats;
(6) using horizontal extruder to extrude the Al-Sr intermediate alloy ingot of preheating, extrusion ratio is 40:1, obtains in the middle of Al-Sr Alloy wire.
In described step (3), use the supersonic frequency 18KHz ~ 22KHz of ultrasound wave melt treatment.
In described step (3), ultrasound wave melt treatment time 10s ~ 60s.
In described step (4), mold preheating temperature 200 DEG C ~ 300 DEG C.
In described step (5), the extruding pad preheating temperature 450 DEG C ~ 500 needed when Al-Sr intermediate alloy ingot and extruding ℃;Horizontal extruder pressurizing unit preheating temperature 300 DEG C ~ 400 DEG C.
In step (1), described technical pure strontium kerosene seals.
Advantage and effect: instant invention overcomes Al4Sr phase size in existing Al-Sr intermediate alloy alterant the thickest, The low problem that can not be rolled into Al-Sr intermediate alloy wire rod of percentage elongation.Provide that a kind of Al4Sr phase size is little, Dispersed precipitate, and Al-Sr intermediate alloy wire rod has high tenacity, can be rolled into the alterant of Al-Sr intermediate alloy wire rod.
Accompanying drawing illustrates:
Fig. 1 is Al-Sr intermediate alloy wire stretching fracture apperance prepared by traditional handicraft;
Fig. 2 is the Al-Sr intermediate alloy wire stretching fracture apperance of embodiment 1 preparation;
Fig. 3 is the Al-Sr intermediate alloy wire stretching fracture apperance of embodiment 2 preparation;
Fig. 4 is Al-Sr intermediate alloy wire microstructure prepared by traditional handicraft;
Fig. 5 is the Al-Sr intermediate alloy wire microstructure of embodiment 1 preparation;
Fig. 6 is the Al-Sr intermediate alloy wire microstructure of embodiment 2 preparation;
Fig. 7 is that ZL102 is gone bad 60min microscopic structure by Al-Sr intermediate alloy wire rod prepared by traditional handicraft;
Fig. 8 is that ZL102 is gone bad 60min microscopic structure by the Al-Sr intermediate alloy wire rod of embodiment 1 preparation;
Fig. 9 is that ZL102 is gone bad 60min microscopic structure by the Al-Sr intermediate alloy wire rod of embodiment 2 preparation.
Detailed description of the invention:
The technological thought of the present invention is to have employed Al-Sr intermediate alloy wire rod prepared by ultrasound wave melt treatment, it is not necessary to Extra add new alloying element, preparation technology low cost, simple to operate, practical.Ultrasound wave melt treatment produces in the solution Cavitation bubble, the effect that Al4Sr phase in Al-Sr intermediate alloy is crushed by the high-energy that the collapse of cavitation bubble produces, make thick Tiny, the disperse that nascent Al4Sr phase size becomes, ultrasound wave plays degasification, removes the gred, purifies the effect purifying melt in addition.Heat Extruding is, by big variable deformation technology, Al4Sr phase in Al-Sr intermediate alloy is played refining effect.A kind of high-ductility of the present invention In the efficient Al-Sr intermediate alloy alterant of property, Al4Sr phase size is little, be evenly distributed, disperse and Al-Sr intermediate alloy alterant There is high tenacity, wire rod can be rolled into.
This preparation method comprises the following steps:
(1) preparation 3.6kg commercial-purity aluminium, 0.4kg technical pure strontium;
(2) graphite crucible of 5kg capacity is dried, then the commercial-purity aluminium prepared is put into graphite crucible carry out melting, melting Temperature is 790 DEG C, adds technical pure strontium after commercial-purity aluminium is completely melt as aluminum liquid;
(3) after technical pure strontium is completely melt, ultrasound wave melt treatment is used;
(4) stand after, stainless steel tube is inserted aluminum liquid 2/3rds depths lead to argon and slowly do surrounding motion, ventilation 2 ~ 3min, is poured in the mould of preheating after standing certain time, and mould is diameter 128mm, the metal die of high 40mm, and room temperature is cold But molding;
(5) the extruding pad preheating of needs when Al-Sr intermediate alloy ingot step (4) prepared and extruding, by horizontal extruder Pressurizing unit preheats;
(6) using horizontal extruder to extrude the Al-Sr intermediate alloy ingot of preheating, extrusion ratio is 40:1, obtains in the middle of Al-Sr Alloy wire.
In described step (3), use the supersonic frequency 18KHz ~ 22KHz of ultrasound wave melt treatment.
In described step (3), ultrasound wave melt treatment time 10s ~ 60s.
In described step (4), mold preheating temperature 200 DEG C ~ 300 DEG C.
In described step (5), the extruding pad preheating temperature 450 DEG C ~ 500 needed when Al-Sr intermediate alloy ingot and extruding ℃;Horizontal extruder pressurizing unit preheating temperature 300 DEG C ~ 400 DEG C.
In step (1), described technical pure strontium kerosene seals.
Further describe in conjunction with present invention, and provide embodiment to further illustrate:
Embodiment 1
(1) preparation 3.6kg commercial-purity aluminium, 0.4kg technical pure strontium (technical pure strontium needs to seal with kerosene);
(2) graphite of 5kg capacity is done pot dry, then the commercial-purity aluminium prepared is put into graphite do pot and carry out melting, melting Temperature is 790 DEG C, adds technical pure strontium after commercial-purity aluminium is completely melt as aluminum liquid;
(3) after technical pure strontium is completely melt, use ultrasonic frequency in 20KHZ ultrasound wave melt treatment;
(4) ultrasound wave melt treatment time 30s;
(5) stand after, then import stainless steel tube insert aluminum liquid 2/3rds depths lead to argon and slowly do surrounding motion, ventilation 2 ~ 3min, is poured in the mould of preheating after standing certain time at once, and mold preheating temperature 260 DEG C, die size is diameter 128mm, the metal type dies of high 40mm.Room temperature cooling molding;
(6) the extruding pad preheating needed when will prepare Al-Sr intermediate alloy ingot with extruding, preheats temperature 490 DEG C, horizontal crowded Press ram preheats, and preheats temperature 350 DEG C;
(7) using horizontal extruder to extrude the Al-Sr intermediate alloy ingot of preheating, extrusion ratio is 40:1, a range of Extrusion ratio, is squeezed into Al-Sr intermediate alloy wire rod;
Prepared Al-Sr intermediate alloy wire rod is carried out Mechanics Performance Testing and microstructure observation, finds and traditional handicraft Comparing, Al-Sr intermediate alloy wire rod percentage elongation improves 5.25%, and in Al-Sr intermediate alloy, Al4Sr phase is more tiny, disperse and It is evenly distributed.
Embodiment 2
(1) preparation 3.6kg commercial-purity aluminium, 0.4kg technical pure strontium (technical pure strontium needs to seal with kerosene);
(2) graphite crucible of 5kg capacity is dried, then the commercial-purity aluminium prepared is put into graphite crucible carry out melting, melting Temperature is 790 DEG C, adds technical pure strontium after commercial-purity aluminium is completely melt as aluminum liquid;
(3) after technical pure strontium is completely melt, use ultrasonic frequency in 22KHz ultrasound wave melt treatment;
(4) ultrasound wave melt treatment time 30s;
(5) stand after, then import stainless steel tube insert aluminum liquid 2/3rds depths lead to argon and slowly do surrounding motion, ventilation 2 ~ 3min, is poured in the mould of preheating after standing certain time at once, and mold preheating temperature 260 DEG C, die size is diameter 128mm, the metal type dies of high 40mm.Room temperature cooling molding;
(6) the extruding pad preheating needed when will prepare Al-Sr intermediate alloy ingot with extruding, preheats temperature 490 DEG C, horizontal crowded Press ram preheats, and preheats temperature 350 DEG C;
(7) using horizontal extruder to extrude the Al-Sr intermediate alloy ingot of preheating, extrusion ratio is 40:1, a range of Extrusion ratio, is squeezed into Al-Sr intermediate alloy wire rod;
Prepared Al-Sr intermediate alloy wire rod is carried out Mechanics Performance Testing and microstructure observation, finds and traditional handicraft Comparing, Al-Sr intermediate alloy wire rod percentage elongation improves 7.56%, has high tenacity, can be rolled into Al-Sr intermediate alloy coiled material; Additionally, prepare the more tiny of Al4Sr phase transformation in Al-Sr intermediate alloy wire rod, in fine particle shape, it is evenly distributed, its equivalence Radius of circle is 20.3um.
Al-Sr intermediate alloy alterant prepared by the present invention compared with other prior aries, Al-Sr intermediate alloy alterant Percentage elongation be improved significantly so that Al-Sr intermediate alloy crimps rolling in process of production and uses, thus improves centre The serviceability of alloy.Meanwhile, such Al-Sr intermediate alloy also improves the modification effect to Al-Si alloy, shortens The rotten stage of incubation of Al-Si alloy.Wherein in Al-Sr intermediate alloy Sr generally presented in intermetallic compound Al4Sr, Therefore, the stability of Al4Sr phase, i.e. it will be gone bad by complexity and diffusion velocity that Sr atom separates out from Al4Sr middle reaches Playing of effect produces important effect, and the stability of Al4Sr phase and its form, size, crystal structure etc. are because have Close.In Al-Sr intermediate alloy alterant prepared by the present invention, Al4Sr phase is tiny, disperse and being evenly distributed, and its percentage elongation obtains Significantly improve, the most also improve Sr diffusion velocity in the melt, shorten the rotten stage of incubation of Al-Si alloy so that it is become Matter effect is significantly improved.

Claims (6)

1. the efficient Al-Sr intermediate alloy alterant preparation method of a high tenacity, it is characterised in that: the method comprises following step Rapid:
(1) preparation 3.6kg commercial-purity aluminium, 0.4kg technical pure strontium;
(2) graphite crucible of 5kg capacity is dried, then the commercial-purity aluminium prepared is put into graphite crucible carry out melting, melting Temperature is 790 DEG C, adds technical pure strontium after commercial-purity aluminium is completely melt as aluminum liquid;
(3) after technical pure strontium is completely melt, ultrasound wave melt treatment is used;
(4) stand after, stainless steel tube is inserted aluminum liquid 2/3rds depths lead to argon and slowly do surrounding motion, ventilation 2 ~ 3min, is poured in the mould of preheating after standing certain time, and mould is diameter 128mm, the metal die of high 40mm, and room temperature is cold But molding;
(5) the extruding pad preheating of needs when Al-Sr intermediate alloy ingot step (4) prepared and extruding, by horizontal extruder Pressurizing unit preheats;
(6) using horizontal extruder to extrude the Al-Sr intermediate alloy ingot of preheating, extrusion ratio is 40:1, obtains in the middle of Al-Sr Alloy wire.
The efficient Al-Sr intermediate alloy alterant preparation method of high tenacity the most according to claim 1, it is characterised in that: In described step (3), use the supersonic frequency 18KHz ~ 22KHz of ultrasound wave melt treatment.
The efficient Al-Sr intermediate alloy alterant preparation method of high tenacity the most according to claim 1, it is characterised in that: In described step (3), ultrasound wave melt treatment time 10s ~ 60s.
The efficient Al-Sr intermediate alloy alterant preparation method of high tenacity the most according to claim 1, it is characterised in that: In described step (4), mold preheating temperature 200 DEG C ~ 300 DEG C.
The efficient Al-Sr intermediate alloy alterant preparation method of high tenacity the most according to claim 1, it is characterised in that: In described step (5), the extruding pad preheating temperature 450 DEG C ~ 500 DEG C needed when Al-Sr intermediate alloy ingot and extruding;Horizontal crowded Press ram preheating temperature 300 DEG C ~ 400 DEG C.
The efficient Al-Sr intermediate alloy alterant preparation method of high tenacity the most according to claim 1, it is characterised in that: In step (1), described technical pure strontium kerosene seals.
CN201610343391.6A 2016-05-23 2016-05-23 Preparation method for high-tenacity efficient Al-Sr intermediate alloy alterant Pending CN105925825A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109112366A (en) * 2018-10-29 2019-01-01 长春工业大学 A kind of processing method of aluminum-silicon alloy alterative
CN115141945A (en) * 2022-08-01 2022-10-04 立中四通轻合金集团股份有限公司 Preparation method of aluminum-strontium intermediate alloy coiled material with strontium content of more than 10wt%

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104195385A (en) * 2014-08-29 2014-12-10 沈阳工业大学 Permanent modifier capable of improving electrical conductivity of hypo eutectic Al-Si alloy as well as preparation method and using method of permanent modifier
CN104711440A (en) * 2015-04-09 2015-06-17 芜湖永裕汽车工业有限公司 Preparation technique of aluminum-strontium alloy modifier
CN104942242A (en) * 2015-06-01 2015-09-30 江苏新创雄铝制品有限公司 Dual grain refinement method for automobile aluminum alloy hub

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104195385A (en) * 2014-08-29 2014-12-10 沈阳工业大学 Permanent modifier capable of improving electrical conductivity of hypo eutectic Al-Si alloy as well as preparation method and using method of permanent modifier
CN104711440A (en) * 2015-04-09 2015-06-17 芜湖永裕汽车工业有限公司 Preparation technique of aluminum-strontium alloy modifier
CN104942242A (en) * 2015-06-01 2015-09-30 江苏新创雄铝制品有限公司 Dual grain refinement method for automobile aluminum alloy hub

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109112366A (en) * 2018-10-29 2019-01-01 长春工业大学 A kind of processing method of aluminum-silicon alloy alterative
CN115141945A (en) * 2022-08-01 2022-10-04 立中四通轻合金集团股份有限公司 Preparation method of aluminum-strontium intermediate alloy coiled material with strontium content of more than 10wt%
CN115141945B (en) * 2022-08-01 2023-10-31 立中四通轻合金集团股份有限公司 Preparation method of aluminum-strontium intermediate alloy coiled material with strontium content being more than 10wt%

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Application publication date: 20160907