CN105924589A - 一种抗紫外线隔热防辐射的pet膜及其制备方法 - Google Patents

一种抗紫外线隔热防辐射的pet膜及其制备方法 Download PDF

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CN105924589A
CN105924589A CN201610471359.6A CN201610471359A CN105924589A CN 105924589 A CN105924589 A CN 105924589A CN 201610471359 A CN201610471359 A CN 201610471359A CN 105924589 A CN105924589 A CN 105924589A
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周开雄
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Abstract

本发明涉及一种抗紫外线隔热防辐射的PET膜及其制备方法，本PET膜由如下重量份的原料组成：PET聚酯切片50‑100份、甲氧基乙酸丙酯2‑10份、丙烯酸乙酯2‑10份、双(2,2,6,6‑四甲基‑4‑哌啶基)癸二酸酯1‑20份、双苯并噁唑0.1‑20份、纳米二氧化钛5‑20份、RC‑E60无硅离型剂1‑10份、HANKINS NCP‑2 0.1‑4份、2‑(2‑羟基‑3‑叔丁基‑5‑甲基苯基)‑5‑氯代苯并三唑3‑20份。本发明制备的PET膜，能够阻隔99.0％以上的波长为290nm‑400nm的紫外线，本PET膜不仅透明，而且还具备抗紫外线、隔热、防辐射的功能，效果优异。

Description

一种抗紫外线隔热防辐射的PET膜及其制备方法
技术领域
本发明涉及一种抗紫外线隔热防辐射的PET膜及其制备方法，属于高分子材料技术领域。
背景技术
PET膜又名膜耐高温聚酯薄膜。它具有优异的物理性能、化学性能及尺寸稳定性、透明性、可回收性，可广泛的应用于磁记录、感光材料、电子、电气绝缘、工业用膜、包装装饰等领域。
紫外线按波长可分为短波区(即UVC：200nm-290nm)、中波区(即UVB：290nm-320nm)和长波区(即UVA：320nm-400nm)。现有技术中，具备抗紫外线功能的工业材料很少，现有技术中一种叫做太阳膜的抗紫外线保护膜，它的抗紫外线功能是通过将具备抗紫外线功能的材料溅射在薄膜上，这类材料一般都是有色金属材料或是无机物。溅射在无色透明的PET薄膜上，薄膜就会呈现出有色金属的颜色，如此会影响薄膜的透过率和雾度，影响视觉效果。如专利CN103057225A、CN 102837460A中所记载的。
发明内容
本发明所要解决的技术问题是提供一种抗紫外线隔热防辐射的PET膜及其制备方法，本发明制备的PET膜，能够阻隔99.0％以上的波长为290nm-400nm的紫外线，本PET膜不仅透明，而且还具备抗紫外线、隔热、防辐射的功能，效果优异。
本发明解决上述技术问题的技术方案如下：一种抗紫外线隔热防辐射的PET膜，由如下重量份的原料组成：
PET聚酯切片50-100份、甲氧基乙酸丙酯2-10份、丙烯酸乙酯2-10份、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯1-20份、双苯并噁唑0.1-20份、纳米二氧化钛5-20份、RC-E60无硅离型剂1-10份、HANKINS NCP-20.1-4份、2-(2-羟基-3-叔丁基-5-甲基苯基)-5-氯代苯并三唑3-20份。
在上述技术方案的基础上，本发明还可以做如下改进。
进一步，所述抗紫外线隔热防辐射的PET膜，由如下重量份的原料组成：
PET聚酯切片100份、甲氧基乙酸丙酯10份、丙烯酸乙酯8份、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯2份、双苯并噁唑2份、纳米二氧化钛5份、RC-E60无硅离型剂4份、HANKINS NCP-2 0.9份、2-(2-羟基-3-叔丁基-5-甲基苯基)-5-氯代苯并三唑10份。
进一步，所述抗紫外线隔热防辐射的PET膜，由如下重量份的原料组成：
PET聚酯切片80份、甲氧基乙酸丙酯7份、丙烯酸乙酯5份、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯8份、双苯并噁唑4份、纳米二氧化钛6份、RC-E60无硅离型剂5份、HANKINS NCP-2 2份、2-(2-羟基-3-叔丁基-5-甲基苯基)-5-氯代苯并三唑10份。
本发明还提供一种抗紫外线隔热防辐射的PET膜的制备方法，包括：
1)称取如下重量份数的原料：
PET聚酯切片50-100份、甲氧基乙酸丙酯2-10份、丙烯酸乙酯2-10份、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯1-20份、双苯并噁唑0.1-20份、纳米二氧化钛5-20份、RC-E60无硅离型剂1-10份、HANKINS NCP-20.1-4份、2-(2-羟基-3-叔丁基-5-甲基苯基)-5-氯代苯并三唑3-20份，
2)向反应釜中加入PET聚酯切片、纳米二氧化钛、RC-E60无硅离型剂和HANKINS NCP-2，在50-105℃，以每分钟150-200rpm的转速搅拌5-30min，得混合物；
3)向反应釜中加入甲氧基乙酸丙酯、丙烯酸乙酯、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯和双苯并噁唑，将反应釜内温度升至200-300℃，压力降至60-90pa以下，反应2-3h，得到聚合熔体，将聚合熔体挤出、切粒、干燥，得到聚酯切片，将聚酯切片熔融挤出、横向拉伸、纵向拉伸，得到PET膜。
在上述技术方案的基础上，本发明还可以做如下改进。
进一步，在步骤3)中，所述干燥的温度为85-200℃，干燥时间为0.1-20小时。
进一步，在步骤3)中，所述熔融挤出温度为250-300℃，所述横向拉伸和纵向拉伸的温度为90-150℃。
本发明的有益效果是：
本发明制备的PET膜，能够阻隔99.0％以上的波长为290nm-400nm的紫外线，本PET膜不仅透明，而且还具备抗紫外线、隔热、防辐射的功能，效果优异。
具体实施方式
以下对本发明的原理和特征进行描述，所举实例只用于解释本发明，并非用于限定本发明的范围。
实施例中所用RC-E60无硅离型剂购买于东莞市泰昌化工有限公司。
实施例中所用UV-326购自南京米兰化工有限公司。
实施例中所用Tinuvin770购自宜兴市天使合成化学有限公司。
实施例1
1)称取如下重量份数的原料：
PET聚酯切片100份、甲氧基乙酸丙酯10份、丙烯酸乙酯8份、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯(Tinuvin770)2份、双苯并噁唑2份、纳米二氧化钛5份、RC-E60无硅离型剂4份、HANKINS NCP-2 0.9份、2-(2-羟基-3-叔丁基-5-甲基苯基)-5-氯代苯并三唑(UV-326)10份；
2)向反应釜中加入PET聚酯切片、纳米二氧化钛、RC-E60无硅离型剂和HANKINS NCP-2，在105℃，以每分钟150rpm的转速搅拌30min，得混合物；
3)向反应釜中加入甲氧基乙酸丙酯、丙烯酸乙酯、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯和双苯并噁唑，将反应釜内温度升至300℃，压力降至90pa以下，反应3h，得到聚合熔体，将聚合熔体挤出、切粒、200℃干燥2小时，得到聚酯切片，将聚酯切片300℃熔融挤出，150℃横向拉伸和纵向拉伸，得到PET膜。
实施例2
1)称取如下重量份数的原料：
PET聚酯切片80份、甲氧基乙酸丙酯7份、丙烯酸乙酯5份、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯(Tinuvin770)8份、双苯并噁唑4份、纳米二氧化钛6份、RC-E60无硅离型剂5份、HANKINS NCP-2 2份、2-(2-羟基-3-叔丁基-5-甲基苯基)-5-氯代苯并三唑(UV-326)10份；
2)向反应釜中加入PET聚酯切片、纳米二氧化钛、RC-E60无硅离型剂和HANKINS NCP-2，在95℃，以每分钟200rpm的转速搅拌10min，得混合物；
3)向反应釜中加入甲氧基乙酸丙酯、丙烯酸乙酯、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯和双苯并噁唑，将反应釜内温度升至300℃，压力降至60pa以下，反应3h，得到聚合熔体，将聚合熔体挤出、切粒、100℃干燥5小时，得到聚酯切片，将聚酯切片250℃熔融挤出，150℃横向拉伸和纵向拉伸，得到PET膜。
检测实施例1-2制备的PET膜，结果如下表所示：
表1 检测结果
以上所述仅为本发明的较佳实施例，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (6)

1.一种抗紫外线隔热防辐射的PET膜，其特征在于，由如下重量份的原料组成：
PET聚酯切片50-100份、甲氧基乙酸丙酯2-10份、丙烯酸乙酯2-10份、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯1-20份、双苯并噁唑0.1-20份、纳米二氧化钛5-20份、RC-E60无硅离型剂1-10份、HANKINS NCP-20.1-4份、2-(2-羟基-3-叔丁基-5-甲基苯基)-5-氯代苯并三唑3-20份。
2.根据权利要求1所述的PET膜，其特征在于，由如下重量份的原料组成：
PET聚酯切片100份、甲氧基乙酸丙酯10份、丙烯酸乙酯8份、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯2份、双苯并噁唑2份、纳米二氧化钛5份、RC-E60无硅离型剂4份、HANKINS NCP-2 0.9份、2-(2-羟基-3-叔丁基-5-甲基苯基)-5-氯代苯并三唑10份。
3.根据权利要求1所述的PET膜，其特征在于，由如下重量份的原料组成：
PET聚酯切片80份、甲氧基乙酸丙酯7份、丙烯酸乙酯5份、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯8份、双苯并噁唑4份、纳米二氧化钛6份、RC-E60无硅离型剂5份、HANKINS NCP-2 2份、2-(2-羟基-3-叔丁基-5-甲基苯基)-5-氯代苯并三唑10份。
4.一种抗紫外线隔热防辐射的PET膜的制备方法，其特征在于，包括：
1)称取如下重量份数的原料：
PET聚酯切片50-100份、甲氧基乙酸丙酯2-10份、丙烯酸乙酯2-10份、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯1-20份、双苯并噁唑0.1-20份、纳米二氧化钛5-20份、RC-E60无硅离型剂1-10份、HANKINS NCP-20.1-4份、2-(2-羟基-3-叔丁基-5-甲基苯基)-5-氯代苯并三唑3-20份，
2)向反应釜中加入PET聚酯切片、纳米二氧化钛、RC-E60无硅离型剂和HANKINS NCP-2，在50-105℃，以每分钟150-200rpm的转速搅拌5-30min，得混合物；
3)向反应釜中加入甲氧基乙酸丙酯、丙烯酸乙酯、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯和双苯并噁唑，将反应釜内温度升至200-300℃，压力降至60-90pa以下，反应2-3h，得到聚合熔体，将聚合熔体挤出、切粒、干燥，得到聚酯切片，将聚酯切片熔融挤出、横向拉伸、纵向拉伸，得到PET膜。
5.根据权利要求4所述的制备方法，其特征在于，在步骤3)中，所述干燥的温度为85-200℃，干燥时间为0.1-20小时。
6.根据权利要求4或5所述的制备方法，其特征在于，在步骤3)中，所述熔融挤出温度为250-300℃，所述横向拉伸和纵向拉伸的温度为90-150℃。
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103522787A (zh) * 2013-09-29 2014-01-22 太仓市鸿运包装材料有限公司 一种可防紫外线的pet热转移膜及其制备方法
CN104149451A (zh) * 2014-08-01 2014-11-19 苏州袭麟光电科技产业有限公司 一种防紫外线隔热汽车膜
CN104961869A (zh) * 2015-05-29 2015-10-07 吉翔宝（太仓）离型材料科技发展有限公司 一种pet离型膜
CN105542405A (zh) * 2016-02-19 2016-05-04 浙江紫光科技有限公司 一种隔热光学薄膜材料

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103522787A (zh) * 2013-09-29 2014-01-22 太仓市鸿运包装材料有限公司 一种可防紫外线的pet热转移膜及其制备方法
CN104149451A (zh) * 2014-08-01 2014-11-19 苏州袭麟光电科技产业有限公司 一种防紫外线隔热汽车膜
CN104961869A (zh) * 2015-05-29 2015-10-07 吉翔宝（太仓）离型材料科技发展有限公司 一种pet离型膜
CN105542405A (zh) * 2016-02-19 2016-05-04 浙江紫光科技有限公司 一种隔热光学薄膜材料

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