CN105923697A - 多级式光催化臭氧氧化反应器及其光催化剂的制备方法 - Google Patents
多级式光催化臭氧氧化反应器及其光催化剂的制备方法 Download PDFInfo
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- CN105923697A CN105923697A CN201610399849.XA CN201610399849A CN105923697A CN 105923697 A CN105923697 A CN 105923697A CN 201610399849 A CN201610399849 A CN 201610399849A CN 105923697 A CN105923697 A CN 105923697A
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- 239000011941 photocatalyst Substances 0.000 title claims abstract description 54
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- 239000002351 wastewater Substances 0.000 claims abstract description 35
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 18
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- 239000004408 titanium dioxide Substances 0.000 claims abstract description 9
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 8
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims abstract description 8
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- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 7
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims abstract description 7
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims abstract description 6
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims abstract description 6
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005751 Copper oxide Substances 0.000 claims abstract description 4
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 claims abstract description 4
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 4
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 210000002583 cell-derived microparticle Anatomy 0.000 claims description 47
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- 238000005453 pelletization Methods 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
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- 230000015556 catabolic process Effects 0.000 description 6
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- 230000000694 effects Effects 0.000 description 5
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- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 4
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
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- FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 description 1
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- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
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- 238000003911 water pollution Methods 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
-
- B01J35/39—
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Catalysts (AREA)
- Physical Water Treatments (AREA)
Abstract
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CN201610399849.XA CN105923697B (zh) | 2016-06-08 | 2016-06-08 | 多级式光催化臭氧氧化反应器及其光催化剂的制备方法 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106881109A (zh) * | 2017-02-20 | 2017-06-23 | 叶华天 | 一种处理高浓度化工污水的催化氧化剂及其制备方法 |
CN107029526A (zh) * | 2017-05-03 | 2017-08-11 | 南京工大环境科技有限公司 | 一种焚烧尾气脱硝与脱二噁英一体化深度处理工艺 |
CN107051471A (zh) * | 2017-02-20 | 2017-08-18 | 叶华天 | 一种处理含酚类、硝基苯污水的催化剂及其制备方法 |
CN108046495A (zh) * | 2018-01-16 | 2018-05-18 | 辽宁省环境科学研究院 | 一种污水深度处理装置及方法 |
CN108751545A (zh) * | 2018-07-06 | 2018-11-06 | 广东益诺欧环保股份有限公司 | 一种处理含游离氯废水的方法和系统 |
CN116462373A (zh) * | 2023-05-25 | 2023-07-21 | 长江生态环保集团有限公司 | 一种复合型污水处理厂污染负荷应急处理方法 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1200959A (zh) * | 1998-04-10 | 1998-12-09 | 中国科学院感光化学研究所 | 可磁分离的光催化剂及其制法 |
JP2000300998A (ja) * | 1999-04-16 | 2000-10-31 | Tao:Kk | 立体光触媒装置 |
CN1513595A (zh) * | 2003-07-28 | 2004-07-21 | 西南石油学院 | 吸附—光催化剂及其制备方法 |
CN101982237A (zh) * | 2010-09-20 | 2011-03-02 | 中国海洋石油总公司 | 一种处理炼油废水臭氧催化氧化催化剂的制法 |
CN102029165A (zh) * | 2010-11-09 | 2011-04-27 | 中国海洋石油总公司 | 一种处理焦化废水的臭氧催化氧化催化剂的制备方法 |
CN103086469A (zh) * | 2013-02-19 | 2013-05-08 | 江苏大地益源环境修复有限公司 | 一种高效光催化水处理方法与装置 |
CN203392892U (zh) * | 2013-08-15 | 2014-01-15 | 陕西理工学院 | 一种光催化磁性无机吸附电镀废水处理装置 |
CN205803050U (zh) * | 2016-06-08 | 2016-12-14 | 鞍山市亿方环境科技有限公司 | 一种多级式光催化臭氧氧化反应器 |
-
2016
- 2016-06-08 CN CN201610399849.XA patent/CN105923697B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1200959A (zh) * | 1998-04-10 | 1998-12-09 | 中国科学院感光化学研究所 | 可磁分离的光催化剂及其制法 |
JP2000300998A (ja) * | 1999-04-16 | 2000-10-31 | Tao:Kk | 立体光触媒装置 |
CN1513595A (zh) * | 2003-07-28 | 2004-07-21 | 西南石油学院 | 吸附—光催化剂及其制备方法 |
CN101982237A (zh) * | 2010-09-20 | 2011-03-02 | 中国海洋石油总公司 | 一种处理炼油废水臭氧催化氧化催化剂的制法 |
CN102029165A (zh) * | 2010-11-09 | 2011-04-27 | 中国海洋石油总公司 | 一种处理焦化废水的臭氧催化氧化催化剂的制备方法 |
CN103086469A (zh) * | 2013-02-19 | 2013-05-08 | 江苏大地益源环境修复有限公司 | 一种高效光催化水处理方法与装置 |
CN203392892U (zh) * | 2013-08-15 | 2014-01-15 | 陕西理工学院 | 一种光催化磁性无机吸附电镀废水处理装置 |
CN205803050U (zh) * | 2016-06-08 | 2016-12-14 | 鞍山市亿方环境科技有限公司 | 一种多级式光催化臭氧氧化反应器 |
Non-Patent Citations (1)
Title |
---|
赵景联等: "磁性纳米TiO_2/Al_2O_3/Fe_3O_4光催化剂的制备及性能研究", 《西安交通大学学报》 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106881109A (zh) * | 2017-02-20 | 2017-06-23 | 叶华天 | 一种处理高浓度化工污水的催化氧化剂及其制备方法 |
CN107051471A (zh) * | 2017-02-20 | 2017-08-18 | 叶华天 | 一种处理含酚类、硝基苯污水的催化剂及其制备方法 |
CN107029526A (zh) * | 2017-05-03 | 2017-08-11 | 南京工大环境科技有限公司 | 一种焚烧尾气脱硝与脱二噁英一体化深度处理工艺 |
CN108046495A (zh) * | 2018-01-16 | 2018-05-18 | 辽宁省环境科学研究院 | 一种污水深度处理装置及方法 |
CN108751545A (zh) * | 2018-07-06 | 2018-11-06 | 广东益诺欧环保股份有限公司 | 一种处理含游离氯废水的方法和系统 |
CN116462373A (zh) * | 2023-05-25 | 2023-07-21 | 长江生态环保集团有限公司 | 一种复合型污水处理厂污染负荷应急处理方法 |
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