CN105922417A - Treating agent with high water resistance for bamboo-plaited articles and preparation method of treating agent - Google Patents
Treating agent with high water resistance for bamboo-plaited articles and preparation method of treating agent Download PDFInfo
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- CN105922417A CN105922417A CN201610345057.4A CN201610345057A CN105922417A CN 105922417 A CN105922417 A CN 105922417A CN 201610345057 A CN201610345057 A CN 201610345057A CN 105922417 A CN105922417 A CN 105922417A
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- treating agent
- silica sol
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K9/00—Chemical or physical treatment of reed, straw, or similar material
- B27K9/002—Cane, bamboo
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a treating agent with high water resistance for bamboo-plaited articles. The treating agent is prepared from the following raw materials in parts by weight: 10-15 parts of corn starch, 10-15 parts of a water borne polyurethane emulsion, 6-8 parts of a PVDF emulsion, 2-4 parts of nanometer barite powder, 1-2 parts of maleic anhydride, 3-5 parts of 25-30% hydrogen peroxide, 1-2 parts of polydimethylsiloxane, 0.1-0.2 part of starch sodium octenylsuccinate, 10-15 parts of a silica sol modifier and 40-50 parts of water. The treating agent for the bamboo-plaited articles, provided by the invention, not only can effectively improve the dyeing property of the bamboo-plaited articles, can prevent cross color and color loss, and has a strong color fixation performance, but also can play a favorable protection role on the surfaces of the bamboo-plaited articles, can reduce color fading and losing, is strong in adhesion, excellent in water resistance, long in service life, wide in application range and strong in practicability, and is environment-friendly.
Description
Technical field
The present invention relates to bamboo weaving inorganic agent technical field, particularly relate to a kind of high water-fast bamboo weaving inorganic agent and preparation method thereof.
Background technology
Bamboo weaving is to cut open with Phyllostachys pubescens Mazei ex H.de Lebaie on mountain to be split into thin bamboo strip or thin bamboo strip silk the various apparatus being woven into and artware.Bamboo handicraft is of long standing and well established, abundant raw material, and its goods are of a great variety, productive life articles for use can be used for, be convenient for people to daily use, moreover it is possible to make high-grade bamboo weaving art product, for artistic appreciation and collection, having great practical value and artistic value, market prospect is the most wide.But, it is commonly encountered the problem altering normal complexion race color during bamboo plaited article colouring, affects its aesthetic property and artistry, increase difficulty of processing.Woven products is also easy to fade the problem such as fade simultaneously, and its water resistance is poor, easily makes moist, goes mouldy, and affects serviceability and the ornamental value of bamboo plaited article.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of high water-fast bamboo weaving inorganic agent and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of high water-fast bamboo weaving inorganic agent, it is to be prepared by the raw material of following weight parts:
Corn starch 10-15, aqueous polyurethane emulsion 10-15, PVDF emulsion 6-8, nano-barite powder 2-4, maleic anhydride 1-2,25-30% hydrogen peroxide 3-5, dimethicone 1-2, starch sodium octenyl succinate 0.1-0.2, silica sol modified dose of 10-15, water 40-50；
The most silica sol modified dose is prepared by the raw materials in: Ludox 5-10, Silane coupling reagent KH-570 0.1-0.2, castor oil polyoxyethylene ether 0.1-0.2, dimethyl diallyl ammonium chloride 0.5-1, sorbitol 0.5-1, citric acid 0.1-0.2, water 5-10；The preparation method of silica sol modified dose is castor oil polyoxyethylene ether, dimethyl diallyl ammonium chloride and Silane coupling reagent KH-570 to be added to the water 1000-1500r/min jointly stir 5-10min, it is subsequently adding Ludox 50-60 DEG C stirring 0.5-1h, add after cooling after remaining raw material is completely dissolved and stir, to obtain final product.
The preparation method of a kind of high water-fast bamboo weaving inorganic agent, comprises the following steps:
(1) corn starch and maleic anhydride are added to the water prior to 80-90 DEG C of stirring 1-2h, then temperature are adjusted to 50-60 DEG C, add 25-30% hydrogen peroxide, PVDF emulsion and silica sol modified dose of stirring 2-4h, after cooling, obtain modified starch colloidal sol；
(2) prior to 60-80 DEG C of mixing 5-10min after nano-barite powder, dimethicone and starch sodium octenyl succinate being mixed, then 10-15min is stirred with the modified starch colloidal sol mixing 1000-1500r/min in (1), it is eventually adding remaining raw material stirring uniform, after filtration, i.e. obtains high water-fast bamboo weaving inorganic agent.
The invention have the advantage that
The present invention prepares silica sol modified dose by dimethyl diallyl ammonium chloride and silane coupler to silica sol modified, compound with maleic anhydride modified starch, it is effectively improved dyestuff to the dyeing ability of bamboo weaving and fixation performance, and combine the interpolation of remaining raw material, make the bamboo weaving inorganic agent obtained can not only be effectively improved the dyeability of bamboo weaving, anti-colour contamination, run color, color pull-out capacity is strong, and the surface of bamboo weaving can be played a good protection, reducing fades fades, adhesive force is strong, water resistance is good, service life is long, applied range, environmental protection, practical.
Detailed description of the invention
A kind of high water-fast bamboo weaving inorganic agent, it is to be prepared by the raw material of following weight parts:
Corn starch 10, aqueous polyurethane emulsion 10, PVDF emulsion 6, nano-barite powder 2, maleic anhydride 1,25% hydrogen peroxide 3, dimethicone 1, starch sodium octenyl succinate 0.1, silica sol modified dose 10, water 40；
The most silica sol modified dose is prepared by the raw materials in: Ludox 5, silane coupler KH570 0.1, castor oil polyoxyethylene ether 0.1, dimethyl diallyl ammonium chloride 0.5, sorbitol 0.5, citric acid 0.1, water 5；The preparation method of silica sol modified dose is castor oil polyoxyethylene ether, dimethyl diallyl ammonium chloride and silane coupler KH570 to be added to the water 1000r/min jointly stir 5min, it is subsequently adding Ludox 50 DEG C stirring 0.5h, add after cooling after remaining raw material is completely dissolved and stir, to obtain final product.
The preparation method of a kind of high water-fast bamboo weaving inorganic agent, comprises the following steps:
(1) corn starch and maleic anhydride are added to the water prior to 80 DEG C of stirring 1h, then temperature are adjusted to 50 DEG C, add 25% hydrogen peroxide, PVDF emulsion and silica sol modified dose of stirring 2h, after cooling, obtain modified starch colloidal sol；
(2) prior to 60 DEG C of mixing 5min after nano-barite powder, dimethicone and starch sodium octenyl succinate being mixed, then 10min is stirred with the modified starch colloidal sol mixing 1000r/min in (1), it is eventually adding remaining raw material stirring uniform, after filtration, i.e. obtains high water-fast bamboo weaving inorganic agent.
In above-mentioned prepared bamboo weaving inorganic agent, add appropriate dyestuff mix homogeneously, then bamboo weaving material is carried out immersion treatment, and the driest.During inspection, firmly come and go wiping 10 times with the absorbent carbasus being impregnated with 65% ethanol at the bamboo weaving material surface after the process of above-mentioned inorganic agent, without decolouring phenomenon.
Resistance to water (24h): do not bubble, obscission.
Claims (2)
1. one kind high water-fast bamboo weaving inorganic agent, it is characterised in that it is to be prepared by the raw material of following weight parts:
Corn starch 10-15, aqueous polyurethane emulsion 10-15, PVDF emulsion 6-8, nano-barite powder 2-4, maleic anhydride 1-2,25-30% hydrogen peroxide 3-5, dimethicone 1-2, starch sodium octenyl succinate 0.1-0.2, silica sol modified dose of 10-15, water 40-50；
Described silica sol modified dose is prepared by the raw materials in: Ludox 5-10, Silane coupling reagent KH-570 0.1-0.2, castor oil polyoxyethylene ether 0.1-0.2, dimethyl diallyl ammonium chloride 0.5-1, sorbitol 0.5-1, citric acid 0.1-0.2, water 5-10；The preparation method of silica sol modified dose is castor oil polyoxyethylene ether, dimethyl diallyl ammonium chloride and Silane coupling reagent KH-570 to be added to the water 1000-1500r/min jointly stir 5-10min, it is subsequently adding Ludox 50-60 DEG C stirring 0.5-1h, add after cooling after remaining raw material is completely dissolved and stir, to obtain final product.
The preparation method of a kind of high water-fast bamboo weaving inorganic agent the most according to claim 1, it is characterised in that comprise the following steps:
(1) corn starch and maleic anhydride are added to the water prior to 80-90 DEG C of stirring 1-2h, then temperature are adjusted to 50-60 DEG C, add 25-30% hydrogen peroxide, PVDF emulsion and silica sol modified dose of stirring 2-4h, after cooling, obtain modified starch colloidal sol；
(2) prior to 60-80 DEG C of mixing 5-10min after nano-barite powder, dimethicone and starch sodium octenyl succinate being mixed, then 10-15min is stirred with the modified starch colloidal sol mixing 1000-1500r/min in (1), it is eventually adding remaining raw material stirring uniform, after filtration, i.e. obtains high water-fast bamboo weaving inorganic agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610345057.4A CN105922417A (en) | 2016-05-24 | 2016-05-24 | Treating agent with high water resistance for bamboo-plaited articles and preparation method of treating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610345057.4A CN105922417A (en) | 2016-05-24 | 2016-05-24 | Treating agent with high water resistance for bamboo-plaited articles and preparation method of treating agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105922417A true CN105922417A (en) | 2016-09-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610345057.4A Pending CN105922417A (en) | 2016-05-24 | 2016-05-24 | Treating agent with high water resistance for bamboo-plaited articles and preparation method of treating agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108189192A (en) * | 2017-12-30 | 2018-06-22 | 黄旭东 | A kind of artificial board of straw |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104139426A (en) * | 2014-06-30 | 2014-11-12 | 索菲亚家居股份有限公司 | Manufacturing method of arc door |
-
2016
- 2016-05-24 CN CN201610345057.4A patent/CN105922417A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104139426A (en) * | 2014-06-30 | 2014-11-12 | 索菲亚家居股份有限公司 | Manufacturing method of arc door |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108189192A (en) * | 2017-12-30 | 2018-06-22 | 黄旭东 | A kind of artificial board of straw |
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Application publication date: 20160907 |