CN105914218B - Gallium nitride based light emitting diode structure of integrated amplifier and preparation method thereof - Google Patents

Gallium nitride based light emitting diode structure of integrated amplifier and preparation method thereof Download PDF

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CN105914218B
CN105914218B CN201610385080.6A CN201610385080A CN105914218B CN 105914218 B CN105914218 B CN 105914218B CN 201610385080 A CN201610385080 A CN 201610385080A CN 105914218 B CN105914218 B CN 105914218B
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gallium nitride
layer
gan
light emitting
emitting diode
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CN105914218A (en
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徐明升
王洪
周泉斌
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South China University of Technology SCUT
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/15Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components with at least one potential-jump barrier or surface barrier specially adapted for light emission
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66446Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET]
    • H01L29/66462Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET] with a heterojunction interface channel or gate, e.g. HFET, HIGFET, SISFET, HJFET, HEMT
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/778Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
    • H01L29/7786Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with direct single heterostructure, i.e. with wide bandgap layer formed on top of active layer, e.g. direct single heterostructure MIS-like HEMT
    • H01L29/7787Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with direct single heterostructure, i.e. with wide bandgap layer formed on top of active layer, e.g. direct single heterostructure MIS-like HEMT with wide bandgap charge-carrier supplying layer, e.g. direct single heterostructure MODFET
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • H01L33/0062Processes for devices with an active region comprising only III-V compounds
    • H01L33/0066Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound
    • H01L33/007Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound comprising nitride compounds

Abstract

The present invention provides the gallium nitride based light emitting diode structure and preparation method thereof with integrated amplifier.Light emitting diode includes: substrate, undoped GaN buffer layer, N-type GaN conductive layer, multi-quantum well active region, p-type gallium nitride conductive layer, current extending, P electrode, high resistant gallium nitride channel layer, AlGaN potential barrier, source electrode, gate electrode;The present invention relates to the gallium nitride based LED constructions with integrated amplifier, avoid parasitic capacitance existing for discrete device circuit connection, inductance, the electrode design portion in the chip of LED on-off will be controlled, it can be effectively improved the response frequency of luminescent device entirety, improve the visible light communication rate based on gallium nitride based LED.

Description

Gallium nitride based light emitting diode structure of integrated amplifier and preparation method thereof
Technical field
The present invention relates to LED technology fields, and in particular to a kind of gallium nitride base light emitting two of integrated amplifier Pole pipe structure and preparation method thereof.
Background technique
Light emitting diode (referred to as " LED ") is a kind of semiconducting solid luminescent device, it is using inside semiconductor material Radiation recombination occurs for conduction band electron and valence band hole, is so that form of photons releases energy and directly shines.It is different by design Semiconductor material forbidden bandwidth, light emitting diode can emit the light of the different-waveband from infrared to ultraviolet.
Gallium nitride based light emitting diode has many advantages, such as that efficient, energy conservation, long-life and switching speed are fast in the world with it Broad development is obtained in range.Gallium nitride based light emitting diode issues blue light, and excitated fluorescent powder obtains yellow light, with original blue light It is mixed to get white light.By quickly switching, communication function may be implemented, therefore the white light LEDs based on gallium nitride have illumination concurrently With the dual function of communication.Illumination communication at present shared white light LEDs constant-current drive circuit and signal amplification circuit are integrated in one It rises, interacts, limit the traffic rate of white light LEDs.
Summary of the invention
The present invention gallium nitride based LED constant-current drive circuit and signal amplification circuit mutual shadow shared for existing illumination communication It rings, the low problem of traffic rate proposes a kind of gallium nitride based LED structure and preparation method thereof of integrated amplifier.
The purpose of the present invention is realized at least through one of following technical solution.
The gallium nitride based light emitting diode structure of integrated amplifier, it is at least successively slow including substrate, gallium nitride under Rush a part, N-type GaN conductive layer, the multi-quantum well active region, p-type gallium nitride conductive layer, current extending, P electrode of layer;Nitrogen The another part for changing gallium buffer layer (insulating layer) is up successively arranged high resistant gallium nitride channel layer, AlGaN potential barrier;AlGaN gesture Barrier layer is equipped with source Ohmic electrode and gate electrode;The diode structure includes transistor current amplification circuit;Current amplifier electricity Route the nitride buffer layer, AlGaN potential barrier, source Ohmic electrode and gate electrode composition;
In the gallium nitride based light emitting diode structure of the integrated amplifier, the current amplification circuit is GaN/ AlGaN hetero-junctions high electron mobility transistor composition.Current amplification circuit is located at the N electrode in conventional LED structure Region;The two-dimensional electron gas of GaN/AlGaN hetero-junctions and the N-type conductive layer of light emitting diode connect.
Ground is advanced optimized, the GaN buffer layer is GaN nucleating layer and unintentional doped gan layer, wherein GaN nucleating layer With a thickness of 10-100 nm, unintentional doped gan layer is with a thickness of 100-4000 nm;
Advanced optimize ground, the doping concentration 2 × 10 of the N-type GaN conductive layer18cm-3-2×1019cm-3
Ground is advanced optimized, the multi-quantum well active region is periodically overlapping InGaN barrier layer and GaN potential well layer;
Ground is advanced optimized, the doping concentration 2 × 10 of magnesium in the p-type gallium nitride conductive layer18cm-3-2×1020cm-3
The method of the preparation gallium nitride based light emitting diode structure with integrated amplifier, including walk as follows It is rapid:
(1) growing gallium nitride LED extension in (MOCVD) reaction chamber is deposited in Metallo-Organic Chemical Vapor according to a conventional method Piece at least successively includes substrate, undoped GaN buffer layer, N-type GaN conductive layer, multi-quantum well active region, p-type gallium nitride under Conductive layer, silicon oxide mask layer;
(2) (1) final gained sample is taken out, deposits silica;
(3) (2) final gained sample by photoetching technique, is removed part of silica, retains the dioxy of masks area SiClx;
(4) sample obtained by (3) is put into inductively coupled plasma etching equipment to the position of removal part of silica GaN etching is carried out, undoped GaN buffer layer is etched to;
(5) sample obtained by (4) is put into Metallo-Organic Chemical Vapor deposition (MOCVD) reaction chamber, in the etching portion of (4) Position grows the gallium nitride layer of unintentional doping;
(6) AlGaN potential barrier is grown on the gallium nitride layer of the unintentional doping of the sample obtained by (5);
(7) sample obtained by (6) is taken out into reaction chamber, depositing Ti Au, photoetching prepares source electrode ohm in AlGaN potential barrier Contact, and it is etched away silicon oxide mask layer;
(8) p-type current extending and P electrode Ohmic contact are prepared on the p-type gallium nitride conductive layer of the sample obtained by (7);
(9) grid Schottky contacts are prepared in the AlGaN potential barrier on the sample obtained by (8).
Compared with prior art, the invention has the advantages that and technical effect:
The present invention is big for existing gallium nitride based LED operating current, the low problem of separation control circuit response frequency, proposes A kind of gallium nitride based LED construction of integrated amplifier, avoids parasitic capacitance existing for discrete device circuit connection, inductance, The electrode design portion in the chip of LED on-off will be controlled, the photoelectric respone time of luminescent device can be shortened, improve luminescent device Whole response frequency improves the visible light communication rate based on gallium nitride based LED.
Detailed description of the invention
Fig. 1 is conventional gallium nitride based LED construction diagrammatic cross-section.
Fig. 2 is gallium nitride based LED construction diagrammatic cross-section of the invention.
Fig. 3 is gallium nitride based LED preparation flow figure of the invention.
Fig. 4 is the time resolution luminosity curve of the present invention and conventional separators part.
In figure: 1, substrate;2, undoped GaN buffer layer;3, N-type GaN conductive layer;4, multi-quantum well active region;5, p-type nitrogen Change gallium conductive layer;6, current extending;7, P electrode;8, high resistant gallium nitride channel layer;9, AlGaN potential barrier;10, source electrode; 11, gate electrode;12, N electrode;13, silicon oxide mask layer.
Specific embodiment
The present invention will be further described with reference to the accompanying drawings and examples, but implementation and protection of the invention is not limited to This.
A kind of gallium nitride based light emitting diode structure of integrated amplifier, as shown in Fig. 2, the light emitting diode is under 1, substrate is followed successively by and;2, undoped GaN buffer layer;3, N-type GaN conductive layer;4, multi-quantum well active region;5, p-type nitrogenizes Gallium conductive layer;6, current extending;7, P electrode;8, high resistant gallium nitride layer;9, AlGaN potential barrier;10, source electrode;11, grid electricity Pole;12, N electrode;13, silicon oxide mask layer.
As a kind of example, the preparation step of the gallium nitride based light emitting diode structure of integrated amplifier is as follows:
(1) Sapphire Substrate is put into Metallo-Organic Chemical Vapor chemical deposition equipment by, conventionally grows nitrogen Change gallium base LED epitaxial wafer;
(2) sample described in (1) is taken out reaction chamber by, deposits silica, with a thickness of 100nm, (a) institute in Fig. 3 Show;
(3) sample described in (2) is used photoetching technique by, is removed part of silica, is retained the dioxy of masks area SiClx, in Fig. 3 shown in (b);
(4) sample described in (3) is put into inductively coupled plasma etching equipment by, carries out gallium nitride etching, such as Fig. 3 In shown in (c);
(5) will be put into equipment of metal organic chemical vapor deposition after sample clean described in (4), successively growing high resistant Gallium nitride layer (gallium nitride of unintentional doping), AlGaN potential barrier, in Fig. 3 shown in (d);
(6) takes out sample described in (5) from the device, after cleaning, depositing Ti Au multilayer, and after photoetching, preparation source electricity Pole degenerates 30 seconds for 800 degrees Celsius, prepares source Ohmic contact, later in Fig. 3 shown in (e);
(7) is by after sample clean described in (6), depositing indium tin oxide, thickness 150nm, as p-type current extending;
(8) deposits CrAu, thickness is 100nm and 100nm respectively, as P ohm for after sample clean described in (7) Contact, in Fig. 3 shown in (f);
(9) after sample clean described in (8), will deposit NiAu, and thickness is 20nm and 300 nm respectively, as grid electricity Pole, as shown in Figure 2.
As example, such as Fig. 4, for the time resolution luminosity curve of the present invention and conventional separators part.In Fig. 4, dotted line To be of the invention as a result, solid line is conventional separators part as a result, ordinate is relative light intensity, abscissa is the time, and unit is Nanosecond.The gallium nitride based LED construction of integrated amplifier avoids parasitic capacitance existing for discrete device circuit connection, inductance, The electrode design portion in the chip of LED on-off will be controlled, the photoelectric respone time of luminescent device can be shortened, improve luminescent device Whole response frequency improves the visible light communication rate based on gallium nitride based LED.
Diode structure produced above includes high electron mobility transistor current amplification circuit.The high electron mobility Rate transistor current amplification circuit includes undoped gallium nitride insulating layer, aluminum gallium nitride barrier layer, source Ohmic electrode and gate electrode group At.
Advanced optimize implementation ground, the GaN buffer layer is GaN nucleating layer and unintentional doped gan layer, wherein GaN at Stratum nucleare is with a thickness of 10-100 nm, and unintentional doped gan layer is with a thickness of 100-4000 nm;The silicon of the N-type GaN conductive layer adulterates Concentration 2 × 1018cm-3-2×1019cm-3;The multi-quantum well active region is periodic InGaN barrier layer and GaN potential well layer;P The doping concentration 2 × 10 of magnesium in type conductive layer18cm-3-2×1020cm-3

Claims (8)

1. the gallium nitride based light emitting diode structure of integrated amplifier, it is characterised in that at least successively include substrate, GaN under A part of buffer layer, N-type GaN conductive layer, multi-quantum well active region, p-type gallium nitride conductive layer, current extending, P electrode; Another part of GaN buffer layer is up successively arranged high resistant gallium nitride channel layer, AlGaN potential barrier;AlGaN potential barrier is equipped with Source Ohmic electrode and gate electrode;The diode structure includes transistor current amplification circuit;Current amplification circuit is by the GaN Buffer layer, AlGaN potential barrier, source Ohmic electrode and gate electrode composition;The multi-quantum well active region is periodically overlapping InGaN barrier layer and GaN potential well layer.
2. the gallium nitride based light emitting diode structure of integrated amplifier according to claim 1, it is characterised in that electric current Amplifying circuit is GaN/AlGaN hetero-junctions high electron mobility transistor composition.
3. the gallium nitride based light emitting diode structure of integrated amplifier according to claim 1, it is characterised in that described Current amplification circuit is located at the N electrode region in conventional LED structure.
4. the gallium nitride based light emitting diode structure of integrated amplifier according to claim 2, it is characterised in that GaN/ The two-dimensional electron gas of AlGaN hetero-junctions and the N-type conductive layer of light emitting diode connect.
5. the gallium nitride based light emitting diode structure of integrated amplifier according to claim 1, it is characterised in that described GaN buffer layer is GaN nucleating layer and unintentional doped gan layer, and wherein GaN nucleating layer is with a thickness of 10-100 nm, unintentional doping GaN layer is with a thickness of 100-4000 nm.
6. the gallium nitride based light emitting diode structure of integrated amplifier according to claim 1, it is characterised in that the N The doping concentration 2 × 10 of type GaN conductive layer18cm-3-2×1019cm-3
7. according to the gallium nitride based light emitting diode structure of integrated amplifier described in claim 1, it is characterised in that the p-type The doping concentration 2 × 10 of magnesium in gallium nitride conductive layer18cm-3-2×1020cm-3
8. preparing the side of the described in any item gallium nitride based light emitting diode structures with integrated amplifier of claim 1 ~ 7 Method, it is characterised in that include the following steps:
(1) growing gallium nitride LED epitaxial wafer in (MOCVD) reaction chamber is deposited in Metallo-Organic Chemical Vapor according to a conventional method, from Under at least successively include that substrate, undoped GaN buffer layer, N-type GaN conductive layer, multi-quantum well active region, p-type gallium nitride are conductive Layer, silicon oxide mask layer;
(2) (1) final gained sample is taken out, deposits silica;
(3) (2) final gained sample by photoetching technique, is removed part of silica, retains the silica of masks area;
(4) sample obtained by (3) is put into inductively coupled plasma etching equipment and the position of removal part of silica is carried out GaN etching, is etched to undoped GaN buffer layer;
(5) sample obtained by (4) is put into Metallo-Organic Chemical Vapor deposition (MOCVD) reaction chamber, the etching position in (4) is raw The gallium nitride layer of long unintentional doping;
(6) AlGaN potential barrier is grown on the gallium nitride layer of the unintentional doping of the sample obtained by (5);
(7) sample obtained by (6) is taken out into reaction chamber, depositing Ti Au, photoetching prepares source electrode ohm in AlGaN potential barrier and connects Touching, and it is etched away silicon oxide mask layer;
(8) p-type current extending and P electrode Ohmic contact are prepared on the p-type gallium nitride conductive layer of the sample obtained by (7);
(9) grid Schottky contacts are prepared in the AlGaN potential barrier on the sample obtained by (8).
CN201610385080.6A 2016-06-03 2016-06-03 Gallium nitride based light emitting diode structure of integrated amplifier and preparation method thereof Active CN105914218B (en)

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Publication number Priority date Publication date Assignee Title
CN106252373B (en) * 2016-09-09 2019-12-03 复旦大学 A kind of GaN base integrated device and preparation method thereof
CN106549031B (en) * 2016-11-25 2019-12-03 复旦大学 A kind of monolithic integrated device and preparation method thereof based on body GaN material
CN108847419A (en) * 2018-07-10 2018-11-20 南方科技大学 A kind of single-slice integrated semiconductor array device and preparation method thereof
CN110289281A (en) * 2019-07-26 2019-09-27 山东大学 A kind of upside-down mounting GaN base HEMT-LED integrated device and preparation method thereof

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CN101393958A (en) * 2007-09-18 2009-03-25 丰田合成株式会社 Group III nitride-based compound semiconductor light-emitting device
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CN205984989U (en) * 2016-06-03 2017-02-22 华南理工大学 Gallium nitride emitting diode structure with amplifier

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
CN101064275A (en) * 2006-04-28 2007-10-31 中国科学院半导体研究所 Method for realizing RTD and HEMT single chip integration using dry etching technology
CN101393958A (en) * 2007-09-18 2009-03-25 丰田合成株式会社 Group III nitride-based compound semiconductor light-emitting device
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