CN105907460A - Preparation method of dry pricklyash peel oil - Google Patents
Preparation method of dry pricklyash peel oil Download PDFInfo
- Publication number
- CN105907460A CN105907460A CN201610410064.8A CN201610410064A CN105907460A CN 105907460 A CN105907460 A CN 105907460A CN 201610410064 A CN201610410064 A CN 201610410064A CN 105907460 A CN105907460 A CN 105907460A
- Authority
- CN
- China
- Prior art keywords
- oil
- pricklyash peel
- pericarpium zanthoxyli
- preparation
- dry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000007650 Aralia spinosa Nutrition 0.000 title claims abstract description 41
- 241000949456 Zanthoxylum Species 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 239000003921 oil Substances 0.000 claims abstract description 69
- 239000002245 particle Substances 0.000 claims abstract description 20
- 238000000605 extraction Methods 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 238000000926 separation method Methods 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 238000010298 pulverizing process Methods 0.000 claims abstract description 4
- 235000019198 oils Nutrition 0.000 claims description 64
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 40
- 239000008158 vegetable oil Substances 0.000 claims description 40
- 239000002893 slag Substances 0.000 claims description 20
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 14
- 102220112166 rs61747639 Human genes 0.000 claims description 13
- 239000000284 extract Substances 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 229910052786 argon Inorganic materials 0.000 claims description 7
- 239000003337 fertilizer Substances 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 3
- 239000007790 solid phase Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 20
- 230000003647 oxidation Effects 0.000 abstract description 7
- 238000007254 oxidation reaction Methods 0.000 abstract description 7
- 239000003183 carcinogenic agent Substances 0.000 abstract description 4
- 239000000539 dimer Substances 0.000 abstract description 4
- 239000010773 plant oil Substances 0.000 abstract 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000010008 shearing Methods 0.000 abstract 1
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 11
- 240000008384 Capsicum annuum var. annuum Species 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- 239000012071 phase Substances 0.000 description 6
- 239000003925 fat Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000000711 cancerogenic effect Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000008157 edible vegetable oil Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 3
- 231100000357 carcinogen Toxicity 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 235000014593 oils and fats Nutrition 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910052756 noble gas Inorganic materials 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000002137 ultrasound extraction Methods 0.000 description 2
- 210000003934 vacuole Anatomy 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- WNEODWDFDXWOLU-QHCPKHFHSA-N 3-[3-(hydroxymethyl)-4-[1-methyl-5-[[5-[(2s)-2-methyl-4-(oxetan-3-yl)piperazin-1-yl]pyridin-2-yl]amino]-6-oxopyridin-3-yl]pyridin-2-yl]-7,7-dimethyl-1,2,6,8-tetrahydrocyclopenta[3,4]pyrrolo[3,5-b]pyrazin-4-one Chemical compound C([C@@H](N(CC1)C=2C=NC(NC=3C(N(C)C=C(C=3)C=3C(=C(N4C(C5=CC=6CC(C)(C)CC=6N5CC4)=O)N=CC=3)CO)=O)=CC=2)C)N1C1COC1 WNEODWDFDXWOLU-QHCPKHFHSA-N 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 241000722363 Piper Species 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000037351 starvation Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/02—Pretreatment
- C11B1/04—Pretreatment of vegetable raw material
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/10—Production of fats or fatty oils from raw materials by extracting
Abstract
The invention discloses a preparation method of dry pricklyash peel oil. The preparation method comprises the steps of conducting mass-transfer extraction on particle interface materials, pulverizing dry pricklyash peel raw materials into powder with the diameter D98 ranging from 10 micrometers to 100 micrometers, mixing the power with plant oil, then applying shearing and extrusion force to the pricklyash peel powder and the plant oil with the frequency being 300-400 thousand cycles/minute, and then conducting solid-liquid separation, so that the finished pricklyash peel oil is obtained. By means of the preparation method of the dry pricklyash peel oil, the problem of oil oxidation caused by the oil temperature ranging from 140 DEG C to 180 DEG C in the traditional process is solved; the situation that cancerogen such as superoxide and dimer is generated due to the high temperature of the traditional extraction process is avoided; the dry pricklyash peel raw materials are pulverized into the power with the diameter D98 ranging from 10 micrometers to 100 micrometers, then extraction is conducted, stewed pricklyash peel is not generated, and the problem that stewed pricklyash peel is difficult to treat is solved; separation residues can be recycled, the environment cannot be polluted, and the extraction rate is high.
Description
Technical field
The application belongs to technical field of seasoning processing, specifically, relates to a kind of dry Pericarpium Zanthoxyli oil
Preparation method.
Background technology
Tradition Fructus Zanthoxyli oil extracting mode has fried method, ultrasonic extraction, SCF-CO 2.
Its way of fried method is: is directly placed into by Pericarpium Zanthoxyli in the edible vegetable oil of heat and seals,
Or being contained by Pericarpium Zanthoxyli in container, container oil-out aperture is less than Pericarpium Zanthoxyli diameter, by 140-180 DEG C
Edible vegetable oil slowly drench in container, blast its fragrance, make effective ingredient dissolve in oil,
Obtain Fructus Zanthoxyli oil.Its shortcoming is: the bad grasp of (1) oil temperature, if temperature is too high, in Pericarpium Zanthoxyli
Fragrance and spicy component is volatile, decompose and lose；If oil temperature is too low, moisture is not readily separated,
It is easily caused spoiled by rancid oil or fat.(2) effective ingredient can not be fully dissolved out, and is only partially into oil
In, cause waste and product cost higher；(3) oils and fats is easily caused oxidation by high temperature, produces
The carcinogen such as raw peroxide and dimer；(4) open making causes aromatic substance
It is heated volatilization.
SCF-CO 2 is that to utilize supercritical CO 2 to have the amide component of Pericarpium Zanthoxyli special
Dissolution, i.e. utilizes pressure and temperature on the impact of supercritical CO 2 solvability by Pericarpium Zanthoxyli
In amide extract, be Japan pepper essential oil, then be equipped with edible vegetable oil and form.Its shortcoming
It is: (1) complex process to be only suitable for single component or same class material extracts, it is impossible to embody
The local flavor of Pericarpium Zanthoxyli；(2) the single extraction time is long, and day output is little, therefore the method
It is not suitable for Pericarpium Zanthoxyli and gets the harvest in quickly big production in season；(3) operating cost is high.
Ultrasonic extraction is to utilize the judder of ultrasound wave, high acceleration, strong cavitation effect
Should, stirring action, reach accelerate composition enter solvent, reach extract Fructus Zanthoxyli oil effect.Its
Shortcoming is: the aromatic oil being applicable to Pericarpium Zanthoxyli surface oil vacuole extracts, to the amide-type in Pericarpium Zanthoxyli sarcocarp
Material extracts not exclusively, and yield is low.
It addition, in addition to supercritical carbon dioxide fluid extraction, remaining extracting method produces Fructus Zanthoxyli oil mistake
Cheng Zhonghui produces substantial amounts of oil green pepper, if oil green pepper is buried process, can pollute.If will
Oil is sold by green pepper, belongs to infringement, thus results in enterprise and faces the process problem to oil green pepper.
Summary of the invention
In view of this, the application causes Oxidation of Fat and Oils, the oil intractable problem of green pepper for high temperature,
Provide the preparation method of a kind of dry Pericarpium Zanthoxyli oil, high temperature can be avoided to cause Oxidation of Fat and Oils to produce carcinogenic
Thing, and separate slag and can recycle, not producing oil green pepper, do not pollute the environment, extraction ratio is high.
In order to solve above-mentioned technical problem, this application discloses the preparation method of a kind of dry Pericarpium Zanthoxyli oil,
Particle interface material mass transfer is used to extract, by dry Pericarpium Zanthoxyli raw material pulverizing to D98=10-100 μm
Powder mixes with vegetable oil, then with vegetable oil, Pricklyash peel is applied 30-40's ten thousand beats/min
Clipping, extruding force, then carry out solid-liquid separation, obtain finished product Fructus Zanthoxyli oil.
Further, following steps are specifically included:
Step 1, it is D98=10-100 μm Pricklyash peel that dry Pericarpium Zanthoxyli is crushed to granularity；
Step 2, in proportion by vegetable oil and the described Pricklyash peel of 10-40 DEG C or 80-130 DEG C
Add in extraction equipment；
Step 3, applies 30-40 ten thousand beat/min to Pricklyash peel with vegetable oil by extraction equipment
Clipping, extruding force；
Step 4, to apply the Pricklyash peel after the clipping of 30-40 ten thousand beats/min, extruding force with
Vegetable oil carries out solid-liquid separation, and liquid phase is finished product Fructus Zanthoxyli oil, and solid phase is for separating slag.
Further, described dry Pericarpium Zanthoxyli is 1:3-20 with the mass ratio of vegetable oil.
Further, the clipping of described 30-40 ten thousand beats/min, extruding force are continuously applied
13-31min。
Preferably, the clipping of described 30-40 ten thousand beats/min, extruding force are continuously applied 26min.
Further, described Pricklyash peel and vegetable oil are applied 30-40 ten thousand beats/min clipping,
Extruding force is carried out in totally-enclosed environment and under inert gas shielding.
Further, described noble gas includes but not limited to: nitrogen, argon.
Further, described separation slag is used for making carbon-point, papermaking, fertilizer.
Compared with prior art, the application can obtain and include techniques below effect:
(1) the application uses particle interface material mass transfer extractive technique at 10-40 DEG C or 80-130 DEG C
Under complete whole part and extract, solve the oils and fats that traditional handicraft is brought because of the oil temperature of 140-180 DEG C
Problem of oxidation, and then avoid traditional extraction technique and produce peroxide, dimer etc. because of high temperature
Carcinogen；
(2) extracting in totally-enclosed environment, the loss solving volatile ingredient is dirty with environment
Dye problem, and stop the extraneous factor pollution to product；Use inert gas shielding, further
Strengthen lipid-antioxidant activity ability；
(3) dry Pericarpium Zanthoxyli raw material powder is broken into the powder of D98=10-100 μm by the application preparation method
End is extracted, and does not produce oil green pepper, solves the oil intractable problem of green pepper, and separation slag can enter
Row recycling, does not pollutes the environment；
(4) the application uses particle interface material mass transfer extractive technique to extract the receipts of dry Pericarpium Zanthoxyli oil
Rate is 2-3 times of traditional handicraft, and extraction efficiency is high, substantially increases the utilization rate of dry Pericarpium Zanthoxyli,
Solve traditional handicraft and extract Pericarpium Zanthoxyli component not exclusively, waste a large amount of raw-material problem, save
Resource；Extraction time shortens to the 1/2-1/5 of traditional handicraft, substantially increases production efficiency.
Certainly, the arbitrary product implementing the application it is not absolutely required to reach above-described simultaneously
All technique effects.
Accompanying drawing explanation
Accompanying drawing described herein is used for providing further understanding of the present application, constitutes the application
A part, the schematic description and description of the application is used for explaining the application, not structure
The improper restriction of the application in pairs.In the accompanying drawings:
Fig. 1 is the preparation method flow chart of the embodiment of the present application dry Pericarpium Zanthoxyli oil；
Fig. 2 is the detection by electronic nose Comparative result figure of the embodiment of the present application.
Detailed description of the invention
Presently filed embodiment is described in detail, thereby to the application below in conjunction with embodiment
How application technology means solve technical problem and reach the process that realizes of technology effect and can fill
Sub-argument solution is also implemented according to this.
The preparation method of a kind of dry Pericarpium Zanthoxyli of present invention oil, uses particle interface material mass transfer to extract,
Dry Pericarpium Zanthoxyli raw material pulverizing is mixed to the powder of D98=10-100 μm with vegetable oil, then to flower
Green pepper powder and vegetable oil apply the clipping of 30-40 ten thousand beats/min, extruding force, then carry out solid-liquid and divide
From, obtain finished product Fructus Zanthoxyli oil.
Particle interface material mass transfer extracts principle: the least surface area of particle is the biggest, simultaneously surface energy
The biggest, particle interface is understood binding molecule material and is formed stable structure, now utilizes powerful
Mechanical energy breaks through the interstitial barriers between particle and molecular substance so that it is material departs from particle interface
It is displaced to solvent.
Seeing Fig. 1, said method specifically includes following steps:
Step 1, it is D98=10-100 μm Pricklyash peel (i.e. 98% that dry Pericarpium Zanthoxyli is crushed to granularity
Powder within 10-100 μ m)；
Selecting this particle size range to be because the tissue of Pericarpium Zanthoxyli and oil vacuole is the most broken, useful component is all
Come out, be more suitable for extracting, the meticulous cost that can increase, effect no significant difference.
Step 2, by the mass ratio of dry Pericarpium Zanthoxyli Yu vegetable oil 1:3-20, by 10-40 DEG C or 80-130 DEG C
Vegetable oil jointly add extraction with the Pricklyash peel that described granularity is D98=10-100 μm and set
In Bei；Described extraction equipment is vibration lapping machine (rod formula)；
Dry Pericarpium Zanthoxyli and the mass ratio of vegetable oil 1:3-20, be the concentration according to market demand Fructus Zanthoxyli oil
Or the content of raw material determines, excessive concentration consumer cannot eat, concentration is too low cannot be embodied
The local flavor of Pericarpium Zanthoxyli.
At 10-40 DEG C or 80-130 DEG C, carry out whole part extraction, solve traditional handicraft because of
The Oxidation of Fat and Oils problem that 140-180 DEG C of high temperature brings, and then stopped traditional extraction technique because of height
Temperature produces the carcinogen such as peroxide, dimer；And required producing can be obtained by regulation temperature
Product local flavor, original fragrant of the dry Pericarpium Zanthoxyli oil that 10-40 DEG C is extracted is good, fiber crops taste foot；80-130℃
The burnt odor taste foot of the dry Pericarpium Zanthoxyli oil extracted, numb taste foot, delicate fragrance are lightly seasoned；
Step 3, applies 30-40 ten thousand beat/min to Pricklyash peel with vegetable oil by extracting equipment
Clipping, extruding force, application time continue 13-31min；Produced by it, energy improves
Molecular activity, has driven the flow at high speed of vegetable oil simultaneously, has also reduced the plant of particle periphery
Concentration difference in oil, makes the material composition on particle interface be quickly moved in vegetable oil.
Preferably, application time continues 26min, and overlong time cost is the highest, and the time is too short to be carried
Take effect (the fiber crops local flavor such as taste, fragrance) the poorest.
Further, described Pricklyash peel and vegetable oil are applied 30-40 ten thousand beats/min clipping,
Extruding force is carried out in totally-enclosed environment and under inert gas shielding.Totally-enclosed environment carries
Take, solve loss and the problem of environmental pollution of volatile ingredient, and stop extraneous factor to product
The pollution of product；Use inert gas shielding, further enhance lipid-antioxidant activity ability.
Wherein, described noble gas includes but not limited to: nitrogen, argon.
Step 4, to apply the Pricklyash peel after the clipping of 30-40 ten thousand beats/min, extruding force with
Vegetable oil carries out solid-liquid separation, selects 2-3 phase solid-liquid separating machine according to the water content of dry Pericarpium Zanthoxyli,
Liquid phase is finished product Fructus Zanthoxyli oil, and solid phase is for separating slag.
Further, described separation slag can be used for making carbon-point, papermaking, fertilizer.
Embodiment 1
Step 1, takes dry Pericarpium Zanthoxyli 1kg, is crushed to the Zanthoxyli Bungeani powder that particle mean size is D98=80 μm
End；
Step 2, the vegetable oil that Pricklyash peel and 8kg are preheated to 30 DEG C or 100 DEG C adds jointly
Enter to vibrate in lapping machine (rod formula)；
Step 3, at totally-enclosed environment and applies with vegetable oil Pricklyash peel under nitrogen protection
Clipping, the extruding force of 300000 beats/min are extracted, and continue 26min；
Step 4, the Pricklyash peel after using solid-liquid separating machine to extract carries out 2-3 with vegetable oil
Phase solid-liquid separation, obtains finished product Fructus Zanthoxyli oil and separates slag, wherein separates slag and is used for making carbon-point.
Embodiment 2
Step 1, takes dry Pericarpium Zanthoxyli 1kg, is crushed to the Zanthoxyli Bungeani powder that particle mean size is D98=50 μm
End；
Step 2, will be preheated to the vegetable oil of 40 DEG C or 130 DEG C altogether with 15kg in Pricklyash peel
With adding in vibration lapping machine (rod formula)；
Step 3, totally-enclosed environment and in argon shield under Pricklyash peel and vegetable oil are applied
Clipping, the extruding force of 350000 beats/min are extracted, and continue 18min；
Step 4, the Pricklyash peel after using solid-liquid separating machine to extract carries out 2-3 with vegetable oil
Phase solid-liquid separation, obtains finished product Fructus Zanthoxyli oil and separates slag, wherein separates slag for papermaking.
Embodiment 3
Step 1, takes dry Pericarpium Zanthoxyli 1kg, is crushed to the Zanthoxyli Bungeani powder that particle mean size is D98=10 μm
End；
Step 2, by common with the vegetable oil that 20kg is preheated to 20 DEG C or 120 DEG C for Pricklyash peel
Add in vibration lapping machine (rod formula)；
Step 3, totally-enclosed environment and in argon shield under Pricklyash peel and vegetable oil are applied
Clipping, the extruding force of 400000 beats/min are extracted, and continue 31min；
Step 4, the Pricklyash peel after using solid-liquid separating machine to extract carries out 2-3 with vegetable oil
Phase solid-liquid separation, obtains finished product Fructus Zanthoxyli oil and separates slag, wherein separates slag and is used for making fertilizer.
Embodiment 4
Step 1, takes dry Pericarpium Zanthoxyli 1kg, is crushed to the Zanthoxyli Bungeani powder that particle mean size is D98=100 μm
End；
Step 2, by common for the vegetable oil being preheated to 10 DEG C or 80 DEG C in Pricklyash peel with 3kg
Add in vibration lapping machine (rod formula)；
Step 3, totally-enclosed environment and in argon shield under Pricklyash peel and vegetable oil are applied
Clipping, the extruding force of 350000 beats/min are extracted, and continue 13min；
Step 4, the Pricklyash peel after using solid-liquid separating machine to extract carries out 2-3 with vegetable oil
Phase solid-liquid separation, obtains finished product Fructus Zanthoxyli oil and separates slag, wherein separates slag and is used for making carbon-point.
Embodiment 5
Step 1, takes dry Pericarpium Zanthoxyli 1kg, is crushed to the Zanthoxyli Bungeani powder that particle mean size is D98=70 μm
End；
Step 2, by common with the vegetable oil that 10kg is preheated to 25 DEG C or 110 DEG C for Pricklyash peel
Add in vibration lapping machine (rod formula)；
Step 3, totally-enclosed environment and in argon shield under Pricklyash peel and vegetable oil are applied
Clipping, the extruding force of 350000 beats/min are extracted, and continue 20min；
Step 4, the Pricklyash peel after using solid-liquid separating machine to extract carries out 2-3 with vegetable oil
Phase solid-liquid separation, obtains finished product Fructus Zanthoxyli oil and separates slag, wherein separates slag and is used for making fertilizer.
Comparative example
Step 1, takes 7kg vegetable oil, is heated to 130 DEG C；
Step 2, takes 1kg dry Pericarpium Zanthoxyli and is directly placed in the edible vegetable oil of 130 DEG C and seals,
3 hours persistent period；
Step 3, by Pericarpium Zanthoxyli with separating of oil, obtains liquid and Fructus Zanthoxyli oil, and solid is " oil green pepper ".
In employing embodiment 2,1kg dry Pericarpium Zanthoxyli raw material is at 130 DEG C of 15kg ± 1 product oils extracted
Suitable with the 7kg ± 1 product oil quality that 1kg dry Pericarpium Zanthoxyli is extracted by comparative example 130 DEG C, yield
Being its 2-3 times, extract yield is high, reduce the cost of raw material.
In Pericarpium Zanthoxyli, component content is the most, and the existing deliberated index of industry is mainly amide and taste
Plumpness, the application passes through detection by electronic nose, sees Fig. 2, and (a) is Pericarpium Zanthoxyli raw material, (b)
For the Fructus Zanthoxyli oil of the embodiment of the present application 4 preparation, (c) is Fructus Zanthoxyli oil prepared by comparative example, knot
Fruit shows that Fructus Zanthoxyli oil prepared by the application is substantially better than the Fructus Zanthoxyli oil that traditional handicraft is extracted.
Said method completely can complete to extract by 13-31min at 10-40 DEG C, it is to avoid oils and fats oxygen
Change, decompose；Totally-enclosed extraction environment can effectively protect the aroma substance composition of Pericarpium Zanthoxyli non-volatile；
Completely can blanketing with inert gas, effectively prevent Oxidation of Fat and Oils.
The separation slag that above-mentioned preparation method produces can recycle: can pass through starvation dry distilling
Produce carbon black；Can be used for paper mill papermaking；May be used for loosing soil agent and return soil as fertilizer
Material.Separation slag owing to producing the most does not has the original physical characteristic of Pericarpium Zanthoxyli, and safety and environmental protection
Process, stopped the oily green pepper transaction illegal incidents in industry.
Above-mentioned preparation method can save cost of labor, cost of labor by 5 people/class reduce to 3 people/
Class.Based on producing 50 tons of Fructus Zanthoxyli oil every day, production line electricity consumption 160-180kw/h completely.
As employ in the middle of description and claim some vocabulary to censure special component or
Method.Those skilled in the art are it is to be appreciated that different regions may be called with different nouns
Same composition.This specification and claims are not used as distinguishing composition with the difference of title
Mode." comprising " as mentioned by the middle of description and claim in the whole text is one open
Term, therefore " comprise but be not limited to " should be construed to." substantially " refer at receivable error model
In enclosing, those skilled in the art can solve described technical problem, base in the range of certain error
Originally described technique effect is reached.Description subsequent descriptions is to implement the better embodiment of the application,
For the purpose of right described description is the rule so that the application to be described, it is not limited to the application
Scope.The protection domain of the application is when being as the criterion depending on the defined person of claims.
Also, it should be noted term " includes ", " comprising " or its any other variant are intended to
Contain comprising of nonexcludability, so that include the commodity of a series of key element or system not only
Including those key elements, but also include other key elements being not expressly set out, or also include
The key element intrinsic for this commodity or system.In the case of there is no more restriction, by language
Sentence " including one the ... " key element that limits, it is not excluded that include described key element commodity or
System there is also other identical element.
Described above illustrate and describes some preferred embodiments of invention, but as it was previously stated, should
When understanding that invention is not limited to form disclosed herein, it is not to be taken as other embodiments
Eliminating, and can be used for other combinations various, amendment and environment, and can be at described herein
In bright contemplated scope, it is modified by above-mentioned teaching or the technology of association area or knowledge.And
Change that those skilled in the art are carried out and change, the most all should be without departing from the spirit and scope of invention
In the protection domain of invention claims.
Claims (8)
1. the preparation method of a dry Pericarpium Zanthoxyli oil, it is characterised in that use particle interface material mass transfer to extract,
Dry Pericarpium Zanthoxyli raw material pulverizing is mixed to the powder of D98=10-100 μm with vegetable oil, then to Pricklyash peel
Apply the clipping of 30-40 ten thousand beats/min, extruding force with vegetable oil, then carry out solid-liquid separation, obtain finished product
Fructus Zanthoxyli oil.
2. the preparation method of dry Pericarpium Zanthoxyli oil as claimed in claim 1, it is characterised in that use particle circle
Face material mass transfer extracts, and specifically includes following steps:
Step 1, it is D98=10-100 μm Pricklyash peel that dry Pericarpium Zanthoxyli is crushed to granularity；
Step 2, adds extraction by the vegetable oil of 10-40 DEG C or 80-130 DEG C with described Pricklyash peel in proportion
In equipment；
Step 3, by extraction equipment Pricklyash peel and vegetable oil applied 30-40 ten thousand beats/min clipping,
Extruding force；
Step 4, to the Pricklyash peel after the applying clipping of 30-40 ten thousand beats/min, extruding force and vegetable oil
Carrying out solid-liquid separation, liquid phase is finished product Fructus Zanthoxyli oil, and solid phase is for separating slag.
3. the preparation method of dry Pericarpium Zanthoxyli oil as claimed in claim 1 or 2, it is characterised in that described dry
Pericarpium Zanthoxyli is 1:3-20 with the mass ratio of vegetable oil.
4. the preparation method of dry Pericarpium Zanthoxyli oil as claimed in claim 1 or 2, it is characterised in that described
Clipping, extruding force that 30-40 is ten thousand beats/min are continuously applied 13-31min.
5. the preparation method of dry Pericarpium Zanthoxyli oil as claimed in claim 1 or 2, it is characterised in that described
Clipping, extruding force that 30-40 is ten thousand beats/min are continuously applied 26min.
6. the preparation method of dry Pericarpium Zanthoxyli oil as claimed in claim 1 or 2, it is characterised in that described right
Pricklyash peel and vegetable oil apply the clipping of 30-40 ten thousand beats/min, extruding force in totally-enclosed environment and
Carry out under inert gas shielding.
7. the preparation method of dry Pericarpium Zanthoxyli oil as claimed in claim 6, it is characterised in that described indifferent gas
Body includes but not limited to: nitrogen, argon.
8. the preparation method of dry Pericarpium Zanthoxyli oil as claimed in claim 2, it is characterised in that described separation slag
For making carbon-point, papermaking, fertilizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610410064.8A CN105907460A (en) | 2016-06-12 | 2016-06-12 | Preparation method of dry pricklyash peel oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610410064.8A CN105907460A (en) | 2016-06-12 | 2016-06-12 | Preparation method of dry pricklyash peel oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105907460A true CN105907460A (en) | 2016-08-31 |
Family
ID=56749851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610410064.8A Pending CN105907460A (en) | 2016-06-12 | 2016-06-12 | Preparation method of dry pricklyash peel oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105907460A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108967959A (en) * | 2018-09-24 | 2018-12-11 | 罗炜欣 | Technique based on wall breaking technology Yu molecule technique for packing processing and seasoning food |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103918802A (en) * | 2014-04-28 | 2014-07-16 | 周顺 | Pure natural zanthoxylum oil and industrial production method thereof |
-
2016
- 2016-06-12 CN CN201610410064.8A patent/CN105907460A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103918802A (en) * | 2014-04-28 | 2014-07-16 | 周顺 | Pure natural zanthoxylum oil and industrial production method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 彭宪等: "正交试验法优选野菊花的高速分散均质提取工艺", 《广东药学院学报》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108967959A (en) * | 2018-09-24 | 2018-12-11 | 罗炜欣 | Technique based on wall breaking technology Yu molecule technique for packing processing and seasoning food |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104323395B (en) | A kind of antioxidant of the peel extract containing Queensland nut and preparation method and application | |
| CN102260594B (en) | Method for extracting black pepper essence oil and black pepper essence oil resin from black paper | |
| JP5198246B2 (en) | Soap made from organic residue and method for producing the same | |
| CN102919390B (en) | Preparation method of cooked flavor spice seasoning oil | |
| CN101664074A (en) | Savoury zanthoxylum fruit essential oil with high concentration and preparation method thereof | |
| CN104450202A (en) | Preparation method of high-purity citrus peel essential oil | |
| CN102757860A (en) | Preparation method of pepper oil | |
| CN104856216A (en) | Treatment method for concrete and absolute type natural extractive suitable for electronic cigarette | |
| CN103571611B (en) | Production technology of fresh green Chinese prickly ash oil | |
| CN102936532A (en) | Extraction process of coconut oil | |
| CN107904017A (en) | A kind of agilawood essential oil preparation process | |
| CN105907460A (en) | Preparation method of dry pricklyash peel oil | |
| CN102960680B (en) | Multidirectional extraction process for fresh peppers | |
| US2384532A (en) | Method of processing spice | |
| CN108283221A (en) | A kind of tea seed nourishing flavored oils and preparation method thereof rich in DHA | |
| CN103766839A (en) | Preparation method of special liquid spice for cooking wine | |
| CN109666538A (en) | A kind of Zanthoxylum essential oil and its preparation process | |
| CN106070719A (en) | A kind of preparation method of fresh zanthoxylum oil | |
| CN100448871C (en) | Method for extracting nimbin | |
| CN101831349B (en) | Method for extracting wheat-germ oil continuously by using microwave secondary solvent | |
| CN103571626A (en) | Extracting technology of green Chinese prickly ash perfume oil | |
| CN104877755A (en) | Processing method for high-quality soybean oil | |
| CN114480013A (en) | Ultrasonic-assisted olive oil extraction method | |
| CN106554851A (en) | A kind of extracting method of anistree natural perfume material | |
| DE10332719B4 (en) | Process for degreasing coconut meat |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160831 |