CN105907022A - High-plasticity insect-trapping 3D printing material and preparation method thereof - Google Patents
High-plasticity insect-trapping 3D printing material and preparation method thereof Download PDFInfo
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- CN105907022A CN105907022A CN201610341543.9A CN201610341543A CN105907022A CN 105907022 A CN105907022 A CN 105907022A CN 201610341543 A CN201610341543 A CN 201610341543A CN 105907022 A CN105907022 A CN 105907022A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
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Abstract
The invention discloses a high-plasticity insect-trapping 3D printing material and a preparation method thereof. The 3D printing material is prepared from the following components in parts by weight: 120-140 parts of ABS (acrylonitrile-butadiene-styrene), 2-8 parts of photodiffusion agent, 2-8 parts of initiator, 10-20 parts of crosslinking agent, 10-20 parts of coupling agent, 10-30 parts of clam shell powder, 2-8 parts of simple substance sulfur, 1-4 parts of nutshell ultramicropowder, 1-6 parts of limonene, 4-20 parts of antimicrobial agent, 2-8 parts of stevia rebaudiana extract, 2-8 parts of noctilucent powder and 0.2-0.4 part of aid. The invention provides a 3D printing material new species for the users to select and use according to needs, thereby greatly widening the application and development space of the 3D printing material mainly prepared from ABS in the aspect of 3D printing materials, and having obvious meanings.
Description
Technical field
The invention belongs to 3D and print field, be specifically related to a kind of 3D printing material and preparation method thereof.
Background technology
The development maked rapid progress along with 3D printing technique, the concept that 3D prints gradually is known by the public.FDM technology is profit
With ABS, polycarbonate (PC), polyphenylsulfone (PPSF), PLA and other thermoplastic are subject to
To adding the filament being hot extruded into as semi-molten state, by the mode being deposited on the basis of storehouse layer by layer, from 3D CAD data
Directly construction prototype.This technology is commonly used to plastotype, assembling, functional test and conceptual design.Additionally, FDM
Technology can apply to draw a design and quickly manufacture.
ABS material, ABS, original name is acrylonitrile-butadiene-styrene copolymer, is domestic fusion sediment (FDM) formula
The essential core of wire rod.From the properties of material, from the perspective of hot junction, the relatively easy printing of ABS plastic.Nothing
Which type of extruder is opinion use, all can extruded material the most glidingly.ABS resilient enough, be suitable for making furnishings or
Ornament, as long as printing with suitable temperature, allows material layer by layer firmly stick, and the intensity of ABS will become at a relatively high.
ABS has flexibility, also only can bend even if bearing pressure, will not fracture.
But on the one hand this material has the characteristic of contract on cooling, can from heating plate local shedding, unsettled, cause and ask
Topic.If it addition, the object height printed is the highest, the most also can flood peel off.Therefore, ABS prints to have lacked and adds
Hot plate.It is uncomfortable that abnormal smells from the patient when on the other hand printing allows people have very much.
Along with development in science and technology and social progress, 3D printed product starts to be not limited only to industrial design, building, engineering and construction
(AEC), automobile, Aero-Space, dentistry and medical industries, education, GIS-Geographic Information System, civil engineering, gun etc.
Field, also begins to come into daily life, in order to make some living utensils or ornament, but at present in life
Application be still embodied in the purposes that the shape of printed product is brought, and the art that its color and shape are formed
Designs etc., the application and development printing 3D there is also the biggest space, simultaneously intensity in degradable rate, toughness and all
Need to be further improved.
Summary of the invention
Goal of the invention: the problem existed for prior art, first technical problem to be solved by this invention is to provide easily
Trapping worm type 3D printed material in plastotype.Second to be solved by this invention technical problem is that this is prone to luring of plastotype
The preparation method of parasite killing type 3D printed material.
Technical scheme: for solving above-mentioned technical problem, the invention provides a kind of trapping worm type 3D being prone to plastotype and prints
According to parts by weight, material, includes that following components is made: ABS 120～140 parts；Light diffusing agent 2～8 parts；Initiator
2～8 parts；Cross-linking agent 10～20 parts；Coupling agent 10～20 parts；Concha Meretricis Seu Cyclinae powder 10～30 parts；Elemental sulfur 2～8 parts；Core
Peach shell superfine powder 1～4 parts；Limonene 1～6 parts；Antibacterial 4～20 parts；Stevia rebaudiana (Bertoni) Hemsl extract 2～8 parts；Noctilucence
Powder 2～8 parts；Auxiliary agent 0.2～0.4 part.
It is further preferred that also include feather powder 2～8 parts according to parts by weight.
Preferably, described light diffusing agent is organosilicon light diffusing agent.
Preferably, according to parts by weight, described antibacterial includes that following components is made: Parmelia tinctorum Despr. extract 1～6 parts；Thin
Lotus flavone extract 1～4 parts；Luan Shu extract 1～6 parts, medical stone powder 1～4 parts.
Preferably, described initiator is thermal initiator.
Preferably, described initiator is the mixture of light trigger and thermal initiator.
Preferably, according to parts by weight, described initiator includes that following components is made: light trigger 1～3 parts；Thermal initiation
Agent 1～5 parts.
Preferably, one or both the mixture during described coupling agent is titanate coupling agent or silane coupler.
Preferably, according to parts by weight, described auxiliary agent includes that following components is made: plasticizer 0.1～0.2 part；Toughener 0.1～
0.2 part.
Invention also provides the preparation method for the above-mentioned trapping worm type 3D printed material being prone to plastotype, including such as
Lower step:
1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes, grafting；
2) it is cooled to 20 DEG C～30 DEG C after stirring, puts into extruder, heating, extrusion, pulverize to obtain preparing being grafted and hand over
The ABS powder of connection agent；
3) by step 2) the ABS powder that obtains and the Concha Meretricis Seu Cyclinae powder of corresponding parts by weight, elemental sulfur, walnut shell ultrafine powder,
Coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；
4) by step 3) gains are while continue to be mixed and stirred for uniform, and mixing adds the sweet of corresponding parts by weight successively
Leaf chrysanthemum extract, antibacterial and limonene；
5) then add luminescent powder and the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；
6) while ultra violet lamp 30～60min, after stirring is cooled to 50 DEG C～55 DEG C, puts in extruder, add
Hot-extrudable, vacuum drying, prepare target product.
As preferably, described step 3) be: by step 2) the ABS powder that obtains and the Concha Meretricis Seu Cyclinae of corresponding parts by weight
Powder, elemental sulfur, walnut shell ultrafine powder, feather powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform.
Beneficial effect: the trapping worm type 3D printed material being prone to plastotype that the present invention provides, has 3D printed material
On the basis of key property, on the one hand significantly enhance the network structure of material, the 3D printed product made with this material
Good toughness, degradable rate is high；On the other hand by initiator, Concha Meretricis Seu Cyclinae powder and the synergism of elemental sulfur, ABS is alleviated
The characteristic of material contract on cooling, effectively reduces flood that may be present when ABS material prints and peels off the problem brought,
Promote plastotype quality；When in component, increase has feather powder further, initiator and elemental sulfur and feather powder synergism,
Incidental local shedding when can effectively overcome ABS material to print, unsettled or flood peel off the problem brought, and enter one
Walk the printing plastotype quality of effective improving product.
Use the product that prints of 3D printed material that the present invention provides simultaneously, there is moulding own and shape brings
On the basis of basic function, on the one hand at night or dark, luminescence can play floor light and identification effect, the opposing party
Face effectively utilizes light to attract fly worm close, its component limonene of the third aspect and Stevia rebaudiana (Bertoni) Hemsl extract synergism so that
The product odour virtue sweet increase allure to fly worm printed, and limonene and antibacterial synergism make the present invention hold concurrently
Have an excellent antimicrobial and anti-inflammation efficacy, and fly worm sperm can be killed effectively suppress the breeding of worm's ovum, therefore at abnormal smells from the patient and light
Under dual function, the present invention has and well lures disinsection efficiency, and cleannes are high, simultaneously work as preferably removing free radical effect
And anti-radiation effect.The 3D printed material that limonene can also be effectively improved with ABS as raw material simultaneously is carrying out high temperature printing
Abnormal smells from the patient during operation, improves working environment, and with the Parmelia tinctorum Despr. extract in antibacterial, Luan Shu extract and medical stone powder
Synergism has good antioxidation, significantly improves the antioxygen of the 3D printed material that the present invention provides further
Change performance and stability；Plus overall composition synergism so that the 3D printed product made with this material is homogeneous,
Stress is uniform, it is easy to cutting plastotype, provides for microscopic carvings the most artificial on the product that printing prepares, cutting, plastotype
Preferably ease for use.
What the present invention provided simultaneously is prone to the preparation method of the trapping worm type 3D printed material of plastotype, by high-speed stirred
During add and be stirred cooling under Stevia rebaudiana (Bertoni) Hemsl extract, antibacterial and limonene, and ultra violet lamp, further
Improve stability and the non-oxidizability of obtained 3D printing consumables.
Entirety extends service life, it is provided that a kind of 3D printed material new varieties select as required for user,
In terms of 3D printed material, it is greatly enlarged the application development space of 3D printed material with ABS as primary raw material,
Meaning is notable.
Detailed description of the invention
According to parts by weight, embodiment 1: a kind of trapping worm type 3D printed material being prone to plastotype, includes that following components is made:
ABS 120 parts；Light diffusing agent 2 parts；Initiator 2 parts；Cross-linking agent 10 parts；Coupling agent 10 parts；Concha Meretricis Seu Cyclinae powder 10 parts；
Elemental sulfur 2 parts；Walnut shell ultrafine powder 1 part；Limonene 1 part；Antibacterial 4 parts；Stevia rebaudiana (Bertoni) Hemsl extract 2 parts；Noctilucence
2 parts of powder；Auxiliary agent 0.2 part.
Wherein light diffusing agent is organosilicon light diffusing agent.
Wherein according to parts by weight, antibacterial includes that following components is made: Parmelia tinctorum Despr. extract 1 part；Mint flavone extract
1 part；Luan Shu extract 1 part, medical stone powder 1 part.
Wherein according to parts by weight, initiator includes that following components is made: light trigger 1 part；Thermal initiator 1 part.
Wherein coupling agent is titanate coupling agent.
Wherein according to parts by weight, auxiliary agent includes that following components is made: plasticizer 0.1 part；Toughener 0.1 part.
Preparation method comprises the steps: 1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes,
Grafting；2) it is cooled to 20 DEG C after stirring, puts into extruder, heating, extrusion, pulverize and obtain preparing graft crosslinking
The ABS powder of agent；3) by step 2) the ABS powder that obtains and the Concha Meretricis Seu Cyclinae powder of corresponding parts by weight, elemental sulfur, core
Peach shell superfine powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；4) by step 3) gains continuation mixing
And while stirring, mixing adds the Stevia rebaudiana (Bertoni) Hemsl extract of corresponding parts by weight, antibacterial and limonene successively；5)
Then add luminescent powder and the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；6) at ultra violet lamp
While 30, after stirring is cooled to 50 DEG C, puts in extruder, add hot-extrudable, vacuum drying, prepare target
Product.After testing, the flexility of material reaches 82.3Mpa, notch impact strength reaches 47.9MJ/m2。
According to parts by weight, embodiment 2: a kind of trapping worm type 3D printed material being prone to plastotype, includes that following components is made:
ABS 140 parts；Light diffusing agent 8 parts；Initiator 8 parts；Cross-linking agent 20 parts；Coupling agent 20 parts；Concha Meretricis Seu Cyclinae powder 30 parts；
Elemental sulfur 8 parts；Walnut shell ultrafine powder 4 parts；Limonene 6 parts；Antibacterial 20 parts；Stevia rebaudiana (Bertoni) Hemsl extract 8 parts；Night
8 parts of light powder；Auxiliary agent 0.4 part.
Wherein light diffusing agent is organosilicon light diffusing agent.
Wherein according to parts by weight, antibacterial includes that following components is made: Parmelia tinctorum Despr. extract 6 parts；Mint flavone extract
4 parts；Luan Shu extract 6 parts, medical stone powder 4 parts.
Wherein according to parts by weight, initiator includes that following components is made: light trigger 3 parts；Thermal initiator 5 parts.
Wherein coupling agent is silane coupler.
Wherein according to parts by weight, auxiliary agent includes that following components is made: plasticizer 0.2 part；Toughener 0.2 part.
Preparation method comprises the steps: 1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes,
Grafting；2) it is cooled to 30 DEG C after stirring, puts into extruder, heating, extrusion, pulverize and obtain preparing graft crosslinking
The ABS powder of agent；3) by step 2) the ABS powder that obtains and the Concha Meretricis Seu Cyclinae powder of corresponding parts by weight, elemental sulfur, core
Peach shell superfine powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；4) by step 3) gains continuation mixing
And while stirring, mixing adds the Stevia rebaudiana (Bertoni) Hemsl extract of corresponding parts by weight, antibacterial and limonene successively；5)
Then add luminescent powder and the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；6) at ultra violet lamp
While 60min, after stirring is cooled to 55 DEG C, puts in extruder, add hot-extrudable, vacuum drying, prepare
Target product.After testing, the flexility of material reaches 82.4Mpa, notch impact strength reaches 47.9MJ/m2。
According to parts by weight, embodiment 3: a kind of trapping worm type 3D printed material being prone to plastotype, includes that following components is made:
ABS 130 parts；Light diffusing agent 5 parts；Initiator 5 parts；Cross-linking agent 15 parts；Coupling agent 15 parts；Concha Meretricis Seu Cyclinae powder 20 parts；
Elemental sulfur 5 parts；Walnut shell ultrafine powder 2 parts；Feather powder 5 parts；Limonene 4 parts；Antibacterial 12 parts；Folium Stevlae Rebaudianae carries
Take thing 5 parts；Luminescent powder 5 parts；Auxiliary agent 0.3 part.
Wherein light diffusing agent is organosilicon light diffusing agent.
Wherein according to parts by weight, antibacterial includes that following components is made: Parmelia tinctorum Despr. extract 4 parts；Mint flavone extract
2 parts；Luan Shu extract 4 parts, medical stone powder 2 parts.
Wherein according to parts by weight, initiator includes that following components is made: thermal initiator 5 parts.
Wherein coupling agent is the mixture of titanate coupling agent and silane coupler, and ratio is 2:3.
Wherein according to parts by weight, auxiliary agent includes that following components is made: plasticizer 0.15 part；Toughener 0.15 part.
Preparation method comprises the steps: 1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes,
Grafting；2) it is cooled to 25 DEG C after stirring, puts into extruder, heating, extrusion, pulverize and obtain preparing graft crosslinking
The ABS powder of agent；3) by step 2) the ABS powder that obtains and the Concha Meretricis Seu Cyclinae powder of corresponding parts by weight, elemental sulfur, core
Peach shell superfine powder, feather powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；4) by step 3) gains
The while of continuing to be mixed and stirred for uniform, mixing adds the Stevia rebaudiana (Bertoni) Hemsl extract of corresponding parts by weight, antibacterial and lemon successively
Lemon alkene；5) then add luminescent powder and the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；6) at purple
While outer light irradiation 45min, after stirring is cooled to 52 DEG C, puts in extruder, add hot-extrudable, vacuum drying,
Prepare target product.After testing, the flexility of material reaches 83.8Mpa, notch impact strength reaches
48.9MJ/m2。
According to parts by weight, embodiment 4: a kind of trapping worm type 3D printed material being prone to plastotype, includes that following components is made:
ABS 125 parts；Light diffusing agent 3 parts；Initiator 3 parts；Cross-linking agent 12 parts；Coupling agent 12 parts；Concha Meretricis Seu Cyclinae powder 15 parts；
Elemental sulfur 4 parts；Walnut shell ultrafine powder 2 parts；Feather powder 4 parts；Limonene 2 parts；Antibacterial 8 parts；Folium Stevlae Rebaudianae extracts
Thing 4 parts；Luminescent powder 4 parts；Auxiliary agent 0.2 part.
Wherein light diffusing agent is organosilicon light diffusing agent.
Wherein according to parts by weight, antibacterial includes that following components is made: Parmelia tinctorum Despr. extract 2 parts；Mint flavone extract
2 parts；Luan Shu extract 2 parts, medical stone powder 2 parts.
Wherein according to parts by weight, initiator includes that following components is made: thermal initiator 3 parts.
Wherein coupling agent is titanate coupling agent.
Wherein according to parts by weight, auxiliary agent includes that following components is made: plasticizer 0.1 part；Toughener 0.1 part.
Preparation method comprises the steps: 1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes,
Grafting；2) it is cooled to 25 DEG C after stirring, puts into extruder, heating, extrusion, pulverize and obtain preparing graft crosslinking
The ABS powder of agent；3) by step 2) the ABS powder that obtains and the Concha Meretricis Seu Cyclinae powder of corresponding parts by weight, elemental sulfur, core
Peach shell superfine powder, feather powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；4) by step 3) gains
The while of continuing to be mixed and stirred for uniform, mixing adds the Stevia rebaudiana (Bertoni) Hemsl extract of corresponding parts by weight, antibacterial and lemon successively
Lemon alkene；5) then add luminescent powder and the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；6) at purple
While outer light irradiation 40min, after stirring is cooled to 50 DEG C, puts in extruder, add hot-extrudable, vacuum drying,
Prepare target product.
After testing, the flexility of material reaches 82.9Mpa, notch impact strength reaches 48.6MJ/m2。
According to parts by weight, embodiment 5: a kind of trapping worm type 3D printed material being prone to plastotype, includes that following components is made:
ABS 135 parts；Light diffusing agent 6 parts；Initiator 6 parts；Cross-linking agent 18 parts；Coupling agent 18 parts；Concha Meretricis Seu Cyclinae powder 25 parts；
Elemental sulfur 6 parts；Walnut shell ultrafine powder 3 parts；Feather powder 6 parts；Limonene 4 parts；Antibacterial 16 parts；Folium Stevlae Rebaudianae carries
Take thing 6 parts；Luminescent powder 6 parts；Auxiliary agent 0.4 part.
Wherein light diffusing agent is organosilicon light diffusing agent.
Wherein according to parts by weight, antibacterial includes that following components is made: Parmelia tinctorum Despr. extract 5 parts；Mint flavone extract
3 parts；Luan Shu extract 5 parts, medical stone powder 3 parts.
Wherein according to parts by weight, initiator includes that following components is made: light trigger 2 parts；Thermal initiator 4 parts.
Wherein coupling agent is the mixture of titanate coupling agent and silane coupler.
Wherein according to parts by weight, auxiliary agent includes that following components is made: plasticizer 0.2 part；Toughener 0.2 part.
Preparation method comprises the steps: 1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes,
Grafting；2) it is cooled to 25 DEG C after stirring, puts into extruder, heating, extrusion, pulverize and obtain preparing graft crosslinking
The ABS powder of agent；3) by step 2) the ABS powder that obtains and the Concha Meretricis Seu Cyclinae powder of corresponding parts by weight, elemental sulfur, core
Peach shell superfine powder, feather powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；4) by step 3) gains
The while of continuing to be mixed and stirred for uniform, mixing adds the Stevia rebaudiana (Bertoni) Hemsl extract of corresponding parts by weight, antibacterial and lemon successively
Lemon alkene；5) then add luminescent powder and the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；6) at purple
While outer light irradiation 50min, after stirring is cooled to 55 DEG C, puts in extruder, add hot-extrudable, vacuum drying,
Prepare target product.After testing, the flexility of material reaches 82.7Mpa, notch impact strength reaches
48.3MJ/m2。
More than implementing row and the present invention is not constituted restriction, relevant staff is in the scope without departing from the technology of the present invention thought
In, carried out various changes and modifications, and all falls within protection scope of the present invention.
Claims (9)
1. the trapping worm type 3D printed material being prone to plastotype, it is characterised in that include following group according to parts by weight
Divide and make: ABS 120～140 parts；Light diffusing agent 2～8 parts；Initiator 2～8 parts；Cross-linking agent 10～20 parts；Even
Connection agent 10～20 parts；Concha Meretricis Seu Cyclinae powder 10～30 parts；Elemental sulfur 2～8 parts；Walnut shell ultrafine powder 1～4 parts；Limonene 1～
6 parts；Antibacterial 4～20 parts；Stevia rebaudiana (Bertoni) Hemsl extract 2～8 parts；Luminescent powder 2～8 parts；Auxiliary agent 0.2～0.4 part.
The trapping worm type 3D printed material being prone to plastotype the most according to claim 1, it is characterised in that according to weight
Amount number also includes feather powder 2～8 parts.
The trapping worm type 3D printed material being prone to plastotype the most according to claim 1, it is characterised in that described light
Diffusant is organosilicon light diffusing agent.
The trapping worm type 3D printed material being prone to plastotype the most according to claim 1, it is characterised in that described anti-
According to parts by weight, microbial inoculum includes that following components is made: Parmelia tinctorum Despr. extract 1～6 parts；Mint flavone extract 1～4 parts；
Luan Shu extract 1～6 parts, medical stone powder 1～4 parts.
The trapping worm type 3D printed material being prone to plastotype the most according to claim 1, it is characterised in that described in draw
Send out agent and include that following components is made according to parts by weight: light trigger 1～3 parts；Thermal initiator 1～5 parts.
The trapping worm type 3D printed material being prone to plastotype the most according to claim 1, it is characterised in that described idol
Connection agent is one or both the mixture in titanate coupling agent or silane coupler.
The trapping worm type 3D printed material being prone to plastotype the most according to claim 1, it is characterised in that described in help
According to parts by weight, agent includes that following components is made: plasticizer 0.1～0.2 part；Toughener 0.1～0.2 part.
8. the preparation method of the trapping worm type 3D printed material being prone to plastotype as described in claim 1～7, its feature exists
In comprising the steps:
1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes, grafting；
2) it is cooled to 20 DEG C～30 DEG C after stirring, puts into extruder, heating, extrusion, pulverize to obtain preparing being grafted and hand over
The ABS powder of connection agent；
3) by step 2) the ABS powder that obtains and the Concha Meretricis Seu Cyclinae powder of corresponding parts by weight, elemental sulfur, walnut shell ultrafine powder,
Coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；
4) by step 3) gains are while continue to be mixed and stirred for uniform, and mixing adds the sweet of corresponding parts by weight successively
Leaf chrysanthemum extract, antibacterial and limonene；
5) then add luminescent powder and the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；
6) while ultra violet lamp 30～60min, after stirring is cooled to 50 DEG C～55 DEG C, puts in extruder, add
Hot-extrudable, vacuum drying, prepare target product.
The preparation method of the trapping worm type 3D printed material being prone to plastotype the most according to claim 8, its feature exists
In, described step 3) be: by step 2) the ABS powder that obtains and the Concha Meretricis Seu Cyclinae powder of corresponding parts by weight, elemental sulfur,
Walnut shell ultrafine powder, feather powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106674935A (en) * | 2016-12-16 | 2017-05-17 | 华南协同创新研究院 | Luminous PLA (Polylactic Acid) wire rod for 3D (Three Dimensional) printing and preparation method thereof |
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