CN105886855A - Aluminum alloy thick plate and production method thereof - Google Patents

Aluminum alloy thick plate and production method thereof Download PDF

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Publication number
CN105886855A
CN105886855A CN201610260303.6A CN201610260303A CN105886855A CN 105886855 A CN105886855 A CN 105886855A CN 201610260303 A CN201610260303 A CN 201610260303A CN 105886855 A CN105886855 A CN 105886855A
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aluminium alloy
thick plate
temperature
rolling
aluminum alloy
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CN105886855B (en
Inventor
吕正风
张华�
孟凡林
孙学明
罗杰
陶志民
郑贵超
徐崇义
魏建民
张启东
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Hangxin Material Technology Co ltd
Longkou Nanshan Aluminum Rolling New Material Co ltd
Shandong Nanshan Aluminium Co Ltd
Yantai Nanshan University
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Shandong Nanshan Aluminium Co Ltd
Yantai Nanshan University
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08Alloys based on aluminium with magnesium as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/047Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metal Rolling (AREA)
  • Continuous Casting (AREA)

Abstract

The invention discloses an aluminum alloy thick plate and a production method thereof. Chemical components of the thick plate include, by mass percentage, 0-0.10% of Si, 0-0.20% of Fe, 0.5-0.80% of Mn, 4.1-4.6% of Mg, 0.15-0.20% of Cr, 0-0.15% of Zn, 0-0.10% of Ti and the balance Al. The method includes burdening, smelting, furnace conversion, furnace side refining, standing, casting, saw cutting, face milling, cast ingot homogenizing treatment, hot rough rolling, rolling at temperature below recrystallization temperature, pre-stretching, stabilized annealing and obtaining of finished products. According to the aluminum alloy thick plate and the production method thereof, the process period is shortened, the process cost is reduced, meanwhile, adverse effects of Fe and Si on corrosion resistance and welding performance are reduced, and the high-quality aluminum alloy plate for ships is obtained as a whole.

Description

A kind of aluminium alloy thick plate and production method thereof
Technical field
The invention belongs to the technical field that marine aluminium alloy produces, particularly relate to a kind of marine aluminium alloy slab and Its production method.
Background technology
5083 aluminium alloys belong to Al-Mg system the most heat-treatable strengthened type wrought aluminium alloy, have in shipbuilding industry It is widely applied.Owing to this alloy has higher sensitivity to intercrystalline corrosion and Peeling Corrosion, existing add Work method is: cold deformation laggard line stabilization annealing processes, and to change the unstability of its tissue, eliminates β Hand down the nethike embrane of grain boundary precipitate, thus improves the corrosion stability of 5083 sheet alloys.But prior art slab Cold deformation needs factory to have chip milling train, invisible increase equipment amount;Secondly, the process flow of prior art is long And it is complicated.At present, existing patent: CN201410777367.4;CN201410776263.1; CN201410776164.3;CN 104388854 A, has the common feature to be: 5083 aluminium alloy cast ingots are successively Through milling face, heating, hot roughing, cool roll, shear, tension straingtening sawing scale, obtain 5083 aluminum peculiar to vessel Alloy plate.Cool temperature of rolling, in the recrystallization zone of 280~340 DEG C, still falls within hot rolling scope.
Summary of the invention
It is an object of the invention to provide a kind of marine aluminium alloy 5083H116 slab, it is at nominal chemical composition On the basis of be optimized (see table 1), the alloy compositions of optimization, can improve aluminium alloy plate plasticity, Corrosion resistance and welding performance.
Table 1 nominal composition compares with chemical composition of the present invention
Another object of the present invention also resides in the marine aluminium alloy 5083H116 slab providing a kind of short process flow Production method.
The present invention adopts the following technical scheme that:
A kind of aluminium alloy thick plate, it is characterised in that the chemical composition of described aluminium alloy thick plate and mass percent For: Si 0~0.10%, Fe 0~0.20%, Mn 0.5~0.80%, Mg 4.1~4.6%, Cr 0.15~0.20%, Zn 0~0.15%, Ti 0~0.10%, surplus is Al.
A kind of above-mentioned aluminium alloy thick plate production method, it is characterised in that described method includes: dispensing → melting → converter → furnace side refine → standing → casting → sawing → milling face → homogenizing cast ingot → hot roughing → again Band warm-rolling system below crystallization temperature → prestretched → stabilizing annealing → finished product.
According to said method, it is characterised in that described method includes:
(1) melting and casting: chemical composition and mass percent by aluminium alloy thick plate prepare raw material, Smelting aluminium alloy raw material under conditions of 720~750 DEG C, when raw material of aluminum alloy 50%~60% is molten into aluminum liquid, Open electromagnetic agitation, after raw material of aluminum alloy all melts, add component additive agent, and carry out skimming, Adjusting component, transfer melt, to holding furnace, carry out furnace side Ar+Cl2Gaseous mixture refine, composition is qualified and casts After making adequate preparation, melt stands appropriate time, through online treatment under the conditions of melt temperature 700~710 DEG C, Pour into aluminium alloy cast ingot;
(2) milling face: by step (1) aluminium alloy cast ingot cutting head cutting tail, milling face;
(3) hot roughing: the aluminium alloy cast ingot after step (2) being processed is heated in step-by-step movement advances stove 480~570 DEG C, it is incubated 10h, is then rolled to the middle sheet material of 1.3~1.4 × finished product thickness, finishing temperature It it is 330~410 DEG C;
(4) band warm-rolling system: in the middle of aluminium alloy step (3) obtained, sheet material on-line cooling is to recrystallization temperature Below degree, in 230~260 DEG C of temperature ranges, band temperature is rolling to finished product thickness, and rolling deformation rate is 30~40%;
(5) stabilizing annealing process: the aluminium alloy thick plate that step (4) obtains is carried out set deformation volume 0.5~ The pre-tension deformation of 1.5%, then 200~240 DEG C of annealings, temperature retention time is 2h~4h.
Beneficial effects of the present invention:
1. a kind of marine aluminium alloy 5083H116 slab is provided, the corrosion resistance of aluminum alloy plate materials can be improve And welding performance.
In production method the most of the present invention during melt melting and casting, cleaning molten uses multi-stage combination melt Purification techniques is (that is: from the beginning of former paving material selection, mixed gas refine in smelting, melt stove, online Plural serial stage SNIF degasification, twin-stage ceramic filter, add a cover the kinds of processes measures such as chute preheating and drying is anti-pollution, Make the gas in melt, slag inclusion get rid of, obtain the Technology of purer melt), make ingot metallurgy quality Reach the level of High Purity, make ingot metallurgy quality meet: grain size 1 grade;[H]≤0.1ml/100gAl;Na < 2PPm;Ca < 4PPm;Slag N20(in every Kg aluminum, size is more than the slag content < 50,000 of 20 μm for < 50K/kg Individual).Forming property and the mechanical property of product are more excellent.
Production method the most of the present invention uses and replaces cold roller and deformed with band warm-rolling system under recrystallization temperature+prestretched, makes Process flow shortens, and reduces process costs, improves quality, it is thus achieved that high-quality marine aluminium alloy slab, There is market prospect and significant economic benefit widely.
Accompanying drawing explanation
Fig. 1 is the aluminium alloy thick plate of present invention grain structure after 200 DEG C/2h anneals;
Fig. 2 is the aluminium alloy thick plate of present invention grain structure after 220 DEG C/4h anneals;
Fig. 3 is the aluminium alloy thick plate of present invention grain structure after 240 DEG C/2h anneals.
Detailed description of the invention
The aluminium alloy thick plate of the present invention, chemical composition and mass percent be: Si 0~0.10%, Fe 0~ 0.20%, Mn 0.5~0.80%, Mg 4.1~4.6%, Cr 0.15~0.20%, Zn 0~0.15%, Ti 0~ 0.10%, surplus is Al.The production method of the present invention includes: dispensing → melting → converter → furnace side refine → quiet Put → cast → sawing → milling face → homogenizing cast ingot → hot roughing → recrystallization temperature below band warm-rolling system → prestretched → stabilizing annealing → finished product.
Below in conjunction with some specific embodiments, the present invention is further described.
A kind of marine aluminium alloy (5083H116) slab, its chemical composition and percent mass such as table 2.
This alloying component measured value (wt%) of table 2
One of production method of marine aluminium alloy 5083H116 slab that one of example 1~3 is the most described, including Following steps:
(1) melting and casting: by chemical composition and the quality hundred of the most described aluminium alloy thick plate of example 1~3 Proportion by subtraction prepares raw material, and wherein, solid material accounts for 40%, and I and II waste material is less than 40%, and remaining is electrolysis Liquid.Smelting aluminium alloy raw material under conditions of 720~750 DEG C, raw material of aluminum alloy 50%~60% melts During for aluminum liquid, open electromagnetic agitation, after raw material of aluminum alloy all melts (720 DEG C), add composition and add Add agent, and carry out skimming, adjusting component, transfer melt to holding furnace, carry out furnace side Ar+Cl2 gaseous mixture essence Refining (STAS), after composition is qualified and casting is made adequate preparation, melt stands appropriate time, at melt temperature 700~ Process through online (SNIF degasification, CCF filter (30PPI+50PPI), crystal grain refinement) under the conditions of 710 DEG C, Pour into aluminium alloy cast ingot.Ingot metallurgy quality meets: grain size 1 grade;[H]=0.079ml/100gAl;Na < 2ppm;Ca < 4PPM;Slag N20< 30K/kg
(2) milling face: by step (1) aluminium alloy cast ingot cutting head cutting tail, milling face.
(3) hot roughing: the aluminium alloy cast ingot after step (2) being processed is heated in step-by-step movement advances stove 560 DEG C/8h+480 DEG C/2h, in 4100mm hot hot rough rolling mill group, then it is rolled to (1.3~1.4 × finished product thickness Degree) middle sheet material, finishing temperature is 351 DEG C.
(4) band warm-rolling system: the middle sheet material on-line cooling 240 of the aluminium alloy that step (3) is obtained~260 DEG C, Band temperature is rolling to finished product thickness 16.13mm.Rolling deformation rate is 36%.
(5) stabilizing annealing processes: the aluminium alloy thick plate that step (4) obtains is carried out set deformation volume 0.8% Pre-tension deformation.Then 200 DEG C of annealings, temperature retention time is 2h.
The two of the production method of the marine aluminium alloy 5083H116 slab that one of example 1~3 is the most described, including Following steps:
(1) melting and casting: by chemical composition and the quality hundred of the most described aluminium alloy thick plate of example 1~3 Proportion by subtraction prepares raw material, and wherein, solid material accounts for 35%, and I and II waste material is less than 35%, and remaining is electrolysis Liquid.Smelting aluminium alloy raw material under conditions of 720~750 DEG C, raw material of aluminum alloy 50%~60% melts During for aluminum liquid, open electromagnetic agitation, after raw material of aluminum alloy all melts (720 DEG C), add composition and add Add agent, and carry out skimming, adjusting component, transfer melt to holding furnace, carry out furnace side Ar+Cl2Gaseous mixture refine (STAS), after composition is qualified and casting is made adequate preparation, melt stands appropriate time, at melt temperature 700~ Process through online (SNIF degasification, CCF filter (30PPI+50PPI), crystal grain refinement) under the conditions of 710 DEG C, Pour into aluminium alloy cast ingot.Ingot metallurgy quality meets: grain size 1 grade;[H]=0.073ml/100gAl;Na < 2ppm;Ca < 4PPM;Slag N20< 30K/kg
(2) milling face: by step (1) aluminium alloy cast ingot cutting head cutting tail, milling face.
(3) hot roughing: the aluminium alloy cast ingot after step (2) being processed is heated in step-by-step movement advances stove 560 DEG C/8h+480 DEG C/2h, in 4100mm hot hot rough rolling mill group, then it is rolled to (1.3~1.4 × finished product thickness Degree) middle sheet material, finishing temperature is 338 DEG C.
(4) band warm-rolling system: the middle sheet material on-line cooling 240 of the aluminium alloy that step (3) is obtained~260 DEG C, Band temperature is rolling to finished product thickness 16.16mm.Rolling deformation rate is 25.4%.
(5) stabilizing annealing processes: the aluminium alloy thick plate that step (4) obtains is carried out set deformation volume 1.0% Pre-tension deformation.Then 220 DEG C of annealings, temperature retention time is 4h.
The three of the production method of the marine aluminium alloy 5083H116 slab that one of example 1~3 is the most described, including Following steps:
(1) melting and casting: by chemical composition and the quality hundred of the most described aluminium alloy thick plate of example 1~3 Proportion by subtraction prepares raw material, and wherein, solid material accounts for 40%, and I and II waste material is less than 40%, and remaining is electrolysis Liquid.Smelting aluminium alloy raw material under conditions of 720~750 DEG C, raw material of aluminum alloy 50%~60% melts During for aluminum liquid, open electromagnetic agitation, after raw material of aluminum alloy all melts (720 DEG C), add composition and add Add agent, and carry out skimming, adjusting component, transfer melt to holding furnace, carry out furnace side Ar+Cl2Gaseous mixture refine (STAS), after composition is qualified and casting is made adequate preparation, melt stands appropriate time, at melt temperature 700~ Process through online (SNIF degasification, CCF filter (30PPI+50PPI), crystal grain refinement) under the conditions of 710 DEG C, Pour into aluminium alloy cast ingot.Ingot metallurgy quality meets: grain size 1 grade;[H]=0.081ml/100gAl;Na < 2ppm;Ca < 4PPM;Slag N20< 30K/kg
(2) milling face: by step (1) aluminium alloy cast ingot cutting head cutting tail, milling face.
(3) hot roughing: the aluminium alloy cast ingot after step (2) being processed is heated in step-by-step movement advances stove 560 DEG C/8h+480 DEG C/2h, in 4100mm hot hot rough rolling mill group, then it is rolled to (1.3~1.4 × finished product thickness Degree) middle sheet material, finishing temperature is 350 DEG C.
(4) band warm-rolling system: the middle sheet material on-line cooling 240 of the aluminium alloy that step (3) is obtained~260 DEG C, Band temperature is rolling to finished product thickness 16.25mm.Rolling deformation rate is 35.4%.
(5) stabilizing annealing processes: the aluminium alloy thick plate that step (4) obtains is carried out set deformation volume 1.5% Pre-tension deformation.Then 240 DEG C of annealings, temperature retention time is 2h.
The production method one of arbitrarily of the marine aluminium alloy 5083H116 slab described in example 1~3 produces slab On take longitudinal sample, at room temperature, detect the mechanical property of aluminium alloy thick plate, anti-crystalline substance by ASTM B928 requirement Between corrosion and exfoliation Corrosion and welding performance.Its result is as shown in table 3.Visible, 5083H116 slab Combination property preferable.Fig. 1-Fig. 3 is 5083H116 grain structure after difference is annealed.
5083H116 Plate properties detection under table 3 room temperature

Claims (3)

1. an aluminium alloy thick plate, it is characterised in that the chemical composition of described aluminium alloy thick plate and percent mass Ratio is: Si 0~0.10%, Fe 0~0.20%, Mn 0.5~0.80%, Mg 4.1~4.6%, Cr 0.15~ 0.20%, Zn 0~0.15%, Ti 0~0.10%, surplus is Al.
2. an aluminium alloy thick plate production method as claimed in claim 1, it is characterised in that described method Including: dispensing → melting → converter → furnace side refine → standing → casting → sawing → milling face → ingot homogenization Band warm-rolling system → prestretched → stabilizing annealing → finished product below process → hot roughing → recrystallization temperature.
Method the most according to claim 2, it is characterised in that described method includes:
(1) melting and casting: chemical composition and mass percent by aluminium alloy thick plate prepare raw material, Smelting aluminium alloy raw material under conditions of 720~750 DEG C, when raw material of aluminum alloy 50%~60% is molten into aluminum liquid, Open electromagnetic agitation, after raw material of aluminum alloy all melts, add component additive agent, and carry out skimming, Adjusting component, transfer melt, to holding furnace, carry out furnace side Ar+Cl2 gaseous mixture refine, and composition is qualified and casts After making adequate preparation, melt stands appropriate time, through online treatment under the conditions of melt temperature 700~710 DEG C, Pour into aluminium alloy cast ingot;
(2) milling face: by step (1) aluminium alloy cast ingot cutting head cutting tail, milling face;
(3) hot roughing: the aluminium alloy cast ingot after step (2) being processed is heated in step-by-step movement advances stove 480~570 DEG C, it is incubated 10h, is then rolled to the middle sheet material of 1.3~1.4 × finished product thickness, finishing temperature It it is 330~410 DEG C;
(4) band warm-rolling system: in the middle of aluminium alloy step (3) obtained, sheet material on-line cooling is to recrystallization temperature Below degree, in 230~260 DEG C of temperature ranges, band temperature is rolling to finished product thickness, and rolling deformation rate is 30~40%;
(5) stabilizing annealing process: the aluminium alloy thick plate that step (4) obtains is carried out set deformation volume 0.5~ The pre-tension deformation of 1.5%, then 200~240 DEG C of annealings, temperature retention time is 2h~4h.
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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105908025A (en) * 2016-06-12 2016-08-31 山东南山铝业股份有限公司 Aluminum alloy thick plate and production method thereof
CN105925858A (en) * 2016-06-12 2016-09-07 山东南山铝业股份有限公司 Aluminum alloy sheet and production method thereof
CN106282694A (en) * 2016-09-20 2017-01-04 池州市安安精工铝业有限公司 A kind of high-strength abrasion-proof aluminium alloy extrusions and preparation method thereof
CN106917017A (en) * 2017-03-28 2017-07-04 山东南山铝业股份有限公司 Aluminum alloy plate materials and its production method
CN107164666A (en) * 2017-05-31 2017-09-15 辽宁忠旺集团有限公司 5083 the ships energetic plate of aluminium alloy and its extrusion process
CN108388706A (en) * 2018-02-01 2018-08-10 广西南南铝加工有限公司 The computational methods of drawing force and its application in a kind of aluminum alloy plate materials preparation process
CN109022958A (en) * 2018-09-18 2018-12-18 天津忠旺铝业有限公司 A kind of manufacturing method of 5083 aluminium alloy thick plate peculiar to vessel
CN109355535A (en) * 2018-11-29 2019-02-19 天津忠旺铝业有限公司 A kind of preparation method of 5083 aluminum alloy plate materials
CN110042283A (en) * 2019-05-08 2019-07-23 烟台南山学院 Strong Alcoa plate preparation method in one kind
CN111961932A (en) * 2020-08-18 2020-11-20 广西南南铝加工有限公司 Preparation method of ultra-flat aluminum alloy medium plate
CN113174500A (en) * 2021-04-29 2021-07-27 郑州明泰实业有限公司 Method for improving O-state bending performance of 5083 alloy

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CN101914710A (en) * 2010-09-16 2010-12-15 东北轻合金有限责任公司 Aluminum alloy sheet for high-speed train structure and manufacture thereof
CN102899541A (en) * 2012-08-29 2013-01-30 东北轻合金有限责任公司 5A06H14 sheet metal with thickness of 8.5mm, and preparation method thereof
CN104894442A (en) * 2015-05-05 2015-09-09 山东南山铝业股份有限公司 Aluminum alloy sheet material for vehicles and preparation method thereof

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JP2007070672A (en) * 2005-09-06 2007-03-22 Furukawa Sky Kk Method for producing aluminum alloy thick plate having excellent fatigue property
CN101037747A (en) * 2007-04-29 2007-09-19 东北轻合金有限责任公司 Aviation aluminum alloy pre-stretching plate and production method thereof
CN101914710A (en) * 2010-09-16 2010-12-15 东北轻合金有限责任公司 Aluminum alloy sheet for high-speed train structure and manufacture thereof
CN102899541A (en) * 2012-08-29 2013-01-30 东北轻合金有限责任公司 5A06H14 sheet metal with thickness of 8.5mm, and preparation method thereof
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105908025A (en) * 2016-06-12 2016-08-31 山东南山铝业股份有限公司 Aluminum alloy thick plate and production method thereof
CN105925858A (en) * 2016-06-12 2016-09-07 山东南山铝业股份有限公司 Aluminum alloy sheet and production method thereof
CN106282694A (en) * 2016-09-20 2017-01-04 池州市安安精工铝业有限公司 A kind of high-strength abrasion-proof aluminium alloy extrusions and preparation method thereof
CN106917017A (en) * 2017-03-28 2017-07-04 山东南山铝业股份有限公司 Aluminum alloy plate materials and its production method
CN107164666A (en) * 2017-05-31 2017-09-15 辽宁忠旺集团有限公司 5083 the ships energetic plate of aluminium alloy and its extrusion process
CN107164666B (en) * 2017-05-31 2018-08-14 辽宁忠旺集团有限公司 The energetic plate of 5083 ship aluminium alloys and its extrusion process
CN108388706A (en) * 2018-02-01 2018-08-10 广西南南铝加工有限公司 The computational methods of drawing force and its application in a kind of aluminum alloy plate materials preparation process
CN109022958A (en) * 2018-09-18 2018-12-18 天津忠旺铝业有限公司 A kind of manufacturing method of 5083 aluminium alloy thick plate peculiar to vessel
CN109355535A (en) * 2018-11-29 2019-02-19 天津忠旺铝业有限公司 A kind of preparation method of 5083 aluminum alloy plate materials
CN110042283A (en) * 2019-05-08 2019-07-23 烟台南山学院 Strong Alcoa plate preparation method in one kind
CN111961932A (en) * 2020-08-18 2020-11-20 广西南南铝加工有限公司 Preparation method of ultra-flat aluminum alloy medium plate
CN113174500A (en) * 2021-04-29 2021-07-27 郑州明泰实业有限公司 Method for improving O-state bending performance of 5083 alloy

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