CN105886169A - Powder detergent bag and preparation method thereof - Google Patents
Powder detergent bag and preparation method thereof Download PDFInfo
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- CN105886169A CN105886169A CN201410771240.1A CN201410771240A CN105886169A CN 105886169 A CN105886169 A CN 105886169A CN 201410771240 A CN201410771240 A CN 201410771240A CN 105886169 A CN105886169 A CN 105886169A
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Abstract
The invention provides a powder detergent bag which is a quantitative solid detergent of which the packaging material is a water-soluble polymer. The content of the powder detergent bag is prepared from the following components in percentage by weight: 20-60% of inorganic base, 5-15% of nonionic surfactant, 8-15% of 4A zeolite, 5-10% of organic acid, 0-5% of sodium citrate, 0-1% of enzyme, 0-0.5% of whitening agent, 0-2% of polymer and the balance of mirabilite. Through formula structure optimization and technology control, the content powder detergent and the water-soluble film packaging material are in synergistic compatibility, and the powder detergent bag has the advantages of fast dissolution in water, good storage stability and short cleaning time.
Description
Technical field
The present invention relates to daily detergent applications.More specifically, the present invention relates to a kind of detergent powder bag and
Its preparation method.
Background technology
Polyvinyl alcohol (PVA) water-soluble film, as a kind of packaging film material, pesticide, detergent,
Application has been arrived in the fields such as food.Compared to other PP, PE, PVC film, the biological degradability of PVA film to get well,
It is dissolved in noresidue after water, and eliminates a lot of trouble when packing for article, packaging can be taken apart directly
Use, conveniently measure.At present, occurred in that PVA film is applied to the product of liquid detergent
The green solidifying pearl of wave laundry, this series products need not contact detergent itself, according to laundry amounts first use when of use
One or two, will not splash the when of use, easily, commercially be favored by a part of consumer.
At present in disclosed PVA water-soluble packed detergent patent, it is all about the water-soluble bag of liquid detergent
Dress dissolving, detection method and the research of packaging molding thereof, water-soluble to PVA without reference to component in detergent powder
The impact of packaging.As CN101517061A discloses a kind of detergent bag, this patent mainly solves detergent
Middle spice hides problem to PVA film abnormal smells from the patient and can fragrance do not mention other through the problem of PVA film
The impact that water soluble film is packed by detergent component.Liquid detergent composition and detergent powder have bigger difference,
The acid-base value of two kinds of products has the biggest difference: general liquid detergent, mainly based on surfactant, contains
A small amount of inorganic or organic salt auxiliary agent, for neutral or low alkalinity；Detergent powder surface-active contents is less than
Liquid detergent, containing the raw materials such as more inorganic salts auxiliary agent such as inorganic alkaline raw material, Sulfates compounding and
Become, be typically high alkalinity.PVA film has fabulous oil resistivity, organic solvent-resistant and carbohydrate etc.,
But highly basic, strong acid, chlorine radical and other can with PVA occur chemical reaction material (as Borax, boric acid,
Some dyestuff etc.), thus PVA film is used as the detergent powder packaging compounding containing plurality of raw materials, need comprehensive
Consider the recipe ingredient impact on PVA film, it is especially desirable to concern as to whether that the dissolubility to film and storage stability have
Impact.
The regular powder commercially available by trial PVA film packaging and concentration powder, through constant temperature and humidity 37 DEG C 75%
Storing January under humidity, the result almost compatibility all there is a problem, PVA film occurs that variable color, dissolubility are deteriorated
Even can not dissolve.For the problems referred to above, the present invention is by the rational proportion of recipe ingredient and production technology
Optimize and revise, get rid of influential component, the production technology of conservative control powder, improve PVA water soluble film and powder
The compatibility of shape detergent, is more suitable for PVA water soluble film packaging than generally conventional detergent formula, can make powdery
Detergent product shelf life of contracting for fixed output quotas is longer.
Summary of the invention
It is an object of the invention to provide a kind of detergent powder bag, it is desirable to provide one is done washing easily and used powder mode
And solve conventional detergent powder formula and be not suitable for the situation of water-solubility PVA packaging film, by optimization of C/C composites structure
With technology controlling and process make content detergent powder and PVA film can good compatibility so that use PVA film bag
The detergent powder of dress is surrounded by well solubility property, good clean effect.
The present invention reaches goal of the invention by following technical method:
A kind of detergent powder bag, is packed by water soluble package material and detergent powder content and forms, and it is special
Levy and be:
Described water soluble package material selection polyvinyl alcohol film or modified polyvinylalcohol thin film；
Described detergent powder content is formed by following components configuration:
Wherein: inorganic base selects sodium silicate, anhydrous partial silicon, metasilicate pentahydrate sodium, sodium carbonate, potassium carbonate and carbonic acid
A kind of or the most several mixing in hydrogen sodium；
Fatty alcohol-polyoxyethylene ether selected by nonionic surfactant；
Organic acid selection citric acid, oxalic acid, linear dodecylbenzene sulfonic acid, tartaric acid and 1-hydroxyl ethylidene-1,1 '-
A kind of or the most several mixing in di 2 ethylhexyl phosphonic acid (i.e. HEDP)；
Enzyme selects the one or any several mixing in protease, lipase, cellulase, amylase.
Brightening agent selects 4-4-stilbenesulphonic acid base diphenyl disodium (trade name CBS-X, CF-351) or hexichol
Any in ethylene triazine amidodisulfonic acid sodium (trade name DMS, DMA-X, 2M/GLT, 33# brightening agent etc.)
One or both mixture；
One in acrylate homopolymer, maleic acid-acrylic acid copolymer and Styrene And Chloroalkyl Acrylates that polymer is selected
Or the most several mixing.
Described detergent powder bag, is characterized in that:
The thickness of water soluble package material is in 35 μm～50 μm；
Nonionic surfactant select carbon chain lengths 12～15 and ethylene oxide number 7～9 fatty alcohol polyoxy
Vinyl Ether
Polymer is graininess.
The preparation method of described detergent powder bag, is characterized in that: implement as follows:
Put into inorganic base, surplus Natrii Sulfas, 3%～10% organic acid successively, in mixer after stir about 5min again
Put into 0～5% sodium citrate, 0～2% polymer, 5～15% nonionic surfactant, 0～1% enzyme, 8～
15%4A zeolite, 0～0.5% brightening agent, discharging after stirring；The hot-seal packing machine bag bled with Horizontal band again
Dress up the cryptomere of 15g～35g or spherical parcel.
Detailed description of the invention
Embodiment 1
First in mixer, put into 20% sodium carbonate, 20% sodium bicarbonate, surplus Natrii Sulfas, 4% dodecyl successively
Benzenesulfonic acid, 1%HEDP, put into again after stir about 5min 2% sodium citrate, 0.5% sodium polyacrylate, 11%
The aliphatic alcohol polyether-7 of C12～C15,0.2% protease, 10%4A zeolite, 0.15%CBS-X, stirring is all
Even rear discharging；Selecting the PVA film of low temperature water-soluble thickness 35 μm, the hot-seal packing machine bled with Horizontal band is packed
Become the cryptomere of 15g-35g or spherical detergent parcel.
Embodiment 2
First in mixer, put into 26% sodium carbonate, 2% metasilicate pentahydrate sodium, 18% sodium bicarbonate, surplus successively
Natrii Sulfas, 9% DBSA, 0.8%HEDP, put into again after stir about 5min 4% sodium citrate, 1.2%
Horse propylene copolymer granule, the aliphatic alcohol polyether-9 of 8%C12～C14,0.15% protease, 0.10% cellulase,
10.5%4A zeolite, 0.20%DMS, discharging after stirring；Select the PVA of low temperature water-soluble thickness 35 μm
Film, the hot-seal packing machine bled with Horizontal band is packaged into the cryptomere of 15g～35g or spherical detergent parcel.
Embodiment 3
First put into successively in mixer 24% sodium carbonate, 5% potassium carbonate, 15% sodium bicarbonate, surplus Natrii Sulfas,
8% DBSA, 1.6%HEDP, put into again after stir about 5min 2.5% sodium citrate, 0.8% gather
Sodium acrylate, the aliphatic alcohol polyether-9 of 8%C12～C15,0.2% lipase, 0.2% protease, 9%4A zeolite,
0.15%CBS-X, discharging after stirring；Select the PVA film of low temperature water-soluble thickness 35 μm, take out with Horizontal band
The hot-seal packing machine of gas is packaged into the cryptomere of 15g～35g or spherical detergent parcel.
Embodiment 4
First in mixer, put into 21% sodium carbonate, 25% sodium bicarbonate, surplus Natrii Sulfas, 4.8% dodecane successively
Base benzenesulfonic acid, 0.5%HEDP, put into again after stir about 5min 3% sodium citrate, 0.5% sodium polyacrylate, 0.5%
Maleic acid-acrylic acid copolymer granule, the aliphatic alcohol polyether-7 of 15%C12～C14,0.1% protease, 0.2 multiple
Synthase, 12%4A zeolite, 0.10%CBS-X, 0.2%DMS, discharging after stirring；Selection low temperature is water-soluble
The PVA film of thickness 35 μm, the hot-seal packing machine bled with Horizontal band is packaged into the cryptomere of 15g～35g or spherical
Detergent parcel.
Embodiment 5
First put into successively in mixer 25% sodium carbonate, 2% anhydrous partial silicon, 16% sodium bicarbonate, surplus Natrii Sulfas,
6% DBSA, 1%HEDP, put into 2% sodium citrate, 0.5% polypropylene again after stir about 5min
Acid sodium, 0.5% horse propylene copolymer granule, the aliphatic alcohol polyether-9 of 12%C12～C14,0.2% protease, 0.10%
Cellulase, 13%4A zeolite, 0.2%CBS-X, discharging after stirring；Select low temperature water-soluble thickness 35 μm
PVA film, the hot-seal packing machine bled with Horizontal band is packaged into the cryptomere of 15g～35g or spherical detergent is little
Bag.
Solubility experiment: all make the square of specification 5cm × 5cm, 20g with PVA film by embodiment 1～5 and wash
Clothing powder bag, selects three kinds of commercially available detergent to do matched group simultaneously, in 37 DEG C, 75% climatic chamber stores 0
Week, 2 weeks, 4 weeks, carry out solubility experiment.
Experimental technique: under room temperature, in the beaker of 1L add 800L tap water, put into 5em magnetic stir bar,
Being placed on magnetic stirring apparatus, adjustment of rotational speed, for can form small whirlpool at the page, fixes rotating speed, surveys respectively
Try the rupture time of each PVA detergent bag, it is judged that dissolve situation.Test result is as shown in table 1:
Table 1
| Dissolubility | 0 week | 2 weeks | 4 weeks |
| Embodiment 1 | 40sec | 1min | 1min32sec |
| Embodiment 2 | 45sec | 1min22sec | 2min04sec |
| Embodiment 3 | 39sec | 1min10sec | 1min46sec |
| Embodiment 4 | 42sec | 1min | 1min25sec |
| Embodiment 5 | 45see | 1min25sec | 2min28sec |
| Commercially available powder 1 | 49see | 5min21sec | 7min17sec |
| Commercially available powder 2 | 59sec | 10min18sec | Can not break |
| Commercially available powder 3 | 53sec | 7min20sec | 12min34sec |
Finding out from the above, along with the prolongation of the time of storage, the PVA bag dissolubility equipped with commercial laundry powder is bright
Aobvious being deteriorated, after storing surrounding, 1 detergent PVA bag can not break dissolving, and other 2 break and wash around
Wash the time, so it is shorter to pack commercial laundry powder shelf life with PVA film.And the PVA laundry of embodiment 1～5
Powder bag is little along with the prolongation dissolubility change of the time of storage, thus can have longer shelf life.
Claims (3)
1. a detergent powder bag, is packed by water soluble package material and detergent powder content and forms, it is characterized in that:
Described water soluble package material selection polyvinyl alcohol film or modified polyvinylalcohol thin film；
Described detergent powder content is formed by following components configuration:
Wherein: a kind of or the most several mixing in sodium silicate, anhydrous partial silicon, metasilicate pentahydrate sodium, sodium carbonate, potassium carbonate and sodium bicarbonate selected by inorganic base；
Fatty alcohol-polyoxyethylene ether selected by nonionic surfactant；
Organic acid selects citric acid, oxalic acid, linear dodecylbenzene sulfonic acid, tartaric acid and 1-hydroxyl ethylidene-1, a kind of or the most several mixing in 1 '-di 2 ethylhexyl phosphonic acid (i.e. HEDP)；
Enzyme selects the one or any several mixing in the mixture of a kind of or any several enzyme of protease, lipase, cellulase, starch enzyme.
Any one or the mixture of two kinds in 4-4-stilbenesulphonic acid base diphenyl disodium (trade name CBS-X, CF-351 etc.) or stilbene triazine amidodisulfonic acid sodium (trade name DMS, DMA-X, 2M/GLT, 33# brightening agent etc.) commodity selected by brightening agent；
A kind of or the most several mixing in acrylate homopolymer, maleic acid-acrylic acid copolymer and Styrene And Chloroalkyl Acrylates that polymer is selected.
2. detergent powder bag as claimed in claim 1, is characterized in that:
The thickness of water soluble package material is in 35 μm～50 μm；
Nonionic surfactant select carbon chain lengths 12～15 and ethoxymer distribution 7～9 fatty alcohol-polyoxyethylene ether polymer be graininess.
3. the preparation method of detergent powder bag as claimed in claim 1 or 2, is characterized in that: implement as follows:
Inorganic base, surplus Natrii Sulfas, 3%～10% organic acid is put into successively in mixer, 0～5% sodium citrate, 0～2% polymer, 5～15% nonionic surfactant, 0～1% enzyme, 8～15%4A zeolite, 0～0.5% brightening agent, discharging after stirring is put into again after stir about 5min；The hot-seal packing machine bled with Horizontal band again is packaged into the cryptomere of 15g～35g or spherical parcel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410771240.1A CN105886169B (en) | 2014-12-15 | 2014-12-15 | Detergent powder packet and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410771240.1A CN105886169B (en) | 2014-12-15 | 2014-12-15 | Detergent powder packet and preparation method thereof |
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| CN105886169A true CN105886169A (en) | 2016-08-24 |
| CN105886169B CN105886169B (en) | 2019-09-13 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106566732A (en) * | 2016-09-30 | 2017-04-19 | 奉化市瑶琴生物科技有限公司 | Phosphorus-free, fluorescent agent-free and preservative-free super-concentrated capsule granule laundry detergent, preparation method and use method thereof |
| CN106675881A (en) * | 2016-12-06 | 2017-05-17 | 钦州市高新技术产业服务中心 | Powdered detergent bag and preparation method thereof |
| CN108315108A (en) * | 2018-04-09 | 2018-07-24 | 深圳市科曼环保科技有限公司 | A kind of environment-friendly highly efficient steel and iron parts dust remover |
| CN108893205A (en) * | 2018-06-21 | 2018-11-27 | 界首市洁净日用品有限公司 | A kind of capsule-type powder laundry detergent |
| CN109231401A (en) * | 2018-08-29 | 2019-01-18 | 广州邦葳纺织助剂有限公司 | A kind of heavy mental treatment agent and preparation method thereof |
| CN111819274A (en) * | 2018-03-08 | 2020-10-23 | 埃科莱布美国股份有限公司 | Solid enzyme detergent compositions and methods of use and manufacture thereof |
| CN115125067A (en) * | 2022-06-28 | 2022-09-30 | 传化集团有限公司日用品分公司 | Clothes detergent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106566732A (en) * | 2016-09-30 | 2017-04-19 | 奉化市瑶琴生物科技有限公司 | Phosphorus-free, fluorescent agent-free and preservative-free super-concentrated capsule granule laundry detergent, preparation method and use method thereof |
| CN106675881A (en) * | 2016-12-06 | 2017-05-17 | 钦州市高新技术产业服务中心 | Powdered detergent bag and preparation method thereof |
| CN111819274A (en) * | 2018-03-08 | 2020-10-23 | 埃科莱布美国股份有限公司 | Solid enzyme detergent compositions and methods of use and manufacture thereof |
| CN111819274B (en) * | 2018-03-08 | 2022-06-21 | 埃科莱布美国股份有限公司 | Solid enzyme detergent compositions and methods of use and manufacture thereof |
| CN108315108A (en) * | 2018-04-09 | 2018-07-24 | 深圳市科曼环保科技有限公司 | A kind of environment-friendly highly efficient steel and iron parts dust remover |
| CN108893205A (en) * | 2018-06-21 | 2018-11-27 | 界首市洁净日用品有限公司 | A kind of capsule-type powder laundry detergent |
| CN109231401A (en) * | 2018-08-29 | 2019-01-18 | 广州邦葳纺织助剂有限公司 | A kind of heavy mental treatment agent and preparation method thereof |
| CN115125067A (en) * | 2022-06-28 | 2022-09-30 | 传化集团有限公司日用品分公司 | Clothes detergent |
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