CN109231401A - A kind of heavy mental treatment agent and preparation method thereof - Google Patents
A kind of heavy mental treatment agent and preparation method thereof Download PDFInfo
- Publication number
- CN109231401A CN109231401A CN201810996842.5A CN201810996842A CN109231401A CN 109231401 A CN109231401 A CN 109231401A CN 201810996842 A CN201810996842 A CN 201810996842A CN 109231401 A CN109231401 A CN 109231401A
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- Prior art keywords
- treatment agent
- heavy mental
- mental treatment
- preparation
- heavy
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
- C02F1/62—Heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/203—Iron or iron compound
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/206—Manganese or manganese compounds
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of heavy mental treatment agent, including following component by weight: 20-45 parts of cellulase；5-25 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid；Single water citric acid 20-40 parts；10-55 parts of deionized water.The invention also discloses the preparation methods of heavy mental treatment agent.Heavy mental treatment agent of the invention can reduce the heavy metal ion content on fabric or clothes, reach control standard, while mitigate pollution of the sewage to ecological environment.
Description
Technical field
The present invention relates to a kind of biological assistants, and in particular to a kind of heavy mental treatment agent and preparation method thereof.
Background technique
With country to ecological energy-saving, environmental protection, health advances calls, to the requirement of chemical residues amount on fabric (clothes)
It is higher and higher.Such as domestic each province's fiber check and measure institute, heavy metal ion content is all limited the quantity on fabric (clothes), country
It is required that common Con trolling index has: arsenic, cadmium, cobalt, chromium, copper, nickel, lead, antimony, iron plasma.If fabric is examined through third party's profession
Mechanism test failure is surveyed, will lead to fabric client can not delivery just-in-time, the only processing of work low price or compensation deals.If gone out
Mouth is abroad just found the problem, and client will undertake the failure costs such as charge for loss of working time, traffic expense, labour cost, cost, pollution charges,
Number is big to be estimated, and this fabric (clothes) dress also brings potential injury to human skin, or even to ecology
Also the pollution for being difficult to degrade is brought.In the prior art, aiming at the problem that finished fabric heavy metals exceeding standard, there is presently no relevant
Processing method and reagent treatment.
Summary of the invention
For overcome the deficiencies in the prior art, one of the objects of the present invention is to provide a kind of heavy mental treatment agent,
It can reduce the heavy metal ion content on fabric or clothes, reach control standard, while mitigate sewage to ecological environment
Pollution.
The second object of the present invention is to provide a kind of preparation method of heavy mental treatment agent.
An object of the present invention adopts the following technical scheme that realization:
A kind of heavy mental treatment agent, which is characterized in that including following component by weight:
Further, the cellulase, 1-hydroxy ethylidene-1,1-diphosphonic acid, single water citric acid weight ratio be 35:10-20:30-
40。
Further, the cellulase, 1-hydroxy ethylidene-1,1-diphosphonic acid, single water citric acid weight ratio be 35:15:34.
Further, the heavy mental treatment agent is prepared by following component by weight:
Further, the heavy mental treatment agent is prepared by following component by weight:
It further, further include carboxymethyl chitosan, the additive amount of the carboxymethyl chitosan is 5-10 parts.
Further, the heavy mental treatment agent is prepared by following component by weight:
The second object of the present invention adopts the following technical scheme that realization:
A kind of preparation method of heavy mental treatment agent characterized by comprising
Material preparation step: each raw material is weighed respectively according to formulation ratio；
Mixing step: the cellulase of formula ratio is placed in reaction kettle, is stirred for the first time, by the surplus stock of formula ratio
It is all added in reaction kettle, second of stirring obtains heavy mental treatment agent.
Further, in mixing step, in first time whipping process, mixing speed 50-200r/min, mixing time is
5-20r/min；In second of whipping process, mixing speed 50-200r/min, mixing time 10-30r/min.
Further, in mixing step, in first time whipping process, mixing speed 100r/min, mixing time is
10r/min；In second of whipping process, mixing speed 150r/min, mixing time 20r/min.
The beneficial effects of the present invention are:
The present invention is used cooperatively using cellulase, 1-hydroxy ethylidene-1,1-diphosphonic acid, single water citric acid, and is optimized matching for each component
Than, 1-hydroxy ethylidene-1,1-diphosphonic acid as chelating agent, single water citric acid (Citric Acid Mono) is used as detergent, 1-hydroxy ethylidene-1,1-diphosphonic acid with
Single water citric acid, cellulase are used cooperatively, and have synergistic effect, the removal efficiency of heavy metal ion can be improved, can reduce
Heavy metal ion content on fabric or clothes reaches control standard, while mitigating pollution of the sewage to ecological environment.In addition,
Due to not only containing amino on carboxymethyl chitosan strand but also containing carboxyl, it is similar to amino acid, is conducive to electrically charged to surface
Pollutant removing, and it is with good water solubility.
Specific embodiment
In the following, being described further in conjunction with specific embodiment to the present invention, it should be noted that is do not collided
Under the premise of, new embodiment can be formed between various embodiments described below or between each technical characteristic in any combination.
A kind of heavy mental treatment agent, including following component by weight:
As the mode that further carries out, the cellulase, 1-hydroxy ethylidene-1,1-diphosphonic acid, single water citric acid weight ratio be
35:10-20:30-40。
As the mode that further carries out, the cellulase, 1-hydroxy ethylidene-1,1-diphosphonic acid, single water citric acid weight ratio be
35:15:34。
As the mode that further carries out, the heavy mental treatment agent by by weight following component preparation and
At:
As the mode that further carries out, the heavy mental treatment agent by by weight following component preparation and
At:
It further include carboxymethyl chitosan as mode is further carried out, the additive amount of the carboxymethyl chitosan is 5-
10 parts.
As the mode that further carries out, the heavy mental treatment agent by by weight following component preparation and
At:
A kind of preparation method of heavy mental treatment agent, comprising:
Material preparation step: each raw material is weighed respectively according to formulation ratio；
Mixing step: the cellulase of formula ratio is placed in reaction kettle, is stirred for the first time, by the surplus stock of formula ratio
It is all added in reaction kettle, second of stirring obtains heavy mental treatment agent.
As the mode that further carries out, in mixing step, in first time whipping process, mixing speed 50-200r/
Min, mixing time 5-20r/min；In second of whipping process, mixing speed 50-200r/min, mixing time 10-
30r/min。
As the mode that further carries out, in mixing step, in first time whipping process, mixing speed 100r/min,
Mixing time is 10r/min；In second of whipping process, mixing speed 150r/min, mixing time 20r/min.
It is specific embodiment of the present invention below, used raw material, equipment etc. remove special limit in the following embodiments
It can be obtained by buying pattern outside fixed.
Embodiment 1:
A kind of heavy mental treatment agent, is prepared by following component by weight: 35 parts of cellulase, hydroxyl
15 parts of ethylene-diphosphonic acid, single 34 parts of water citric acid, 16 parts of deionized water.
A kind of preparation method of heavy mental treatment agent, comprising:
Material preparation step: each raw material is weighed respectively according to formulation ratio；
Mixing step: the cellulase of formula ratio is placed in reaction kettle, is stirred for the first time, mixing speed 100r/
Min, mixing time 10r/min the surplus stock of formula ratio are all added in reaction kettle, second of stirring, mixing speed
Heavy mental treatment agent is obtained for 150r/min, mixing time 20r/min.
Embodiment 2:
A kind of heavy mental treatment agent, is prepared by following component by weight: 30 parts of cellulase, hydroxyl
15 parts of ethylene-diphosphonic acid, single 30 parts of water citric acid, 30 parts of deionized water.
A kind of preparation method of heavy mental treatment agent, comprising:
Material preparation step: each raw material is weighed respectively according to formulation ratio；
Mixing step: the cellulase of formula ratio is placed in reaction kettle, is stirred for the first time, mixing speed 150r/
Min, mixing time 15r/min the surplus stock of formula ratio are all added in reaction kettle, second of stirring, mixing speed
Heavy mental treatment agent is obtained for 150r/min, mixing time 30r/min.
Embodiment 3:
A kind of heavy mental treatment agent, is prepared by following component by weight: 40 parts of cellulase, hydroxyl
10 parts of ethylene-diphosphonic acid, single 30 parts of water citric acid, 20 parts of deionized water.
A kind of preparation method of heavy mental treatment agent, comprising:
Material preparation step: each raw material is weighed respectively according to formulation ratio；
Mixing step: the cellulase of formula ratio is placed in reaction kettle, is stirred for the first time, mixing speed 100r/
Min, mixing time 20r/min the surplus stock of formula ratio are all added in reaction kettle, second of stirring, mixing speed
Heavy mental treatment agent is obtained for 150r/min, mixing time 20r/min.
Embodiment 4:
The characteristics of the present embodiment is: a kind of heavy mental treatment agent is prepared by following component by weight:
35 parts of cellulase, 15 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, single 34 parts of water citric acid, 8 parts of carboxymethyl chitosan, 16 parts of deionized water.
It is other same as Example 1.
Embodiment 5:
The characteristics of the present embodiment is: a kind of heavy mental treatment agent is prepared by following component by weight:
35 parts of cellulase, 15 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, single 34 parts of water citric acid, 5 parts of carboxymethyl chitosan, 16 parts of deionized water.
It is other same as Example 1.
Embodiment 6:
The characteristics of the present embodiment is: a kind of heavy mental treatment agent is prepared by following component by weight:
35 parts of cellulase, 15 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, single 34 parts of water citric acid, 10 parts of carboxymethyl chitosan, 16 parts of deionized water.
It is other same as Example 1.
Performance detection:
Detect foundation: the measurement part 2 of GB/T 17593.2-2007 textile heavy metal: inductively coupled plasma is former
Sub- emission spectrometry.
For the fabric of remaining exceeded heavy metal ion exceeded (iron ion, chromium ion, copper ion, nickel ion), see
Table 1；Above-mentioned fabric is divided into six pieces, respectively after the processing of the inorganic agent of the present embodiment 1-6, testing result such as the following table 1；
Table 1
As it can be seen from table 1 exceeded iron ion remaining to fabric, chromium ion, copper ion, nickel ion, by this hair
After the heavy mental treatment agent processing of bright embodiment 1-6, it is attained by the requirement of client outlet.Wherein, it is not adding
It is best with the effect of embodiment 1 in the heavy mental treatment agent (embodiment 1-3) of carboxymethyl chitosan；It is being added to hydroxyl first
It is best with the effect of embodiment 4 in the heavy mental treatment agent (embodiment 4-6) of base enclosure glycan；The heavy metal of embodiment 4-6
The treatment effect of ion processing agent is better than the heavy mental treatment agent of embodiment 1-3.
The above embodiment is only the preferred embodiment of the present invention, and the scope of protection of the present invention is not limited thereto,
The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed range.
Claims (10)
1. a kind of heavy mental treatment agent, which is characterized in that including following component by weight:
2. heavy mental treatment agent as described in claim 1, which is characterized in that the cellulase, 1-hydroxy ethylene-1,1-diphosphonic
The weight ratio of sour, single water citric acid is 35:10-20:30-40.
3. heavy mental treatment agent as claimed in claim 2, which is characterized in that the cellulase, 1-hydroxy ethylene-1,1-diphosphonic
The weight ratio of sour, single water citric acid is 35:15:34.
4. heavy mental treatment agent as described in claim 1, which is characterized in that by following component preparation by weight
At:
5. heavy mental treatment agent as claimed in claim 4, which is characterized in that by following component preparation by weight
At:
6. heavy mental treatment agent as described in claim 1, which is characterized in that it further include carboxymethyl chitosan, the hydroxyl
The additive amount of methyl chitosan is 5-10 parts.
7. heavy mental treatment agent as claimed in claim 6, which is characterized in that by following component preparation by weight
At:
8. a kind of preparation method of the heavy mental treatment agent as described in claim 1-7 any one, which is characterized in that packet
It includes:
Material preparation step: each raw material is weighed respectively according to formulation ratio；
Mixing step: the cellulase of formula ratio is placed in reaction kettle, is stirred for the first time, and the surplus stock of formula ratio is whole
It is added in reaction kettle, second of stirring obtains heavy mental treatment agent.
9. the preparation method of heavy mental treatment agent as claimed in claim 8, which is characterized in that in mixing step, first
In secondary whipping process, mixing speed 50-200r/min, mixing time 5-20r/min；In second of whipping process, stirring
Speed is 50-200r/min, mixing time 10-30r/min.
10. the preparation method of heavy mental treatment agent as claimed in claim 9, which is characterized in that in mixing step, first
In secondary whipping process, mixing speed 100r/min, mixing time 10r/min；In second of whipping process, mixing speed is
150r/min, mixing time 20r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810996842.5A CN109231401A (en) | 2018-08-29 | 2018-08-29 | A kind of heavy mental treatment agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810996842.5A CN109231401A (en) | 2018-08-29 | 2018-08-29 | A kind of heavy mental treatment agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109231401A true CN109231401A (en) | 2019-01-18 |
Family
ID=65068087
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810996842.5A Pending CN109231401A (en) | 2018-08-29 | 2018-08-29 | A kind of heavy mental treatment agent and preparation method thereof |
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Citations (6)
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|---|---|---|---|---|
| US5712238A (en) * | 1996-08-02 | 1998-01-27 | Chan; Wu Hsiung | Multipurpose cleaning agent |
| CN1083002C (en) * | 1994-04-13 | 2002-04-17 | 普罗格特-甘布尔公司 | Detergent compositions |
| CN104710027A (en) * | 2013-12-13 | 2015-06-17 | 大连克林尔化学品科技有限公司 | Novel corrosion and scale inhibitor and production method thereof |
| CN105886169A (en) * | 2014-12-15 | 2016-08-24 | 上海和黄白猫有限公司 | Powder detergent bag and preparation method thereof |
| CN106222667A (en) * | 2016-08-22 | 2016-12-14 | 青岛文创科技有限公司 | A kind of nickel-plated metal polishing agent |
| CN107868708A (en) * | 2016-09-27 | 2018-04-03 | 夏安娜 | A kind of transparent liquid detergent and preparation method thereof |
-
2018
- 2018-08-29 CN CN201810996842.5A patent/CN109231401A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083002C (en) * | 1994-04-13 | 2002-04-17 | 普罗格特-甘布尔公司 | Detergent compositions |
| US5712238A (en) * | 1996-08-02 | 1998-01-27 | Chan; Wu Hsiung | Multipurpose cleaning agent |
| CN104710027A (en) * | 2013-12-13 | 2015-06-17 | 大连克林尔化学品科技有限公司 | Novel corrosion and scale inhibitor and production method thereof |
| CN105886169A (en) * | 2014-12-15 | 2016-08-24 | 上海和黄白猫有限公司 | Powder detergent bag and preparation method thereof |
| CN106222667A (en) * | 2016-08-22 | 2016-12-14 | 青岛文创科技有限公司 | A kind of nickel-plated metal polishing agent |
| CN107868708A (en) * | 2016-09-27 | 2018-04-03 | 夏安娜 | A kind of transparent liquid detergent and preparation method thereof |
Non-Patent Citations (1)
| Title |
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| 刘伟: "《生物高分子材料及其应用研究》", 31 March 2018, 电子科技大学出版社 * |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 510000 No. 16, No. 2 Lane, Fengjiang Second Road, Xizhou Village, Xintang Town, Zengcheng District, Guangzhou City, Guangdong Province Applicant after: Guangzhou Bangwei New Material Co.,Ltd. Address before: 510000 No. 16, No. 2 Lane, Fengjiang Second Road, Xizhou Village, Xintang Town, Zengcheng District, Guangzhou City, Guangdong Province Applicant before: GUANGZHOU BANGWEI WEAVING AUXILIARY AGENT Co.,Ltd. |
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190118 |