CN105885336A - Microporous 3D printing product, and preparation method and application thereof - Google Patents
Microporous 3D printing product, and preparation method and application thereof Download PDFInfo
- Publication number
- CN105885336A CN105885336A CN201610353339.9A CN201610353339A CN105885336A CN 105885336 A CN105885336 A CN 105885336A CN 201610353339 A CN201610353339 A CN 201610353339A CN 105885336 A CN105885336 A CN 105885336A
- Authority
- CN
- China
- Prior art keywords
- parts
- agent
- weight
- printed product
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
Abstract
The invention discloses a microporous 3D printing product, and a preparation method and application thereof. The 3D printing material is prepared from the following components in parts by weight: 120-140 parts of ABS (acrylonitrile-butadiene-styrene), 2-8 parts of photodiffusion agent, 2-8 parts of initiator, 10-20 parts of crosslinking agent, 10-20 parts of coupling agent, 10-30 parts of oyster shell powder, 2-8 parts of bentonite, 1-4 parts of medical stone powder, 1-4 parts of nutshell ultramicropowder, 1-6 parts of limonene and 0.2-0.4 part of aid. The invention provides a 3D printing product new species for the users to select and use according to needs, thereby greatly widening the application and development space of the 3D printing product mainly prepared from ABS in the aspect of 3D printing, and having obvious meanings.
Description
Technical field
The invention belongs to 3D and print field, be specifically related to a kind of 3D printed product and preparation method and application.
Background technology
The development maked rapid progress along with 3D printing technique, the concept that 3D prints gradually is known by the public.FDM technology is profit
With ABS, polycarbonate (PC), polyphenylsulfone (PPSF), PLA and other thermoplastic are subject to
To adding the filament being hot extruded into as semi-molten state, by the mode being deposited on the basis of storehouse layer by layer, from 3D CAD data
Directly construction prototype.This technology is commonly used to plastotype, assembling, functional test and conceptual design.Additionally, FDM
Technology can apply to draw a design and quickly manufacture.
ABS material, ABS, original name is acrylonitrile-butadiene-styrene copolymer, is domestic fusion sediment (FDM) formula
The essential core of wire rod.From the properties of material, from the perspective of hot junction, the relatively easy printing of ABS plastic.Nothing
Which type of extruder is opinion use, all can extruded material the most glidingly.ABS resilient enough, be suitable for making furnishings or
Ornament, as long as printing with suitable temperature, allows material layer by layer firmly stick, and the intensity of ABS will become at a relatively high.
ABS has flexibility, also only can bend even if bearing pressure, will not fracture.But during this material on the one hand printing
It is uncomfortable that abnormal smells from the patient allows people have very much, and the product variety function on the other hand printed is limited, it is impossible to meet market many
Sample demand.
Along with development in science and technology and social progress, 3D printed product starts to be not limited only to industrial design, building, engineering and construction
(AEC), automobile, Aero-Space, dentistry and medical industries, education, GIS-Geographic Information System, civil engineering, gun etc.
Field, also begins to come into daily life, in order to make some living utensils or ornament, but at present in life
Application be still embodied in the purposes that the shape of printed product is brought, and the art that its color and shape are formed
Designs etc., the application and development printing 3D there is also the biggest space, simultaneously intensity in degradable rate, toughness and all
Need to be further improved.
Summary of the invention
Goal of the invention: the problem existed for prior art, first technical problem to be solved by this invention is to provide micro-
Pass 3D printed product.Second preparation side that technical problem is that this pore type 3D printed product to be solved by this invention
Method.3rd technical problem to be solved by this invention is to provide the application of described pore type 3D printed product.
Technical scheme: for solving above-mentioned technical problem, the invention provides a kind of pore type 3D printed product, according to weight
Amount number includes that following components is made: ABS 120～140 parts；Light diffusing agent 2～8 parts；Initiator 2～8 parts；Hand over
Connection agent 10～20 parts；Coupling agent 10～20 parts；Oyster shell powder 10～30 parts；Bentonite 2～8 parts；Medical stone powder 1～
4 parts；Walnut shell ultrafine powder 1～4 parts；Limonene 1～6 parts；Auxiliary agent 0.2～0.4 part.
It is further preferred that also include nano-silver ionic 2～8 parts according to parts by weight.
Preferably, described light diffusing agent is organosilicon light diffusing agent.
Preferably, described initiator is thermal initiator.
Preferably, described initiator is the mixture of light trigger and thermal initiator.
Preferably, according to parts by weight, described initiator includes that following components is made: light trigger 1～3 parts；Thermal initiation
Agent 1～5 parts.
Preferably, one or both the mixture during described coupling agent is titanate coupling agent or silane coupler.
Preferably, according to parts by weight, described auxiliary agent includes that following components is made: plasticizer 0.1～0.2 part；Toughener 0.1～
0.2 part.
Invention also provides the preparation method for above-mentioned pore type 3D printed product, comprise the steps:
1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes, grafting；
2) it is cooled to 20 DEG C～30 DEG C after stirring, puts into extruder, heating, extrusion, pulverize to obtain preparing being grafted and hand over
The ABS powder of connection agent；
3) by step 2) the ABS powder that obtains and the oyster shell powder of corresponding parts by weight, bentonite, walnut shell ultra micro
Powder, medical stone powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；
4) by step 3) gains are while continue to be mixed and stirred for uniform, and mixing adds the phase processed through atomization successively
Answer the limonene of parts by weight；
5) then add the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；
6) while ultra violet lamp 30～60min, after stirring is cooled to 50 DEG C～55 DEG C, three-dimensional fast shaping is passed through
Technology, adds hot-extrudable moulding, vacuum drying, prepares target product.
Preferably, described step 4) be: by step 3) gains are while continue to be mixed and stirred for uniform, mix successively
Close limonene and the nano-silver ionic adding the corresponding parts by weight through atomization process.
Invention also provides the application in making the ornament with microcellular structure of the above-mentioned pore type 3D printed product.
Beneficial effect: the pore type 3D printed product that the present invention provides, on the one hand significantly enhances the network structure of product,
Being effectively improved the toughness of product, degradable rate is high；On the other hand by thermal initiator, bentonite, oyster shell powder and core
The synergism of peach shell superfine powder so that product itself has certain microcellular structure；Its component limonene is the most effective simultaneously
Improve abnormal smells from the patient during ABS material high-temperature fusion, improve working environment, and with medical stone powder synergism, there is antioxygen
Change effect and purifying functions, significantly improve antioxygenic property and the stability of the present invention the most further, micro-herein in connection with it
Pore structure has excellent anticorrosion concurrently and de-tastes fresh-keeping and purifying effect；When in component, increase has nano-silver ionic further, permissible
On the microcellular structure and purifying functions of the present invention, further play antibiotic effect.In microcellular structure and said components
Under synergism, advantages of good adsorption effect of the present invention so that it extensively can be applied as functional product, it is particluarly suitable for last
Step of overall modelling is made various interest, dicoration and the ornament of adsorption cleaning bacteriostasis efficacy or the functional product of having concurrently, real
Have concurrently by property interest, in terms of 3D printed product, be greatly enlarged the application development space of 3D printed product, meaning
Justice is notable.
The preparation method of the pore type 3D printed product that the present invention provides simultaneously, by being atomized during high-speed stirred
Add and under limonene, and ultra violet lamp, be stirred cooling, improve the steady of obtained 3D printed product further
Qualitative and non-oxidizability.
Entirety extends service life, it is provided that the new varieties of a kind of 3D printed product select as required for user,
In terms of 3D printing, it is greatly enlarged the application development space of 3D printed product with ABS as primary raw material, meaning
Significantly.
Detailed description of the invention
According to parts by weight, embodiment 1: a kind of pore type 3D printed product, includes that following components is made: ABS 120
Part；Light diffusing agent 2 parts；Initiator 2 parts；Cross-linking agent 10 parts；Coupling agent 10 parts；Oyster shell powder 10 parts；Swelling
2 parts of soil；Medical stone powder 1 part；Walnut shell ultrafine powder 1 part；Limonene 1 part；Auxiliary agent 0.2 part.
Wherein light diffusing agent is organosilicon light diffusing agent.
Wherein according to parts by weight, initiator includes that following components is made: light trigger 1 part；Thermal initiator 1 part.
Wherein coupling agent is titanate coupling agent.
Wherein according to parts by weight, auxiliary agent includes that following components is made: plasticizer 0.1 part；Toughener 0.1 part.
Preparation method comprises the steps: 1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes,
Grafting；2) it is cooled to 20 DEG C after stirring, puts into extruder, heating, extrusion, pulverize and obtain preparing graft crosslinking
The ABS powder of agent；3) by step 2) the ABS powder that obtains and the oyster shell powder of corresponding parts by weight, bentonite,
Walnut shell ultrafine powder, medical stone powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；4) by step 3) institute
Thing while continue to be mixed and stirred for uniform, mixing adds the Fructus Citri Limoniae of the corresponding parts by weight processed through atomization successively
Alkene；5) then add the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；6) at ultra violet lamp 30
While, after stirring is cooled to 50 DEG C, by three-dimensional fast shaping technology, add hot-extrudable moulding, vacuum drying, system
For obtaining target product.After testing, the flexility of material reaches 82.2Mpa, notch impact strength reaches
47.3MJ/m2。
According to parts by weight, embodiment 2: a kind of pore type 3D printed product, includes that following components is made: ABS 140
Part；Light diffusing agent 8 parts；Initiator 8 parts；Cross-linking agent 20 parts；Coupling agent 20 parts；Oyster shell powder 30 parts；Swelling
8 parts of soil；Medical stone powder 4 parts；Walnut shell ultrafine powder 4 parts；Limonene 6 parts；Auxiliary agent 0.4 part.
Wherein light diffusing agent is organosilicon light diffusing agent.
Wherein according to parts by weight, initiator includes that following components is made: light trigger 3 parts；Thermal initiator 5 parts.
Wherein coupling agent is silane coupler.
Wherein according to parts by weight, auxiliary agent includes that following components is made: plasticizer 0.2 part；Toughener 0.2 part.
Preparation method comprises the steps: 1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes,
Grafting；2) it is cooled to 30 DEG C after stirring, puts into extruder, heating, extrusion, pulverize and obtain preparing graft crosslinking
The ABS powder of agent；3) by step 2) the ABS powder that obtains and the oyster shell powder of corresponding parts by weight, bentonite,
Walnut shell ultrafine powder, medical stone powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；4) by step 3) institute
Thing while continue to be mixed and stirred for uniform, mixing adds the Fructus Citri Limoniae of the corresponding parts by weight processed through atomization successively
Alkene；5) then add the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；6) at ultra violet lamp 60min
While, after stirring is cooled to 55 DEG C, by three-dimensional fast shaping technology, add hot-extrudable moulding, vacuum drying, system
For obtaining target product.After testing, the flexility of material reaches 82.6Mpa, notch impact strength reaches
47.6MJ/m2。
According to parts by weight, embodiment 3: a kind of pore type 3D printed product, includes that following components is made: ABS 130
Part；Light diffusing agent 5 parts；Initiator 5 parts；Cross-linking agent 15 parts；Coupling agent 15 parts；Oyster shell powder 20 parts；Swelling
5 parts of soil；Medical stone powder 3 parts；Walnut shell ultrafine powder 2 parts；Nano-silver ionic 5 parts；Limonene 4 parts；Auxiliary agent 0.3
Part.
Wherein light diffusing agent is organosilicon light diffusing agent.
Wherein according to parts by weight, initiator includes that following components is made: thermal initiator 5 parts.
Wherein coupling agent is the mixture of titanate coupling agent and silane coupler, and ratio is 3:2.
Wherein according to parts by weight, auxiliary agent includes that following components is made: plasticizer 0.15 part；Toughener 0.15 part.
Preparation method comprises the steps: 1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes,
Grafting；2) it is cooled to 25 DEG C after stirring, puts into extruder, heating, extrusion, pulverize and obtain preparing graft crosslinking
The ABS powder of agent；3) by step 2) the ABS powder that obtains and the oyster shell powder of corresponding parts by weight, bentonite,
Walnut shell ultrafine powder, medical stone powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；4) by step 3) institute
Thing while continue to be mixed and stirred for uniform, mixing adds the limonene of the corresponding parts by weight processed through atomization successively
And nano-silver ionic；5) then add the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；6) at purple
While outer light irradiation 45min, after stirring is cooled to 52 DEG C, by three-dimensional fast shaping technology, add hot-extrudable moulding,
Vacuum drying, prepares target product.After testing, the flexility of material reaches 83.7Mpa, notch shock
Intensity reaches 48.8MJ/m2。
According to parts by weight, embodiment 4: a kind of pore type 3D printed product, includes that following components is made:
ABS 125 parts；Light diffusing agent 3 parts；Initiator 3 parts；Cross-linking agent 12 parts；Coupling agent 12 parts；Oyster shell powder
15 parts；Bentonite 4 parts；Medical stone powder 2 parts；Walnut shell ultrafine powder 2 parts；Nano-silver ionic 4 parts；Limonene 2
Part；Auxiliary agent 0.2 part.
Wherein light diffusing agent is organosilicon light diffusing agent.
Wherein according to parts by weight, initiator includes that following components is made: thermal initiator 3 parts.
Wherein coupling agent is titanate coupling agent.
Wherein according to parts by weight, auxiliary agent includes that following components is made: plasticizer 0.1 part；Toughener 0.1 part.
Preparation method comprises the steps: 1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes,
Grafting；2) it is cooled to 25 DEG C after stirring, puts into extruder, heating, extrusion, pulverize and obtain preparing graft crosslinking
The ABS powder of agent；3) by step 2) the ABS powder that obtains and the oyster shell powder of corresponding parts by weight, bentonite,
Walnut shell ultrafine powder, medical stone powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；4) by step 3) institute
Thing while continue to be mixed and stirred for uniform, mixing adds the limonene of the corresponding parts by weight processed through atomization successively
And nano-silver ionic；5) then add the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；6) at purple
While outer light irradiation 40min, after stirring is cooled to 50 DEG C, by three-dimensional fast shaping technology, add hot-extrudable moulding,
Vacuum drying, prepares target product.After testing, the flexility of material reaches 83.1Mpa, notch shock
Intensity reaches 47.9MJ/m2。
According to parts by weight, embodiment 5: a kind of pore type 3D printed product, includes that following components is made: ABS 135
Part；Light diffusing agent 6 parts；Initiator 6 parts；Cross-linking agent 18 parts；Coupling agent 18 parts；Oyster shell powder 25 parts；Swelling
6 parts of soil；Medical stone powder 3 parts；Walnut shell ultrafine powder 3 parts；Nano-silver ionic 6 parts；Limonene 4 parts；Auxiliary agent 0.4
Part.
Wherein light diffusing agent is organosilicon light diffusing agent.
Wherein according to parts by weight, initiator includes that following components is made: light trigger 2 parts；Thermal initiator 4 parts.
Wherein coupling agent is the mixture of titanate coupling agent and silane coupler.
Wherein according to parts by weight, auxiliary agent includes that following components is made: plasticizer 0.2 part；Toughener 0.2 part.
Preparation method comprises the steps: 1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes,
Grafting；2) it is cooled to 25 DEG C after stirring, puts into extruder, heating, extrusion, pulverize and obtain preparing graft crosslinking
The ABS powder of agent；3) by step 2) the ABS powder that obtains and the oyster shell powder of corresponding parts by weight, bentonite,
Walnut shell ultrafine powder, medical stone powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；4) by step 3) institute
Thing while continue to be mixed and stirred for uniform, mixing adds the limonene of the corresponding parts by weight processed through atomization successively
And nano-silver ionic；5) then add the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；6) at purple
While outer light irradiation 50min, after stirring is cooled to 55 DEG C, by three-dimensional fast shaping technology, add hot-extrudable moulding,
Vacuum drying, prepares target product.After testing, the flexility of material reaches 82.8Mpa, notch shock
Intensity reaches 48.2MJ/m2。
Above-described embodiment provide pore type 3D printed product, make in last step of overall modelling various have concurrently interest,
Ornamental and the ornament of adsorption cleaning bacteriostasis efficacy or functional product, practicality interest has concurrently, from 3D printed product
Aspect, is greatly enlarged the application development space of 3D printed product, and meaning is notable, can widely promote.
More than implementing row and the present invention is not constituted restriction, relevant staff is in the scope without departing from the technology of the present invention thought
In, carried out various changes and modifications, and all falls within protection scope of the present invention.
Claims (10)
1. a pore type 3D printed product, it is characterised in that include that following components is made according to parts by weight: ABS
120～140 parts；Light diffusing agent 2～8 parts；Initiator 2～8 parts；Cross-linking agent 10～20 parts；Coupling agent 10～20
Part；Oyster shell powder 10～30 parts；Bentonite 2～8 parts；Medical stone powder 1～4 parts；Walnut shell ultrafine powder 1～4 parts；
Limonene 1～6 parts；Auxiliary agent 0.2～0.4 part.
Pore type 3D printed product the most according to claim 1, it is characterised in that also include according to parts by weight
Nano-silver ionic 2～8 parts.
Pore type 3D printed product the most according to claim 1, it is characterised in that described light diffusing agent is organic
Silicon light diffusing agent.
Pore type 3D printed product the most according to claim 1, it is characterised in that described initiator is thermal initiation
Agent, or be the mixture of light trigger and thermal initiator.
Pore type 3D printed product the most according to claim 1, it is characterised in that described initiator is according to weight
Number includes that following components is made: light trigger 1～3 parts；Thermal initiator 1～5 parts.
Pore type 3D printed product the most according to claim 1, it is characterised in that described coupling agent is titanate esters
One or both mixture in coupling agent or silane coupler.
Pore type 3D printed product the most according to claim 1, it is characterised in that described auxiliary agent is according to weight portion
Number includes that following components is made: plasticizer 0.1～0.2 part；Toughener 0.1～0.2 part.
8. the preparation method of the pore type 3D printed product as described in claim 1～7, it is characterised in that include as follows
Step:
1) ABS particle high-temperature is melted, add initiator and cross-linking agent mixes, grafting；
2) it is cooled to 20 DEG C～30 DEG C after stirring, puts into extruder, heating, extrusion, pulverize to obtain preparing being grafted and hand over
The ABS powder of connection agent；
3) by step 2) the ABS powder that obtains and the oyster shell powder of corresponding parts by weight, bentonite, walnut shell ultra micro
Powder, medical stone powder, coupling agent and auxiliary agent, add hot mixing and high-speed stirred is uniform；
4) by step 3) gains are while continue to be mixed and stirred for uniform, and mixing adds the phase processed through atomization successively
Answer the limonene of parts by weight；
5) then add the light diffusing agent of corresponding parts by weight, continue to be mixed and stirred for uniformly；
6) while ultra violet lamp 30～60min, after stirring is cooled to 50 DEG C～55 DEG C, three-dimensional fast shaping is passed through
Technology, adds hot-extrudable moulding, vacuum drying, prepares target product.
The preparation method of pore type 3D printed product the most according to claim 8, it is characterised in that described step
4) it being: by step 3) gains are while continue to be mixed and stirred for uniform, and mixing adds the phase processed through atomization successively
Answer limonene and the nano-silver ionic of parts by weight.
10. the pore type 3D printed product as described in claim 1～9 is in making the ornament with microcellular structure
Application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610353339.9A CN105885336A (en) | 2016-05-25 | 2016-05-25 | Microporous 3D printing product, and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610353339.9A CN105885336A (en) | 2016-05-25 | 2016-05-25 | Microporous 3D printing product, and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105885336A true CN105885336A (en) | 2016-08-24 |
Family
ID=56717800
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610353339.9A Pending CN105885336A (en) | 2016-05-25 | 2016-05-25 | Microporous 3D printing product, and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105885336A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103788565A (en) * | 2014-01-14 | 2014-05-14 | 广州优塑塑料科技有限公司 | Conductive 3D (three-dimensional) printing plastic wire and production method thereof |
| CN103980591A (en) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | Electronic radiation crosslinked polymeric material for 3D printing, preparation method and product thereof |
| CN104072935A (en) * | 2014-06-13 | 2014-10-01 | 福来宝电子(深圳)有限公司 | ABS (acrylonitrile butadiene styrene) material used for 3D (three dimensional) printing and manufacturing process thereof |
| CN104530668A (en) * | 2014-12-17 | 2015-04-22 | 广州飞胜高分子材料有限公司 | 3D printing material having self-cleaning antibacterial function as well as preparation method and application of 3D printing material |
| CN104861603A (en) * | 2015-05-29 | 2015-08-26 | 江苏浩宇电子科技有限公司 | 3D printing material with mosquito-repellent and noctilucent effects as well as application |
-
2016
- 2016-05-25 CN CN201610353339.9A patent/CN105885336A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103788565A (en) * | 2014-01-14 | 2014-05-14 | 广州优塑塑料科技有限公司 | Conductive 3D (three-dimensional) printing plastic wire and production method thereof |
| CN103980591A (en) * | 2014-04-30 | 2014-08-13 | 中国科学院化学研究所 | Electronic radiation crosslinked polymeric material for 3D printing, preparation method and product thereof |
| CN104072935A (en) * | 2014-06-13 | 2014-10-01 | 福来宝电子(深圳)有限公司 | ABS (acrylonitrile butadiene styrene) material used for 3D (three dimensional) printing and manufacturing process thereof |
| CN104530668A (en) * | 2014-12-17 | 2015-04-22 | 广州飞胜高分子材料有限公司 | 3D printing material having self-cleaning antibacterial function as well as preparation method and application of 3D printing material |
| CN104861603A (en) * | 2015-05-29 | 2015-08-26 | 江苏浩宇电子科技有限公司 | 3D printing material with mosquito-repellent and noctilucent effects as well as application |
Non-Patent Citations (1)
| Title |
|---|
| 常景玲 主编: "《天然生物活性物质及其制备技术》", 31 August 2007 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104861603B (en) | A kind of 3D printed material with anophelifuge and luminous effect and application | |
| CN104893267B (en) | 3D printed material with anophelifuge photosensitive effect and preparation method and application | |
| EP1728899A4 (en) | Fabric for clothing and process for producing the same | |
| JP2016000763A5 (en) | ||
| CN103214738A (en) | Rapid prototyping material and preparation method thereof | |
| CN103319826B (en) | A kind of Water-soluble clay composition and preparation method thereof | |
| CN105885336A (en) | Microporous 3D printing product, and preparation method and application thereof | |
| CN104404651A (en) | Flame-retardant modified polyester wig fiber textile and manufacturing method thereof | |
| CN109706545A (en) | A kind of micro porous hollow graphene sea-island fibre and its manufacturing method | |
| CN105994404A (en) | Insect trapping and killing 3D printed product with micropore structure and preparation method thereof | |
| Chang et al. | Multifunctional soy protein gels with excellent initial adhesion and bonding strength based on a mussel-inspired redox self-catalytic and oyster-inspired organic-inorganic hybrid dual-bionic strategy | |
| CN106009469A (en) | Micro-pore bacterium-inhibiting type 3D printing product as well as preparation method and application thereof | |
| CN105778396A (en) | 3D printing material with bacteriostatic function and preparation method thereof | |
| CN104610716A (en) | BMC material for molding decorative plate and preparation method thereof | |
| CN105778399A (en) | Bacteriostatic 3D printing material easy in molding and preparation method thereof | |
| CN106046652A (en) | Antibacterial 3D printing product with microporous structure, and preparation method thereof | |
| CN105968677A (en) | High-plasticity 3D printing material and preparation method thereof | |
| CN105778395A (en) | 3D printing material with function of trapping and killing insects and preparation method thereof | |
| CN105994391A (en) | Insect trapping and killing 3D printed product with micropore structure and preparation method thereof | |
| CN103772856A (en) | Polyvinyl-chloride composite plastic and preparation method thereof | |
| CN106010498A (en) | Multiplex insect-trapping/killing 3D printing product and preparation method thereof | |
| TWI650381B (en) | Microwave heating composite material and its manufacturing method | |
| CN105860418A (en) | Easy-to-plasticize bacterial inhibition type 3D printing material and preparation method thereof | |
| CN104629167A (en) | Foaming polypropylene material and preparation method thereof | |
| CN106009468A (en) | Microporous-structure antibacterial 3D printing product and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160824 |
|
| RJ01 | Rejection of invention patent application after publication |