CN105878054A - LED-UV phototherapy glue scrubbing-free sealing layer glue and preparation method thereof - Google Patents
LED-UV phototherapy glue scrubbing-free sealing layer glue and preparation method thereof Download PDFInfo
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- CN105878054A CN105878054A CN201610214824.8A CN201610214824A CN105878054A CN 105878054 A CN105878054 A CN 105878054A CN 201610214824 A CN201610214824 A CN 201610214824A CN 105878054 A CN105878054 A CN 105878054A
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- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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Abstract
The invention discloses LED-UV phototherapy glue scrubbing-free sealing layer glue. The LED-UV phototherapy glue scrubbing-free sealing layer glue is prepared from, by weight concentration, 7-90% of oligomer, 7-90% of active monomers, 1-10% of photoinitiator, 1-10% of a mercaptan compound and 0.1-1% of stabilizer. The invention further discloses a preparation method of the LED-UV phototherapy glue scrubbing-free sealing layer glue. The scrubbing-free sealing layer glue can basically overcome the oxygen inhibition phenomenon, has a very high curing reaction rate and can be completely cured under an LED-UV weak light source, the situations that floating glue exists and the surface is not dry do not exist, and the curing time is shortened to about 60 s from general 120 s. Therefore, in the nail beautifying process, the scrubbing process is omitted, the nail beautifying process becomes simple, and manpower, material resources and time cost are saved.
Description
Technical field
The invention belongs to material chemistry technical field, particularly relate to LED-UV phototherapy glue exempt from clean sealing glue and
Its preparation method.
Background technology
Phototherapy glue, also known as UV nail polish glue, belongs to the one of nial polish in color make-up, is coated in nail surface, warp
UV light solidify to form thin film after irradiating, lucuriant in design, gloss is full so that the great aesthetic feeling of fingernail, deep by wide
The welcome of big women and liking.
At present, on market nial polish mainly have water-based nail polish, nitro nial polish, UV phototherapy glue this in three,
To have adhesive force good with other two kinds of nial polishs are compared for UV phototherapy glue, and the retention time is long, glossiness advantages of higher.
The main flow having become nail salon uses product.
Current UV phototherapy glue is the formula for the design of UV mercury lamp light source, along with the rise of LED,
LED-UV light source the most progressively substitutes UV mercury lamp light source, and future will become main flow, because of the light for solidification
The spectral characteristic in source changes, and current UV phototherapy glue formula is badly in need of improvement.
Now, the phototherapy glue used on the market is three step glue: primer, color glue, sealing glue, the most in due order
Sequence is respectively coated with and solidifies.Nail lamp is mainly with CCFL+LED as light source, and optical source wavelength peak value is
250nm、395nm.Nail lamp power is generally 12-36W.
Current UV phototherapy glue product existing defects need improvement, including length hardening time, exist floating glue,
Need cleaning.The use of phototherapy glue and solidification process be exposed in air ambient according to radical polymerization principle
Carrying out, the oxygen molecule in air has very important inhibition to radical polymerization, especially low
Under the low light level of power LED-UV lamp, oxygen inhibition phenomenon is particularly evident.
Each layer (primer, face glue, color glue) of present three step phototherapy glue is solid under nail lamp after having coated
The change time is required to more than 120s, and top layer still remains one layer of floating glue the most completely crued, it is impossible to surface drying.
Need to continue to be coated with overlapping colours glue after solidifying due to primer, need after color adhesive curing to continue coating sealing glue, so this
The floating glue of two-layer can need not process, and it can be handed over next step color glue dough-making powder glue being coated on face
Connection curing reaction, but the floating glue of residual after nail lamp irradiates solidification on last sealing glue then must be used
Cotton or cotton swab are stained with ethanol by its scrub.3rd step sealing glue is called to clean sealing in the industry, uses this
Plant and clean sealing so that the slightly aobvious complexity of manicure technique, human and material resources and time cost increased.
Summary of the invention
The weak point that it is an object of the invention to overcome prior art to exist and provide a kind of LED-UV light
Treat glue exempt from clean sealing glue, the present invention exempt from clean sealing glue can substantially overcome oxygen inhibition phenomenon, have very
High curing reaction speed, can realize being fully cured under the such weak light source of LED-UV, not there are
The situation of floating glue, not surface drying, and also shortened to about 60s by general 120s hardening time.Therefore exist
Eliminate scouring process during manicure so that manicure technique becomes simple, saved human and material resources and time
Between cost.
The technical solution used in the present invention is: a kind of LED-UV phototherapy glue exempts to clean sealing glue, comprises following
The raw material of weight percent concentration: oligomer 7～90%, activated monomer 7～90%, light trigger 1～10%,
Sulfur alcohol compound 1～10%, stabilizer 0.1～1%.
As the further improvement to technique scheme, described LED-UV phototherapy glue exempts to clean sealing glue,
Comprise the raw material of following weight percent concentration: oligomer 45～55%, activated monomer 30～40%, light-initiated
Agent 6～8%, sulfur alcohol compound 6.5～8.5%, stabilizer 0.4～0.6%.Weight percent when described raw material
Specific concentration within the above range time, prepared LED-UV phototherapy glue exempt from clean sealing glue curing reaction speed
Higher, hardening time is shorter.
As the further improvement to technique scheme, described oligomer is unsaturated polyester (UP), propylene oxide
In acid esters, urethane acrylate, polyether acrylate, polyester acrylate, pure acrylic resin extremely
Few one.
As the further improvement to technique scheme, described activated monomer selected from Monofunctional monomers and/or
Bifunctional monomer.
As the further improvement to technique scheme, described Monofunctional monomers is acryloyl morpholine
(ACMO), vinylacetate (VA), Isooctyl acrylate monomer (EHA), isobornyl acrylate (IBOA),
In isobornyl methacrylate (IBOMA), crylic acid hydroxy ester, methacrylic acid hydroxyl ester at least
A kind of.Described crylic acid hydroxy ester is preferably Hydroxyethyl Acrylate (HEA) and/or hydroxypropyl acrylate
(HPA)；Described methacrylic acid hydroxyl ester is preferably hydroxyethyl methacrylate (HEMA) and/or first
Base hydroxypropyl acrylate (HPMA).
As the further improvement to technique scheme, described bifunctional monomer is 1,6-hexanediol two propylene
Acid esters (HDDA), 1,4 butanediol diacrylate (BDDA), tri (propylene glycol) diacrylate
(TPGDA), neopentylglycol dimethacrylate (NPGDMA), ethylene glycol dimethacrylate
(EGDMA) at least one in.
The ultraviolet light of 250nm and 395nm wavelength is had response to absorb by described light trigger, causes photopolymerization
Reaction.As the further improvement to technique scheme, described light trigger is 1-hydroxycyclohexylphenyl
Ketone (184), 2-hydroxy-2-methyl-1-phenyl-1-acetone (1173), 2,4,6-trimethylbenzoyl-hexichol
At least one in base phosphine oxide (TPO), 2-isopropyl thioxanthone (ITX).Light trigger can absorb purple
Outer heat input, produces free radical, then causes coating oligomer and monomer to realize polymerization, crosslinking, make system hand over
It is unified into film.
As the further improvement to technique scheme, described sulfur alcohol compound is ethylene glycol bisthioglycolate (3-sulfydryl
Propionic ester) (GDMP), 1,4-butanediol two (3-thiopropionate) (BDMP), trimethylolpropane tris
In (3-thiopropionate) (TMPMP), tetramethylolmethane four (3-thiopropionate) (PETMP) at least
A kind of.
As the further improvement to technique scheme, described stabilizer be MEHQ (MEHQ),
P-tert-Butylcatechol (TBC), p-methyl phenol, para-aminophenol, paranitrophenol, the tert-butyl group pair
Hydroxyanisol (BHA), 2,6 di tert butyl 4 methyl phenol (BHT), three (2,4-DI-tert-butylphenol compounds)
Phosphite ester (168), three (N-nitroso-group-N-Phenylhydroxylamine) aluminium salt (510), NO free radical piperidine alcohols (701)
In at least one.
The LED-UV phototherapy glue of the present invention exempt from clean sealing glue by formula add sulfur alcohol compound and
Stabilizer improves curing efficiency and overcomes oxygen inhibition phenomenon.
Specifically, the present invention is to add the thio-alcohol containing sulfydryl (-SH) in radically curing system
Compound (namely sulfhydryl compound), so in radical polymerization process, in the presence of having oxygen, alkyl is certainly
Being combined with oxygen atom by base, form peroxy radical, newly-generated peroxy radical again can be by capturing mercaptan
The hydrogen atom of upper sulfydryl produces sulfydryl free radical, and polyreaction is again to carry out, and the existence of such oxygen is the most not
Can cause the generation of oxygen inhibition phenomenon, very big due to the activity of sulfydryl free radical on the contrary, the speed of polymerization has
The biggest raising.Then high due to sulfur alcohol compound activity, can dissociate sulfydryl free radical, is not having
Ultraviolet light also can slowly occur dark reaction under irradiating, therefore to improve the storage stability of product, the present invention
In system, add stabilizer, neutralize free sulfydryl free radical out, the generation of suppression dark reaction.
Scouring sealing glue of exempting from of the present invention can overcome oxygen inhibition existing under LED-UV nail lamp weak light source
As, eliminate the phenomenon of the not dry viscous hands in top layer, technique and the step wiping floating glue can be exempted during manicure.
Scouring sealing glue of exempting from of the present invention can realize in 30-60S under LED-UV nail lamp is irradiated
All solidstate, is greatly shortened the hardening time compared to existing frequently-used sealing glue 90-120S.
Present invention also offers described LED-UV phototherapy glue exempt from clean sealing glue preparation method, including with
Lower step:
(1) by described oligomer, activated monomer, light trigger, sulfur alcohol compound, stabilizer mixing；
(2) at normal temperatures and pressures, the raw material mixed is stirred dispersion so that light trigger is the most molten
Solving, each component is fully dispersed；
(3) standing sloughs bubble or vacuum sloughs bubble.
As the further improvement to technique scheme, carry out under conditions of rotating speed is 800～1500rpm
Dispersed with stirring.
Relative to prior art, the invention have the benefit that
The LED-UV phototherapy glue of the present invention is exempted to clean sealing glue and is passed through can substantially overcome oxygen inhibition phenomenon, tool
There is the highest curing reaction speed, can realize being fully cured under the such weak light source of LED-UV, not deposit
There iing the situation of floating glue, not surface drying, and hardening time is also being shortened to about 60s by general 120s.Cause
This eliminates scouring process during manicure so that manicure technique becomes simple, has saved human and material resources
And time cost.Thus the property easy to use of existing product can be improved, provide more preferable experience for client.
The preparation method that the LED-UV phototherapy glue of the present invention exempts to clean sealing glue is simple, convenient.
Detailed description of the invention
For better illustrating the object, technical solutions and advantages of the present invention, below in conjunction with specific embodiment pair
The present invention is described further.
Embodiment 1
Urethane acrylate (Sartomer 996), the epoxy acrylate (sand of 10wt% according to 45wt%
Many agates E151), the acryloyl morpholine (ACMO, Japanese emerging people) of 10wt%, the 1,6-HD of 20wt%
Diacrylate (HDDA, Changxing EM221), the 2,4,6-trimethylbenzoy-dipheny oxidation of 6wt%
Phosphine (TPO, long day green wood), tetramethylolmethane four (3-thiopropionate) (PETMP tri-well of 8.5wt%
Learn), three (N-nitroso-group-N-Phenylhydroxylamine) aluminium salt of 0.5wt% (510, English profit science and technology) mixed material feeding, often
Under the conditions of normal temperature and pressure, stir with the speed of 1000rpm in blender, make light trigger fully dissolve and respectively
Component is fully dispersed, then stand slough bubble, just obtained clarification bright exempt from clean sealing glue.
Embodiment 2
Urethane acrylate (Changxing DR-U120), the polyester acrylate of 20wt% according to 30wt%
The hydroxyethyl methacrylate (HEMA, Mitsubishi) of (Changxing 6355), 35wt%, the 1-of 5wt%
Hydroxycyclohexyl phenyl ketone (184, long day green wood), the 2 of 3wt%, 4,6-trimethylbenzoy-dipheny
Phosphine oxide (TPO, long day green wood), 3wt% trimethylolpropane tris (3-thiopropionate) (TMPMP,
Essence Dehua learn), the tetramethylolmethane four (3-thiopropionate) (PETMP Mitsui Chemicals) of 3.5wt%, 0.2wt%
Three (N-nitroso-group-N-Phenylhydroxylamine) aluminium salt (510, English profit science and technology), the 2,6-di-t-butyl-4-of 0.3wt%
Methylphenol (BHT, peaceful Kang Huagong) mixed material feeding, under normal temperature and pressure conditions, with 1200rpm in blender
Speed stirring, make light trigger fully dissolve fully dispersed with each component, then stand slough bubble, just
Obtained clarification bright exempt from clean sealing glue.
Embodiment 3
Urethane acrylate (Changxing DR-U240), the epoxy acrylate of 15wt% according to 30wt%
(Sartomer E151), 10wt% pure acrylic resin (Changxing 6530B-4O), the acryloyl of 10wt%
Quinoline (ACMO, Japanese emerging people), the hydroxyethyl methacrylate (HEMA, Mitsubishi) of 20wt%, 2wt%
1-hydroxycyclohexyl phenyl ketone (184, long day green wood), the 2 of 6wt%, 4,6-trimethylbenzoyls-two
Phenyl phosphine oxide (TPO, long day green wood), 2wt% tetramethylolmethane four (3-thiopropionate) (PETMP,
Mitsui Chemicals), the BDO two (3-thiopropionate) of 4.5wt% (BDMP, essence Dehua is learned), 0.1wt%
P-methyl phenol, the para-aminophenol of 0.2wt%, three (2,4-DI-tert-butylphenol compounds) phosphite ester of 0.2wt%
Mixed material feeding, under normal temperature and pressure conditions, in blender, the speed with 800rpm stirs, and makes light trigger fill
Dividing dissolving and each component fully dispersed, then stand and slough bubble, the scouring of exempting from just having obtained clarification bright is sealed
Layer glue.
Embodiment 4
Different pungent according to the polyether acrylate of 7wt%, 35wt% vinylacetate (VA), 25wt% acrylic acid
Ester (EHA), 30wt%1,4-butanediol diacrylate (BDDA), 1.9wt%2-hydroxy-2-methyl-1-benzene
Base-1-acetone (1173), 1wt% ethylene glycol bisthioglycolate (3-thiopropionate) (GDMP), 0.1wt% are to hydroxyl
Methyl phenyl ethers anisole (MEHQ), mixed material feeding, under normal temperature and pressure conditions, with the speed of 800rpm in blender
Stirring, makes light trigger fully dissolve fully dispersed with each component, then stands and sloughs bubble, just obtains
Clarify bright exempting from and clean sealing glue.
Embodiment 5
According to 25wt% epoxy acrylate, 40wt% urethane acrylate, 25wt% polyester acrylate,
7wt% neopentylglycol dimethacrylate (NPGDMA), 1wt%2-isopropyl thioxanthone (ITX),
1.7wt% trimethylolpropane tris (3-thiopropionate) (TMPMP), 0.3wt% p-tert-Butylcatechol
(TBC) mixed material feeding, under normal temperature and pressure conditions, in blender, the speed with 1000rpm stirs, and makes
Light trigger fully dissolves fully dispersed with each component, then stands and sloughs bubble, has just obtained clarification bright
Exempt from clean sealing glue.
Embodiment 6
According to 25wt% epoxy acrylate, 20wt% urethane acrylate, 20wt% isobornyl methyl-prop
Olefin(e) acid ester (IBOMA), 20wt% hydroxypropyl acrylate (HPA), 8wt%2,4,6-trimethylbenzoyl
Base-diphenyl phosphine oxide (TPO), wt% ethylene glycol bisthioglycolate (3-thiopropionate) (GDMP), wt%1,4-
Butanediol two (3-thiopropionate) (BDMP), paranitrophenol, tert-butyl group MEHQ (BHA),
NO free radical piperidine alcohols (701) mixed material feeding, under normal temperature and pressure conditions, with 1500rpm in blender
Speed stirring, make light trigger fully dissolve fully dispersed with each component, then stand slough bubble, just
Obtained clarification bright exempt from clean sealing glue.
Exempting from the LED-UV phototherapy glue of the present invention cleans sealing can be under conventional nail lamp be irradiated
Being fully cured in 30-60S, glue is not floated on top layer, exempts to clean, is easy to use quick, time saving and energy saving.
Last institute is it should be noted that, above example is only in order to illustrate technical scheme rather than to this
The restriction of invention protection domain, although the present invention being explained in detail with reference to preferred embodiment, this area
It is to be appreciated by one skilled in the art that technical scheme can be modified or equivalent, and
Spirit and scope without departing from technical solution of the present invention.
Claims (10)
1. a LED-UV phototherapy glue exempts to clean sealing glue, it is characterised in that: comprise following percentage by weight
The raw material of concentration: oligomer 7～90%, activated monomer 7～90%, light trigger 1～10%, thio-alcohol
Compound 1～10%, stabilizer 0.1～1%.
LED-UV phototherapy glue the most according to claim 1 exempts to clean sealing glue, it is characterised in that: institute
State oligomer to be unsaturated polyester (UP), epoxy acrylate, urethane acrylate, polyether acrylate, gather
At least one in ester acrylate, pure acrylic resin.
LED-UV phototherapy glue the most according to claim 1 exempts to clean sealing glue, it is characterised in that: institute
State activated monomer selected from Monofunctional monomers and/or bifunctional monomer.
LED-UV phototherapy glue the most according to claim 3 exempts to clean sealing glue, it is characterised in that: institute
State Monofunctional monomers for acryloyl morpholine, vinylacetate, Isooctyl acrylate monomer, isobornyl acrylate,
At least one in isobornyl methacrylate, crylic acid hydroxy ester, methacrylic acid hydroxyl ester.
LED-UV phototherapy glue the most according to claim 3 exempts to clean sealing glue, it is characterised in that: institute
State bifunctional monomer be 1,6 hexanediol diacrylate, 1,4 butanediol diacrylate, two contractings 3 the third two
In alcohol diacrylate, neopentylglycol dimethacrylate, ethylene glycol dimethacrylate at least one
Kind.
LED-UV phototherapy glue the most according to claim 1 exempts to clean sealing glue, it is characterised in that: institute
Stating light trigger is 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, 2,4,6-front three
At least one in base benzoyl-diphenyl phosphine oxide, 2-isopropyl thioxanthone.
LED-UV phototherapy glue the most according to claim 1 exempts to clean sealing glue, it is characterised in that: institute
State sulfur alcohol compound be ethylene glycol bisthioglycolate (3-thiopropionate), 1,4-butanediol two (3-thiopropionate),
At least one in trimethylolpropane tris (3-thiopropionate), tetramethylolmethane four (3-thiopropionate).
LED-UV phototherapy glue the most according to claim 1 exempts to clean sealing glue, it is characterised in that: institute
Stating stabilizer is MEHQ, p-tert-Butylcatechol, p-methyl phenol, para-aminophenol, right
Nitrophenol, tert-butyl group MEHQ, 2,6 di tert butyl 4 methyl phenol, three (2,4-di-tert-butyls
Phenol) phosphite ester, three (N-nitroso-group-N-Phenylhydroxylamine) aluminium salt, at least one in NO free radical piperidine alcohols.
9. exempt to clean the preparation of sealing glue according to the LED-UV phototherapy glue according to any one of claim 1～8
Method, it is characterised in that: comprise the following steps:
(1) by described oligomer, activated monomer, light trigger, sulfur alcohol compound, stabilizer mixing；
(2) at normal temperatures and pressures, the raw material mixed is stirred dispersion so that light trigger is the most molten
Solving, each component is fully dispersed；
(3) standing sloughs bubble or vacuum sloughs bubble.
LED-UV phototherapy glue the most according to claim 9 exempts to clean the preparation method of sealing glue, its
It is characterised by: under conditions of rotating speed is 800～1500rpm, be stirred dispersion.
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| CN201610214824.8A CN105878054B (en) | 2016-04-07 | 2016-04-07 | LED-UV phototherapy glue exempts to clean sealing glue and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610214824.8A CN105878054B (en) | 2016-04-07 | 2016-04-07 | LED-UV phototherapy glue exempts to clean sealing glue and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN105878054A true CN105878054A (en) | 2016-08-24 |
| CN105878054B CN105878054B (en) | 2018-11-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610214824.8A Active CN105878054B (en) | 2016-04-07 | 2016-04-07 | LED-UV phototherapy glue exempts to clean sealing glue and preparation method thereof |
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| CN107987581A (en) * | 2018-01-03 | 2018-05-04 | 洛阳科迪艺思树脂有限公司 | A kind of disposable sealing of UV-LED nails and preparation method thereof |
| CN108477809A (en) * | 2018-05-31 | 2018-09-04 | 北京云绘智能科技有限公司 | A kind of intelligence nail art device and manicure method |
| CN108611042A (en) * | 2018-03-22 | 2018-10-02 | 深圳市姿彩科技有限公司 | LED solidification drop glue |
| CN109010129A (en) * | 2018-06-29 | 2018-12-18 | 广州杰奥斯精细化工有限公司 | A kind of wearability it is good and can self-healing UV nail polish sealing and preparation method thereof |
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| CN107987581A (en) * | 2018-01-03 | 2018-05-04 | 洛阳科迪艺思树脂有限公司 | A kind of disposable sealing of UV-LED nails and preparation method thereof |
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| CN109010129A (en) * | 2018-06-29 | 2018-12-18 | 广州杰奥斯精细化工有限公司 | A kind of wearability it is good and can self-healing UV nail polish sealing and preparation method thereof |
| WO2021007658A1 (en) * | 2019-07-12 | 2021-01-21 | Mondofix Inc. | Thiol-based adhesive formulations for repairing windshields |
| CN110917068A (en) * | 2019-12-05 | 2020-03-27 | 山东益丰生化环保股份有限公司 | UV-cured environment-friendly nail polish and preparation method thereof |
| CN111035575A (en) * | 2019-12-16 | 2020-04-21 | 山东益丰生化环保股份有限公司 | Uv-cured modified thiol resin nail polish and preparation method thereof |
| CN111607332A (en) * | 2020-06-18 | 2020-09-01 | 上海固柯胶带科技有限公司 | Rubber layer composition and protective film |
| WO2022012694A1 (en) * | 2020-07-17 | 2022-01-20 | Guangdong Huarun Paints Co., Ltd. | Uv-led curable and yellowing resistant coating composition |
| CN113398005A (en) * | 2021-05-13 | 2021-09-17 | 广州市鸿耀化工有限公司 | Velvet nail oil glue seal layer and preparation method thereof |
| CN113304070A (en) * | 2021-06-16 | 2021-08-27 | 广州蓝之天化工科技发展有限公司 | High-gloss low-yellowing wash-free sealing layer and preparation method thereof |
| CN116376494A (en) * | 2021-12-23 | 2023-07-04 | 武汉宜田科技发展有限公司 | Medium-low temperature water boiling glue suitable for cutting large-size silicon wafer |
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Denomination of invention: LED-UV phototherapy glue scrubbing-free sealing layer glue and preparation method thereof Effective date of registration: 20200320 Granted publication date: 20181116 Pledgee: China Co truction Bank Corp Guangzhou green finance reform and innovation pilot area Huadu Branch Pledgor: UV TECH MATERIAL Ltd. Registration number: Y2020980000908 |