CN105861993A - Colored resin spectacle lens and preparation method thereof - Google Patents
Colored resin spectacle lens and preparation method thereof Download PDFInfo
- Publication number
- CN105861993A CN105861993A CN201610325025.8A CN201610325025A CN105861993A CN 105861993 A CN105861993 A CN 105861993A CN 201610325025 A CN201610325025 A CN 201610325025A CN 105861993 A CN105861993 A CN 105861993A
- Authority
- CN
- China
- Prior art keywords
- layer
- valve
- vacuum chamber
- oxygen
- open
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
- C23C14/28—Vacuum evaporation by wave energy or particle radiation
- C23C14/30—Vacuum evaporation by wave energy or particle radiation by electron bombardment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/021—Cleaning or etching treatments
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/021—Cleaning or etching treatments
- C23C14/022—Cleaning or etching treatments by means of bombardment with energetic particles or radiation
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0694—Halides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/081—Oxides of aluminium, magnesium or beryllium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/083—Oxides of refractory metals or yttrium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/085—Oxides of iron group metals
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/086—Oxides of zinc, germanium, cadmium, indium, tin, thallium or bismuth
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/10—Glass or silica
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/10—Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
Landscapes
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Health & Medical Sciences (AREA)
- Ophthalmology & Optometry (AREA)
- Physics & Mathematics (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Surface Treatment Of Optical Elements (AREA)
Abstract
The invention relates to a colored resin spectacle lens. The colored resin spectacle lens comprises a resin lens base body, wherein a hardened film layer is evaporated on the front surface of the resin lens base body; an absorbing material film layer is evaporated on the surface of the hardened film layer; an anti-reflection film group layer is evaporated on the surface of the absorbing material film layer; a metal oxide film layer is evaporated on the anti-reflection film group layer; and a fluoride film layer is evaporated on the metal oxide film layer. The resin spectacle lens adopting the structure can play a blue light absorbing role while guaranteeing high visible light transmittance and oil and UV resistance, so that the colored resin spectacle lens which is resistant to UV and blue light is achieved. A preparation method can effectively guarantee the deposition mass of all the film layers, greatly improves the qualification rate of lens, and endows the lens with an excellent oil and UV resistant effect, as well as good smoothness.
Description
Technical field
The present invention relates to a kind of lens, particularly to a kind of color resin lens and preparation method thereof.
Background technology
Along with raising and the reinforcement of aesthetic consciousness of people's living standard, people increasingly emphasize independent in mind and action, sunglasses
More and more universal, colour lens consumption is increasing.Colour lens or tinted lens are the advocations of each user personality, simultaneously
Overwhelming majority colour lens are completed by the deposition that lens materials carries out dyestuff or pigment, this method by with
The deposition of dyestuff assisted by the solvent of dyeing auxiliaries, simultaneously with motion and the diffusion of heating process, beneficially dyestuff or pigment.Since
Occurring in that staining technique, eyeglass becomes colorful from colourless, shows extremely strong advantage in various occasions, such as, has
Under the scene of strong sunlight or ultraviolet light, wear the dark brown or grey eyeglass with certain depth (hiding rare of more than 70%), have
Filter the effect of sunshine, be eyes from damage, simultaneously can be apparent see object clearly, also have and there is large stretch of area again
Snowfield or the water surface, strong reflective or dazzle has an extremely strong injury to eyes, is difficult to differentiate object, if this simultaneously
In the case of, if wearing dark brown or containing polarization effect dark brown eyeglass, can significantly filter reflective or dazzle.Have this
Substantially for eye protection and the function seeing object clearly, tinted lens is current popular eyeglass category, shades of colour
Occur, more add attraction.
But the manufacturing process of various colour lens is a full solvent volatilization and dyestuff or the process of pigment volatilization, mistake
With significantly to human body stimulating course in journey, by ventilating or isolation, can effectively reduce this stimulation, but most
Colour lens is that efficiency is the lowest, and cost is the highest by manually or automatically completing by a width, and due to eyeglass
Cure profile is different different with the material of eyeglass, and temperature and time is also had the concentration of coloring agent to be difficult to control by dyeing course, leads
Causing be not parked in complementary color or have scrapping of significant proportion, domestic have a lot, such as in the method improving this problem:
1. the change of lens materials, refers mainly to the degree of polymerization and declines, and strand becomes the longest, and intermolecular density is relatively low, so that dye
Material is easier to deposition.In conventional material, the eyeglass of CR39 and 1.56 refractive indexes is easier coloring, high-index material due to
Main material is polyurethane, polymerization densification, and dyeing becomes highly difficult, though half an hour, dye level under 200 Fahrenheit temperature
Also only 45%, also PC material is difficult to dyeing, and changes the degree of polymerization of high-index material or PC, and difficulty is very big.So it is this
The effect of method is not clearly.
2. adding various solvents, such as: phenmethylol etc., add some surfactants simultaneously, this method is conducive to dye
Material or the dispersion of pigment and deposition, but to some injury of human body, irritant, and in use due to the degree of eyeglass
Number difference, thickness is the most different, and dyeing time can change, and this makes dyeing be difficult to control, and final effect is not fine.
3. using special hardening liquid to dye in rear surface, as long as this eyeglass semi-finished lenses, this eyeglass is front
Surface has had the stiffening layer of protection eyeglass, and this stiffening layer has the feature of good spalling resistance and heatproof, when
After rear surface is processed the number of degrees, rear surface is an exposed surface, then in adding that rear surface painting last layer can dye
Hard liquid, this hardening liquid has certain hardness and can carry out solidifying the feature of poststaining, after completing whole process, then whole
Individual eyeglass is immersed in coloring agent and dyes, and owing to have employed rear surface coating dyeing technology, has cut off material to dyeing
Impact.But owing to all concentrating on rear surface, the more difficult control of the degree of depth.
The method of mass coloration, since surface penetration difficulty is very big, the method having occurred as soon as material body dyeing, this side
The major part of method is dyestuff or pigment to be applied directly in material monomer, by a series of polymerisation, dyestuff or
Pigment is not involved in polymerization, thus protects the polymerisation of lens monomer itself unaffected.But owing to eyeglass is a kind of optics
Parts, in manufacturing process, can relate to high-accuracy filtration, so the particle that pigment is more than 300nm is often filtered, thus shadow
Ring color.And dyestuff can participate in reaction substantially, cause affecting other physical properties of eyeglass, so this technology is seldom by industry
Use.
Accordingly, it is now desired to develop a kind of stable film layer color resin lens and preparation method thereof.
Summary of the invention
The technical problem to be solved in the present invention is, for existing deficiency, it is provided that a kind of high-quality, antiultraviolet and suction
Receive the color resin lens of blue light.
In order to solve above-mentioned technical problem, the technical solution used in the present invention is, this color resin lens includes resin
Eyeglass matrix, the front surface of described resin lens matrix is coated with one layer and adds hard membrane layer, described in add the surface of hard membrane layer and be coated with one layer
Absorbing material film layer, the surface of described absorbing material film layer is coated with one layer of antireflective coating group layer；Described antireflective coating group layer
On be coated with layer of metal oxide membranous layer, described metal oxide film layer is coated with one layer of fluoride films layer；Described absorbing material
Film layer is by silica, tin indium oxide, five oxidation Tritanium/Trititaniums, zirconium dioxide, tantalum pentoxide, di-iron trioxide, three oxidations two
The combination of one or more in chromium and zinc selenide.
Use technique scheme, by plating stiffened scratch resistant layer, absorption on the front surface of resin lens matrix successively
Material film layers, antireflective coating group layer, metal oxide film layer and fluoride films layer, use edge to block fixture, so that respectively
Layer film will not deposit on the edge of eyeglass body in deposition process；Absorbing material is used the mode of evaporation, in vacuum
Under environment, it is evaporated to add the surface of hard membrane layer, can successfully make this color resin lens have one layer and absorb blue light
Colorful film, absorbing material film layer by silica, tin indium oxide, five oxidation Tritanium/Trititaniums, zirconium dioxide, tantalum pentoxide,
The combination of one or more in di-iron trioxide, chrome green and zinc selenide, can by adjust each film thickness and
Preparation technology so that prepared film has the effect of the blue light that absorbing wavelength is 400 ~ 500nm, it is possible to achieve eyeglass has
Also there is while colour antiultraviolet and absorb the effect of blue light, thus the most attractive in appearance but also protect eyes.
The present invention further improvement is that, described in add hard membrane layer, described absorbing material film layer, described antireflective coating group
Layer, metal oxide film layer and fluoride films layer all use electron-beam vapor deposition method to deposit.Use electron-beam vapor deposition method certain
Deposit each layer film under vacuum, the film of high-quality high permeability can be obtained, make each layer film at eyeglass body simultaneously
On have the most attached work power, all disposable deposition under vacuum conditions of the most all of film layer obtains, and can make each
The attached work power of layer film is more preferable, the more stable pollution simultaneously prevented in manufacturing process；In addition the method prepares speed soon, produces
Efficiency is high.
The present invention further improvement is that, the target that described absorbing material film layer is used is by described silver halide and institute
State cupric oxide to mix, and compaction moulding under the load of 280KN, then 400 DEG C of temperature lower calcinations 12 hours in Muffle furnace
Prepare absorbing material target.The method of this self-control target is simple and convenient controlled, can save production cost.
The present invention further improvement is that, described in add the thickness of hard membrane layer be 300 ~ 400nm；Described absorbing material film layer
Thickness be 10 ~ 20nm；The thickness of described antireflective coating group layer is 280 ~ 320nm；The thickness of described metal oxide film layer is 10 ~
20nm；The thickness of described fluoride films layer is 5 ~ 10nm.
The present invention further improvement is that, described rear surface antireflective coating group layer be followed successively by the first silicon dioxide layer, first
Zirconia layer, the second silicon dioxide layer, the second zirconia layer, the 3rd silicon dioxide layer.In the collocation that the front surface of eyeglass uses
For P1/P2/Super Hydrophobic/(SiO2/ZrO2/SiO2/ZrO2/SiO2)/HC/Lens, wherein SiO2Refractive index
It is 1.45, ZrO2Refractive index be 2.176, by the SiO of multilayer2Film and ZrO2Film, adjust simultaneously each layer hyaline membrane parameter and
Preparation process condition so that antireflective coating has well reflection and absorbs the effect of ultraviolet, ensure that simultaneously its high can
See light transmission rate.
The present invention further improvement is that, the thickness of described first silicon dioxide layer is 30 ~ 50nm, described first zirconium oxide
The thickness of layer is 40 ~ 60nm, described second silicon dioxide layer 50 ~ 60nm, described second zirconia layer 40 ~ 50nm, the described 3rd
Silicon dioxide layer is 50 ~ 60nm.
The problem that the present invention is to be solved is to provide the preparation method of a kind of color resin lens structure.
In order to solve above-mentioned technical problem, the technical solution used in the present invention is, this preparation method uses multiple true chambers
Be connected the evaporated device formed, and each vacuum chamber is spaced by valve, and this preparation method specifically includes following steps:
(1) Chemical cleaning of resin lens matrix: 1. in order to remove the organic matter of resin lens matrix surface, first with hydrogen peroxide and
Clean by deionized water after the ultrasonic 20 ~ 30min of immersion of the mixed solution (volume ratio is 3:1) of the concentrated sulfuric acid；2. eyeglass matrix
Successively put into ultrasonic 25 ~ 35min in acetone soln, ethanol solution and deionized water, to improve resin lens matrix surface activity,
Thus increase the adhesion of film and resin lens matrix material；3. clean and resin lens matrix is placed in baking oven does after terminating
Dry, after drying substrate is put into pallet, then torr has the pallet of substrate send into pre-deposition room.
(2) acquisition of equipment vacuum: start mechanical pump, open side and take out valve II, each vacuum chamber is vacuumized；Work as vacuum
When degree reaches 1 ~ 8Pa, close side and take out valve II, open side and take out valve I, and start molecular pump, open slide valve, use molecular pump to respectively
Individual vacuum chamber vacuumizes further；After molecular pump accelerates, stable operation is until vacuum reaches 1 ~ 5 × 10-3Pa；Open and add
Hot device, arranging heating-up temperature is 150 ~ 200 DEG C；When the vacuum in the vacuum chamber of electron beam evaporation instrument reaches 1 ~ 3 × 10-7
Start electron beam gun during Pa, adjust the position of electron beam so that it is be positioned at the centre adding hard membrane layer target；
(3) ion beam cleaning is carried out in pre-deposition indoor: argon plasma cleans；Open argon gas valve, be passed through argon gas, to resin
Eyeglass matrix carries out ion beam cleaning, and scavenging period is 3 ~ 5 min；Cleaning closes argon gas valve after completing；Open the first vacuum chamber
Room valve, has the pallet of substrate to send into the first vacuum chamber by torr；
(4) add the preparation of hard membrane layer: substrate enters the first vacuum chamber along with pallet, regulate line, at resin lens matrix
Being deposited with one layer on front surface and add hard membrane layer, the evaporation time is 5 ~ 10min；Close electron beam gun, open argon gas valve and oxygen valve, past
Vacuum chamber is passed through argon gas and oxygen, carries out argon oxygen plasma etch, and etch period is 2 ~ 5min；Close argon gas valve and oxygen
Valve, opens the second vacuum chamber valve, and torr has the pallet of substrate send into the second vacuum chamber；
(5) preparation of absorbing material film layer: substrate enters the second vacuum chamber along with pallet, regulates line, is adding hard membrane layer
Surface on be deposited with layer of absorbent film, the evaporation time is 15 ~ 20min；Close electron beam gun, open oxygen valve, toward true
Plenum chamber is passed through oxygen, carries out total oxygen plasma etching, and etch period is 2 ~ 5min；Close oxygen valve, open the 3rd vacuum
Chamber valve, has the pallet of substrate to send into the 3rd vacuum chamber by torr；
(6) preparation of antireflective coating group layer: substrate enters the 3rd vacuum chamber along with pallet, regulates line, thin at absorbing material
Being deposited with antireflective coating group layer on the surface of film layer, the evaporation time is 15 ~ 20min；Close electron beam gun；Open argon gas valve and oxygen
Valve, is passed through argon gas and oxygen toward vacuum chamber, carries out argon oxygen plasma etch, and etch period is 3 ~ 6min；Close argon gas valve
And oxygen valve, open the 4th vacuum chamber valve, torr has the pallet of substrate send into the 4th vacuum chamber；
(7) preparation of metal oxide film layer: substrate enters the 4th vacuum chamber along with pallet, regulates line, at antireflective coating
Evaporation metal oxide membranous layer on the surface of group layer, the evaporation time is 10 ~ 15min；Close electron beam gun；Open oxygen valve, past
Vacuum chamber is passed through oxygen, carries out total oxygen plasma etching, and etch period is 1 ~ 2min；Close oxygen valve, open the 5th true
Plenum chamber valve, has the pallet of substrate to send into the 5th vacuum chamber by torr；
(8) preparation of fluoride films layer: substrate enters the 5th vacuum chamber along with pallet, regulates line, at metal oxide film
Being deposited with fluoride films layer on the surface of layer, the evaporation time is 5 ~ 8min；Close electron beam gun；Open oxygen valve, toward vacuum chamber
Being passed through oxygen, carry out total oxygen plasma etching, etch period is 1 ~ 2min；Close oxygen valve, open the pre-chamber valves that exits, will
Torr has the pallet feeding of substrate to exit chamber in advance；
(9) release vacuum: open and exit chamber intake valve in advance, be passed through air, take out eyeglass.
Using electron-beam vapor deposition method, electron gun therein is e shape electron gun, and the advantage of this electron beam gun is to be difficult to make deposition
Film is contaminated, and the power of deposition is big, and the film quality of deposition is high；Multiple vacuum chamber can be used in preparation process
Connecting, resin lens matrix is at each vacuum chamber equipped with the crucible of the target of each film layer, and substrate depends at each vacuum chamber
Each chamber of secondary feeding is also sequentially depositing each layer film, and crucible uses cold-crucible, can avoid crucible material evaporation and
React between itself and membrane material；The temperature of post processing, time and atmosphere all can affect the transmitance of film and to purple
The reflection of outside line and absorption, use argon oxygen etching and total oxygen to be etched with the attached work power beneficially submitted between each tunic, make each tunic
Combine more closely.
As the preferred version of the present invention, described metal oxide film layer is magnesium oxide films layer or bismuth oxide film layer.This gold
Belong to the oxide membranous layer attached work as binder course, beneficially antireflective coating group layer Yu the fluoride films layer of oil-stain-preventing, improve resin
The uniformity of eyeglass overlay film.
As the preferred version of the present invention, described fluoride films layer is magnesium fluoride film layer or sodium fluoride film layer or calcirm-fluoride film
Layer.
Compared with prior art, the invention has the beneficial effects as follows: a kind of color resin lens and its preparation side are provided
Method, this structure makes resin eyeglass have while ensure that high visible light transmissivity and oil-stain-preventing antiultraviolet can
Absorb the effect of blue light, it is achieved that the color resin lens of antiultraviolet and blue light；This preparation method each layer of energy effective guarantee
The deposition quality of film, is greatly enhanced the qualification rate of eyeglass, makes eyeglass have oil-stain-preventing and effect of antiultraviolet of excellence, and
There is good slickness.
Accompanying drawing explanation
It is clearly understood to make present disclosure be easier to, below according to specific embodiment and combine accompanying drawing, right
The present invention is described in further detail:
Fig. 1 is the structural representation of embodiments of the invention 1 color resin lens structure；
Wherein: wherein: 1-fluoride films layer；2-metal oxide film layer；3-antireflective coating group layer；4-absorbing material film layer；5-
Add hard membrane layer；6-resin lens matrix.
Detailed description of the invention
Embodiment 1: as it is shown in figure 1, this color resin lens structure is P1/P2/(SiO2/ZrO2/SiO2/ZrO2/
SiO2)/(ITO/SiO2/ZrO2)/HC/Lens；Wherein P1 is fluoride films layer 1；P1 is alkalescent metal oxide film layer 2,
(SiO2/ZrO2/SiO2/ZrO2/SiO2) it is antireflective coating group layer 3, absorbing material film layer 4, HC is stiffening layer 5, and Lens is tree
Fat eyeglass matrix 6.
Embodiment 2: the preparation method of embodiment 1, comprises the steps:
This preparation method use multiple true chambers be connected formed evaporated device, each vacuum chamber is spaced by valve,
This preparation method specifically includes following steps:
(1) Chemical cleaning of resin lens matrix: 1. in order to remove the organic matter of resin lens matrix surface, first with hydrogen peroxide and
Clean by deionized water after the ultrasonic 25min of immersion of the mixed solution (volume ratio is 3:1) of the concentrated sulfuric acid；2. eyeglass matrix successively
Put into ultrasonic 35min in acetone soln, ethanol solution and deionized water, to improve resin lens matrix surface activity, thus increase
Add the adhesion of film and resin lens matrix material；3. clean, after terminating, resin lens matrix is placed in oven drying, be dried
After substrate is put into pallet, then torr is had substrate pallet send into pre-deposition room.
(2) acquisition of equipment vacuum: start mechanical pump, open side and take out valve II, each vacuum chamber is vacuumized；Work as vacuum
When degree reaches 6Pa, close side and take out valve II, open side and take out valve I, and start molecular pump, open slide valve, use molecular pump to each
Vacuum chamber vacuumizes further；After molecular pump accelerates, stable operation is until vacuum reaches 5 × 10-3Pa；Open heater,
Arranging heating-up temperature is 180 DEG C；When the vacuum in the vacuum chamber of electron beam evaporation instrument reaches 2 × 10-7Electronics is started during Pa
Bundle rifle, adjusts the position of electron beam so that it is be positioned at the centre adding hard membrane layer target；
(3) ion beam cleaning is carried out in pre-deposition indoor: argon plasma cleans；Open argon gas valve, be passed through argon gas, to resin
Eyeglass matrix carries out ion beam cleaning, and scavenging period is 4min；Cleaning closes argon gas valve after completing；Open the first vacuum chamber valve
Door, has the pallet of substrate to send into the first vacuum chamber by torr；
(4) add the preparation of hard membrane layer: substrate enters the first vacuum chamber along with pallet, regulate line, at resin lens matrix
Being deposited with one layer on front surface and add hard membrane layer, the evaporation time is 8min；Close electron beam gun, open argon gas valve and oxygen valve, toward true
Plenum chamber is passed through argon gas and oxygen, carries out argon oxygen plasma etch, and etch period is 4min；Close argon gas valve and oxygen valve,
Open the second vacuum chamber valve, torr has the pallet of substrate send into the second vacuum chamber；
(5) preparation of absorbing material film layer: substrate enters the second vacuum chamber along with pallet, regulates line, is adding hard membrane layer
Surface on be deposited with layer of absorbent film, by use many targets vacuum chamber, rotary target material realizes, evaporation the time time
Between be respectively 2min, 2min, 3min, closedown electron beam gun, open oxygen valve, be passed through oxygen toward vacuum chamber, carry out total oxygen etc.
Plasma etching, etch period is 4min；Close oxygen valve, open the 3rd vacuum chamber valve, torr has the pallet of substrate send
Enter the 3rd vacuum chamber；
(6) preparation of antireflective coating group layer: substrate enters the 3rd vacuum chamber along with pallet, regulates line, thin at absorbing material
Being deposited with antireflective coating group layer on the surface of film layer, by using double target vacuum chamber, rotary target material realizes, the evaporation time time
Between be respectively 2min, 2min, 4min, 3min, 4min；Close electron beam gun；Open argon gas valve and oxygen valve, lead to toward vacuum chamber
Entering argon gas and oxygen, carry out argon oxygen plasma etch, etch period is 5min；Close argon gas valve and oxygen valve, open the 4th
Vacuum chamber valve, has the pallet of substrate to send into the 4th vacuum chamber by torr；
(7) preparation of metal oxide film layer: substrate enters the 4th vacuum chamber along with pallet, regulates line, at antireflective coating
Evaporation metal oxide membranous layer on the surface of group layer, the evaporation time is 13min；Close electron beam gun；Open oxygen valve, toward vacuum
Chamber is passed through oxygen, carries out total oxygen plasma etching, and etch period is 2min；Close oxygen valve, open the 5th vacuum chamber
Valve, has the pallet of substrate to send into the 5th vacuum chamber by torr；
(8) preparation of fluoride films layer: substrate enters the 5th vacuum chamber along with pallet, regulates line, at metal oxide film
Being deposited with fluoride films layer on the surface of layer, the evaporation time is 7min；Close electron beam gun；Open oxygen valve, lead to toward vacuum chamber
Entering oxygen, carry out total oxygen plasma etching, etch period is 2min；Close oxygen valve, open and pre-exit chamber valves, torr is had
The pallet of substrate is sent into and is exited chamber in advance；
(9) release vacuum: open and exit chamber intake valve in advance, be passed through air, take out eyeglass.
Test result is: this color resin lens can absorb the blue light of 400 ~ 500nm, can obtain 20 ~ 80% degree of depth
Adjustable color resin eyeglass；Use ITO/SiO2/ZrO2The absorbing material film layer prepared, can obtain the coloured silk of the degree of depth of 80%
Chromoresin eyeglass, the transmitance of the blue light of its 400 ~ 500nm is only 15% ~ 20%.
Can also use away while deposit in preparation process, resin lens matrix is passed by with various uniform speed successively
Each vacuum chamber has then deposited all of film layer, and uniform translational speed can obtain uniform film, the most so
Be conducive to improving thin film deposition quality, it is to avoid the pollution of different materials；During this external preparation, antireflective coating group layer is permissible
Same vacuum chamber deposits, by using double target vacuum equipment, rotates eyeglass body and realize, be so conducive to saving
Cost, it is adaptable to be widely popularized.
The general principle of the present invention, principal character and advantage have more than been shown and described.The technical staff of the industry should
Understanding, the present invention is not restricted to the described embodiments, and the simply explanation present invention's described in above-described embodiment and specification is former
Reason, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these changes and improvements
Both fall within scope of the claimed invention.
Claims (9)
1. a color resin lens, including resin lens matrix, it is characterised in that the front surface of described resin lens matrix
Be coated with one layer and add hard membrane layer, described in add the surface of hard membrane layer and be coated with layer of absorbent film layer, described absorbing material film layer
Surface be coated with one layer of antireflective coating group layer；It is coated with layer of metal oxide membranous layer, described metal on described antireflective coating group layer
One layer of fluoride films layer it is coated with on oxide membranous layer；Described absorbing material film layer is by silica, tin indium oxide, five oxidations three
The combination of one or more in titanium, zirconium dioxide, tantalum pentoxide, di-iron trioxide, chrome green and zinc selenide.
Color resin lens the most according to claim 1, it is characterised in that described in add hard membrane layer, described absorbing material
Film layer, described antireflective coating group layer, metal oxide film layer and fluoride films layer all use electron-beam vapor deposition method to deposit.
Color resin lens the most according to claim 2, it is characterised in that described absorbing material film layer is used
Target is described silver halide and described cupric oxide to be mixed, and compaction moulding under the load of 280KN, then in Muffle furnace
12 hours prepared absorbing material targets of 400 DEG C of temperature lower calcinations.
Color resin lens the most according to claim 3, it is characterised in that described in add the thickness of hard membrane layer be 300 ~
400nm；The thickness of described absorbing material film layer is 10 ~ 20nm；The thickness of described antireflective coating group layer is 280 ~ 320nm；Institute
The thickness stating metal oxide film layer is 10 ~ 20nm；The thickness of described fluoride films layer is 5 ~ 10nm.
Color resin lens the most according to claim 4, it is characterised in that described antireflective coating group layer is followed successively by first
Silicon dioxide layer, the first zirconia layer, the second silicon dioxide layer, the second zirconia layer, the 3rd silicon dioxide layer.
Color resin lens the most according to claim 5, it is characterised in that the thickness of described first silicon dioxide layer is
30 ~ 50nm, the thickness of described first zirconia layer is 40 ~ 60nm, described second silicon dioxide layer 50 ~ 60nm, described second oxygen
Changing zirconium layer 40 ~ 50nm, described 3rd silicon dioxide layer is 50 ~ 60nm.
7. one kind such as the preparation method according to the color resin lens as described in any one of claim 1-6, it is characterised in that should
Preparation method use multiple true chambers be connected formed evaporated device, each vacuum chamber is spaced by valve, and this is prepared
Method specifically includes following steps:
(1) Chemical cleaning of resin lens matrix: 1. in order to remove the organic matter of resin lens matrix surface, by volume ratio be first
The hydrogen peroxide of 3:1 and the mixed solution of the concentrated sulfuric acid, clean by deionized water after soaking ultrasonic 20 ~ 30min；2. eyeglass matrix first
After put into ultrasonic 25 ~ 35min in acetone soln, ethanol solution and deionized water, with improve resin lens matrix surface activity, from
And increase the adhesion of film and resin lens matrix material；3. clean, after terminating, resin lens matrix be placed in oven drying,
After drying substrate is put into pallet, then torr has the pallet of substrate send into pre-deposition room；
(2) acquisition of equipment vacuum: start mechanical pump, open side and take out valve II, each vacuum chamber is vacuumized；When vacuum reaches
During to 1 ~ 8Pa, close side and take out valve II, open side and take out valve I, and start molecular pump, open slide valve, use molecular pump true to each
Plenum chamber vacuumizes further；After molecular pump accelerates, stable operation is until vacuum reaches 1 ~ 5 × 10-3Pa；Open heater,
Arranging heating-up temperature is 150 ~ 200 DEG C；When the vacuum in the vacuum chamber of electron beam evaporation instrument reaches 1 ~ 3 × 10-7Open during Pa
Dynamic electron beam gun, adjusts the position of electron beam so that it is be positioned at the centre adding hard membrane layer target；
(3) ion beam cleaning is carried out in pre-deposition indoor: argon plasma cleans；Open argon gas valve, be passed through argon gas, to resin
Eyeglass matrix carries out ion beam cleaning, and scavenging period is 3 ~ 5 min；Cleaning closes argon gas valve after completing；Open the first vacuum chamber
Room valve, has the pallet of substrate to send into the first vacuum chamber by torr；
(4) add the preparation of hard membrane layer: substrate enters the first vacuum chamber along with pallet, regulate line, at resin lens matrix
Being deposited with one layer on front surface and add hard membrane layer, the evaporation time is 5 ~ 10min；Close electron beam gun, open argon gas valve and oxygen valve, past
Vacuum chamber is passed through argon gas and oxygen, carries out argon oxygen plasma etch, and etch period is 2 ~ 5min；Close argon gas valve and oxygen
Valve, opens the second vacuum chamber valve, and torr has the pallet of substrate send into the second vacuum chamber；
(5) preparation of absorbing material film layer: substrate enters the second vacuum chamber along with pallet, regulates line, is adding hard membrane layer
Surface on be deposited with layer of absorbent film, the evaporation time is 15 ~ 20min；Close electron beam gun, open oxygen valve, toward true
Plenum chamber is passed through oxygen, carries out total oxygen plasma etching, and etch period is 2 ~ 5min；Close oxygen valve, open the 3rd vacuum
Chamber valve, has the pallet of substrate to send into the 3rd vacuum chamber by torr；
(6) preparation of antireflective coating group layer: substrate enters the 3rd vacuum chamber along with pallet, regulates line, thin at absorbing material
Being deposited with antireflective coating group layer on the surface of film layer, the evaporation time is 15 ~ 20min；Close electron beam gun；Open argon gas valve and oxygen
Valve, is passed through argon gas and oxygen toward vacuum chamber, carries out argon oxygen plasma etch, and etch period is 3 ~ 6min；Close argon gas valve
And oxygen valve, open the 4th vacuum chamber valve, torr has the pallet of substrate send into the 4th vacuum chamber；
(7) preparation of metal oxide film layer: substrate enters the 4th vacuum chamber along with pallet, regulates line, at antireflective coating
Evaporation metal oxide membranous layer on the surface of group layer, the evaporation time is 10 ~ 15min；Close electron beam gun；Open oxygen valve, past
Vacuum chamber is passed through oxygen, carries out total oxygen plasma etching, and etch period is 1 ~ 2min；Close oxygen valve, open the 5th true
Plenum chamber valve, has the pallet of substrate to send into the 5th vacuum chamber by torr；
(8) preparation of fluoride films layer: substrate enters the 5th vacuum chamber along with pallet, regulates line, at metal oxide film
Being deposited with fluoride films layer on the surface of layer, the evaporation time is 5 ~ 8min；Close electron beam gun；Open oxygen valve, toward vacuum chamber
Being passed through oxygen, carry out total oxygen plasma etching, etch period is 1 ~ 2min；Close oxygen valve, open the pre-chamber valves that exits, will
Torr has the pallet feeding of substrate to exit chamber in advance；
(9) release vacuum: open and exit chamber intake valve in advance, be passed through air, take out eyeglass.
8. such as the preparation method of color resin lens according to claim 7, it is characterised in that described metal oxide
Film layer is magnesium oxide films layer or bismuth oxide film layer.
9. such as the preparation method of color resin lens according to claim 8, it is characterised in that described fluoride films layer
For magnesium fluoride film layer or sodium fluoride film layer or calcirm-fluoride film layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610325025.8A CN105861993B (en) | 2016-05-17 | 2016-05-17 | Color resin spectacle lens and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610325025.8A CN105861993B (en) | 2016-05-17 | 2016-05-17 | Color resin spectacle lens and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105861993A true CN105861993A (en) | 2016-08-17 |
| CN105861993B CN105861993B (en) | 2018-10-30 |
Family
ID=56635353
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610325025.8A Active CN105861993B (en) | 2016-05-17 | 2016-05-17 | Color resin spectacle lens and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105861993B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107505728A (en) * | 2017-07-31 | 2017-12-22 | 江苏淘镜有限公司 | A kind of processing technology that specialized lens are driven for production safety |
| CN108572479A (en) * | 2018-04-17 | 2018-09-25 | 昆山龙腾光电有限公司 | Display device |
| CN109570125A (en) * | 2018-12-17 | 2019-04-05 | 上海万明眼镜有限公司 | A kind of stiffened manufacturing process of PC optical mirror slip |
| CN109613716A (en) * | 2018-12-28 | 2019-04-12 | 厦门美澜光电科技有限公司 | A kind of anti-oxidant anti-blue light band pattern eyeglass and preparation method thereof |
| CN110468378A (en) * | 2019-09-12 | 2019-11-19 | 西安邮电大学 | A kind of preparation method of densification five oxidation two tantalum film |
| CN110703363A (en) * | 2019-10-24 | 2020-01-17 | 明灏科技（北京）有限公司 | Lens coating processing technology, lens and computer storage medium |
| CN110865427A (en) * | 2019-11-28 | 2020-03-06 | 厦门朵彩光学科技有限公司 | Seawater-resistant coated sunglasses and preparation method thereof |
| CN111890710A (en) * | 2020-07-31 | 2020-11-06 | 潘学龙 | Resin lens for shielding high-frequency radiation and manufacturing method thereof |
| CN111897035A (en) * | 2020-07-31 | 2020-11-06 | 潘学龙 | Resin lens for shielding high-frequency radiation and production process thereof |
| CN111962026A (en) * | 2020-07-30 | 2020-11-20 | 苏州瑞康真空科技有限公司 | Film coating method for spectacle lens |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105404022A (en) * | 2015-12-31 | 2016-03-16 | 奥特路（漳州）光学科技有限公司 | Blue light-filtering sterilizing wear-resistant lens and manufacturing method thereof |
| CN105425414A (en) * | 2015-12-31 | 2016-03-23 | 奥特路（漳州）光学科技有限公司 | Blue light filtering lens and preparation method thereof |
| CN105425417A (en) * | 2015-12-31 | 2016-03-23 | 奥特路（漳州）光学科技有限公司 | Blue light filtering, water and oil dirt preventing and wear resisting lens and preparation method thereof |
| CN105425418A (en) * | 2015-12-31 | 2016-03-23 | 奥特路（漳州）光学科技有限公司 | Blue light filtering, radiation protection and wear resisting lens and preparation method thereof |
| CN105425419A (en) * | 2015-12-31 | 2016-03-23 | 奥特路（漳州）光学科技有限公司 | Blue light filtering and wear resisting lens and preparation method thereof |
-
2016
- 2016-05-17 CN CN201610325025.8A patent/CN105861993B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105404022A (en) * | 2015-12-31 | 2016-03-16 | 奥特路（漳州）光学科技有限公司 | Blue light-filtering sterilizing wear-resistant lens and manufacturing method thereof |
| CN105425414A (en) * | 2015-12-31 | 2016-03-23 | 奥特路（漳州）光学科技有限公司 | Blue light filtering lens and preparation method thereof |
| CN105425417A (en) * | 2015-12-31 | 2016-03-23 | 奥特路（漳州）光学科技有限公司 | Blue light filtering, water and oil dirt preventing and wear resisting lens and preparation method thereof |
| CN105425418A (en) * | 2015-12-31 | 2016-03-23 | 奥特路（漳州）光学科技有限公司 | Blue light filtering, radiation protection and wear resisting lens and preparation method thereof |
| CN105425419A (en) * | 2015-12-31 | 2016-03-23 | 奥特路（漳州）光学科技有限公司 | Blue light filtering and wear resisting lens and preparation method thereof |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107505728A (en) * | 2017-07-31 | 2017-12-22 | 江苏淘镜有限公司 | A kind of processing technology that specialized lens are driven for production safety |
| CN108572479A (en) * | 2018-04-17 | 2018-09-25 | 昆山龙腾光电有限公司 | Display device |
| CN109570125A (en) * | 2018-12-17 | 2019-04-05 | 上海万明眼镜有限公司 | A kind of stiffened manufacturing process of PC optical mirror slip |
| CN109613716A (en) * | 2018-12-28 | 2019-04-12 | 厦门美澜光电科技有限公司 | A kind of anti-oxidant anti-blue light band pattern eyeglass and preparation method thereof |
| CN109613716B (en) * | 2018-12-28 | 2022-03-18 | 厦门美澜光电科技有限公司 | Anti-oxidation blue-light-proof patterned lens and preparation method thereof |
| CN110468378A (en) * | 2019-09-12 | 2019-11-19 | 西安邮电大学 | A kind of preparation method of densification five oxidation two tantalum film |
| CN110703363A (en) * | 2019-10-24 | 2020-01-17 | 明灏科技（北京）有限公司 | Lens coating processing technology, lens and computer storage medium |
| CN110865427A (en) * | 2019-11-28 | 2020-03-06 | 厦门朵彩光学科技有限公司 | Seawater-resistant coated sunglasses and preparation method thereof |
| CN110865427B (en) * | 2019-11-28 | 2021-06-01 | 厦门朵彩光学科技有限公司 | Seawater-resistant coated sunglasses and preparation method thereof |
| CN111962026A (en) * | 2020-07-30 | 2020-11-20 | 苏州瑞康真空科技有限公司 | Film coating method for spectacle lens |
| CN111890710A (en) * | 2020-07-31 | 2020-11-06 | 潘学龙 | Resin lens for shielding high-frequency radiation and manufacturing method thereof |
| CN111897035A (en) * | 2020-07-31 | 2020-11-06 | 潘学龙 | Resin lens for shielding high-frequency radiation and production process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105861993B (en) | 2018-10-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105861993B (en) | Color resin spectacle lens and preparation method thereof | |
| EP3268776B1 (en) | Ophthalmic lens article comprising an antireflective coating in the visible region for low luminance conditions | |
| CN105866975A (en) | Color change resin spectacle lens and preparation method thereof | |
| CN110794490A (en) | Design and preparation method of medium-wave infrared antireflection film | |
| CN208207410U (en) | A kind of plated film resin lens containing sieve and silica-sesquioxide layer | |
| CN105556346A (en) | Optical article with gradient photochromism | |
| CN107111000A (en) | Being included in ultraviolet region has the optical article of interference coatings of high reflectance | |
| CN105859153A (en) | Antifogging antireflection visible-light double-function coated glass and preparation method thereof | |
| CN112198730A (en) | Variable-color bionic leaf for hyperspectral stealth camouflage | |
| CN105084781B (en) | A kind of golden low radiation film coating glass and preparation method thereof | |
| CN110255922A (en) | A kind of double-silver low-emissivity coated glass and preparation method thereof | |
| JP6858860B2 (en) | Anti-reflective coated articles and how to make them | |
| JP2012523974A (en) | Method for manufacturing dimming optical element and dimming optical element | |
| CN106435496A (en) | Grass-green double-silver low-radiation energy-saving window film and preparation method thereof | |
| CN105866976A (en) | Ultraviolet-proof lens structure and preparation method thereof | |
| CN101493534B (en) | Dereflection screen of display and method for making same | |
| WO2021032804A1 (en) | Spectacle lens with filter effect for blue light and spectacles | |
| CN106536172A (en) | Method for dyeing transparent article made of polymeric substrate with gradient tint | |
| CN109628880B (en) | Anti-oxidation and anti-corrosion lens with patterns and preparation method thereof | |
| CN108828697B (en) | Eimeria antioxidant anti-reflection corrosion-resistant lens and preparation method thereof | |
| CN115079440B (en) | Progressive color-changing film lens and manufacturing process thereof | |
| CN212135086U (en) | Seven-color sunglasses lens | |
| CN215375990U (en) | Lens of low UV reflection rete design of concave-convex form | |
| US20210325697A1 (en) | An ophthalmic lens for improving night driving vision and a method for obtaining the same | |
| CN105082670B (en) | A kind of green sunshade type coated glass and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |