CN212135086U - Seven-color sunglasses lens - Google Patents

Seven-color sunglasses lens Download PDF

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CN212135086U
CN212135086U CN202020456369.4U CN202020456369U CN212135086U CN 212135086 U CN212135086 U CN 212135086U CN 202020456369 U CN202020456369 U CN 202020456369U CN 212135086 U CN212135086 U CN 212135086U
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layer
color
arc
visible light
coating
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吴春凯
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Mingyue Lens Co ltd
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Mingyue Lens Co ltd
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Abstract

The utility model relates to a seven various sunglasses pieces, comprising a substrate, the substrate is including arc convex surface and arc concave surface, from interior to exterior has set gradually first hard coating, first coating film layer on the arc convex surface, from interior to exterior has set gradually the second on the arc concave surface and has added hard coating, absorbed layer, second coating film layer, first coating film layer, second coating film layer constitute by antireflection multilayer membrane heap and water proof membrane. The beneficial effects of the utility model are that realize the batch production of sunglasses lens through coating process, be suitable for current all lens materials, low in production cost, production stability is high, and does not have the pollution to the living environment.

Description

Seven-color sunglasses lens
Technical Field
The utility model relates to a lens, especially a seven various sunglasses lenses belongs to glasses lens technical field.
Background
Sunglasses, also known as sun lenses, are used only for shading sun. In life, too many light sources can generate harmful light, especially sunlight; the light rays emitted from the inside of the sunlight comprise: visible light, infrared, ultraviolet, and the like. In the sunlight, the light flux is usually adjusted by adjusting the pupil size, and when the light intensity exceeds the adjusting capacity of the human eyes, the human eyes are damaged. The sunglasses can effectively filter partial light, prevent eyes of people from being burnt by strong light, and can also prevent ultraviolet rays from damaging cornea and sight line membrane, and the high-quality sunglasses can filter up to 97 percent of light entering eyes to avoid damage.
Currently, the sunglasses on the market mainly have two types of lenses, one of which is a polarized sunglasses lens, and the polarized sunglasses lens is manufactured according to the polarization principle of light, so as to effectively filter the scattered light in the light, such as the shutter principle. It is mainly composed of a polarizing film and a substrate carrier, and is produced by mainly adhering the polarizing film on the surface of a lens or sandwiching the polarizing film between lenses before thermosetting molding of a resin lens. The other type is a dyed sunglass lens, the lens mainly adopts dyed particles to absorb light, the most common process is to soak a resin lens in liquid containing a dyed substance, the liquid is heated, the surface molecular gap of the resin lens is enlarged after the resin lens is heated, the dyed particles dissolved in the liquid can enter the molecular gap, dyeing is completed after cooling, a dyed layer on the surface of the lens can absorb light with different wavelengths according to different dyed particles, the deeper dyeing is, the more dyed particles enter the lens, and the better the light absorption is.
The polarized sunglasses are high in production process requirement, complex in production process, low in qualification rate, high in price all the time, large in diopter influence in the production process, and large in quantity of goods are not laid on the market all the time. The process of dyeing the lens is simpler, but most of dyeing particles are organic dyes, so that the process of fading and lightening exists in the process of using the lens in life, and meanwhile, the pollution of the dyeing powder to the water environment is larger. Whether the polarized sunglasses or the dyed sunglasses have great limitation on the materials of the lenses, partial lens materials cannot be dyed due to small molecular gaps, and the polarized sunglasses cannot be manufactured due to poor bonding force between some lens materials and the polarizing films.
SUMMERY OF THE UTILITY MODEL
The utility model aims to solve the technical problem that the shortcoming of the prior art is overcome, a seven-color sunglasses lens suitable for batch production is provided.
In order to solve the technical problem, the utility model provides a pair of seven various sunglasses pieces, comprises a substrate, the substrate is including arc convex surface and arc concave surface, from interior to exterior has set gradually first hard coating, first coating film layer on the arc convex surface, from interior to exterior has set gradually the second on the arc concave surface and has added hard coating, absorbed layer, second coating film layer, first coating film layer, second coating film layer constitute by antireflection multilayer membrane heap and waterproof membrane, the waterproof membrane covers in the surface that antireflection multilayer antireflection membrane heap.
The utility model discloses a coating process adds absorbing film, antireflection coating and water proof membrane on the lens substrate in the lump, is different from traditional sunglasses (be polarisation sunglasses and dyeing sunglasses), uses visible light absorbing material, makes the visible light absorption layer through coating process to optimize the rete design from the well, obtain the sunglasses piece of different visible light projection ratio and the sunglasses piece of different colours.
Preferably, the base material is a resin substrate made of an acrylate, polyurethane or acryl material, and has a refractive index of 1.499, 1.552, 1.600, 1.670 or 1.71.
Preferably, first hard coating, second hard coating all are by-10 hard coating or-11 hard coating preparation and form, first hard coating, second hard coating's thickness is 3 μm, first hard coating, second hard coating all have arc convex surface and arc concave surface, the arc concave surface of first hard coating and the arc convex surface of substrate are laminated mutually, the arc convex surface of second hard coating and the arc concave surface of substrate are laminated mutually.
When the resin substrate is made of acrylic ester or acrylic material, the hardening layer adopts-10 hardening liquid, and when the resin substrate is made of polyurethane material, the hardening layer adopts-11 hardening liquid. The hardened layer is mainly used for improving the corrosion resistance and the friction resistance of the resin substrate, and different hardened layers are needed to be matched with different base materials in order to improve the binding force between the coating material and the base materials, so that better coating layer binding force can be obtained. The hardened layer is prepared by a dip coating method, and specifically, an organic silicon protective layer is coated on the whole surface of the substrate, and a thermochemical and mechanical hardened protective layer with the thickness of about 3 mu m, namely the hardened layer, is formed after high-temperature curing. The abrasion resistance of the hardened resin lens surface is very close to that of a glass lens, and the transmittance is slightly increased.
Preferably, the absorption layer is composed of low refractive index films and visible light absorption films alternately arranged, and both top and bottom surfaces of the absorption layer are visible light absorption films.
In addition, the absorbing layer is provided with an arc convex surface and an arc concave surface, the first coating layer and the second coating layer are also provided with an arc convex surface and an arc concave surface respectively, the arc convex surface of the absorbing layer is attached to the arc concave surface of the second hardening layer, the arc concave surface of the absorbing layer is attached to the arc convex surface of the second coating layer, and the arc concave surface of the first coating layer is attached to the arc convex surface of the first hardening layer.
Preferably, the visible light absorption film is made of a visible light absorption material, the visible light absorption material being a metal material and a metal oxide material, the metal material being chromium (Cr) or nickel (ni)Chromium alloy, the metal oxide material is titanium oxide (TiO) or titanium pentoxide (Ti)3O5). In addition, the visible light absorbing material may also be silicon (Si).
Preferably, the total number of the film layers of the absorption layer is 7-15, and the thickness of the absorption layer is 130 nm-350 nm.
Preferably, the antireflection multilayer film stack is composed of low refractive index films and zirconium dioxide films which are alternately arranged, and both the top surface and the bottom surface of the antireflection multilayer film stack are low refractive index films.
The total number of layers of the antireflection multilayer film stack is 5, and the thickness of the antireflection multilayer film stack is 300-450 nm.
Preferably, the thickness of the waterproof film is 3 nm.
Preferably, the low refractive index film is made of a low refractive index material, which is silicon dioxide.
The utility model discloses a manufacturing of sunglasses piece is realized to coating film technology, and its coating film technology mainly lies in the design of absorbed layer and antireflection multilayer membrane heap, is applied to sunglasses piece with the extinction of materials such as Cr, TiO.
The utility model has the advantages that: the method realizes the batch production of the sunglasses lenses by the coating process, is suitable for all the existing lens materials, and has the advantages of low production cost, high production stability and no pollution to living environment.
Drawings
Fig. 1 is a schematic structural diagram of the present invention.
Fig. 2 is a schematic view of the visible light transmittance of the sunglass lens in embodiment 1 of the present invention.
Fig. 3 is a schematic view of the visible light reflectivity of the sunglass lens according to embodiment 1 of the present invention.
Fig. 4 is a schematic view of the visible light transmittance of the sunglass lens in embodiment 2 of the present invention.
Fig. 5 is a schematic view of the visible light reflectance of the sunglass lens according to embodiment 2 of the present invention.
Fig. 6 is a schematic view of the visible light transmittance of the sunglass lens in embodiment 3 of the present invention.
Fig. 7 is a schematic view of the visible light reflectance of the sunglass lens according to embodiment 3 of the present invention.
In the figure: 1. the coating comprises a base material, 2, a first hardening layer, 3, a second hardening layer, 4, an absorption layer, 5, a first coating layer and 6, a second coating layer.
Detailed Description
As shown in fig. 1, a seven-color sunglasses lens comprises a substrate 1, wherein the substrate 1 comprises an arc-shaped convex surface and an arc-shaped concave surface, a first hardening layer 2 and a first coating layer 5 are sequentially arranged on the arc-shaped convex surface from inside to outside, a second hardening layer 3, an absorption layer 4 and a second coating layer 6 are sequentially arranged on the arc-shaped concave surface from inside to outside, the first coating layer 5 and the second coating layer 6 are formed by an antireflection multilayer film stack and a waterproof film, and the waterproof film covers the outer surface of the antireflection multilayer film stack. Wherein, the substrate 1 is a resin substrate, the resin substrate is made of acrylate, polyurethane or acrylic material, and the refractive index is 1.499, 1.552, 1.600, 1.670 or 1.71; the first hardening layer 2 and the second hardening layer 3 are both prepared from-10 hardening liquid (from Dohn optical Co., Ltd.) or-11 hardening liquid (from Dohn optical Co., Ltd.), the thicknesses of the first hardening layer 2 and the second hardening layer 3 are 3 micrometers, the first hardening layer 2 and the second hardening layer 3 are respectively provided with an arc-shaped convex surface and an arc-shaped concave surface, the arc-shaped concave surface of the first hardening layer 2 is attached to the arc-shaped convex surface of the substrate 1, the arc-shaped convex surface of the second hardening layer 3 is attached to the arc-shaped concave surface of the substrate 1, the absorption layer 4 is provided with an arc-shaped convex surface and an arc-shaped concave surface, the first coating layer 5 and the second coating layer 6 are also respectively provided with an arc-shaped convex surface and an arc-shaped concave surface, the arc-shaped convex surface of the absorption layer 4 is attached to the arc-shaped concave surface of the second hardening layer 3, the arc-shaped concave surface of the absorption layer 4 is attached to the arc-shaped convex surface of the second coating layer 6, and the arc-shaped concave surface of the first coating layer 5; the absorption layer 4 consists of low-refractive-index films and visible light absorption films which are alternately arranged, the total number of the film layers of the absorption layer 4 is 7-15, the thickness of the absorption layer 4 is 130-350 nm, the thickness of each low-refractive-index film is 15-90 nm, the thickness of each visible light absorption film is 4-16 nm, each low-refractive-index film is made of a low-refractive-index material, each visible light absorption film is made of a visible light absorption material, the visible light absorption materials are chromium (Cr), nickel-chromium alloy, titanium oxide (TiO), titanium pentoxide (Ti 3O 5) or silicon (Si), and the low-refractive-index material is silicon dioxide; the total number of layers of antireflection multilayer film stack is 5, and the thickness of antireflection multilayer film stack is 300 ~ 450nm, and antireflection multilayer film stack comprises the low refracting index membrane and the zirconium dioxide membrane of setting in turn, and the top surface and the bottom surface of antireflection multilayer film stack are low refracting index membrane, and the low refracting index material that low refracting index membrane used is silicon dioxide, and the thickness of single low refracting index membrane is 37 ~ 132nm, and the thickness of single zirconium dioxide membrane is 28 ~ 92nm, and the thickness of waterproof membrane is 3 nm.
Example 1
The grey, luminousness is 15%'s sunglasses lens that this embodiment provided, including 1.60 super tough substrate, this substrate has arc convex surface and arc concave surface, at the arc concave surface, all be equipped with the stiffened layer that thickness is 3 mu m on the arc convex surface, be equipped with the coating film layer outside the stiffened layer of arc convex surface, be equipped with absorbed layer and coating film layer outside the stiffened layer of arc concave surface, the coating film layer comprises antireflection multilayer membrane heap and water proof membrane, the water proof membrane covers the surface in antireflection multilayer membrane heap. The hardened layer adopts 10 hardening liquid of Dohn optics Limited company, and the hardened layer is formed by coating an organic silicon protective layer on the surface of the whole substrate through a dip-coating method and then curing at high temperature to form a hardened layer with the thickness of 3 mu m, and the hardened layer can increase the corrosion resistance and the friction resistance of the resin sheet, thereby providing better adhesive force for subsequent coating, and the refractive index of the material is 1.50. The total number of the absorption layers is 15, the absorption layers are composed of low-refractive-index films and visible light absorption films which are alternately arranged, the low-refractive-index films are made of low-refractive-index materials (namely silicon dioxide), the visible light absorption films are made of visible light absorption materials, and the visible light absorption materials are Cr and TiO. The total number of piles of antireflection multilayer membrane is 5, and the water proof membrane is the one deck to antireflection multilayer membrane stack comprises silicon dioxide and the zirconium dioxide of setting in turn, and the top surface and the bottom surface of antireflection multilayer membrane stack are silicon dioxide. The visible light transmittance of the sunglass lens of the embodiment is 15% as shown in fig. 2; the visible reflectance is shown in fig. 3.
In addition, an absorption layerSee table 1, and the parameters of the antireflection multilayer film stack and the waterproofing film are shown in table 2. The absorption layer adopts a vacuum coating technology, and the process comprises the following steps: 1.60 super-tough single-hardened lens is insulated at 70 ℃, plasma is assisted for 90s in Ar protective atmosphere, and the argon flow is 20cm3/s, evaporating an absorption layer, wherein the absorption layer comprises 15 layers, and the used materials are Cr, TiO and SiO2
TABLE 1
Film layer Material Thickness (nm) Coating rate (nm/s) Auxiliary time(s)
1 Cr 8 0.3
2 SiO2 32.12 0.8
3 TiO 13.3 0.5
4 SiO2 60.1 0.8
5 IPC 60
6 TiO 15.5 0.5
7 SiO2 17.5 0.8
8 IPC 60
9 TiO 15.5 0.5
10 SiO2 59.68 0.8
11 IPC 60
12 TiO 9.5 0.5
13 SiO2 89.5 0.8
14 IPC 60
15 TiO 13.5 0.5
As can be seen from the above table, Cr and TiO areThe main part of the absorption layer absorbs the visible light from 380 to 780nm through the metal or metal oxide material and then passes through Cr, TiO and SiO2The constant accumulation of (a) reduces the visible light transmittance to 15%. Thus, different visible light transmittances can be obtained with different stack thicknesses and numbers of layers. Wherein the refractive index (expressed by N) and extinction coefficient (expressed by K) of TiO are as follows:
wavelength of light N K Wavelength of light N K Wavelength of light N K
380 2.93 0.17 520 2.52 0.43 660 2.44 0.75
400 2.82 0.20 540 2.50 0.48 680 2.44 0.79
420 2.74 0.23 560 2.49 0.52 700 2.43 0.84
440 2.67 0.27 580 2.47 0.56 720 2.43 0.88
460 2.62 0.31 600 2.46 0.61 740 2.43 0.93
480 2.58 0.35 620 2.46 0.66 760 2.43 0.98
500 2.55 0.39 640 2.45 0.70 780 2.43 1.02
The refractive index (denoted by N) and extinction coefficient (denoted by K) of Cr are:
wavelength of light N K Wavelength of light N K Wavelength of light N K
380 1.92 1.99 520 2.39 2.28 660 1.85 3.05
400 2.22 1.88 540 2.32 2.39 680 1.77 3.16
420 2.39 1.87 560 2.24 2.50 700 1.70 3.27
440 2.47 1.91 580 2.16 2.61 720 1.63 3.37
460 2.50 1.98 600 2.08 2.72 740 1.57 3.48
480 2.48 2.07 620 2.00 2.83 760 1.50 3.58
500 2.44 2.17 640 1.92 2.94 780 1.44 3.68
From this, it is clear that the extinction coefficients of Cr and TiO are as above at a wavelength of 380-780nm, and therefore the color of the sunglasses is neutral gray, and the color thereof is known from the CIE1976 (CIE 1976 means a color body) color system: y (luminance factor representing color) luminance is 15.8, L (lightness representing color) lightness is 45.65, a (red-green value representing color) red-green value is 0.98, b (yellow-blue value representing color) yellow-blue value is 0.51; the position of the color in the color profile, i.e. the color coordinate x is 0.3415 and y is 0.3465. SiO 22The protective film mainly plays a role in balancing the stress of Cr and TiO, has a protective effect, can prevent the Cr and TiO from being oxidized, and provides support for the design of a rear antireflection film. And IPC assists in improving the compactness of the film and reducing the drift of water absorption and the like after the film is coated.
TABLE 2
Film layer Material Thickness (nm) Coating rate (nm/s)
1 SiO2 103.5 0.3
2 ZrO2 28.1 0.5
3 SiO2 37.3 0.8
4 ZrO2 75.1 0.5
5 SiO2 120.1 0.8
6 Water-proof material 3.0 0.3
Thus, ZrO2For antireflection of the main component of the multilayer stack, by ZrO2The light transmittance of the sunglass lens can be reduced by the reflection effect on visible light.
Example 2
The present embodiment is different from embodiment 1 in that: the sunglass lens of this example is neutral gray and has a light transmittance of 30%. The test parameters for the absorber layer are shown in table 3, and the test parameters for the antireflection multilayer film stack and the waterproofing film are shown in table 4.
TABLE 3
Film layer Material Thickness (nm) Coating rate (nm/s) Auxiliary time(s)
1 Cr 6.8 0.3
2 SiO2 16.6 0.8
3 TiO 9.5 0.5
4 SiO2 45.3 0.8
5 IPC 60
6 TiO 10.5 0.5
7 SiO2 89.4 0.8
8 IPC 60
9 TiO 10.5 0.5
10 SiO2 70.68 0.8
11 IPC 60
12 TiO 8.5 0.5
13 SiO2 47.5 0.8
14 IPC 60
15 TiO 10.5 0.5
TABLE 4
Film layer Material Thickness (nm) Coating rate (nm/s)
1 SiO2 63.5 0.3
2 ZrO2 58.1 0.5
3 SiO2 42.28 0.8
4 ZrO2 91.4 0.5
5 SiO2 83.1 0.8
6 Water-proof material 3.0 0.3
Wherein the waterproof material is M12 waterproof material of Dongguan Taiyue Limited company. The sun lens of this embodiment has a light transmittance of 30% as shown in fig. 4, and a light reflection as shown in fig. 5. The color of the sunglass lenses is known from CIE 1976: y is 30.9, L is 59.33, a is 0.68, b is-0.51; color coordinates x is 0.3368, y is: 0.3325.
example 3
The present embodiment is different from embodiment 1 in that: the sunglass lens of this example is dark brown, and its light transmittance is 30%. The test parameters of the absorbing layer are shown in table 5, and the test parameters of the antireflection multilayer film stack and the waterproof film are shown in table 6.
TABLE 5
Film layer Material Thickness (nm) Coating rate (nm/s)
1 Cr 6.8 0.3
2 SiO2 50.1 0.8
3 Cr 4.8 0.3
4 SiO2 19.8 0.8
5 Cr 4.8 0.3
6 SiO2 37.21 0.8
7 Cr 6.8 0.3
TABLE 6
Film layer Material Thickness (nm) Coating rate (nm/s)
1 SiO2 132.0 0.3
2 ZrO2 68.5 0.5
3 SiO2 95.59 0.8
4 ZrO2 42.25 0.5
5 SiO2 103.5 0.8
6 Water-proof material 3.0 0.3
Wherein the waterproof material is M12 waterproof material of Dongguan Taiyue Limited company. The sun lens of this embodiment has a light transmittance of 30% as shown in fig. 6, and a light reflection as shown in fig. 7. The color of the sunglass lenses is known from CIE 1976: y is 31.5, L is 57.33, a is 9.58, b is 8.03; color coordinates x is 0.3588, y is: 0.3405.
in addition to the above examples, the present invention can have other embodiments, for example, the substrate can be 1.499 substrate, 1.552 substrate, 1.600 acrylic substrate, 1.600MR-8 substrate, 1.670MR-7 substrate or 1.710 substrate besides the 1.60 super-tough substrate. All the technical solutions formed by adopting equivalent substitutions or equivalent transformations fall within the protection scope claimed by the present invention.

Claims (10)

1. The utility model provides a seven various sunglass lenses, includes the substrate, the substrate is including arc convex surface and arc concave surface, its characterized in that: the arc-shaped convex surface is sequentially provided with a first hardening layer and a first coating layer from inside to outside, the arc-shaped concave surface is sequentially provided with a second hardening layer, an absorption layer and a second coating layer from inside to outside, the first coating layer and the second coating layer are formed by an antireflection multilayer film stack and a waterproof film, and the waterproof film covers the outer surface of the antireflection multilayer film stack.
2. The seven-color sunglass lens according to claim 1, wherein: the base material is a resin substrate made of acrylate, polyurethane or acrylic material, and the refractive index of the resin substrate is 1.499, 1.552, 1.600, 1.670 or 1.71.
3. The seven-color sunglass lens according to claim 1, wherein: the first hardening layer and the second hardening layer are both prepared from-10 hardening liquid or-11 hardening liquid, and the thickness of the first hardening layer and the thickness of the second hardening layer are both 3 micrometers.
4. The seven-color sunglass lens according to claim 1, wherein: the absorption layer is composed of low-refractive-index films and visible light absorption films which are alternately arranged, and the top surface and the bottom surface of the absorption layer are both visible light absorption films.
5. The colorful sunglass lens of claim 4, wherein: the visible light absorption film is made of a visible light absorption material, the visible light absorption material is a metal material and a metal oxide material, the metal material is chromium or nickel-chromium alloy, and the metal oxide material is titanium oxide.
6. The colorful sunglass lens of claim 5, wherein: the total number of the film layers of the absorption layer is 7-15, and the thickness of the absorption layer is 130-350 nm.
7. The seven-color sunglass lens according to claim 1, wherein: the antireflection multilayer film stack is composed of low-refractive-index films and zirconium dioxide films which are alternately arranged, and the top surface and the bottom surface of the antireflection multilayer film stack are both low-refractive-index films.
8. The seven-color sunglass lens according to claim 7, wherein: the total number of layers of the antireflection multilayer film stack is 5, and the thickness of the antireflection multilayer film stack is 300-450 nm.
9. The seven-color sunglass lens according to claim 1, wherein: the thickness of the waterproof membrane is 3 nm.
10. The seven-color sunglass lens according to claim 7, wherein: the low refractive index film is made of a low refractive index material, and the low refractive index material is silicon dioxide.
CN202020456369.4U 2020-01-20 2020-04-01 Seven-color sunglasses lens Active CN212135086U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112946919A (en) * 2021-04-22 2021-06-11 上海康耐特光学有限公司 Laminating type functional resin lens and preparation method and application thereof
WO2024138918A1 (en) * 2022-12-30 2024-07-04 江苏万新光学有限公司 Weak-absorption, low-reflection, clear-base-color and anti-blue-light resin lens and preparation method therefor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112946919A (en) * 2021-04-22 2021-06-11 上海康耐特光学有限公司 Laminating type functional resin lens and preparation method and application thereof
WO2024138918A1 (en) * 2022-12-30 2024-07-04 江苏万新光学有限公司 Weak-absorption, low-reflection, clear-base-color and anti-blue-light resin lens and preparation method therefor

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