CN105861121A - 一种节能抗磨汽油机油及其制备方法 - Google Patents

一种节能抗磨汽油机油及其制备方法 Download PDF

Info

Publication number
CN105861121A
CN105861121A CN201610221256.4A CN201610221256A CN105861121A CN 105861121 A CN105861121 A CN 105861121A CN 201610221256 A CN201610221256 A CN 201610221256A CN 105861121 A CN105861121 A CN 105861121A
Authority
CN
China
Prior art keywords
gasoline engine
engine oil
oil
ester
resistant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610221256.4A
Other languages
English (en)
Other versions
CN105861121B (zh
Inventor
黄毅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hebei Shengqi Lubricating Oil Technology Co ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610221256.4A priority Critical patent/CN105861121B/zh
Publication of CN105861121A publication Critical patent/CN105861121A/zh
Application granted granted Critical
Publication of CN105861121B publication Critical patent/CN105861121B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022—Ethene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024—Propene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C10M2207/2825—Esters of (cyclo)aliphatic oolycarboxylic acids used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/285—Esters of aromatic polycarboxylic acids
    • C10M2207/2855—Esters of aromatic polycarboxylic acids used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086—Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C10M2219/068—Thiocarbamate metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明公开了一种节能抗磨汽油机油及其制备方法，所述节能抗磨汽油机油由下述重量份的原料组成：单烯基丁二酰亚胺0.7‑0.9份、烷基苯磺酸钙0.4‑0.6份、乙丙共聚物5‑10份、4,4'‑二辛基二苯胺0.1‑0.3份、2,2'‑亚甲基双‑(4‑甲基‑6‑叔丁基苯酚)0.1‑0.3份、二丁基二硫代磷酸锌0.2‑0.4份、聚甲基丙烯酸酯0.3‑0.5份、二甲基硅油0.002‑0.005份、抗磨剂0.6‑0.9份、基础油75‑85份。本发明节能抗磨汽油机油，解决了现有技术中存在的汽油机油抗磨性能差的问题，大大延长了汽油机油的使用寿命，降低了成本，且环保节能，适用范围广，非常实用。

Description

一种节能抗磨汽油机油及其制备方法
技术领域
本发明涉及润滑油技术领域，是一种节能抗磨汽油机油及其制备方法。
背景技术
长期以来，人们一直关注着国内外内燃机油开发研制的状况：内燃机油开发研究的主要目的是选用合适的基础油，平衡各种添加剂的用量。通过大量的实验室试验、模拟试验和发动机台架试验，合理地确定内燃机油的组成。尽管目前控制汽车排放的发展方向主要针对着汽油中的芳烃和铅，但更少的燃料燃烧就意味着更少的排放，尤其是作为主要温室气体的二氧化碳的排放会更少。因此，润滑油一个显著的发展趋势是向更低粘度、更苛刻的挥发性要求，更好燃料经济性的节能型发展。节约不可再生的石油资源使得无论是汽油机油还是柴油都需要延长换油期。
发动机是汽车的心脏，其内有许多相互摩擦运动的金属表面，这些部件运动速度快、环境差，工作温度可达400-600℃，必须使用机油对发动机起到如下作用：1.润滑减磨：活塞和汽缸之间，主轴和轴瓦之间均存在着快速的相对滑动，要防止零件过快的磨损，则需要在两个滑动表面间建立油膜，有足够厚度的油膜将相对滑动的零件表面隔开，从而达到减少磨损的目的；2.冷却降温：机油能够将热量带回机油箱再散发至空气中帮助水箱冷却发动机。3.清洗清洁：机油能够将发动机零件上的碳化物、油泥、磨损金属颗粒通循环带回机油箱，通过润滑油的流动，冲洗零件工作面上产生的脏物。
目前较常用的机油主要为矿物油和合成油，该两种类型的机油均包括基础油和添加剂，其中矿物油由矿物基础油和添加剂混配制成。虽然矿物油存在着很多缺点，但由于其来源广泛，成本较低，目前仍得到了广泛的应用，本领域技术人员通过调整矿物基础油的比例以及添加剂的组份含量来提高机油的性能，但由于现有的有机添加剂在高温高压条件下会分解失效，无机添加剂由于颗粒较大导入摩擦界面性能差，从而影响发动机性能的发挥。
发明内容
针对现有技术的不足，本发明解决技术问题之一是提供一种节能抗磨汽油机油。
本发明解决技术问题之二是提供上述节能抗磨汽油机油的制备方法。
本发明的技术方案如下：
一种节能抗磨汽油机油，由下述重量份的原料组成：单烯基丁二酰亚胺0.7-0.9份、烷基苯磺酸钙0.4-0.6份、乙丙共聚物5-10份、4,4'-二辛基二苯胺0.1-0.3份、2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)0.1-0.3份、二丁基二硫代磷酸锌0.2-0.4份、聚甲基丙烯酸酯0.3-0.5份、二甲基硅油0.002-0.005份、抗磨剂0.6-0.9份、基础油75-85份。
所述的基础油由壬二酸二(2-乙基己基)酯、偏苯三酸三壬酯、1,2,4-苯三甲酸三(2-乙基己基)酯混合而成，所述壬二酸二(2-乙基己基)酯、偏苯三酸三壬酯、1,2,4-苯三甲酸三(2-乙基己基)酯的质量比为(1-3)：(1-3)：(1-3)。
优选地，所述的抗磨剂由40-60wt％N,N-二异辛基二硫代氨基甲酸钼和40-60wt％N,N-二(十三)烷基二硫代氨基甲酸钼组成。
本发明还提供了上述节能抗磨汽油机油的制备方法：将单烯基丁二酰亚胺、烷基苯磺酸钙、乙丙共聚物、4,4'-二辛基二苯胺、2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)、二丁基二硫代磷酸锌、聚甲基丙烯酸酯、二甲基硅油、抗磨剂、基础油加入调和釜中混合均匀，即得所述节能抗磨汽油机油。
本发明节能抗磨汽油机油，解决了现有技术中存在的汽油机油抗磨性能差的问题，大大延长了汽油机油的使用寿命，降低了成本，且环保节能，适用范围广，非常实用。
具体实施方式
下面结合实施例对本发明做进一步的说明，以下所述，仅是对本发明的较佳实施例而已，并非对本发明做其他形式的限制，任何熟悉本专业的技术人员可能利用上述揭示的技术内容加以变更为同等变化的等效实施例。凡是未脱离本发明方案内容，依据本发明的技术实质对以下实施例所做的任何简单修改或等同变化，均落在本发明的保护范围内。
实施例各原料介绍：
2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)，CAS号：119-47-1。
壬二酸二(2-乙基己基)酯，CAS号：103-24-2。
偏苯三酸三壬酯，CAS号：35415-27-1。
1,2,4-苯三甲酸三(2-乙基己基)酯，CAS号：3319-31-1。
二丁基二硫代磷酸锌，CAS号：6990-43-8。
烷基苯磺酸钙采用专利申请号：200810011923.1中实施例1的方法制备。
4,4'-二辛基二苯胺，CAS号：101-67-7。
乙丙共聚物，CAS号：9010-79-1，采用大庆高新技术产业开发区林强油剂制品有限公司的型号为T613A的乙丙共聚物。
二甲基硅油，CAS号：63148-62-9，采用道康宁PMX-200常规粘度消泡剂二甲基硅油，粘度350cs。
聚甲基丙烯酸酯，按照专利申请号：201410753667.9中实施例1的方法制备。
单烯基丁二酰亚胺，其结构式如下：
其中，PIB为分子量为1000的聚异丁烯，n＝3。
N,N-二(十三)烷基二硫代氨基甲酸钼，其结构式如下：其结构式如下：
其中R为直链十三烷基。
N,N-二异辛基二硫代氨基甲酸钼，其结构式如下：
其中R为异辛基，其结构式如下：
实施例1
节能抗磨汽油机油原料(重量份)：单烯基丁二酰亚胺0.8份、烷基苯磺酸钙0.5份、乙丙共聚物7份、4,4'-二辛基二苯胺0.2份、2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)0.2份、二丁基二硫代磷酸锌0.3份、聚甲基丙烯酸酯0.4份、二甲基硅油0.003份、抗磨剂0.7份、基础油78份。
所述的基础油由壬二酸二(2-乙基己基)酯、偏苯三酸三壬酯、1,2,4-苯三甲酸三(2-乙基己基)酯按质量比为1：1：1搅拌混合均匀得到。
所述的抗磨剂由50wt％N,N-二异辛基二硫代氨基甲酸钼和50wt％N,N-二(十三)烷基二硫代氨基甲酸钼搅拌混合均匀得到。
节能抗磨汽油机油制备：
将基础油总重量二分之一的基础油(即基础油总重量的一半)加入调和釜中，升温至85℃，加入乙丙共聚物、聚甲基丙烯酸酯，400转/分搅拌40分钟；加入剩余二分之一基础油，保持温度为60℃，加入单烯基丁二酰亚胺、烷基苯磺酸钙，400转/分搅拌25分钟；加入抗磨剂、4,4'-二辛基二苯胺、2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)、二丁基二硫代磷酸锌、二甲基硅油，400转/分搅拌35分钟，冷却至室温。得到实施例1的节能抗磨汽油机油。
实施例2
与实施例1基本相同，区别仅仅在于：所述的基础油由偏苯三酸三壬酯、1,2,4-苯三甲酸三(2-乙基己基)酯按质量比为1：1搅拌混合均匀得到。得到实施例2的节能抗磨汽油机油。
实施例3
与实施例1基本相同，区别仅仅在于：所述的基础油由壬二酸二(2-乙基己基)酯、1,2,4-苯三甲酸三(2-乙基己基)酯按质量比为1：1搅拌混合均匀得到。得到实施例3的节能抗磨汽油机油。
实施例4
与实施例1基本相同，区别仅仅在于：所述的基础油由壬二酸二(2-乙基己基)酯、偏苯三酸三壬酯按质量比为1：1搅拌混合均匀得到。得到实施例4的节能抗磨汽油机油。
实施例5
与实施例1基本相同，区别仅仅在于：所述的抗磨剂仅为N,N-二异辛基二硫代氨基甲酸钼。得到实施例5的节能抗磨汽油机油。
实施例6
与实施例1基本相同，区别仅仅在于：所述的抗磨剂仅为N,N-二(十三)烷基二硫代氨基甲酸钼。得到实施例6的节能抗磨汽油机油。
测试例1
对实施例1-6的节能抗磨汽油机油使用性能进行测试，油品磨斑直径和平均摩擦力数据均为四球摩擦试验机试验数据，其试验方法根据GB/T12583-90，四球试验机设置条件为负载40kgf，转速1500rpm，运行时间1h，初始温度40℃。具体测试结果见表1。
表1：节能抗磨汽油机油使用性能测试结果表
比较实施例1与实施例2-4，实施例1(壬二酸二(2-乙基己基)酯、偏苯三酸三壬酯、1,2,4-苯三甲酸三(2-乙基己基)酯复配)使用性能明显优于实施例2-4(壬二酸二(2-乙基己基)酯、偏苯三酸三壬酯、1,2,4-苯三甲酸三(2-乙基己基)酯中任意二者复配)；比较实施例1与实施例5-6，实施例1(N,N-二异辛基二硫代氨基甲酸钼和N,N-二(十三)烷基二硫代氨基甲酸钼复配)使用性能明显优于实施例5-6(N,N-二异辛基二硫代氨基甲酸钼和N,N-二(十三)烷基二硫代氨基甲酸钼中单一原料)。
测试例2
实验根据SH/T 0193-2008润滑油氧化安定性的测定-旋转氧弹法检测，氧化时间越长则抗氧性越好。具体结果见表2。
表2：氧化安定性测试结果表
氧化时间/min
实施例1 327
实施例2 304
实施例3 312
实施例4 305
实施例5 315
实施例6 313
比较实施例1与实施例2-4，实施例1(壬二酸二(2-乙基己基)酯、偏苯三酸三壬酯、1,2,4-苯三甲酸三(2-乙基己基)酯复配)抗氧化性能明显优于实施例2-4(壬二酸二(2-乙基己基)酯、偏苯三酸三壬酯、1,2,4-苯三甲酸三(2-乙基己基)酯中任意二者复配)；比较实施例1与实施例5-6，实施例1(N,N-二异辛基二硫代氨基甲酸钼和N,N-二(十三)烷基二硫代氨基甲酸钼复配)抗氧化性能明显优于实施例5-6(N,N-二异辛基二硫代氨基甲酸钼和N,N-二(十三)烷基二硫代氨基甲酸钼中单一原料)。

Claims (3)

1.一种节能抗磨汽油机油，其特征在于，由下述重量份的原料组成：单烯基丁二酰亚胺0.7-0.9份、烷基苯磺酸钙0.4-0.6份、乙丙共聚物5-10份、4,4'-二辛基二苯胺0.1-0.3份、2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)0.1-0.3份、二丁基二硫代磷酸锌0.2-0.4份、聚甲基丙烯酸酯0.3-0.5份、二甲基硅油0.002-0.005份、抗磨剂0.6-0.9份、基础油75-85份；
所述的基础油由壬二酸二(2-乙基己基)酯、偏苯三酸三壬酯、1,2,4-苯三甲酸三(2-乙基己基)酯混合而成，所述壬二酸二(2-乙基己基)酯、偏苯三酸三壬酯、1,2,4-苯三甲酸三(2-乙基己基)酯的质量比为(1-3)：(1-3)：(1-3)。
2.如权利要求1所述的节能抗磨汽油机油，其特征在于：所述的抗磨剂由40-60wt％N,N-二异辛基二硫代氨基甲酸钼和40-60wt％N,N-二(十三)烷基二硫代氨基甲酸钼组成。
3.如权利要求1或2所述的节能抗磨汽油机油的制备方法，其特征在于：将单烯基丁二酰亚胺、烷基苯磺酸钙、乙丙共聚物、4,4'-二辛基二苯胺、2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚)、二丁基二硫代磷酸锌、聚甲基丙烯酸酯、二甲基硅油、抗磨剂、基础油加入调和釜中混合均匀，即得所述节能抗磨汽油机油。
CN201610221256.4A 2016-04-11 2016-04-11 一种节能抗磨汽油机油及其制备方法 Active CN105861121B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610221256.4A CN105861121B (zh) 2016-04-11 2016-04-11 一种节能抗磨汽油机油及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610221256.4A CN105861121B (zh) 2016-04-11 2016-04-11 一种节能抗磨汽油机油及其制备方法

Publications (2)

Publication Number Publication Date
CN105861121A true CN105861121A (zh) 2016-08-17
CN105861121B CN105861121B (zh) 2018-12-25

Family

ID=56637504

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610221256.4A Active CN105861121B (zh) 2016-04-11 2016-04-11 一种节能抗磨汽油机油及其制备方法

Country Status (1)

Country Link
CN (1) CN105861121B (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107723058A (zh) * 2017-11-22 2018-02-23 苏州永创达电子有限公司 一种抗磨润滑油
CN108277069A (zh) * 2018-03-26 2018-07-13 昆仑天迅石化（北京）有限公司 一种汽车发动机润滑油及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101195786A (zh) * 2006-12-07 2008-06-11 中国石油天然气股份有限公司 汽油机油组合物
US20130005624A1 (en) * 2010-03-12 2013-01-03 Idemitsu Kosan Co., Ltd. Lubricant composition
CN103666661A (zh) * 2012-09-20 2014-03-26 中国石油化工股份有限公司 汽油机油组合物及其用途
CN104046418A (zh) * 2013-03-13 2014-09-17 中国石油天然气股份有限公司 一种轻负荷柴油/汽油轿车发动机润滑油组合物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101195786A (zh) * 2006-12-07 2008-06-11 中国石油天然气股份有限公司 汽油机油组合物
US20130005624A1 (en) * 2010-03-12 2013-01-03 Idemitsu Kosan Co., Ltd. Lubricant composition
CN103666661A (zh) * 2012-09-20 2014-03-26 中国石油化工股份有限公司 汽油机油组合物及其用途
CN104046418A (zh) * 2013-03-13 2014-09-17 中国石油天然气股份有限公司 一种轻负荷柴油/汽油轿车发动机润滑油组合物

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
张剑 等: "《现代润滑技术》", 31 January 2008, 冶金工业出版社 *
杨俊杰: "《润滑油脂及其添加剂》", 31 July 2011, 石油工业出版社 *
王先会: "《工业润滑油生产与应用》", 31 January 2011, 中国石化出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107723058A (zh) * 2017-11-22 2018-02-23 苏州永创达电子有限公司 一种抗磨润滑油
CN108277069A (zh) * 2018-03-26 2018-07-13 昆仑天迅石化（北京）有限公司 一种汽车发动机润滑油及其制备方法

Also Published As

Publication number Publication date
CN105861121B (zh) 2018-12-25

Similar Documents

Publication Publication Date Title
CN101851548B (zh) 一种长寿命柴油发动机机油
CN105695054B (zh) 一种超低粘度的节能汽油机油及其制备方法
CN104745278A (zh) 一种环保节能的柴油机油及其制备方法
CN105542922A (zh) 一种超长换油里程的节能柴油机油及其制备方法
CN111394159A (zh) 一种经济性汽油机油sn5w/30及其制备方法
CN106566617A (zh) 一种节能环保的柴油机油的制备方法
CN105670755B (zh) 一种手动变速箱油
CN106967481A (zh) 发动机纳米养护剂及其制备方法和应用
CN107474928A (zh) 一种重负荷液力传动润滑油组合物
CN102690714B (zh) 一种铁路中高速柴油发动机润滑油组合物
CN105542912B (zh) 一种高粘度修复型降低尾气的发动机抗磨剂及其制备方法
CN105861121A (zh) 一种节能抗磨汽油机油及其制备方法
CN107892980A (zh) 船用柴油机油组合物及其用途
CN105462655A (zh) 一种超低粘度节能型发动机减摩剂及其制备方法
CN105481741A (zh) 含受阻酚的苯二胺基硫代甲酸酯，含该化合物的抗氧剂及其在燃气发动机润滑油中的应用
CN105733768A (zh) 一种矿区专用重载爬坡柴油机油及其制备方法
CN102775352B (zh) 顺-12羟基十八碳烯-3-甲基-咪唑六氟磷酸盐离子液体及含有该离子液体的四冲程发动机润滑油组合物
CN100569417C (zh) 一种金属纳米微粒表面调理剂
CN106916614A (zh) 抗极压润滑油添加剂和润滑油
CN105695056B (zh) 一种低灰分、长寿命、环保城市燃气发动机用油
CN1042743C (zh) 润滑油添加剂组合物
CN106281583A (zh) 润滑剂及其制备方法
CN1181168C (zh) 一种发动机润滑油组合物
CN107338092A (zh) 内燃机车油组合物及其用途
KR101813238B1 (ko) 내한성, 내열성 친환경 등속조인트용 그리스 조성물 및 그의 제조방법

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20181108

Address after: 311421 new village, Chun Jiang Street, Fuyang District, Hangzhou, Zhejiang

Applicant after: HANGZHOU FUYANG WEIWEN ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD.

Address before: 200092 302, 3 Lane 248 lane, Tianbao West Road, Hongkou District, Shanghai.

Applicant before: Huang Yi

GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20200415

Address after: No.66, East Ring Road, Xinxing Industrial Park, Jize Development Zone, Handan City, Hebei Province

Patentee after: Hebei Shengqi lubricating oil Technology Co.,Ltd.

Address before: 311421 Chunjiang Street New Village, Fuyang District, Hangzhou City, Zhejiang Province

Patentee before: HANGZHOU FUYANG WEIWEN ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd.

PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: An energy-saving and anti-wear gasoline engine oil and its preparation method

Granted publication date: 20181225

Pledgee: Handan Bank Co.,Ltd. Jize Branch

Pledgor: Hebei Shengqi lubricating oil Technology Co.,Ltd.

Registration number: Y2024980038520

PC01 Cancellation of the registration of the contract for pledge of patent right

Granted publication date: 20181225

Pledgee: Handan Bank Co.,Ltd. Jize Branch

Pledgor: Hebei Shengqi lubricating oil Technology Co.,Ltd.

Registration number: Y2024980038520