CN105860929A - Environment-friendly efficient automatic-inflation tire repair fluid and preparation method thereof - Google Patents

Environment-friendly efficient automatic-inflation tire repair fluid and preparation method thereof Download PDF

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Publication number
CN105860929A
CN105860929A CN201610212902.0A CN201610212902A CN105860929A CN 105860929 A CN105860929 A CN 105860929A CN 201610212902 A CN201610212902 A CN 201610212902A CN 105860929 A CN105860929 A CN 105860929A
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China
Prior art keywords
environment
epoxy resin
preparation
repair liquid
friendly high
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CN201610212902.0A
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CN105860929B (en
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卫晓利
张发兴
孙亚丽
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Sichuan University of Science and Engineering
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Sichuan University of Science and Engineering
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/12Materials for stopping leaks, e.g. in radiators, in tanks

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)

Abstract

The invention belongs to the technical field of preparation of chemical adhesives, and in particular relates to an environment-friendly efficient automatic-inflation tire repair fluid and a preparation method thereof. The environment-friendly efficient automatic-inflation tire repair fluid comprises the following raw materials in percentage by mass: 30-40% of modified waterborne polyurethane-epoxy resin emulsion, 8-10% of rubber powder, 1-2% of sawdust powder, 1-3% of ethylene glycol, 2-5% of polyvinyl alcohol, 0.5-1% of OP-10, 0.5-1% of lauryl sodium sulfate, 8-10% of water, and 28-49% of compressed nitrogen gas, based on 100% in total. The automatic-inflation tire repair fluid is green and environmentally-friendly, takes water-based materials as raw materials, and does not contain an organic solvent; moreover, the raw materials do not contain ammonia gas and do not contain a corrosive solvent, so that the emulsion is neutral, and hubs are not corroded; nitrogen gas which is safe, does not burn and does not explode is adopted, and the atmosphere is not polluted due to the fact that Freon is not contained; and the high-cohesiveness modified waterborne polyurethane-epoxy resin emulsion is used as a film-forming substance, so that the use time of the tire is greatly prolonged.

Description

A kind of environment-friendly high-efficiency Automatic-inflating tyre repair liquid and preparation method thereof
Technical field
The invention belongs to chemical adhesive preparing technical field, be specially a kind of environment-friendly high-efficiency Automatic-inflating tyre repair liquid and Preparation method.
Background technology
At present, along with rapid economic development, the automobile pollution of China has broken through 100,000,000.
Automobile greatly facilitates the life of people.But, work as automotive tire burst, around there is no again car repair shop Time, changing tire is the pretty troublesome and laborious thing of part.There are many Automatic-inflating tyre repair liquids at present, but generally existed Organic solvent, some contains the Freon gas forbidden already, and some has the strongest corrosivity to wheel hub, in a lot of tyre repairing fluids Adhesive ingredients adhesion strength is low, and tyre surface adhesion is more weak, and after tire patching, universal durability is not all right, within have more than is needed several hours, just goes out The phenomenon the most slowly leaked.In a word, a lot of tire patchings the most on the market are universal not environmentally for night, corrode wheel hub, and adhesion is weak, durable Property difference shortcoming.
Summary of the invention
The present invention is just for above technical problem, it is provided that a kind of environmental protection, the environmental protection that efficient, adhesion is strong, persistency is good Efficiently Automatic-inflating tyre repair liquid.
Another object of the present invention is to provide the preparation of a kind of environment-friendly high-efficiency Automatic-inflating tyre repair liquid of above-mentioned record Method.
The concrete technical scheme of the present invention is as follows:
A kind of environment-friendly high-efficiency Automatic-inflating tyre repair liquid, including the raw material of following weight/mass percentage composition:
Gross mass percentage composition sum is 100%.
As preferably, environment-friendly high-efficiency Automatic-inflating tyre repair liquid includes the raw material of following weight/mass percentage composition:
Solid wt in described modified aqueous polyurethane-epoxy resin latex is 35%.
The preparation method of environment-friendly high-efficiency Automatic-inflating tyre repair liquid comprises the following steps:
Weigh above each raw material in above ratio, then by uniform for raw material stirring tinning gland, be filled with nitrogen and be i.e. prepared into Environment-friendly high-efficiency Automatic-inflating tyre repair liquid.
Described modified aqueous polyurethane-epoxy resin latex, is the aqueous breast prepared by polyurethane and epoxy acrylic Liquid.There is after this emulsion film forming splendid adhesion and hot-air aging resistance.The adhesion of its excellence combines sawdust and rubber powder The filling effect of end particle, can make to be filled at tyre damage uniform, closely knit, it is ensured that tire is air tight for half a year.Described changes Property aqueous polyurethane-epoxy resin latex preparation method be divided into two steps: first 20g epoxy resin E-44 will add 10g propylene Acid, adds tertiary ammonia catalyst n-N dimethyl aniline 0.5g, and at 110 DEG C, stirring reaction 2h, gets only epoxy acrylic resin; Then in epoxy acrylic resin, add 20gTDI, 10g PTMEG PPG400, react 3h at 80 DEG C, add hydrophilic expansion Chain agent DMPA1-2g, after reaction 1h, adds 60g water, high-speed stirred emulsifying, i.e. prepares modified aqueous polyurethane-epoxy resin Emulsion.The raw material pointed out in the application is commercially available prod, rubber powder and sawdust powder and was generally selected the powder of 20 mesh sieves.
The positive effect of the present invention is embodied in:
(1), environmental protection, raw material is all water-based material, without organic solvent.
(2), raw material without ammonia, without aggressive solvent, emulsion is neutrality, does not corrode wheel hub.
(3), using nitrogen, secure and non-combustible burns and does not explodes, without freon, and not atmosphere pollution.
(4), use the modified aqueous polyurethane-epoxy resin latex of high-adhesion as film forming matter, extend greatly Use time of tire.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with detailed description of the invention pair The present invention is described in further detail, but this should not being interpreted as, the scope of the above-mentioned theme of the present invention is only limitted to following enforcement Example.
Embodiment 1:
A kind of environment-friendly high-efficiency Automatic-inflating tyre repair liquid, including the raw material of following weight/mass percentage composition:
The step that is embodied as of this environment-friendly high-efficiency Automatic-inflating tyre repair liquid is:
Being configured by mass percentage by above raw material, stir tinning gland, is filled with nitrogen.Embodiment 2:
A kind of environment-friendly high-efficiency Automatic-inflating tyre repair liquid, including the raw material of following weight/mass percentage composition:
Preparation method is with embodiment 1.
Embodiment 3:
A kind of environment-friendly high-efficiency Automatic-inflating tyre repair liquid, including the raw material of following weight/mass percentage composition:
Preparation method is with example 1.
Based on embodiment 1, all parameters are all consistent with embodiment 1 with step, change " the poly-ammonia of modified water-soluble Ester-epoxy resin latex ", rubber powder, the addition of sawdust powder, measure the durability of this tyre repairing fluid.Design parameter such as following table institute Show:
The impact on the durability of this tyre repairing fluid of the table 1 main component addition
As can be seen from the above table, in terms of weight/mass percentage composition, only when " modified aqueous polyurethane-epoxy resin latex " Addition is 30-40%, the addition 8%-10% of rubber powder, when the addition of sawdust powder is 1-2%, this inflating and tire-patching liquid Performance is best.

Claims (5)

1. an environment-friendly high-efficiency Automatic-inflating tyre repair liquid, it is characterised in that include the raw material of following weight/mass percentage composition:
Modified aqueous polyurethane-epoxy resin latex 30-40%
Rubber powder 8-10%
Sawdust powder 1-2%
Ethylene glycol 1-3%
Polyvinyl alcohol 2-5%
OP-10 0.5-1%
Sodium lauryl sulphate 0.5-1%
Water 8-10%
Compressed nitrogen 28-49%,
Gross mass percentage composition sum is 100%.
Environment-friendly high-efficiency Automatic-inflating tyre repair liquid the most according to claim 1, it is characterised in that include that following percent mass contains The raw material of amount:
Modified aqueous polyurethane-epoxy resin latex 30%
Rubber powder 8%
Sawdust powder 1%
Ethylene glycol 1%
Polyvinyl alcohol 2%
OP-10 0.5%
Sodium lauryl sulphate 0.5%
Water 8%
Compressed nitrogen 49%.
3. according to environment-friendly high-efficiency Automatic-inflating tyre repair liquid described in claim 1 or claim 2, it is characterised in that: described modification Solid content wt in aqueous polyurethane-epoxy resin latex is 35%.
4. according to the preparation method of environment-friendly high-efficiency Automatic-inflating tyre repair liquid described in claim 1 or claim 2, it is characterised in that Comprise the following steps:
Weigh each raw material in above ratio, then by uniform for raw material stirring tinning gland, be filled with nitrogen and be i.e. prepared into environment-friendly high-efficiency Automatic-inflating tyre repair liquid.
5., according to the preparation method of environment-friendly high-efficiency Automatic-inflating tyre repair liquid described in claim 1 or claim 2, its feature exists In: described modified aqueous polyurethane-epoxy resin latex preparation method is divided into two steps: first by 20g epoxy resin E-44 Adding 10g acrylic acid, add tertiary ammonia catalyst n-N dimethyl aniline 0.5g, at 110 DEG C, stirring reaction 2h, prepares epoxy Acrylic resin;Then in epoxy acrylic resin, add 20gTDI, 10g PTMEG PPG400, react 3h at 80 DEG C, then Adding hydrophilic chain extender DMPA1-2g, after reaction 1h, add 60g water, with agitator, high-speed stirring mixes emulsion form and prepares modification Aqueous polyurethane-epoxy resin latex.
CN201610212902.0A 2016-04-07 2016-04-07 A kind of environment-friendly high-efficiency Automatic-inflating tyre repair liquid and preparation method thereof Active CN105860929B (en)

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CN201610212902.0A CN105860929B (en) 2016-04-07 2016-04-07 A kind of environment-friendly high-efficiency Automatic-inflating tyre repair liquid and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883790A (en) * 2017-04-20 2017-06-23 深圳市爱动科技有限公司 A kind of emergency repair of tire liquid and preparation method thereof
CN107201209A (en) * 2017-05-14 2017-09-26 谢新昇 A kind of preparation method of Automatic-inflating tyre repair liquid
CN111533939A (en) * 2020-05-28 2020-08-14 无锡安睿驰科技有限公司 Self-healing safety tire

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1062363A (en) * 1990-12-11 1992-07-01 王海峰 Efficacious liquid for automatically repairing inner tube of tyre
CN1369533A (en) * 2001-04-25 2002-09-18 孔繁清 Antiexplosion prick-resisting adhesive for tyre and its preparing process
CN1962803A (en) * 2006-11-21 2007-05-16 崔集 Self-sealing agent for vehicular tyre
CN102070998A (en) * 2010-12-14 2011-05-25 浙江工业大学 Automatic inflation tyre-repairing solution

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1062363A (en) * 1990-12-11 1992-07-01 王海峰 Efficacious liquid for automatically repairing inner tube of tyre
CN1369533A (en) * 2001-04-25 2002-09-18 孔繁清 Antiexplosion prick-resisting adhesive for tyre and its preparing process
CN1962803A (en) * 2006-11-21 2007-05-16 崔集 Self-sealing agent for vehicular tyre
CN102070998A (en) * 2010-12-14 2011-05-25 浙江工业大学 Automatic inflation tyre-repairing solution

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
M.A.约翰逊: "《气雾剂手册:配方·技术·市场》", 31 March 2004 *
刘春华,等: "环氧树脂改性水性聚氨酯-丙烯酸酯的初步研究", 《聚氨酯工业》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883790A (en) * 2017-04-20 2017-06-23 深圳市爱动科技有限公司 A kind of emergency repair of tire liquid and preparation method thereof
CN107201209A (en) * 2017-05-14 2017-09-26 谢新昇 A kind of preparation method of Automatic-inflating tyre repair liquid
CN111533939A (en) * 2020-05-28 2020-08-14 无锡安睿驰科技有限公司 Self-healing safety tire

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