CN102443337A - Special high-performance nanocomposite epoxy coating for ships and its preparation method - Google Patents
Special high-performance nanocomposite epoxy coating for ships and its preparation method Download PDFInfo
- Publication number
- CN102443337A CN102443337A CN2010105051919A CN201010505191A CN102443337A CN 102443337 A CN102443337 A CN 102443337A CN 2010105051919 A CN2010105051919 A CN 2010105051919A CN 201010505191 A CN201010505191 A CN 201010505191A CN 102443337 A CN102443337 A CN 102443337A
- Authority
- CN
- China
- Prior art keywords
- component
- epoxy resin
- pigment
- epoxy coating
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
Relating to the coating field, the invention specifically relates to a special high-performance nanocomposite epoxy coating for ship and its preparation method. The special high-performance nanocomposite epoxy coating for ships comprises the following two components that: by weight parts, component one consists of epoxy resin, petroleum resin, a rust resisting pigment, a coloring pigment, an extender pigment, an additive, and a solvent, and component two consists of a solvent and a curing agent, with the component one and the component two in a weight ratio of 100:5-100:100. The preparation method includes: adding the component one into the component two, stirring them uniformly, and applying the mixture on a substrate, conducting curing at a temperature of 10DEGC-120DEG C for 5min-15d, thus forming a special high-performance nanocomposite epoxy coating for ships. The high-performance ballast tank nanocomposite epoxy coating of the invention has good corrosion resistance and impermeability, and can satisfy the requirements of new national standards for ship ballast tank paint.
Description
Technical field
The present invention relates to paint field, be specially a kind of high-performance ship special-purpose nanometer composite epoxy coating and preparation method thereof.
Background technology
Ballast tank of ship is used for storing or the emptying seawater for a long time, to keep hull balance.Like this, ballast tank stands the infiltration of seawater and the test of alternation of wetting and drying throughout the year, so ballast tank is the most serious position of corrosion on the hull, has become the maximum potential safety hazard of boats and ships.
In November, 2004; Set up joint working group by the Baltic Sea and International Maritime board of management (BINCO), International Association of Classification Societies's shipping tissues such as (IA Cs) according to the requirement of MSC77 and DE47, on the basis of the guide of A.798 (19) resolution issue and TSCF 15 standards of oil carrier structure cooperation forum (The Tanker Structure Co-operative Forum) (being called for short TSCF), drafted " ballast tank of ship supercoat standard of performance " (PerformanceStandard for Protective Coatings for Dedicated seawater ballast tanks in all types of shipsand double side skin spaces of bulk carriers) (abbreviation PSPC) draft.On December 8th, 2006, in the MSC82 of IMO conference, formally passed through ballast tank ballast tank of ship supercoat standard of performance, and the boats and ships that require on July 1st, 2008 to sign a contract later on begin to execute this standard.China has also put into effect new national standard " ballast tank of ship lacquer (GB/T6823-2008) " in time to PSPC.
Chinese patent (publication number CN101134867) discloses a kind of shipping ballast cabin coating composition.Its adopts special fluid petroleum resin to epoxy resin modification, and utilizes the collaborative solidification of solidifying agent to obtain the high-performance epoxy coating composition of high comprehensive performance, that do not contain tar, as to apply to load seawater corrosive environments such as ballast tank of ship.Shipping ballast cabin coating before 2008 all must be through the strictness check of the new national standard of putting into effect.Study novel shipping ballast cabin coating the coating investigator is had higher requirement, the work of this respect demands urgently carrying out.
Summary of the invention
The invention provides a kind of high-performance ship special-purpose nanometer composite epoxy coating that satisfies up-to-date national standard " ballast tank of ship lacquer (GB/T6823-2008) " and preparation method thereof.The high-performance ship special-purpose nanometer composite epoxy coating that is obtained has excellent storage stability, is difficult for sinking to the bottom.
Technical scheme of the present invention is:
A kind of high-performance ship special-purpose nanometer composite epoxy coating, described high-performance ship special-purpose nanometer composite epoxy coating is made up of following two components;
Count by weight, component one comprises following component and content:
10～60 parts of epoxy resin;
1～15 part of petroleum resin;
5～65 parts of rust-stabilising pigments;
1～30 part of tinting pigment;
1～50 part of pigment extender;
0.5～5 part of auxiliary agent;
0.5～70 part of solvent;
Count by weight, component two comprises following component and content:
0～80 part of solvent;
20～100 parts in solidifying agent;
Component one is (100: 5)～(100: 100) with the weight proportion of component two.
Described epoxy resin is bisphenol A type epoxy resin; Bisphenol f type epoxy resin; Dihydroxyphenyl propane D type epoxy resin; Bisphenol-s epoxy resin; The methylol bisphenol A type epoxy resin; Bisphenol-A epoxy resin; Organic-silicon-modified bisphenol A type epoxy resin; Organic titanium modified bisphenol A type epoxy resin; Modified nylon epoxy resin; Fluorinated epoxy resin; Line style phenol formaldehyde (PF) epoxy resin; Ortho-cresol formaldehyde epoxy resin; Aliphatic glycidyl ether epoxy resin; Glycidyl ester type epoxy resin; One of glycidyl amine type epoxy resin or composite.
Described petroleum resin refer to one of C5, C9 petroleum resin, coumarone indene resin or composite.
Described solidifying agent is polymeric amide, modified polyamine or phenol aldehyde modified amine.At present, commercially available polyamide curing agent, as: YD-115, YD-127, YD-128, V-115, V-125 or V-140 etc.Phenol aldehyde modified amine, as: JA-1,701,702,703,703-A T31 etc.The modified multicomponent amine hardener is like TY-200, TY-203, TY-300, TY-3051, TY-650, TY-651, TY-600, TG-011, AH-1, AH-2 or AH-3 etc.
Described rust-stabilising pigment is the mixture of nanometer iron cpd, and its particulate forms the coacervate of active nano particle, and median size is less than 300nm.Count by weight, the chemical constitution of its mixture is Ca:＜15 (being generally 0～11); Fe:30-55; Mg:＜7 (being generally 1～5); Mn:＜7 (being generally 1～5); Zn:8-35.As: Ferrinov-100, Ferrinov-110, Ferrinov-500 or the Ferrinov-501 that can adopt Canadian ferrinov pigment company.
Among the present invention, " mixture of nanometer iron cpd " implication is this mixture by ferrite, magnetite, franklinite, magnesioferrite is that two or more of main body are formed, and its primary partical is in the nanoscale scope.
Described tinting pigment is a kind of or composite of white titanium pigment, zinc oxide, lithopone, stibium trioxide, carbon black, yellow oxide of iron, red iron oxide, barba hispanica, ultramarine, red, toluidine red, pthalocyanine blue, phthalocyanine green etc.
Described pigment extender is a kind of or composite of ground barium sulfate, process white, GL ground limestone, precipitated calcium carbonate, talcum powder, china clay, mica powder etc.
Described auxiliary agent is coating dispersion agent, skimmer, flow agent and/or an anti-settling agent commonly used.Dispersion agent, as: the Anti-Terra-P of BYK company, Anti-Terra-204 or Disperbyk-163; The EFKA-44 or the EFKA-47 of Holland EFKA company; 904 or 904S of the Taiwan modest company of moral.Skimmer, as: the Perenol E1 of Henkel company, Perenol F40, Perenol S4, Perenol S400 or Perenol S43; 5500 or 6500 of the Taiwan modest company of moral; The Tego Airex930 of Tego company or Tego Flow300; Flow agent, as: the BYK-VP-354 of BYK company, 3609 or 3529; The Tego Flow300 of Tego company, Tego FlowZFS460 or Tego Glide 100.Anti-settling agent has two types, and one type is the THIXCIN derivatives class, as: the Rilanit Special Micro of Henkel company or Rilanit HT Extra; Another kind of is the organic bentonite class, as: the BENTONE 27 of U.S. NL company or BENTONE 34.
The preparation method of described high-performance ship special-purpose nanometer composite epoxy coating, undertaken by following order and step:
1) preparation method of component one: add solvent, epoxy resin, petroleum resin in the reaction kettle, 200-500rpm stirred 10-20 minute; Add auxiliary agent again, 200-500rpm stirred 5-10 minute, added rust-stabilising pigment, tinting pigment, pigment extender at last, and 500-1500rpm stirred 20-40 minute, and discharging is filtered, packing;
2) preparation method of component two: add solvent, solidifying agent in the reaction kettle, 200-500rpm stirred 10-20 minute, and discharging is filtered, packing.
The preparation method of described high-performance ship special-purpose nanometer composite epoxy coating; When component one adds component two, stir, construct on base material; Solidify 5 minutes～15 days (general 25 ℃ time be 5～7 days) at 10 ℃～120 ℃, form high-performance ship special-purpose nanometer composite epoxy coating.
Among the present invention, solvent is a solvent commonly used in the preparation epoxy coating, like one of toluene, YLENE, propyl carbinol or pimelinketone etc. or composite.
Advantage of the present invention is following:
1, high-performance ballast tank nano composite epoxy coating of the present invention is made up of the mixture of epoxy resin, nanometer iron cpd, ambient cure agent etc.; This coating has remarkable Corrosion Protection; Coating has solidity to corrosion and permeability resistance preferably, satisfies new ballast tank of ship lacquer request of national standard.
2, high-performance ballast tank nano composite epoxy coating of the present invention poisonous rust-stabilising pigment such as leaded chromium not is an environment-friendly type coating.
3, the used rust-stabilising pigment of high-performance ballast tank nano composite epoxy coating of the present invention is compared with poisonous rust-stabilising pigments such as chromium, and price is low.Therefore, this coating has the advantages that cost is low, market competitiveness is strong.
Embodiment
The evaluation method of high-performance ship special-purpose nanometer composite epoxy coating of the present invention is following:
(1) sample preparation methods
Use Q235 hot rolling normal carbon steel plate as base material; Every size of sample is 200mm * 400mm * 3mm; Carry out sand blasted surface and handle, the spraying inorganic primer for zinc silicate shop, the test piece of application shop primer should be placed in the open-air atmosphere weather aging 2 months.Adopt low-pressure water to clean or other gentle methods, clean is carried out on the test piece surface after aging, be placed in the air seasoning environment dry then.On the test piece of doing the open-air atmosphere weather aging, adopt spraying method to carry out the ballast tank application.The drying conditions of various coating is 25 ± 2 ℃ of dryings 7 days.The build of various coatings is at 320 ± 20 μ m.
(2) simulation ballast tank condition test
TP and evaluation method are with reference to national standard " GB/T6823-2008 ballast tank of ship lacquer ".Simulate the condition of true ballast tank, a testing campaign is two weeks to load artificial seawater, week zero load.Seawater temperature remains on (35 ± 2) ℃.At simulation ballast tank condition test device---in the ballast tank coating test wave cabin, the situation of simulation upperdeck, test plate (panel) back (50 ± 2) ℃/12h adds (20 ± 2) ℃/cooling 12h circulation; Test piece is periodic with natural or artificial seawater spilling, simulation boats and ships pitching and rolling motion, and spilling is spaced apart 3s or shorter; The line coating of scratching to ground, that traverse width is arranged on the plate.
Comparative example 1
The preparation method of component one: join YLENE 40kg, E51 epoxy resin 15kg, C5 petroleum resin 2kg in the reaction kettle, 300rpm (rev/min) stirred 15 minutes; Add Anti-Terra-P dispersion agent 0.2kg, Perenol E1 skimmer 0.1kg, Tego Flow300 flow agent 0.3kg, Rilanit Special Micro anti-settling agent 0.4kg again; 400rpm stirred 10 minutes, added white titanium pigment 2kg (granularity is 325 orders), talcum powder 40kg (granularity is 500 orders) at last, and 1000rpm stirred 30 minutes; Discharging; Filter, packing obtains component one.
The preparation method of component two: add solvent toluene 30kg, propyl carbinol 40kg, TY-651 polyamide curing agent 30kg in the reaction kettle, 200-500rpm stirred 10 minutes, and discharging is filtered, packing.
According to weight ratio, component one: component two=100: 80, when in component one, adding component two, stir, spraying is dry.
Comparative example 2
The preparation method of component one: join YLENE 15kg, E51 epoxy resin 30kg, C9 petroleum resin 7kg in the reaction kettle, 300rpm stirred 15 minutes; Add EFKA-44 dispersion agent 0.5kg, Perenol S43 skimmer 0.8kg, Tego Glide 100 flow agent 0.7kg, BENTONE 34 anti-settling agent 1kg again; 400rpm stirred 10 minutes, added white titanium pigment 25kg (granularity is 325 orders), talcum powder 20kg (granularity is 800 orders) at last, and 1000rpm stirred 30 minutes; Discharging; Filter, packing obtains component one.
The preparation method of component two: add solvent toluene 25kg, propyl carbinol 25kg, TY-651 polyamide curing agent 50kg in the reaction kettle, 200-500rpm stirred 15 minutes, and discharging is filtered, packing.
According to weight ratio, component one: component two=100: 50, when in component one, adding component two, stir, spraying is dry.
Comparative example 3
The preparation method of component one: join YLENE 17kg, E51 epoxy resin 50kg, coumarone petroleum resin 12kg in the reaction kettle, 300rpm stirred 15 minutes; Add Disperbyk-163 dispersion agent 0.3kg, PerenolS400 skimmer 1kg, Tego Flow ZFS460 flow agent 1kg, BENTONE 27 anti-settling agent 1.7kg again; 400rpm stirred 10 minutes, added white titanium pigment 15kg (granularity is 325 orders), talcum powder 2kg (granularity is 1000 orders) at last, and 1000rpm stirred 30 minutes; Discharging; Filter, packing obtains component one.
The preparation method of component two: add solvent toluene 5kg, pimelinketone 5kg, TY-200 polyamide curing agent 90kg in the reaction kettle, 200-500rpm stirred 20 minutes, and discharging is filtered, packing.
According to weight ratio, component one: component two=100: 20, when in component one, adding component two, stir, spraying is dry.
Embodiment 1
The preparation method of component one: join YLENE 40kg, E51 epoxy resin 15kg, C5 petroleum resin 2kg in the reaction kettle, 300rpm stirred 15 minutes; Add Anti-Terra-P dispersion agent 0.2kg, PerenolE1 skimmer 0.1kg, Tego Flow300 flow agent 0.3kg, Rilanit Special Micro anti-settling agent 0.4kg again; 400rpm stirred 10 minutes, added Ferrinov-100 rust-stabilising pigment 38kg, white titanium pigment 2kg (granularity is 325 orders), talcum powder 2kg (granularity is 500 orders) at last, and 1000rpm stirred 30 minutes; Discharging; Filter, packing obtains component one.
The preparation method of component two: add solvent toluene 30kg, propyl carbinol 40kg, TY-651 polyamide curing agent 30kg in the reaction kettle, 200-500rpm stirred 10 minutes, and discharging is filtered, packing.
According to weight ratio, component one: component two=100: 80, when in component one, adding component two, stir, spraying is dry.
Embodiment 2
The preparation method of component one: join YLENE 15kg, E51 epoxy resin 30kg, C9 petroleum resin 7kg in the reaction kettle, 300rpm stirred 15 minutes; Add EFKA-44 dispersion agent 0.5kg, Perenol S43 skimmer 0.8kg, Tego Glide 100 flow agent 0.7kg, BENTONE 34 anti-settling agent 1kg again; 400rpm stirred 10 minutes, added Ferrinov-500 rust-stabilising pigment 18kg, white titanium pigment 25kg (granularity is 325 orders), talcum powder 2kg (granularity is 800 orders) at last, and 1000rpm stirred 30 minutes; Discharging; Filter, packing obtains component one.
The preparation method of component two: add solvent toluene 25kg, propyl carbinol 25kg, TY-651 polyamide curing agent 50kg in the reaction kettle, 200-500rpm stirred 15 minutes, and discharging is filtered, packing.
According to weight ratio, component one: component two=100: 50, when in component one, adding component two, stir, spraying is dry.
Embodiment 3
The preparation method of component one: join YLENE 17kg, E51 epoxy resin 50kg, coumarone petroleum resin 12kg in the reaction kettle, 300rpm stirred 15 minutes; Add Disperbyk-163 dispersion agent 0.3kg, PerenolS400 skimmer 1kg, Tego Flow ZFS460 flow agent 1kg, BENTONE 27 anti-settling agent 1.7kg again; 400rpm stirred 10 minutes, added Ferrinov-501 rust-stabilising pigment 11kg, white titanium pigment 5kg (granularity is 325 orders), talcum powder 1kg (granularity is 1000 orders) at last, and 1000rpm stirred 30 minutes; Discharging; Filter, packing obtains component one.
The preparation method of component two: add solvent toluene 5kg, pimelinketone 5kg, TY-200 polyamide curing agent 90kg in the reaction kettle, 200-500rpm stirred 20 minutes, and discharging is filtered, packing.
According to weight ratio, component one: component two=100: 20, when in component one, adding component two, stir, spraying is dry.
The result of the simulation ballast tank condition test of table 1 ballast tank of ship coating
Can be found out that by table 1 through 180 days test, the foaming of embodiment 1,2,3 and the grading of corrosion all reached best level, and free of pinholes, near the overlooking cut spread width and also is lower than 8mm, and sticking power is greater than 3.5MPa, and force of cohesion is greater than 3.0MPa.1,2,3 of comparative examples do not reach the index request of national standard " GB/T6823-2008 ballast tank of ship lacquer ".
Claims (7)
1. a high-performance ship special-purpose nanometer composite epoxy coating is characterized in that, described high-performance ship special-purpose nanometer composite epoxy coating is made up of following two components;
Count by weight, component one comprises following component and content:
10～60 parts of epoxy resin;
1～15 part of petroleum resin;
5～65 parts of rust-stabilising pigments;
1～30 part of tinting pigment;
1～50 part of pigment extender;
0.5～5 part of auxiliary agent;
0.5～70 part of solvent;
Count by weight, component two comprises following component and content:
0～80 part of solvent;
20～100 parts in solidifying agent;
Component one is 100: 5～100: 100 with the weight proportion of component two.
2. high-performance ship special-purpose nanometer composite epoxy coating according to claim 1 is characterized in that: epoxy resin is one of bisphenol A type epoxy resin, bisphenol f type epoxy resin, dihydroxyphenyl propane D type epoxy resin, bisphenol-s epoxy resin, methylol bisphenol A type epoxy resin, bisphenol-A epoxy resin, organic-silicon-modified bisphenol A type epoxy resin, organic titanium modified bisphenol A type epoxy resin, modified nylon epoxy resin, fluorinated epoxy resin, line style phenol formaldehyde (PF) epoxy resin, ortho-cresol formaldehyde epoxy resin, aliphatic glycidyl ether epoxy resin, glycidyl ester type epoxy resin, glycidyl amine type epoxy resin or composite.
3. high-performance ship special-purpose nanometer composite epoxy coating according to claim 1; It is characterized in that: rust-stabilising pigment is the mixture of nanometer iron cpd; Its particulate forms the coacervate of active nano particle, and median size is counted less than 300nm by weight; The chemical constitution of its mixture is Ca:＜15; Fe:30-55; Mg:＜7; Mn:＜7; Zn:8-35.
4. high-performance ship special-purpose nanometer composite epoxy coating according to claim 1 is characterized in that: tinting pigment is a kind of or composite of white titanium pigment, zinc oxide, lithopone, stibium trioxide, carbon black, yellow oxide of iron, red iron oxide, barba hispanica, ultramarine, red, toluidine red, pthalocyanine blue, phthalocyanine green.
5. high-performance ship special-purpose nanometer composite epoxy coating according to claim 1 is characterized in that: pigment extender is a kind of or composite of ground barium sulfate, process white, GL ground limestone, precipitated calcium carbonate, talcum powder, china clay, mica powder.
6. the preparation method of high-performance ship special-purpose nanometer composite epoxy coating according to claim 1 is characterized in that, is undertaken by following order and step:
1) preparation method of component one: add solvent, epoxy resin, petroleum resin in the reaction kettle, 200-500rpm stirred 10-20 minute; Add auxiliary agent again, 200-500rpm stirred 5-10 minute, added rust-stabilising pigment, tinting pigment, pigment extender at last, and 500-1500rpm stirred 20-40 minute, and discharging is filtered, packing;
2) preparation method of component two: add solvent, solidifying agent in the reaction kettle, 200-500rpm stirred 10-20 minute, and discharging is filtered, packing.
7. the preparation method of high-performance ship special-purpose nanometer composite epoxy coating according to claim 6; It is characterized in that: when said component one adds component two; Stir; Construct on base material, solidified 5 minutes～15 days, form high-performance ship special-purpose nanometer composite epoxy coating at 10 ℃～120 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105051919A CN102443337A (en) | 2010-10-13 | 2010-10-13 | Special high-performance nanocomposite epoxy coating for ships and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105051919A CN102443337A (en) | 2010-10-13 | 2010-10-13 | Special high-performance nanocomposite epoxy coating for ships and its preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102443337A true CN102443337A (en) | 2012-05-09 |
Family
ID=46006286
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105051919A Pending CN102443337A (en) | 2010-10-13 | 2010-10-13 | Special high-performance nanocomposite epoxy coating for ships and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102443337A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103602210A (en) * | 2013-10-10 | 2014-02-26 | 安徽真信涂料有限公司 | Rust-resisting paint specially used for ship ballast water tanks and preparation method thereof |
| CN104059470A (en) * | 2014-06-26 | 2014-09-24 | 蓝星（成都）新材料有限公司 | Epoxy resin anti-rust paint and preparation method thereof |
| WO2015021921A1 (en) * | 2013-08-13 | 2015-02-19 | 厦门大学 | Environmentally friendly fluorosiloxane-containing heavy-duty epoxy resin coating and preparation method thereof |
| CN104559653A (en) * | 2013-10-29 | 2015-04-29 | 中国石油天然气集团公司 | Hydrogenated bisphenol A epoxy deck paint and preparation method thereof |
| CN107936759A (en) * | 2017-11-08 | 2018-04-20 | 北京碧海舟腐蚀防护工业股份有限公司 | Low surface treatment paint and its application |
| CN111172489A (en) * | 2019-12-18 | 2020-05-19 | 中海油常州涂料化工研究院有限公司 | Anti-corrosion method for metal coating of open-frame seawater vaporizer |
| CN111253832A (en) * | 2020-02-07 | 2020-06-09 | 华北水利水电大学 | Heavy-duty anticorrosive paint and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080196619A1 (en) * | 2005-06-17 | 2008-08-21 | Ferrinov Inc. | Anti-Corrosion Pigments Coming Form Dust Of An Electric Arc Furnace And Containing Sacrificial Calcum |
| CN101372600A (en) * | 2007-08-24 | 2009-02-25 | 上海开林造漆厂 | Double-component epoxide resin type anti-rust lacquer and preparation thereof |
-
2010
- 2010-10-13 CN CN2010105051919A patent/CN102443337A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080196619A1 (en) * | 2005-06-17 | 2008-08-21 | Ferrinov Inc. | Anti-Corrosion Pigments Coming Form Dust Of An Electric Arc Furnace And Containing Sacrificial Calcum |
| CN101372600A (en) * | 2007-08-24 | 2009-02-25 | 上海开林造漆厂 | Double-component epoxide resin type anti-rust lacquer and preparation thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015021921A1 (en) * | 2013-08-13 | 2015-02-19 | 厦门大学 | Environmentally friendly fluorosiloxane-containing heavy-duty epoxy resin coating and preparation method thereof |
| CN103602210A (en) * | 2013-10-10 | 2014-02-26 | 安徽真信涂料有限公司 | Rust-resisting paint specially used for ship ballast water tanks and preparation method thereof |
| CN103602210B (en) * | 2013-10-10 | 2016-03-23 | 安徽真信涂料有限公司 | A kind of rust-inhibiting paint being exclusively used in marine ballast water tank and preparation method thereof |
| CN104559653A (en) * | 2013-10-29 | 2015-04-29 | 中国石油天然气集团公司 | Hydrogenated bisphenol A epoxy deck paint and preparation method thereof |
| CN104059470A (en) * | 2014-06-26 | 2014-09-24 | 蓝星（成都）新材料有限公司 | Epoxy resin anti-rust paint and preparation method thereof |
| CN104059470B (en) * | 2014-06-26 | 2016-07-06 | 蓝星（成都）新材料有限公司 | A kind of Epoxy resin antirust paint and preparation method thereof |
| CN107936759A (en) * | 2017-11-08 | 2018-04-20 | 北京碧海舟腐蚀防护工业股份有限公司 | Low surface treatment paint and its application |
| CN111172489A (en) * | 2019-12-18 | 2020-05-19 | 中海油常州涂料化工研究院有限公司 | Anti-corrosion method for metal coating of open-frame seawater vaporizer |
| CN111253832A (en) * | 2020-02-07 | 2020-06-09 | 华北水利水电大学 | Heavy-duty anticorrosive paint and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102443337A (en) | Special high-performance nanocomposite epoxy coating for ships and its preparation method | |
| CN102352171B (en) | Novel environment-friendly coating with superhigh marine environment corrosion resistance and preparation method and application thereof | |
| CN101481576B (en) | Ultra-thick film solvent-free thermal spraying quick-drying heavy-duty anti-corrosive paint and preparation thereof | |
| CN105419564A (en) | Nano graphene oxide modified double-component aqueous epoxy anti-corrosion coating and preparation method thereof | |
| CN101824265A (en) | Low-surface treatment moisture cured heavy anti-corrosion coating | |
| CN101899256A (en) | Water-based transparent anticorrosive paint, preparation method and application method thereof | |
| CN102443339B (en) | Ultrahigh-hardness organic protection coating and preparation method thereof | |
| CN103342946A (en) | Epoxy antirust coating and preparation method thereof | |
| CN103834264A (en) | Aluminum oxide-containing polyaniline zinc powder flake epoxy heavy anti-corrosion coating and preparation method thereof | |
| CN107556886A (en) | A kind of graphite-epoxy alkene zinc powder coating | |
| CN1986711A (en) | Acid-proof wear-proof anticorrosive paint and its preparing method | |
| CN108165131A (en) | A kind of wheel shaft aqueous electrostatic epoxy anticorrosion primer and preparation method thereof | |
| CN105086770A (en) | Iron oxide red water-based epoxy rust-proof primer and preparing method thereof | |
| CN103333581B (en) | A kind of Nano cerium oxide/epoxy composite paint and preparation method thereof | |
| CN101255290B (en) | Marine reinforced concrete anticorrosion paint and preparation method thereof | |
| CN103214917B (en) | Marine corrosion-resistant epoxy aluminum-magnesium-nickel rear earth rich nanometer material and preparation method thereof | |
| CN101608089A (en) | Waterborne epoxy coating for non-bilged compartments | |
| CN101255291B (en) | Marine reinforced concrete anticorrosion paint and preparation method thereof | |
| CN105802448B (en) | A kind of water-based epoxy zinc rich primer of dual cure | |
| CN105038547A (en) | Preparation method of low-VOC (volatile organic compound) high-solid-content polyurea anticorrosive paint | |
| CN103254725A (en) | Ocean heavy anti-corrosion epoxy aluminum-nickel-rich nano-coating and preparation method thereof | |
| CN112457743A (en) | Water-based waterproof coating and preparation method thereof | |
| CN103965734B (en) | Coating composition for ballast tank of ship and preparation method of coating composition | |
| CN110527406A (en) | Graphene water-based anticorrosive paint and preparation method thereof | |
| CN103242737B (en) | Marine heavy anti-corrosion epoxy nano coating rich in aluminium, manganese and rare earth and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120509 |