CN109294396A - A kind of water-based epoxy zinc-rich primer - Google Patents

A kind of water-based epoxy zinc-rich primer Download PDF

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Publication number
CN109294396A
CN109294396A CN201811133447.0A CN201811133447A CN109294396A CN 109294396 A CN109294396 A CN 109294396A CN 201811133447 A CN201811133447 A CN 201811133447A CN 109294396 A CN109294396 A CN 109294396A
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CN
China
Prior art keywords
agent
parts
water
rich primer
based epoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811133447.0A
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Chinese (zh)
Inventor
赵惠清
赵惠红
李东海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Meishibang Paint and Chemicals Co Ltd
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Tianjin Meishibang Paint and Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Meishibang Paint and Chemicals Co Ltd filed Critical Tianjin Meishibang Paint and Chemicals Co Ltd
Priority to CN201811133447.0A priority Critical patent/CN109294396A/en
Publication of CN109294396A publication Critical patent/CN109294396A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/106Anti-corrosive paints containing metal dust containing Zn

Abstract

The invention provides a kind of water-based epoxy zinc-rich primer, including host agent and curing agent.The host agent includes following component according to parts by weight: 70-75 parts of zinc powder, coalescing agent 1 are 8.0-12.2 parts, anti-settling agent 1 is 0.6-1.0 parts, anti-settling agent 2 is 0.4-0.5 parts, 3.8-6.5 parts of amine epoxy hardener, 0.5-1.0 parts of dispersing agent, 0.1-0.4 parts of defoaming agent, 8.0-12.0 parts of filler.The curing agent includes following component according to parts by weight: 66.0-74.0 parts of epoxy emulsion, pH adjusting agent are 0.5-1.0 parts, coalescing agent 2 is 10.0-28.0 parts, 0.5-1.6 parts of anti-flash rusting agent, 7.4-11.0 parts of deionized water.The host agent and the quality proportioning of curing agent are 3:1.The invention has the advantages and positive effects of: there is excellent antiseptic property and adhesive force, easily construct, fast drying.

Description

A kind of water-based epoxy zinc-rich primer
Technical field
The invention is related to coating manufacturing field, and in particular to a kind of water-based epoxy zinc-rich primer.
Background technique
Currently, world's steel construction barracks, drilling machine, engineering truck machinery equipment and components, need about 400,000 tons of coating year, valence About 6,000,000,000 yuan of value.The steel construction barracks used in world wide, drilling machine, engineering truck machinery equipment and components coating are substantially For solvent based coating.Solvent based coating is in steel construction barracks, drilling machine, engineering truck machinery equipment and components anticorrosive construction Conventional variety that is extensive, applying for a long time is obtained, by testing adjustment repeatedly, outstanding workability and antiseptic property are in steel It is verified in structure barracks, drilling machine, engineering truck machinery equipment and components production and use process.Its routine is mating such as Under:
Outside barracks It is other
Solvent type epoxy zinc rich primer 50μm 50μm
Solvent type epoxy intermediate coat 150μm 80μm
Solvent borne polyurethane finishing coat 60μm 50μm
It is total 260μm 180μm
Due to the environmental problem and flammable security risk of solvent based coating pollution so that water paint development into Degree is accelerated.Water paint its with higher technology content, and will gradually be promoted in the industry.
Summary of the invention
The problem to be solved by the invention is to provide a kind of water-based epoxy zinc-rich primer, with excellent antiseptic property and Adhesive force is easily constructed, fast drying.
In order to solve the above technical problems, the invention the technical solution adopted is that: a kind of water-based epoxy zinc-rich primer, packet Include host agent and curing agent.
The host agent includes following component according to parts by weight: 70-75 parts of zinc powder, coalescing agent 1 are 8.0-12.2 parts, prevent Heavy agent 1 is 0.6-1.0 parts, anti-settling agent 2 is 0.4-0.5 parts, 3.8-6.5 parts of amine epoxy hardener, 0.5-1.0 parts of dispersing agent, 0.1-0.4 parts of defoaming agent, 8.0-12.0 parts of filler.The curing agent includes following component: epoxy emulsion according to parts by weight 66.0-74.0 parts, pH adjusting agent be 0.5-1.0 parts, coalescing agent 2 is 10.0-28.0 parts, 0.5-1.6 parts of anti-flash rusting agent, go from Sub- water 7.4-11.0 parts.The host agent and the quality proportioning of curing agent are 3:1.
Further, the anti-settling agent 1 is bentonite SD-2, and the anti-settling agent 2 is Wa Ke company gas silicon HDK-H-18.
Further, the dispersing agent is AFCONA-6226, and the defoaming agent is TEGO810.
Further, the pH adjusting agent is AMP-95.
Further, the coalescing agent 1 is alcohol ether analog assistant, and the coalescing agent 2 is alcohol analog assistant.
Further, the anti-flash rusting agent is the mixture of one or both of German Lodge difficult to understand company L8AF and L8NF.
Further, the thickener is BYK-425.
Further, the epoxy emulsion is the aqueous epoxy resins E-291 of South Asia chemistry.
Further, the filler is ferrophosphorus powder.
Further, the host agent is prepared by the method included the following steps: coalescing agent 1, stirring being first added according to quantity Under be slowly added to anti-settling agent 1 and anti-settling agent 2, high speed dispersion about 5min is added amine epoxy hardener, is then stirring to after uniform Lower addition dispersing agent and defoaming agent stirring 15min are mixed, filler is then added, is ground to fineness with sand milling less than 40 μ after being uniformly dispersed M is filtered to remove abrasive sand, and zinc powder is added, and adjusts solid point with coalescing agent 1 after being dispersed to fineness less than 40 μm, filters and packages As host agent.
The curing agent is prepared by the method included the following steps: according to quantity adjusting epoxy emulsion, deionized water, pH Agent, coalescing agent 2 and anti-flash rusting agent mixing are uniformly dispersed, and after adjusting solid part with water, filter and package as curing agent.
The invention has the advantages and positive effects of: coalescing agent have solubilization, can make epoxy resin and Curing agent further reacts, and improves crosslink density, is improved comprehensive performance, good water resistance and impact resistance, attachment Power is strong, while again more environmentally friendly.
Specific embodiment
Detailed description of specific embodiments of the invention is provided below.
Epoxy emulsion selects the lotion kind made of 1 type epoxy resin E-20, the specially water-base epoxy of South Asia chemistry Resin E-291, other raw material sources are as follows.
Embodiment 1:
A kind of water-based epoxy zinc-rich primer, including host agent and curing agent, the host agent includes such as the following group according to parts by weight Part: 70 parts of zinc powder, coalescing agent 1 are 9.0 parts, anti-settling agent 1 is 1.0 parts, anti-settling agent 2 is 0.5 part, amine epoxy hardener 6.5 Part, 1.0 parts of dispersing agent, 0.4 part of defoaming agent, 11.6 parts of filler.
The curing agent includes following component according to parts by weight: 66.0 parts of epoxy emulsion, 1.0 parts of pH adjusting agent, film forming Auxiliary agent 2 is 24.1 parts, 0.5 part of anti-flash rusting agent, 8.4 parts of deionized water.
Embodiment 2:
A kind of water-based epoxy zinc-rich primer, including host agent and curing agent, the host agent includes such as the following group according to parts by weight Part: 75 parts of zinc powder, coalescing agent 1 are 11.0 parts, anti-settling agent 1 is 0.6 part, anti-settling agent 2 is 0.4 part, amine epoxy hardener 3.8 Part, 0.5 part of dispersing agent, 0.1 part of defoaming agent, 8.6 parts of filler.
The curing agent includes following component according to parts by weight: 74.0 parts of epoxy emulsion, 0.8 part of pH adjusting agent, film forming Auxiliary agent 2 is 12.6 parts, 1.6 parts of anti-flash rusting agent, 11.0 parts of deionized water.
Embodiment 3:
A kind of water-based epoxy zinc-rich primer, including host agent and curing agent, the host agent includes such as the following group according to parts by weight Part: 72.9 parts of zinc powder, coalescing agent 1 are 12.2 parts, anti-settling agent 1 is 0.8 part, anti-settling agent 2 is 0.5 part, amine epoxy hardener 4.6 parts, 0.8 part of dispersing agent, 0.2 part of defoaming agent, 8.0 parts of filler.
The curing agent includes following component according to parts by weight: 68 parts of epoxy emulsion, 0.7 part of pH adjusting agent, film forming help Agent 2 is 22.9 parts, 1.0 parts of anti-flash rusting agent, 7.4 parts of deionized water.
Water-based epoxy zinc-rich primer is prepared by the method included the following steps in embodiment 1-3:
The host agent is prepared by the method included the following steps: coalescing agent 1 being first added according to quantity, slowly adds under stirring Enter anti-settling agent 1 and anti-settling agent 2, high speed dispersion about 5min is added amine epoxy hardener, is then added under stiring to after uniform Dispersing agent and defoaming agent stir 15min, and filler is then added, and are ground to fineness with sand milling less than 40 μm after being uniformly dispersed, cross and filter out Abrasive sand is gone, zinc powder is added, solid point is adjusted with coalescing agent 1 after being dispersed to fineness less than 40 μm, filters and packages as host agent.
The curing agent is prepared by the method included the following steps: according to quantity adjusting epoxy emulsion, deionized water, pH Agent, coalescing agent 2 and anti-flash rusting agent mixing are uniformly dispersed, and after adjusting solid part with water, filter and package as curing agent.
Product when in use, in the ratio that the host agent and the quality proportioning of curing agent are 3:1 then stir with paint It stirs evenly.Water-based epoxy zinc-rich primer of the invention is suitable for steel construction barracks, drilling machine, engineering truck machinery equipment and components, Deionized water can be added to dilute to adjust working viscosity, specific dilution ratio is 0-5% according to actual situations of construction.It is described It is best that 15 minutes construction effects are placed after host agent and the mixing of two component of curing agent.Form of construction work can be using spraying, roller coating and brush It applies.Form of construction work is different, and dilution ratio can be variant.
The performance test results of the made water-based epoxy zinc-rich primer of above embodiments are as follows.
As can be seen from the above table, water-based epoxy zinc-rich primer obtained can satisfy existing steel construction barracks, drilling machine, work Journey vehicle mechanical equipment and the requirement of components coating, good water resistance and impact resistance, adhesive force are strong.
The embodiment of the invention is described in detail above, but the content is only the preferable of the invention Embodiment should not be considered as limiting the scope of the invention.It is all according to equivalent change made by the invention range with Improve etc., it shall still fall within the scope of this patent.

Claims (10)

1. a kind of water-based epoxy zinc-rich primer, including host agent and curing agent, it is characterised in that:
The host agent includes following component according to parts by weight: 70-75 parts of zinc powder, coalescing agent 1 are 8.0-12.2 parts, anti-settling agent 1 is 0.6-1.0 parts, anti-settling agent 2 is 0.4-0.5 parts, 3.8-6.5 parts of amine epoxy hardener, 0.5-1.0 parts of dispersing agent, defoaming 0.1-0.4 parts of agent, 8.0-12.0 parts of filler;
The curing agent includes following component according to parts by weight: 66.0-74.0 parts of epoxy emulsion, 0.5-1.0 parts of pH adjusting agent, Coalescing agent 2 is 10.0-28.0 parts, 0.5-1.6 parts of anti-flash rusting agent, 7.4-11.0 parts of deionized water;
The host agent and the quality proportioning of curing agent are 3:1.
2. a kind of water-based epoxy zinc-rich primer according to claim 1, it is characterised in that: the anti-settling agent 1 is bentonite SD-2, the anti-settling agent 2 are Wa Ke company gas silicon HDK-H-18.
3. a kind of water-based epoxy zinc-rich primer according to claim 1, it is characterised in that: the dispersing agent is AFCONA- 6226, the defoaming agent is TEGO810.
4. a kind of water-based epoxy zinc-rich primer according to claim 1, it is characterised in that: the pH adjusting agent is AMP- 95。
5. a kind of water-based epoxy zinc-rich primer according to claim 1, it is characterised in that: the coalescing agent 1 is alcohol ether Analog assistant, the coalescing agent 2 are alcohol analog assistant.
6. a kind of water-based epoxy zinc-rich primer according to claim 1, it is characterised in that: the anti-flash rusting agent is Germany The mixture of one or both of Lodge company L8AF and L8NF difficult to understand.
7. a kind of water-based epoxy zinc-rich primer according to claim 1, it is characterised in that: the thickener is BYK-425.
8. a kind of water-based epoxy zinc-rich primer according to claim 1, it is characterised in that: the epoxy emulsion is South Asia Aqueous epoxy resins E-291.
9. a kind of water-based epoxy zinc-rich primer according to claim 1, it is characterised in that: the filler is ferrophosphorus powder.
10. a kind of water-based epoxy zinc-rich primer described in -9 any one according to claim 1, it is characterised in that:
The host agent is prepared by the method included the following steps: coalescing agent 1 being first added according to quantity, is slowly added to prevent under stirring Heavy agent 1 and anti-settling agent 2, high speed dispersion about 5min are added amine epoxy hardener, dispersion are then added under stiring to after uniform Agent and defoaming agent stir 15min, and filler is then added, and are ground to fineness with sand milling less than 40 μm after being uniformly dispersed, are filtered to remove and grind Zinc powder is added in frosted, adjusts solid point with coalescing agent 1 after being dispersed to fineness less than 40 μm, filters and packages as host agent;
The curing agent is prepared by the method included the following steps: according to quantity by epoxy emulsion, deionized water, multifunctional assistant Agent, coalescing agent 2 and anti-flash rusting agent mixing are uniformly dispersed, and after adjusting solid part with water, filter and package as curing agent.
CN201811133447.0A 2018-09-27 2018-09-27 A kind of water-based epoxy zinc-rich primer Pending CN109294396A (en)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110128917A (en) * 2019-06-14 2019-08-16 绵阳麦思威尔科技有限公司 Low-VOC aqueous epoxy zinc rich primer and preparation method thereof
CN110591505A (en) * 2019-09-26 2019-12-20 中国海洋石油集团有限公司 Thick-coating type water-based epoxy zinc-rich anticorrosive paint and preparation method thereof
CN110903737A (en) * 2019-11-29 2020-03-24 深圳市肯德高建材有限公司 Environment-friendly two-component water-based epoxy zinc-rich special coating composition and preparation method thereof
CN111763462A (en) * 2020-07-01 2020-10-13 深圳市澳卓建材有限公司 Environment-friendly coating

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102863874A (en) * 2012-09-27 2013-01-09 中远关西涂料化工(天津)有限公司 Water-base epoxy zinc-rich priming paint and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102863874A (en) * 2012-09-27 2013-01-09 中远关西涂料化工(天津)有限公司 Water-base epoxy zinc-rich priming paint and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110128917A (en) * 2019-06-14 2019-08-16 绵阳麦思威尔科技有限公司 Low-VOC aqueous epoxy zinc rich primer and preparation method thereof
CN110591505A (en) * 2019-09-26 2019-12-20 中国海洋石油集团有限公司 Thick-coating type water-based epoxy zinc-rich anticorrosive paint and preparation method thereof
CN110591505B (en) * 2019-09-26 2021-07-13 中国海洋石油集团有限公司 Thick-coating type water-based epoxy zinc-rich anticorrosive paint and preparation method thereof
CN110903737A (en) * 2019-11-29 2020-03-24 深圳市肯德高建材有限公司 Environment-friendly two-component water-based epoxy zinc-rich special coating composition and preparation method thereof
CN110903737B (en) * 2019-11-29 2021-06-25 深圳市肯德高建材有限公司 Environment-friendly two-component water-based epoxy zinc-rich special coating composition and preparation method thereof
CN111763462A (en) * 2020-07-01 2020-10-13 深圳市澳卓建材有限公司 Environment-friendly coating

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Application publication date: 20190201

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