CN105860740B - History old architecture survey waterproof insectproof material preparation and application method - Google Patents
History old architecture survey waterproof insectproof material preparation and application method Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention discloses a kind of history old architecture survey waterproof insectproof material preparation method, carries out as follows：Including preparing raw material, prepare refractory mineral cream, prepare fire resisting fat material, prepare mothproofing agent, it prepares vaseline mixture and sequentially adds hydrophober in vaseline mixture, coalescents, mothproofing agent and etc., the history old architecture survey waterproof insectproof material of preparation using the present invention has stronger fire resistance and preferable water proofing property, also have both mothproof effect simultaneously, and the good fluidity of coating, convenient for construction, it is coated in the beam of history ancient building with it, purlin, rafter, the service life and holding time of wood materials can effectively be extended after on the wooden structures such as column or on wood materials modelled after an antique, it constructs again after heating the protective materials of preparation when construction and is conducive to be promoted the mobility and permeability of protective materials, so that protective materials is penetrated into and forms certain thickness protective layer inside wood materials, be conducive to improve the fire protecting performance of wood materials.
Description
Technical field
The present invention relates to Techniques of Relics Protection fields, specifically design a kind of history old architecture survey waterproof insectproof material preparation
And application method.
Background technology
China is the ancient civilized country with more than 5000 years history, and ancestors leave thick and solid cultural heritage to us, wrap
It is innumerable to include ancient building, bamboo caving, woodcarving, mural painting, painting and calligraphy, sculpture, inscriptions on precipices, metal and ceramic etc., also constantly
Unearthed a large amount of historical relics are all the treasures of our people, these historical relics are not only the treasure and generation of Chinese people
The treasure of the boundary people has very high academic research, value of art appreciation, with the improvement of people's living standards, to text
The appreciation demand of object is also increasingly surging, but people also easily bring certain damage while appreciating historical relic to historical relic, special
It is not some ancient buildings, beam, purlin, column etc. are mostly wooden structures, have good burning and propagating flame performance, if occurring
Net fire effect is hardly imaginable；In addition there are some pseudo-classic architectures, a large amount of wooden structures are also used, to ensure these wooden materials
There is material preferable fire protecting performance often need to coat fire proofing material on its surface, but these fire proofing materials are only capable of playing certain resistance
Combustion acts on, and flameproof effect is bad while cannot have both the effect of waterproof.
Invention content
In order to solve the above technical problems, one of the objects of the present invention is to provide a kind of history old architecture survey waterproof materials
Preparation method, the outer surface that the material prepared with this method is coated in history ancient building or material modelled after an antique to be protected can be risen simultaneously
To fire prevention, waterproof and mothproof effect.
The second object of the present invention is：A kind of history old architecture survey waterproof material application method is provided, using the party
Method coats fire-proof and water-proof material, and fire-proof and water-proof insect prevention material has preferable permeability.
Technical solution is as follows：What an object of the present invention was realized in：
A kind of history old architecture survey waterproof insectproof material preparation method, key are to carry out according to the following steps：
Step (1) prepares raw material：Count by weight percentage, the refractory mineral matter of 6-10%, the bonding of 3-7% are weighed
Agent, the fire retardant fire-proof additive of 2-5%, the organic solvent of 12-15%, the coalescents of 2-5%, the hydrophober of 1-2%, 2-
4% diluent, the curing agent of 1-3%, the mothproofing agent of 3-6% and the fire retardant resin of surplus；
Step (2) prepares refractory mineral cream：Refractory mineral matter is pulverized and sieved, screenings is put into agitator tank and is added
The adhesive of half stirs evenly, and continues to stir to get refractory mineral cream after then adding fire retardant fire-proof additive；
Step (3)：Prepare fire resisting fat material：Be added in fire retardant resin after organic solvent and diluent be uniformly mixing to obtain it is resistance to
Fiery fat material；
Step (4)：Prepare mothproofing agent：Yellow cinnamon leaf, folium artemisiae argyi and burmann cinnamon leaf are pressed into 4-5:1-2:After the ratio mixing of 2-3, powder
It is broken, crushed material is put into reaction kettle and ethyl alcohol is added and is impregnated 5-10 hours, the amount of alcohol being added is yellow cinnamon leaf, folium artemisiae argyi and the moon
3-5 times of spiceleaf mixture weight；It, then will filter by the mixture filtering of yellow cinnamon leaf, folium artemisiae argyi, burmann cinnamon leaf and ethyl alcohol after immersion
Liquid is concentrated to give required mothproofing agent；
Step (5)：Refractory mineral cream and fire resisting fat material are put into blending tank together, remaining adhesive is added, and add
Thermal agitation obtains vaseline mixture in 3-6 hours；
Step (6)：It stirs evenly, adds after sequentially adding hydrophober, coalescents, mothproofing agent in vaseline mixture
Continue stirring 1-2 hours after curing agent.
The history old architecture survey waterproof insectproof material prepared using the technical program is with stronger fire resistance and preferably
Water proofing property, while also having both mothproof effect, and the good fluidity of coating, convenient for construction, history ancient building be coated in it
The wooden structures such as beam, purlin, rafter, column on or wood materials modelled after an antique on after when can effectively extend service life and the preservation of wood materials
Between.
As preferred：Count by weight percentage, the refractory mineral matter is by the quartz sand of 20-30%, the carbon of 15-30%
Sour calcium and the aluminium oxide of surplus composition.
Count by weight percentage, described adhesive is by the waterglass of 30-50% and the carboxymethyl cellulose group of 50-70%
At.
Count by weight percentage, the fire retardant fire-proof additive by the zinc borate of 20-35%, the antimony oxide of 6-12% and
The decabromodiphenyl oxide of surplus forms.
Count by weight percentage, the fire retardant resin is by the nitrile rubber of 10-20%, epoxy resin, the 5- of 5-25%
15% Vinylidene Chloride and the phenolic resin composition of surplus.
Count by weight percentage, the organic solvent is by the ethylene glycol ether of 14-25%, the ethyl acetate of 6-10%
And the tung oil composition of surplus.Dissolubility using this scheme solvent and other compositions is good, while the tung oil in solvent also has one
The effect of fixed waterproof, anti-corrosion and desinsection.
Above-mentioned coalescents are propandiol butyl ether, and the hydrophober is polysiloxanes powder；Count by weight percentage, institute
State butyl acetate of the diluent by 30-60%, the styrene of 8-15% and the isopropanol composition of surplus；By weight percentage
It calculates, the curing agent is made of the diethylenetriamine of the aminoethyl piperazine AE and 60-75% of 25-40%.It is advantageous using this scheme
In the mobility for improving protective materials, and protective materials obtained is not necessarily to hot setting, is very suitable for be heated at high temperature
Wooden ancient building.
The sieve mesh number being sieved described in step (2) is 100-150 mesh.Refractory mineral matter exquisiteness such as powder after sieving, has
It is uniformly mixed conducive to other materials.
Heating temperature described in step (5) is 60-90 DEG C.The mobility of fire resisting fat material can be improved in heating, reduces its viscosity,
Be conducive to fire resisting fat material and refractory mineral cream is uniformly mixed.
The second object of the present invention is to what is be achieved：A kind of history old architecture survey waterproof insectproof materials'use method,
Its key is：The protective materials prepared by history old architecture survey waterproof insectproof material preparation method is heated to 35-40 DEG C
It is coated in the outer surface of history ancient building to be protected or antique wood afterwards.Protective materials viscosity after being heated using the technical program
It reduces, convenient for construction, while its mobility and permeability are more preferable, can penetrate into and form certain thickness protection inside wood materials
Layer is conducive to the fire protecting performance for improving wood materials.
Advantageous effect：The history old architecture survey waterproof insectproof material of preparation using the present invention has stronger fire resistance
And preferable water proofing property, while mothproof effect is also had both, and the good fluidity of coating is coated in history convenient for construction with it
Service life and the guarantor of wood materials can effectively be extended after on the wooden structures such as beam, purlin, rafter, the column of ancient building or on wood materials modelled after an antique
Deposit the time, when construction will preparation protective materials heat after construct be conducive to be promoted the mobility and permeability of protective materials again,
So that protective materials is penetrated into and form certain thickness protective layer inside wood materials, is conducive to the fire protecting performance for improving wood materials.
Specific implementation mode
With reference to embodiment and test data, the invention will be further described.
A kind of embodiment 1, history old architecture survey waterproof insectproof material preparation method, carries out according to the following steps：
Step (1) prepares raw material：Count by weight percentage, 6% refractory mineral matter is weighed, 3% adhesive, 2%
Fire retardant fire-proof additive, 12% organic solvent, 2% coalescents, 1% hydrophober, 2% diluent, 1% consolidates
Agent, 3% mothproofing agent and 68% fire retardant resin；
Step (2) prepares refractory mineral cream：The crushing of refractory mineral matter is sieved with 100 mesh sieve, screenings is put into agitator tank
And the adhesive that half is added stirs evenly, and continues to stir to get refractory mineral after then adding fire retardant fire-proof additive
Cream；
Step (3)：Prepare fire resisting fat material：Be added in fire retardant resin after organic solvent and diluent be uniformly mixing to obtain it is resistance to
Fiery fat material；
Step (4)：Prepare mothproofing agent：Yellow cinnamon leaf, folium artemisiae argyi and burmann cinnamon leaf are pressed 4:1:After 2 ratio mixing, crush, by powder
In the input that minces reaction kettle and ethyl alcohol immersion 5 hours is added, the amount of alcohol being added is yellow cinnamon leaf, folium artemisiae argyi and burmann cinnamon leaf mixture
3 times of weight；By the mixture filtering of yellow cinnamon leaf, folium artemisiae argyi, burmann cinnamon leaf and ethyl alcohol after immersion, institute then is arrived into filtrate concentration
The mothproofing agent needed；
Step (5)：Refractory mineral cream and fire resisting fat material are put into blending tank together, remaining adhesive is added, and add
Heat to 60 DEG C of stirrings obtain vaseline mixture in 3 hours；
Step (6)：It stirs evenly, adds after sequentially adding hydrophober, coalescents, mothproofing agent in vaseline mixture
Continue stirring 1 hour after curing agent.
Count by weight percentage, the refractory mineral matter is by 20% quartz sand, 15% calcium carbonate and 65% oxidation
Aluminium forms, and described adhesive is made of 30% waterglass and 70% carboxymethyl cellulose, the fire retardant fire-proof additive by
20% zinc borate, 6% antimony oxide and 74% decabromodiphenyl oxide composition, the fire retardant resin by 10% nitrile rubber, 5%
Epoxy resin, 5% Vinylidene Chloride and 80% phenolic resin composition, the organic solvent by 14% ethylene glycol ether,
6% ethyl acetate and 80% tung oil composition, the diluent is by 30% butyl acetate, 8% styrene and 62%
Isopropanol forms, and the curing agent is made of the diethylenetriamine of 25% aminoethyl piperazine AE and 75%, the coalescents
For propandiol butyl ether, the hydrophober is polysiloxanes powder.
A kind of embodiment 2, history old architecture survey waterproof insectproof material preparation method, carries out according to the following steps：
Step (1) prepares raw material：Count by weight percentage, 10% refractory mineral matter is weighed, 7% adhesive, 5%
Fire retardant fire-proof additive, 15% organic solvent, 5% coalescents, 2% hydrophober, 4% diluent, 3% solidification
Agent, 6% mothproofing agent and 43% fire retardant resin；
Step (2) prepares refractory mineral cream：Refractory mineral matter be crushed into 150 mesh sieve, screenings is put into agitator tank
And the adhesive that half is added stirs evenly, and continues to stir to get refractory mineral after then adding fire retardant fire-proof additive
Cream；
Step (3)：Prepare fire resisting fat material：Be added in fire retardant resin after organic solvent and diluent be uniformly mixing to obtain it is resistance to
Fiery fat material；
Step (4)：Prepare mothproofing agent：Yellow cinnamon leaf, folium artemisiae argyi and burmann cinnamon leaf are pressed 5:2:After 3 ratio mixing, crush, by powder
In the input that minces reaction kettle and ethyl alcohol immersion 10 hours is added, the amount of alcohol being added is yellow cinnamon leaf, folium artemisiae argyi and burmann cinnamon leaf mixing
5 times of object weight；By the mixture filtering of yellow cinnamon leaf, folium artemisiae argyi, burmann cinnamon leaf and ethyl alcohol after immersion, then filtrate is concentrated to give
Required mothproofing agent；
Step (5)：Refractory mineral cream and fire resisting fat material are put into blending tank together, remaining adhesive is added, and add
Heat to 90 DEG C of stirrings obtain vaseline mixture in 6 hours；
Step (6)：It stirs evenly, adds after sequentially adding hydrophober, coalescents, mothproofing agent in vaseline mixture
Continue stirring 2 hours after curing agent.
Count by weight percentage, the refractory mineral matter is by 30% quartz sand, 30% calcium carbonate and 40% oxidation
Aluminium forms, and described adhesive is made of 50% waterglass and 50% carboxymethyl cellulose, the fire retardant fire-proof additive by
35% zinc borate, 12% antimony oxide and 53% decabromodiphenyl oxide composition, the fire retardant resin by 20% nitrile rubber,
25% epoxy resin, 15% Vinylidene Chloride and 40% phenolic resin composition, the organic solvent by 25% ethylene second two
Alcohol ether, 10% ethyl acetate and 65% tung oil composition, the diluent by 60% butyl acetate, 15% styrene and
25% isopropanol composition, the curing agent is made of the diethylenetriamine of 40% aminoethyl piperazine AE and 60%, it is described at
Film auxiliary agent is propandiol butyl ether, and the hydrophober is polysiloxanes powder.
A kind of embodiment 3, history old architecture survey waterproof insectproof material preparation method, carries out according to the following steps：
Step (1) prepares raw material：Count by weight percentage, 8% refractory mineral matter is weighed, 5% adhesive, 3%
Fire retardant fire-proof additive, 13% organic solvent, 3% coalescents, 1.5% hydrophober, 3% diluent, 2%
Curing agent, 5% mothproofing agent and 56.5% fire retardant resin；
Step (2) prepares refractory mineral cream：Refractory mineral matter be crushed into 130 mesh sieve, screenings is put into agitator tank
And the adhesive that half is added stirs evenly, and continues to stir to get refractory mineral after then adding fire retardant fire-proof additive
Cream；
Step (3)：Prepare fire resisting fat material：Be added in fire retardant resin after organic solvent and diluent be uniformly mixing to obtain it is resistance to
Fiery fat material；
Step (4)：Prepare mothproofing agent：Yellow cinnamon leaf, folium artemisiae argyi and burmann cinnamon leaf are pressed 4.5:4.5:After 2.5 ratio mixing, powder
It is broken, crushed material is put into reaction kettle and ethyl alcohol is added and is impregnated 8 hours, the amount of alcohol being added is yellow cinnamon leaf, folium artemisiae argyi and burmannii
4 times of leaf mixture weight；It is then that filtrate is dense by the mixture filtering of yellow cinnamon leaf, folium artemisiae argyi, burmann cinnamon leaf and ethyl alcohol after immersion
Required mothproofing agent is arrived in contracting；
Step (5)：Refractory mineral cream and fire resisting fat material are put into blending tank together, remaining adhesive is added, and add
Heat to 70 DEG C of stirrings obtain vaseline mixture in 5 hours；
Step (6)：It stirs evenly, adds after sequentially adding hydrophober, coalescents, mothproofing agent in vaseline mixture
Continue stirring 1.5 hours after curing agent.
Count by weight percentage, the refractory mineral matter is by 25% quartz sand, 22% calcium carbonate and 53% oxidation
Aluminium forms, and described adhesive is made of 40% waterglass and 60% carboxymethyl cellulose, the fire retardant fire-proof additive by
25% zinc borate, 9% antimony oxide and 66% decabromodiphenyl oxide composition, the fire retardant resin by 15% nitrile rubber,
15% epoxy resin, 10% Vinylidene Chloride and 60% phenolic resin composition, the organic solvent by 19% ethylene second
Glycol ethers, 8% ethyl acetate and 73% tung oil composition, the diluent is by 45% butyl acetate, 11% styrene
And 44% isopropanol forms, the curing agent is made of the diethylenetriamine of 32% aminoethyl piperazine AE and 68%, described
Coalescents are propandiol butyl ether, and the hydrophober is polysiloxanes powder.
Embodiment 4, a kind of history old architecture survey waterproof insectproof materials'use method will be by any one of embodiment 1-3 institutes
Protective materials prepared by the history old architecture survey waterproof insectproof material preparation method of preparation is coated in after being heated to 35 DEG C and waits protecting
Protect the outer surface of history ancient building.
Embodiment 5, a kind of history old architecture survey waterproof insectproof materials'use method will be by any one of embodiment 1-3 institutes
Protective materials prepared by the history old architecture survey waterproof insectproof material preparation method of preparation is coated in after being heated to 40 DEG C and waits protecting
Protect the outer surface of antique wood.
With reference to test example and test data, the invention will be further described.
(1) test material, as shown in table 1.
(2) test sample preparation method：
Take the plank that six pieces of block specifications are 1016mm × 19mm × 10mm number respectively be 1. -7.；
The history that each component raw material in test group 1, test group 2 and test group 3 is pressed respectively described in embodiment 1,2,3 is ancient
It is to be made on plank 1., 2., 3. that building fire protection waterproof insectproof material preparation method, which is made and is applied directly to number after protective materials,
Obtain test sample I, test sample II and test sample III；
Each group raw material in test group 4 and experiment 5 is prevented by the history ancient building described in embodiment 1 and embodiment 2 respectively
After protective materials is made in fiery waterproof insectproof material preparation method, then it is coated in after protective materials is separately heated to 35 DEG C and 40 DEG C
Number is that test sample IV and test sample V are made on plank 4., 5.；
It is that control VI is made on plank 6. that commercially available fire proofing material in control group 6, which is applied directly to number,；
It is that plank 7. does not make any processing and obtains blank control VII by number.
(3) test method：
1, impermeability is measured by the regulation of GB/T 16777-2008.
2, fire-retarding of wood measures, and is measured by the regulation of GA/T 42.2-92.
3, the test of oxygen index (OI) is measured by the regulation of GB/T 2406-93.
4, Anti-moth-eating is tested, and is carried out by the regulation of DA/T 27-2000.
(4) test result, as shown in table 2 and table 3.
As can be seen that the blank control for not making any processing does not have water proofing property, flaming combustion from the test result of table 2
Time is long, and loss rate of quality after burning is high, therefore the blank plank for not making any processing is neither waterproof and cannot prevent fires；With it is common
The control of fire proofing material processing is compared, and five groups of test samples all have good impermeability, good water-proof effect, and commercially available common
Fire proofing material poor waterproof properties；The control of the more common fire proofing material processing of oxygen index (OI) of five groups of test samples, which is compared, to be had significantly
It is promoted, it is horizontal to have reached fire retardant timber；The flaming combustion time of five groups of test samples is with the processing of common fire proofing material to photograph
Than significantly reducing, loss rate of quality after burning is also reduced significantly compared with control group, therefore five groups of test samples have reached resistance
The requirement of firebrand product, while the more commercially available common fire proofing material of its fire line, compared to more preferably, it is after heating protective materials that spy is standby
The test sample IV and test sample V of re-coating, compared with other three groups of test samples, oxygen index (OI) increases, when flaming combustion
Between significantly reduce, also more other three groups of test samples are low for loss rate of quality after burning, therefore can be determined that anti-using history ancient building
When fiery waterproof insectproof materials'use method coating protective materials, more preferably, this is mainly due to coatings to protect for the fire protecting performance of timber
Material temperature has preferable mobility and permeability, has penetrated into wood internal compared with Wood temperature height, protective materials when material,
Certain thickness fireprotection layer is formd inside historical relic, therefore its fire protecting performance is more preferable.
Note：+++ indicate severe intoxication phenomenon, ++ indicate severe intoxication phenomenon ,-indicate to have no apparent intoxicating phenomenon
From table 3 it can be seen that not making the blank control of any processing and using control group made from common fire proofing material
It is poor to common wood borers repellence, it cannot resist and damage by worms substantially, and use history old architecture survey provided by the present invention
Five groups of test samples after waterproof insectproof material preparation method is prepared and coated all have good Anti-moth-eating function.
It is and existing in conclusion a kind of history old architecture survey waterproof insectproof material preparation method provided by the present invention
Fire proofing material preparation method compared to having both fire prevention, waterproof and mothproof effect simultaneously, it is ancient using history provided by the present invention
When building fire protection waterproof insectproof materials'use method is to wooden or other inflammable wooden ancient building coating protective materials, material has
Preferable mobility and permeability, certain thickness fireprotection layer is formd on the surface of timber and inside, so that being coated
Wood materials have better fire protecting performance.
Finally, it should be noted that foregoing description is only the preferred embodiment of the present invention, the ordinary skill people of this field
Member under the inspiration of the present invention, without prejudice to the purpose of the present invention and the claims, can make table as multiple types
Show, such transformation is each fallen within protection scope of the present invention.
Claims (4)
1. a kind of history old architecture survey waterproof insectproof material preparation method, it is characterised in that carry out according to the following steps：
Step (1) prepares raw material：Count by weight percentage, the refractory mineral matter of 6-10%, the adhesive of 3-7%, 2- are weighed
5% fire retardant fire-proof additive, the organic solvent of 12-15%, the coalescents of 2-5%, the hydrophober of 1-2%, 2-4%'s is dilute
Release agent, the curing agent of 1-3%, the mothproofing agent of 3-6% and the fire retardant resin of surplus；
Step (2) prepares refractory mineral cream：Refractory mineral matter is pulverized and sieved, screenings is put into agitator tank and is added two points
One of adhesive stir evenly, continue to stir to get refractory mineral cream after then adding fire retardant fire-proof additive；
Step (3)：Prepare fire resisting fat material：It is uniformly mixing to obtain fire resisting fat after organic solvent and diluent is added in fire retardant resin
Material；
Step (4)：Prepare mothproofing agent：Yellow cinnamon leaf, folium artemisiae argyi and burmann cinnamon leaf are pressed into 4-5:1-2:After the ratio mixing of 2-3, crush, it will
In crushed material input reaction kettle and ethyl alcohol immersion 5-10 hours is added, the amount of alcohol being added is yellow cinnamon leaf, folium artemisiae argyi and burmann cinnamon leaf
3-5 times of mixture weight；It is then that filtrate is dense by the mixture filtering of yellow cinnamon leaf, folium artemisiae argyi, burmann cinnamon leaf and ethyl alcohol after immersion
Contracting obtains required mothproofing agent；
Step (5)：Refractory mineral cream and fire resisting fat material are put into blending tank together, remaining adhesive is added, and heat and stir
It mixes 3-6 hours and obtains vaseline mixture；
Step (6)：It is stirred evenly after sequentially adding hydrophober, coalescents, mothproofing agent in vaseline mixture, adds solidification
Continue stirring 1-2 hours after agent；
Count by weight percentage, the refractory mineral matter is by the quartz sand of 20-30%, the calcium carbonate and surplus of 15-30%
Aluminium oxide composition；
Count by weight percentage, the organic solvent is by the ethylene glycol ether of 14-25%, the ethyl acetate of 6-10% and remaining
The tung oil of amount forms；
Count by weight percentage, described adhesive is made of the waterglass of 30-50% and the carboxymethyl cellulose of 50-70%；
Count by weight percentage, the fire retardant fire-proof additive is by the zinc borate of 20-35%, the antimony oxide of 6-12% and surplus
Decabromodiphenyl oxide composition；
Count by weight percentage, the fire retardant resin is by the nitrile rubber of 10-20%, epoxy resin, the 5-15% of 5-25%
Vinylidene Chloride and surplus phenolic resin composition；
The coalescents are propandiol butyl ether, and the hydrophober is polysiloxanes powder；Count by weight percentage, described dilute
Release butyl acetate of the agent by 30-60%, the styrene of 8-15% and the isopropanol composition of surplus；Count by weight percentage, institute
Curing agent is stated to be made of the diethylenetriamine of the aminoethyl piperazine AE and 60-75% of 25-40%.
2. history old architecture survey waterproof insectproof material preparation method according to claim 1, it is characterised in that：Step
(2) sieve mesh number being sieved described in is 100-150 mesh.
3. history old architecture survey waterproof insectproof material preparation method according to claim 1, it is characterised in that：Step
(5) heating temperature described in is 60-90 DEG C.
4. a kind of history old architecture survey waterproof insectproof materials'use method, it is characterised in that：It will be by any one of claim 1-3
Protective materials prepared by the history old architecture survey waterproof insectproof material preparation method is coated in after being heated to 35-40 DEG C and waits for
The outer surface of History of conservancy ancient building or antique wood.
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| CN201610402432.4A CN105860740B (en) | 2016-06-08 | 2016-06-08 | History old architecture survey waterproof insectproof material preparation and application method |
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| CN105860740B true CN105860740B (en) | 2018-09-21 |
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| CN112795267A (en) * | 2021-01-29 | 2021-05-14 | 应急管理部四川消防研究所 | Fireproof coating, antique wood hanging plate and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1076208A (en) * | 1992-03-11 | 1993-09-15 | 盛建平 | Fire retarding antistatic paint |
| CN101979437A (en) * | 2010-11-16 | 2011-02-23 | 莱芜金鼎电子材料有限公司 | Phosphorus-nitrogen composite expanded composition and preparation method and application thereof |
| CN102850716A (en) * | 2012-09-20 | 2013-01-02 | 常熟市永祥机电有限公司 | Flame retardant conductive composite material |
| CN102850902A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Corrosion-resistant fireproof coating |
| CN104910796A (en) * | 2015-06-05 | 2015-09-16 | 江苏理工学院 | Mildew-proof and mothproof coating for ancient wooden buildings in humid environments in middle and lower reaches of Yangtze River and preparation method of mildew-proof and mothproof coating |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101709199A (en) * | 2009-12-17 | 2010-05-19 | 中华全国供销合作总社西安生漆涂料研究所 | Antique building decorative coating |
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2016
- 2016-06-08 CN CN201610402432.4A patent/CN105860740B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1076208A (en) * | 1992-03-11 | 1993-09-15 | 盛建平 | Fire retarding antistatic paint |
| CN101979437A (en) * | 2010-11-16 | 2011-02-23 | 莱芜金鼎电子材料有限公司 | Phosphorus-nitrogen composite expanded composition and preparation method and application thereof |
| CN102850902A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Corrosion-resistant fireproof coating |
| CN102850716A (en) * | 2012-09-20 | 2013-01-02 | 常熟市永祥机电有限公司 | Flame retardant conductive composite material |
| CN104910796A (en) * | 2015-06-05 | 2015-09-16 | 江苏理工学院 | Mildew-proof and mothproof coating for ancient wooden buildings in humid environments in middle and lower reaches of Yangtze River and preparation method of mildew-proof and mothproof coating |
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