CN105860740A - Preparation method and application method of fire proofing, water proofing and insect preventing material for historical ancient building - Google Patents
Preparation method and application method of fire proofing, water proofing and insect preventing material for historical ancient building Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a preparation method of a fire proofing, water proofing and insect preventing material for a historical ancient building. The preparation method is implemented according to the following steps of preparing raw materials, preparing fire-resistant mineral paste, preparing fire-resistant fat materials, preparing a mothproofing agent, preparing a petrolatum mixture, sequentially adding a water repellent, a film forming aid and the mothproofing agent into the petrolatum mixture and the like. The fire proofing, water proofing and insect preventing historical ancient building material prepared by adopting the method has the high fire resistance and the good waterproofness, also has the mothproofing effect and is good in fluidity and convenient to construct, and the life and the preservation time of woody materials can be effectively prolonged when a woody structure such as a beam, a purlin, a rafter and a pillar which are arranged on the historical ancient building or an imitation antique woody material is coated with the fire proofing, water proofing and insect preventing material; the prepared protection material is heated and then constructed during construction, the mode is beneficial for improving the fluidity and the permeability of the protection material, the protection material permeates into the woody material to form a protection layer with a certain thickness, and the protection layer is beneficial for improving the fireproof performance of the woody material.
Description
Technical field
The present invention relates to Techniques of Relics Protection field, specific design one history old architecture survey waterproof insectproof material method of preparation and use.
Background technology
China is an ancient civilized country with more than 5000 year history, ancestors leave abundant cultural heritage to us, including ancient building, bamboo caving, woodcarving, mural painting, painting and calligraphy, sculpture, inscriptions on precipices, metal and ceramic etc. are innumerable, the a large amount of historical relics being the most constantly unearthed are all the treasures of our people, these historical relics are not only the treasure of Chinese people, also it is the treasure of the people of the world, there is the highest academic research, value of art appreciation, raising along with living standards of the people, the most surging to the appreciation demand of historical relic, but people the most easily bring certain damage to historical relic while appreciating historical relic, particularly some ancient buildings, its beam, purlin, posts etc. are mostly wooden structures, there is good burning and propagating flame performance, if breaking out of fire consequence is hardly imaginable；Additionally also have some building in the style of the ancients, also use substantial amounts of wooden structures, often need to be at its surface-coated fire proofing material for guaranteeing that these wood materials have preferable fire protecting performance, but these fire proofing materials are only capable of playing certain fire retardation, can not have waterproof effect while that flameproof effect being bad concurrently.
Summary of the invention
For solving above technical problem; an object of the present invention is to provide a kind of history old architecture survey waterproof material preparation method, and the material prepared by the method is coated in the outer surface of history ancient building to be protected or material modelled after an antique can simultaneously work as fire prevention, waterproof and mothproof effect.
The two of the purpose of the present invention are: provide a kind of history old architecture survey waterproof material using method, use the method coating fire-proof and water-proof material, and fire-proof and water-proof insect protected material has preferable permeability.
Technical scheme is as follows: an object of the present invention is achieved in that
A kind of history old architecture survey waterproof insectproof material preparation method, it it is critical only that and sequentially includes the following steps:
Step (1) prepares raw material: count by weight percentage, weigh the refractory mineral matter of 6-10%, the binding agent of 3-7%, the difficult combustion fire-proof additive of 2-5%, the organic solvent of 12-15%, the coalescents of 2-5%, the hydrophober of 1-2%, the diluent of 2-4%, the firming agent of 1-3%, the mothproofing agent of 3-6% and the difficult combustion resin of surplus；
Step (2) prepares refractory mineral cream: refractory mineral matter pulverized and sieved, and is put into by siftage in agitator tank and adds the binding agent of 1/2nd and stirs, and continues stirring and obtain refractory mineral cream after then adding difficult combustion fire-proof additive；
Step (3): prepare fire-resistant fat material: be uniformly mixing to obtain fire-resistant fat material after adding organic solvent and diluent in difficulty combustion resin；
Step (4): prepare mothproofing agent: after Folium Cinnamomi porrecti, Folium Artemisiae Argyi and Folium Cinnamomi burmannii being mixed in the ratio of 4-5:1-2:2-3, pulverize, being put into by ground product in reactor and add soak with ethanol 5-10 hour, the amount of alcohol added is Folium Cinnamomi porrecti, Folium Artemisiae Argyi and 3-5 times of Folium Cinnamomi burmannii mixture weight；The mixture of Folium Cinnamomi porrecti, Folium Artemisiae Argyi, Folium Cinnamomi burmannii and ethanol after soaking filters, and then filtrate be concentrated to give required mothproofing agent；
Step (5): put in blending tank together with fire-resistant fat material by refractory mineral cream, adds remaining binding agent, and heated and stirred 3-6 hour obtains vaseline mixture；
Step (6): stir after being sequentially added into hydrophober, coalescents, mothproofing agent in vaseline mixture, continues stirring 1-2 hour after adding firming agent.
The history old architecture survey waterproof insectproof material using the technical program to prepare has stronger fire resistance and preferable water proofing property, the most also have mothproof effect concurrently, and the good fluidity of coating, be easy to construction, be coated in it on wooden structures such as the beam of history ancient building, purlin, rafter, post or on Archaizing wood material after can effectively extend life-span and the holding time of wood materials.
As preferably: count by weight percentage, described refractory mineral matter is by the quartz sand of 20-30%, the calcium carbonate of 15-30% and the aluminium oxide composition of surplus.
Count by weight percentage, described binding agent is made up of the waterglass of 30-50% and the carboxymethyl cellulose of 50-70%.
Count by weight percentage, described difficult combustion fire-proof additive is made up of the decabromodiphenyl oxide of the Firebrake ZB of 20-35%, the stibium oxide of 6-12% and surplus.
Count by weight percentage, described difficult combustion resin is by the nitrile rubber of 10-20%, the phenolic resin composition of the epoxy resin of 5-25%, the Vinylidene Chloride of 5-15% and surplus.
Count by weight percentage, described organic solvent is made up of the Oleum Verniciae fordii of the ethylene glycol ether of 14-25%, the ethyl acetate of 6-10% and surplus.Using this scheme solvent good with the dissolubility of other compositions, the Oleum Verniciae fordii in solvent also has certain waterproof, anticorrosion and the effect of parasite killing simultaneously.
Above-mentioned coalescents is propandiol butyl ether, and described hydrophober is polysiloxanes powder；Count by weight percentage, described diluent is by the butyl acetate of 30-60%, the styrene of 8-15% and the isopropanol composition of surplus；Count by weight percentage, described firming agent is made up of the diethylenetriamine of aminoethyl piperazine AE and 60-75% of 25-40%.Use this scheme to be conducive to improving the mobility of protective material, and the protective material prepared is without hot setting, is especially suitable for carrying out the wooden ancient building of high-temperature heating.
The sieve number sieved described in step (2) is 100-150 mesh.Refractory mineral matter exquisiteness such as powder after sieving, is conducive to and other materials mix homogeneously.
Described in step (5), heating-up temperature is 60-90 DEG C.Heating can improve the mobility of fire-resistant fat material, reduces its viscosity, the most fire-resistant fat material and refractory mineral cream mix homogeneously.
The two of the purpose of the present invention are achieved in that a kind of history old architecture survey waterproof insectproof materials'use method, and it it is critical only that: is heated to after 35-40 DEG C being coated in history ancient building to be protected or the outer surface of antique wood by the protective material prepared by history old architecture survey waterproof insectproof material preparation method.Using the protective material viscosity after the technical program heating to reduce, it is simple to construction, its mobility and permeability are more preferable simultaneously, can penetrate into wood materials and be internally formed certain thickness overcoat, are conducive to improving the fire protecting performance of wood materials.
Beneficial effect: use the history old architecture survey waterproof insectproof material of the preparation of the present invention to have stronger fire resistance and preferable water proofing property, the most also have mothproof effect concurrently, and the good fluidity of coating, it is easy to construction, it is coated in the beam of history ancient building with it, purlin, rafter, life-span and the holding time of wood materials can be effectively extended after on the wooden structures such as post or on Archaizing wood material, be conducive to promoting mobility and the permeability of protective material by constructing again after the protective material heating of preparation during construction, make protective material penetrate into wood materials and be internally formed certain thickness overcoat, be conducive to improving the fire protecting performance of wood materials.
Detailed description of the invention
Below in conjunction with embodiment and test data, the invention will be further described.
Embodiment 1, a kind of history old architecture survey waterproof insectproof material preparation method, sequentially include the following steps:
Step (1) prepares raw material: count by weight percentage, weigh the refractory mineral matter of 6%, the binding agent of 3%, the difficult combustion fire-proof additive of 2%, the organic solvent of 12%, the coalescents of 2%, the hydrophober of 1%, the diluent of 2%, the firming agent of 1%, 3% mothproofing agent and 68% difficult combustion resin；
Step (2) prepares refractory mineral cream: refractory mineral matter was pulverized 100 mesh sieves, is put into by siftage in agitator tank and adds the binding agent of 1/2nd and stirs, and continues stirring and obtain refractory mineral cream after then adding difficult combustion fire-proof additive；
Step (3): prepare fire-resistant fat material: be uniformly mixing to obtain fire-resistant fat material after adding organic solvent and diluent in difficulty combustion resin；
Step (4): prepare mothproofing agent: after Folium Cinnamomi porrecti, Folium Artemisiae Argyi and Folium Cinnamomi burmannii being mixed in the ratio of 4:1:2, pulverize, being put into by ground product in reactor and add soak with ethanol 5 hours, the amount of alcohol added is 3 times of Folium Cinnamomi porrecti, Folium Artemisiae Argyi and Folium Cinnamomi burmannii mixture weight；Will soak after Folium Cinnamomi porrecti, Folium Artemisiae Argyi, Folium Cinnamomi burmannii and ethanol mixture filter, then by filtrate concentrate to required mothproofing agent；
Step (5): put in blending tank together with fire-resistant fat material by refractory mineral cream, adds remaining binding agent, and is heated to 60 DEG C of stirrings and obtains vaseline mixture in 3 hours；
Step (6): stir after being sequentially added into hydrophober, coalescents, mothproofing agent in vaseline mixture, continues stirring 1 hour after adding firming agent.
nullCount by weight percentage，Described refractory mineral matter is by 20% quartz sand，15% calcium carbonate and the aluminium oxide composition of 65%，Described binding agent is made up of the waterglass of 30% and the carboxymethyl cellulose of 70%，Described difficulty fires the Firebrake ZB that fire-proof additive is by 20%、6% stibium oxide and the decabromodiphenyl oxide composition of 74%，Described difficulty fires the nitrile rubber that resin is by 10%，The epoxy resin of 5%、5% Vinylidene Chloride and the phenolic resin composition of 80%，Described organic solvent by 14% ethylene glycol ether、The ethyl acetate of 6% and the Oleum Verniciae fordii composition of 80%，Described diluent by 30% butyl acetate，The styrene of 8% and the isopropanol composition of 62%，Described firming agent is made up of the diethylenetriamine of the aminoethyl piperazine AE and 75% of 25%，Described coalescents is propandiol butyl ether，Described hydrophober is polysiloxanes powder.
Embodiment 2, a kind of history old architecture survey waterproof insectproof material preparation method, sequentially include the following steps:
Step (1) prepares raw material: count by weight percentage, weigh 10% refractory mineral matter, the binding agent of 7%, the difficult combustion fire-proof additive of 5%, the organic solvent of 15%, the coalescents of 5%, the hydrophober of 2%, the diluent of 4%, the firming agent of 3%, 6% mothproofing agent and 43% difficult combustion resin；
Step (2) prepares refractory mineral cream: refractory mineral matter was pulverized 150 mesh sieves, is put into by siftage in agitator tank and adds the binding agent of 1/2nd and stirs, and continues stirring and obtain refractory mineral cream after then adding difficult combustion fire-proof additive；
Step (3): prepare fire-resistant fat material: be uniformly mixing to obtain fire-resistant fat material after adding organic solvent and diluent in difficulty combustion resin；
Step (4): prepare mothproofing agent: after Folium Cinnamomi porrecti, Folium Artemisiae Argyi and Folium Cinnamomi burmannii being mixed in the ratio of 5:2:3, pulverize, being put into by ground product in reactor and add soak with ethanol 10 hours, the amount of alcohol added is 5 times of Folium Cinnamomi porrecti, Folium Artemisiae Argyi and Folium Cinnamomi burmannii mixture weight；The mixture of Folium Cinnamomi porrecti, Folium Artemisiae Argyi, Folium Cinnamomi burmannii and ethanol after soaking filters, and then filtrate be concentrated to give required mothproofing agent；
Step (5): put in blending tank together with fire-resistant fat material by refractory mineral cream, adds remaining binding agent, and is heated to 90 DEG C of stirrings and obtains vaseline mixture in 6 hours；
Step (6): stir after being sequentially added into hydrophober, coalescents, mothproofing agent in vaseline mixture, continues stirring 2 hours after adding firming agent.
nullCount by weight percentage，Described refractory mineral matter is by 30% quartz sand，30% calcium carbonate and the aluminium oxide composition of 40%，Described binding agent is made up of the waterglass of 50% and the carboxymethyl cellulose of 50%，Described difficulty fires the Firebrake ZB that fire-proof additive is by 35%、12% stibium oxide and the decabromodiphenyl oxide composition of 53%，Described difficulty fires the nitrile rubber that resin is by 20%，The epoxy resin of 25%、15% Vinylidene Chloride and the phenolic resin composition of 40%，Described organic solvent by 25% ethylene glycol ether、10% ethyl acetate and the Oleum Verniciae fordii composition of 65%，Described diluent by 60% butyl acetate，The styrene of 15% and the isopropanol composition of 25%，Described firming agent is made up of the diethylenetriamine of the aminoethyl piperazine AE and 60% of 40%，Described coalescents is propandiol butyl ether，Described hydrophober is polysiloxanes powder.
Embodiment 3, a kind of history old architecture survey waterproof insectproof material preparation method, sequentially include the following steps:
Step (1) prepares raw material: count by weight percentage, weigh the refractory mineral matter of 8%, the binding agent of 5%, the difficult combustion fire-proof additive of 3%, the organic solvent of 13%, the coalescents of 3%, the hydrophober of 1.5%, the diluent of 3%, the firming agent of 2%, 5% mothproofing agent and the difficult combustion resin of 56.5%；
Step (2) prepares refractory mineral cream: refractory mineral matter was pulverized 130 mesh sieves, is put into by siftage in agitator tank and adds the binding agent of 1/2nd and stirs, and continues stirring and obtain refractory mineral cream after then adding difficult combustion fire-proof additive；
Step (3): prepare fire-resistant fat material: be uniformly mixing to obtain fire-resistant fat material after adding organic solvent and diluent in difficulty combustion resin；
Step (4): prepare mothproofing agent: after Folium Cinnamomi porrecti, Folium Artemisiae Argyi and Folium Cinnamomi burmannii being mixed in the ratio of 4.5:4.5:2.5, pulverize, being put into by ground product in reactor and add soak with ethanol 8 hours, the amount of alcohol added is 4 times of Folium Cinnamomi porrecti, Folium Artemisiae Argyi and Folium Cinnamomi burmannii mixture weight；Will soak after Folium Cinnamomi porrecti, Folium Artemisiae Argyi, Folium Cinnamomi burmannii and ethanol mixture filter, then by filtrate concentrate to required mothproofing agent；
Step (5): put in blending tank together with fire-resistant fat material by refractory mineral cream, adds remaining binding agent, and is heated to 70 DEG C of stirrings and obtains vaseline mixture in 5 hours；
Step (6): stir after being sequentially added into hydrophober, coalescents, mothproofing agent in vaseline mixture, continues stirring 1.5 hours after adding firming agent.
nullCount by weight percentage，Described refractory mineral matter is by 25% quartz sand，22% calcium carbonate and the aluminium oxide composition of 53%，Described binding agent is made up of the waterglass of 40% and the carboxymethyl cellulose of 60%，Described difficulty fires the Firebrake ZB that fire-proof additive is by 25%、The stibium oxide of 9% and the decabromodiphenyl oxide composition of 66%，Described difficulty fires the nitrile rubber that resin is by 15%，The epoxy resin of 15%、The Vinylidene Chloride of 10% and the phenolic resin composition of 60%，Described organic solvent by 19% ethylene glycol ether、The ethyl acetate of 8% and the Oleum Verniciae fordii composition of 73%，Described diluent by 45% butyl acetate，The styrene of 11% and the isopropanol composition of 44%，Described firming agent is made up of the diethylenetriamine of the aminoethyl piperazine AE and 68% of 32%，Described coalescents is propandiol butyl ether，Described hydrophober is polysiloxanes powder.
Embodiment 4; a kind of history old architecture survey waterproof insectproof materials'use method, is coated in the outer surface of history ancient building to be protected after protective material prepared by the history old architecture survey waterproof insectproof material preparation method as prepared by any one of embodiment 1-3 is heated to 35 DEG C.
Embodiment 5; a kind of history old architecture survey waterproof insectproof materials'use method, is coated in the outer surface of antique wood to be protected after protective material prepared by the history old architecture survey waterproof insectproof material preparation method as prepared by any one of embodiment 1-3 is heated to 40 DEG C.
Below in conjunction with test example and test data, the invention will be further described.
(1) test material, as shown in table 1.
(2) test sample preparation method:
Take the plank that six pieces of block specifications are 1016mm × 19mm × 10mm the most numbered 1.-7.；
It is applied directly on numbered plank 1., 2., 3. after each component raw material in test group 1, test group 2 and test group 3 is made protective material by the history old architecture survey waterproof insectproof material preparation method described in embodiment 1,2,3 respectively prepare test sample I, test sample II and test sample III；
After group raw material each in test group 4 and test 5 is made protective material by the history old architecture survey waterproof insectproof material preparation method described in embodiment 1 and embodiment 2 respectively, then it is coated on numbered plank 4., 5. prepared test sample IV and test sample V after protective material is separately heated to 35 DEG C and 40 DEG C；
It is applied directly to the commercially available fire proofing material in matched group 6 on numbered plank 6. prepare comparison VI；
Numbered plank 7. is not made any process and obtains blank VII.
(3) test method:
1, impermeability, is measured by the regulation of GB/T 16777-2008.
2, fire-retarding of wood measures, and is measured by the regulation of GA/T 42.2-92.
3, the test of oxygen index (OI), is measured by the regulation of GB/T 2406-93.
4, Anti-moth-eating test, is carried out by the regulation of DA/T 27-2000.
(4) result of the test, as shown in table 2 and table 3.
It can be seen that the blank not making any process does not have water proofing property from the result of the test of table 2, the flaming combustion time is long, and loss rate of quality after burning is high, and the blank plank the most not making any process can not waterproof can not be prevented fires again；Compared with the comparison that common fire proofing material processes, five groups of test samples are respectively provided with good impermeability, good water-proof effect, and commercially available common fire proofing material water resistance is poor；The comparison that the more common fire proofing material of oxygen index (OI) of five groups of test samples processes is compared to have and is obviously improved, and has reached difficult firebrand material level；nullThe flaming combustion time of five groups of test samples significantly reduces compared with the comparison that common fire proofing material processes，Loss rate of quality after burning the most relatively matched group reduces significantly，Therefore five groups of test samples have reached the requirement of flame-retardant wooden product，The more commercially available common fire proofing material of its fire line is compared more preferably simultaneously，Spy is standby is by the test sample IV being coated with after protective material heating and test sample V，Compared with other three groups of test samples，Its oxygen index (OI) raises，The flaming combustion time significantly reduces，The most other three groups of test samples of loss rate of quality after burning are low，When therefore can be determined that employing history old architecture survey waterproof insectproof materials'use method coating protective material，The fire protecting performance of timber is more preferably，This is high mainly due to material temperature relatively Wood temperature during coating protective material，Protective material has preferable mobility and permeability，Penetrate into wood internal，It has been internally formed certain thickness fireprotection layer at historical relic，Therefore its fire protecting performance is more preferable.
Note: +++ represent severe intoxication phenomenon, ++ representing severe intoxication phenomenon ,-expression has no obvious intoxicating phenomenon
As can be seen from Table 3, the blank not making any process and the matched group using common fire proofing material to prepare are to common wood borers repellence difference, substantially can not resist and damage by worms, and five groups of test samples after using history old architecture survey waterproof insectproof material preparation method provided by the present invention to prepare and coat are respectively provided with good Anti-moth-eating function.
In sum, a kind of history old architecture survey waterproof insectproof material preparation method provided by the present invention, have fire prevention, waterproof and mothproof effect concurrently compared with existing fire proofing material preparation method simultaneously, when using history old architecture survey waterproof insectproof materials'use method provided by the present invention to wooden or other inflammable wooden ancient buildings coating protective material, material has preferable mobility and permeability, on the surface of timber and be internally formed certain thickness fireprotection layer, hence in so that the wood materials being applied has more preferable fire protecting performance.
Finally it should be noted that; foregoing description is only the preferred embodiments of the present invention; those of ordinary skill in the art is under the enlightenment of the present invention; on the premise of present inventive concept and claim; represent, within such conversion each falls within protection scope of the present invention as can making multiple types.
Claims (10)
1. a history old architecture survey waterproof insectproof material preparation method, it is characterised in that enter according to the following steps
OK:
Step (1) prepares raw material: count by weight percentage, weigh the refractory mineral matter of 6-10%, 3-7%
Binding agent, the difficult combustion fire-proof additive of 2-5%, the organic solvent of 12-15%, the coalescents of 2-5%, 1-2%
Hydrophober, the diluent of 2-4%, the firming agent of 1-3%, the mothproofing agent of 3-6% and the difficult combustion resin of surplus；
Step (2) prepares refractory mineral cream: refractory mineral matter pulverized and sieved, siftage is put into agitator tank
In and add the binding agent of 1/2nd and stir, continue stirring after then adding difficult combustion fire-proof additive
Obtain refractory mineral cream；
Step (3): prepare fire-resistant fat material: after adding organic solvent and diluent in difficulty combustion resin, stirring is all
Even obtain fire-resistant fat material；
Step (4): prepare mothproofing agent: Folium Cinnamomi porrecti, Folium Artemisiae Argyi and Folium Cinnamomi burmannii are mixed in the ratio of 4-5:1-2:2-3
After conjunction, pulverize, ground product put in reactor and add soak with ethanol 5-10 hour, the ethanol added
Amount is Folium Cinnamomi porrecti, Folium Artemisiae Argyi and 3-5 times of Folium Cinnamomi burmannii mixture weight；Folium Cinnamomi porrecti after soaking, Folium Artemisiae Argyi, the moon
The mixture of Herba Pelargonii Graveolentis and ethanol filters, and then filtrate be concentrated to give required mothproofing agent；
Step (5): refractory mineral cream is put in blending tank together with fire-resistant fat material, adds remaining bonding
Agent, and heated and stirred 3-6 hour obtains vaseline mixture；
Step (6): after being sequentially added into hydrophober, coalescents, mothproofing agent in vaseline mixture, stirring is all
Even, continue stirring 1-2 hour after adding firming agent.
History old architecture survey waterproof insectproof material preparation method the most according to claim 1, its feature
Being: count by weight percentage, described refractory mineral matter is by the quartz sand of 20-30%, the carbonic acid of 15-30%
The aluminium oxide composition of calcium and surplus.
History old architecture survey waterproof insectproof material preparation method the most according to claim 1, its feature
Being: count by weight percentage, described binding agent is fine by the waterglass of 30-50% and the carboxymethyl of 50-70%
Dimension element composition.
History old architecture survey waterproof insectproof material preparation method the most according to claim 1, its feature
Being: count by weight percentage, described difficult combustion fire-proof additive is by the Firebrake ZB of 20-35%, 6-12%
The decabromodiphenyl oxide composition of stibium oxide and surplus.
History old architecture survey waterproof insectproof material preparation method the most according to claim 1, its feature
Being: count by weight percentage, described difficult combustion resin is by the nitrile rubber of 10-20%, the epoxy of 5-25%
The phenolic resin composition of resin, the Vinylidene Chloride of 5-15% and surplus.
History old architecture survey waterproof insectproof material preparation method the most according to claim 1, its feature
Being: count by weight percentage, described organic solvent is by the ethylene glycol ether of 14-25%, 6-10%
The Oleum Verniciae fordii composition of ethyl acetate and surplus.
History old architecture survey waterproof insectproof material preparation method the most according to claim 1, its feature
Being: described coalescents is propandiol butyl ether, described hydrophober is polysiloxanes powder；Percentage by weight
Than calculating, described diluent is by the butyl acetate of 30-60%, the styrene of 8-15% and the isopropanol group of surplus
Become；Count by weight percentage, described firming agent is by the two of aminoethyl piperazine AE and 60-75% of 25-40%
Ethylene triamine forms.
History old architecture survey waterproof insectproof material preparation method the most according to claim 1, its feature
It is: the sieve number sieved described in step (2) is 100-150 mesh.
History old architecture survey waterproof insectproof material preparation method the most according to claim 1, its feature
It is: described in step (5), heating-up temperature is 60-90 DEG C.
10. a history old architecture survey waterproof insectproof materials'use method, it is characterised in that: will be by right
Require protective material prepared by the history old architecture survey waterproof insectproof material preparation method described in any one of 1-9
It is heated to after 35-40 DEG C being coated in history ancient building to be protected or the outer surface of antique wood.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112795267A (en) * | 2021-01-29 | 2021-05-14 | 应急管理部四川消防研究所 | Fireproof coating, antique wood hanging plate and preparation method thereof |
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| CN1076208A (en) * | 1992-03-11 | 1993-09-15 | 盛建平 | Fire retarding antistatic paint |
| CN101709199A (en) * | 2009-12-17 | 2010-05-19 | 中华全国供销合作总社西安生漆涂料研究所 | Antique building decorative coating |
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| CN102850716A (en) * | 2012-09-20 | 2013-01-02 | 常熟市永祥机电有限公司 | Flame retardant conductive composite material |
| CN102850902A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Corrosion-resistant fireproof coating |
| CN104910796A (en) * | 2015-06-05 | 2015-09-16 | 江苏理工学院 | Mildew-proof and mothproof coating for ancient wooden buildings in humid environments in middle and lower reaches of Yangtze River and preparation method of mildew-proof and mothproof coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1076208A (en) * | 1992-03-11 | 1993-09-15 | 盛建平 | Fire retarding antistatic paint |
| CN101709199A (en) * | 2009-12-17 | 2010-05-19 | 中华全国供销合作总社西安生漆涂料研究所 | Antique building decorative coating |
| CN101979437A (en) * | 2010-11-16 | 2011-02-23 | 莱芜金鼎电子材料有限公司 | Phosphorus-nitrogen composite expanded composition and preparation method and application thereof |
| CN102850902A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Corrosion-resistant fireproof coating |
| CN102850716A (en) * | 2012-09-20 | 2013-01-02 | 常熟市永祥机电有限公司 | Flame retardant conductive composite material |
| CN104910796A (en) * | 2015-06-05 | 2015-09-16 | 江苏理工学院 | Mildew-proof and mothproof coating for ancient wooden buildings in humid environments in middle and lower reaches of Yangtze River and preparation method of mildew-proof and mothproof coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112795267A (en) * | 2021-01-29 | 2021-05-14 | 应急管理部四川消防研究所 | Fireproof coating, antique wood hanging plate and preparation method thereof |
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