CN105854793B - 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 - Google Patents
一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 Download PDFInfo
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- CN105854793B CN105854793B CN201610195223.7A CN201610195223A CN105854793B CN 105854793 B CN105854793 B CN 105854793B CN 201610195223 A CN201610195223 A CN 201610195223A CN 105854793 B CN105854793 B CN 105854793B
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 27
- 229910021645 metal ion Inorganic materials 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 238000010521 absorption reaction Methods 0.000 title claims description 13
- 239000002131 composite material Substances 0.000 title abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 229920001448 anionic polyelectrolyte Polymers 0.000 claims abstract description 10
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 230000032683 aging Effects 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 5
- 238000005342 ion exchange Methods 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 159000000013 aluminium salts Chemical class 0.000 claims description 4
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 4
- 159000000003 magnesium salts Chemical class 0.000 claims description 4
- 239000002048 multi walled nanotube Substances 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 2
- 229940059939 kayexalate Drugs 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 239000002109 single walled nanotube Substances 0.000 claims description 2
- 238000002525 ultrasonication Methods 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 230000003213 activating effect Effects 0.000 claims 1
- 150000001450 anions Chemical class 0.000 abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 9
- 239000011229 interlayer Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003463 adsorbent Substances 0.000 abstract description 3
- 239000002041 carbon nanotube Substances 0.000 abstract description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 abstract description 3
- 125000000524 functional group Chemical group 0.000 abstract description 3
- 238000009830 intercalation Methods 0.000 abstract description 3
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- 238000002156 mixing Methods 0.000 description 7
- 239000012266 salt solution Substances 0.000 description 6
- 239000003643 water by type Substances 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 4
- 229960001545 hydrotalcite Drugs 0.000 description 4
- 229910001701 hydrotalcite Inorganic materials 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000002604 ultrasonography Methods 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 229910002601 GaN Inorganic materials 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006392 deoxygenation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000002488 metal-organic chemical vapour deposition Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
- B01J20/205—Carbon nanostructures, e.g. nanotubes, nanohorns, nanocones, nanoballs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/261—Drying gases or vapours by adsorption
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/024—Purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/12—Separation of ammonia from gases and vapours
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
Abstract
Description
Claims (6)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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CN201711215423.5A CN107970889A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201810000927.3A CN107961763A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201810000924.XA CN108079951A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201810000926.9A CN108079952A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201610195223.7A CN105854793B (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201711218383.XA CN107803182A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
Applications Claiming Priority (1)
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CN201610195223.7A CN105854793B (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
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CN201711218383.XA Division CN107803182A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201810000927.3A Division CN107961763A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201810000926.9A Division CN108079952A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201711215423.5A Division CN107970889A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201810000924.XA Division CN108079951A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
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CN105854793A CN105854793A (zh) | 2016-08-17 |
CN105854793B true CN105854793B (zh) | 2018-01-30 |
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CN201810000927.3A Pending CN107961763A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201610195223.7A Active CN105854793B (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201711218383.XA Pending CN107803182A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201810000924.XA Pending CN108079951A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201810000926.9A Pending CN108079952A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201711215423.5A Pending CN107970889A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
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CN201810000927.3A Pending CN107961763A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
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CN201711218383.XA Pending CN107803182A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201810000924.XA Pending CN108079951A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201810000926.9A Pending CN108079952A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
CN201711215423.5A Pending CN107970889A (zh) | 2016-03-31 | 2016-03-31 | 一种吸附超纯氨中金属离子的碳纳米管/LDHs复合材料的制备方法 |
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CN111559742A (zh) * | 2019-12-25 | 2020-08-21 | 江西悦安新材料股份有限公司 | 一种提高碳纳米管稳定性的方法 |
CN112090378A (zh) * | 2020-07-29 | 2020-12-18 | 淮阴工学院 | 光热转化增强型微胶囊相变材料的制备方法 |
CN112683871B (zh) * | 2021-01-05 | 2021-09-21 | 江苏雨松环境修复研究中心有限公司 | 土壤铬离子含量检测方法 |
CN113104872B (zh) * | 2021-05-24 | 2022-10-21 | 北京化工大学 | 一种一步法制备有机分子插层水滑石阵列的方法 |
CN113318709A (zh) * | 2021-06-04 | 2021-08-31 | 董鹏 | 一种油污吸附剂及其制备方法 |
Citations (5)
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CN101066526A (zh) * | 2007-04-20 | 2007-11-07 | 北京化工大学 | 一种水滑石/碳纳米管异质结构材料及其制备方法 |
CN102350279A (zh) * | 2011-06-22 | 2012-02-15 | 浙江大学 | 一种制备碳纳米管/层状双金属氢氧化物复合物的方法 |
CN102502519A (zh) * | 2011-11-03 | 2012-06-20 | 浙江大学 | 一种在水性溶液中制备剥离型层状材料/碳纳米管复合物的方法 |
WO2013093519A2 (en) * | 2011-12-22 | 2013-06-27 | Bio Nano Consulting | Carbon nanotube aerogels and xerogels for co2 capture |
CN104952636A (zh) * | 2015-05-14 | 2015-09-30 | 北京化工大学 | 一种纳米碳/水滑石阵列复合材料的制备方法 |
Family Cites Families (3)
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CN102806068B (zh) * | 2012-08-15 | 2014-08-06 | 苏州金宏气体股份有限公司 | 去除超纯氨中金属离子的碳纳米管和分子筛复合物的制备方法 |
CN104610575B (zh) * | 2015-01-26 | 2018-09-14 | 合肥学院 | 一种锌铝-层状双氢氧化物包覆碳纳米管复合粉体及其制备方法 |
CN105153464B (zh) * | 2015-09-29 | 2019-02-19 | 合肥学院 | 一种阻燃抑烟碳纳米管/镍铝层状双氢氧化物复合粉体及其制备方法和应用 |
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2016
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CN108079952A (zh) | 2018-05-29 |
CN107961763A (zh) | 2018-04-27 |
CN107970889A (zh) | 2018-05-01 |
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