CN105854525A - Novel environment-friendly air purifying material and preparation method thereof - Google Patents
Novel environment-friendly air purifying material and preparation method thereof Download PDFInfo
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- CN105854525A CN105854525A CN201610393944.9A CN201610393944A CN105854525A CN 105854525 A CN105854525 A CN 105854525A CN 201610393944 A CN201610393944 A CN 201610393944A CN 105854525 A CN105854525 A CN 105854525A
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- sodium
- hexameta phosphate
- sodium tripolyphosphate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1487—Removing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/50—Combinations of absorbents
- B01D2252/504—Mixtures of two or more absorbents
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- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses a novel environment-friendly air purifying material and a preparation method thereof. The air purifying material is prepared from, by weight, 45-55 parts of methacrylamide, 35-45 parts of maleimide, 20-30 parts of polyvinyl alcohol, 12-14 parts of aluminium hydroxide, 6-8 parts of zinc fluosilicate, 10-14 parts of active carbon fiber, 15-25 parts of kieselguhr, 2-4 parts of fibroin, 3-5 parts of sodium cocoyl glycinate and 7-9 parts of sodium tripolyphosphate and sodium hexametaphosphate, wherein the ratio of the weight part of sodium tripolyphosphate to the weight part of sodium hexametaphosphate is (6-8):1. The novel environment-friendly air purifying material has excellent air purifying performance; with formaldehyde as the example, the formaldehyde absorption rate almost reaches 100%. The property is possibly related to the ratio of the weight part of sodium tripolyphosphate to the weight part of sodium hexametaphosphate in the raw materials, and the purifying effect is the best when the ratio of the weight part of sodium tripolyphosphate to the weight part of sodium hexametaphosphate is (6-8):1.
Description
Technical field
The invention belongs to air purification field, be specifically related to a kind of environmental protection air cleaning new material and preparation method thereof.
Background technology
Air cleaning refer to for indoor various environmental problems provide sterilizing, depositing dust except haze, dispel harmful finishing residual with
And the total solution of abnormal flavour etc., so can be effectively improved life, office conditions, promote physical and mental health.Indoor environmental pollution
Thing and pollution source mainly include radgas, mycete, particulate matter, finishing residual, second hand smoking etc..
Current indoor owing to having used the finishing of multiple artificial material, thus there is this pollution such as formaldehyde, toluene and harmful gas
Being widely present, this creates serious harm to the health of people.Material for air purification is mainly by physical absorption, change at present
The technology such as method, catalysis remove nuisance.
The conventional main active charcoal of physisorption material, activated carbon is because having big specific surface area, it is easy to absorb in air
Harmful gas, is widely used in indoor air purification the most in daily life.But commercially available activated carbon only have powder with
Granular two classes, but this activated carbon also exists and easily flies upward and inaesthetic shortcoming.
Summary of the invention
It is an object of the invention to provide a kind of environmental protection air cleaning new material and preparation method thereof.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
A kind of environmental protection air cleaning new material, is prepared from by the raw material of following weight portion: Methacrylamide, 45～55 parts；
Maleimide, 35～45 parts；Polyvinyl alcohol, 20～30 parts；Aluminium hydroxide, 12～14 parts；Zinc fluosilicate, 6～8 parts；Live
Property carbon fiber, 10～14 parts；Kieselguhr, 15～25 parts；Fibroin, 2～4 parts；Sodium cocoyl glycinate, 3～5 parts；Trimerization
Sodium phosphate and sodium hexameta phosphate totally 7～9 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 6～8:1.
Further, described environmental protection air cleaning new material is prepared from by the raw material of following weight portion: Methacrylamide,
50 parts；Maleimide, 40 parts；Polyvinyl alcohol, 25 parts；Aluminium hydroxide, 13 parts；Zinc fluosilicate, 7 parts；Activated carbon
Fiber, 12 parts；Kieselguhr, 20 parts；Fibroin, 3 parts；Sodium cocoyl glycinate, 4 parts；Sodium tripolyphosphate and six inclined phosphorus
Totally 8 parts of sodium of acid, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 7:1.
Further, described environmental protection air cleaning new material is prepared from by the raw material of following weight portion: Methacrylamide,
45 parts；Maleimide, 35 parts；Polyvinyl alcohol, 20 parts；Aluminium hydroxide, 12 parts；Zinc fluosilicate, 6 parts；Activated carbon
Fiber, 10 parts；Kieselguhr, 15 parts；Fibroin, 2 parts；Sodium cocoyl glycinate, 3 parts；Sodium tripolyphosphate and six inclined phosphorus
Totally 7 parts of sodium of acid, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 6:1.
Further, described environmental protection air cleaning new material is prepared from by the raw material of following weight portion: Methacrylamide,
55 parts；Maleimide, 45 parts；Polyvinyl alcohol, 30 parts；Aluminium hydroxide, 14 parts；Zinc fluosilicate, 8 parts；Activated carbon
Fiber, 14 parts；Kieselguhr, 25 parts；Fibroin, 4 parts；Sodium cocoyl glycinate, 5 parts；Sodium tripolyphosphate and six inclined phosphorus
Totally 9 parts of sodium of acid, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 8:1.
The preparation method of above-mentioned environmental protection air cleaning new material, comprises the steps:
Step S1, weighs Methacrylamide, maleimide, polyvinyl alcohol, aluminium hydroxide, Zinc fluosilicate, activated carbon fibre
Dimension, kieselguhr, sodium cocoyl glycinate, sodium tripolyphosphate and sodium hexameta phosphate；
Step S2, uses wet ball-milling method by said components mix homogeneously, is incubated 2 hours under the conditions of 100～110 DEG C, add
Fibroin, stirs；
Step S3, heats at 200～210 DEG C, compressing, dries, to obtain final product.
Advantages of the present invention:
The air cleaning new material that the present invention provides has the air purification effect of excellence, and particularly with formaldehyde, clearance is the highest.
And, air cleaning new material of the present invention will not volatile organic compounds matter, environment protection health.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit scope with this.To the greatest extent
The present invention is explained in detail by pipe with reference to preferred embodiment, it will be understood by those within the art that, can be to the present invention
Technical scheme modify or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: the preparation of air cleaning new material
Parts by weight of raw materials compares:
Methacrylamide, 50 parts；Maleimide, 40 parts；Polyvinyl alcohol, 25 parts；Aluminium hydroxide, 13 parts；Fluorine silicon
Acid zinc, 7 parts；Activated carbon fiber, 12 parts；Kieselguhr, 20 parts；Fibroin, 3 parts；Sodium cocoyl glycinate, 4 parts；
Sodium tripolyphosphate and sodium hexameta phosphate totally 8 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 7:1.
Preparation method:
Step S1, weighs Methacrylamide, maleimide, polyvinyl alcohol, aluminium hydroxide, Zinc fluosilicate, activated carbon fibre
Dimension, kieselguhr, sodium cocoyl glycinate, sodium tripolyphosphate and sodium hexameta phosphate；
Step S2, uses wet ball-milling method by said components mix homogeneously, is incubated 2 hours under the conditions of 105 DEG C, add silk egg
In vain, stir；
Step S3, heats at 205 DEG C, compressing, dries, to obtain final product.
Embodiment 2: the preparation of air cleaning new material
Parts by weight of raw materials compares:
Methacrylamide, 45 parts；Maleimide, 35 parts；Polyvinyl alcohol, 20 parts；Aluminium hydroxide, 12 parts；Fluorine silicon
Acid zinc, 6 parts；Activated carbon fiber, 10 parts；Kieselguhr, 15 parts；Fibroin, 2 parts；Sodium cocoyl glycinate, 3 parts；
Sodium tripolyphosphate and sodium hexameta phosphate totally 7 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 6:1.
Preparation method:
Step S1, weighs Methacrylamide, maleimide, polyvinyl alcohol, aluminium hydroxide, Zinc fluosilicate, activated carbon fibre
Dimension, kieselguhr, sodium cocoyl glycinate, sodium tripolyphosphate and sodium hexameta phosphate；
Step S2, uses wet ball-milling method by said components mix homogeneously, is incubated 2 hours under the conditions of 105 DEG C, add silk egg
In vain, stir；
Step S3, heats at 205 DEG C, compressing, dries, to obtain final product.
Embodiment 3: the preparation of air cleaning new material
Parts by weight of raw materials compares:
Methacrylamide, 55 parts；Maleimide, 45 parts；Polyvinyl alcohol, 30 parts；Aluminium hydroxide, 14 parts；Fluorine silicon
Acid zinc, 8 parts；Activated carbon fiber, 14 parts；Kieselguhr, 25 parts；Fibroin, 4 parts；Sodium cocoyl glycinate, 5 parts；
Sodium tripolyphosphate and sodium hexameta phosphate totally 9 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 8:1.
Preparation method:
Step S1, weighs Methacrylamide, maleimide, polyvinyl alcohol, aluminium hydroxide, Zinc fluosilicate, activated carbon fibre
Dimension, kieselguhr, sodium cocoyl glycinate, sodium tripolyphosphate and sodium hexameta phosphate；
Step S2, uses wet ball-milling method by said components mix homogeneously, is incubated 2 hours under the conditions of 105 DEG C, add silk egg
In vain, stir；
Step S3, heats at 205 DEG C, compressing, dries, to obtain final product.
Embodiment 4: the preparation of air cleaning new material
Parts by weight of raw materials compares:
Methacrylamide, 50 parts；Maleimide, 40 parts；Polyvinyl alcohol, 25 parts；Aluminium hydroxide, 13 parts；Fluorine silicon
Acid zinc, 7 parts；Activated carbon fiber, 12 parts；Kieselguhr, 20 parts；Fibroin, 3 parts；Sodium cocoyl glycinate, 4 parts；
Sodium tripolyphosphate and sodium hexameta phosphate totally 8 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 6:1.
Preparation method:
Step S1, weighs Methacrylamide, maleimide, polyvinyl alcohol, aluminium hydroxide, Zinc fluosilicate, activated carbon fibre
Dimension, kieselguhr, sodium cocoyl glycinate, sodium tripolyphosphate and sodium hexameta phosphate；
Step S2, uses wet ball-milling method by said components mix homogeneously, is incubated 2 hours under the conditions of 105 DEG C, add silk egg
In vain, stir；
Step S3, heats at 205 DEG C, compressing, dries, to obtain final product.
Embodiment 5: the preparation of air cleaning new material
Parts by weight of raw materials compares:
Methacrylamide, 50 parts；Maleimide, 40 parts；Polyvinyl alcohol, 25 parts；Aluminium hydroxide, 13 parts；Fluorine silicon
Acid zinc, 7 parts；Activated carbon fiber, 12 parts；Kieselguhr, 20 parts；Fibroin, 3 parts；Sodium cocoyl glycinate, 4 parts；
Sodium tripolyphosphate and sodium hexameta phosphate totally 8 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 8:1.
Preparation method:
Step S1, weighs Methacrylamide, maleimide, polyvinyl alcohol, aluminium hydroxide, Zinc fluosilicate, activated carbon fibre
Dimension, kieselguhr, sodium cocoyl glycinate, sodium tripolyphosphate and sodium hexameta phosphate；
Step S2, uses wet ball-milling method by said components mix homogeneously, is incubated 2 hours under the conditions of 105 DEG C, add silk egg
In vain, stir；
Step S3, heats at 205 DEG C, compressing, dries, to obtain final product.
Embodiment 6: comparative example, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 5:1
Parts by weight of raw materials compares:
Methacrylamide, 50 parts；Maleimide, 40 parts；Polyvinyl alcohol, 25 parts；Aluminium hydroxide, 13 parts；Fluorine silicon
Acid zinc, 7 parts；Activated carbon fiber, 12 parts；Kieselguhr, 20 parts；Fibroin, 3 parts；Sodium cocoyl glycinate, 4 parts；
Sodium tripolyphosphate and sodium hexameta phosphate totally 8 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 5:1.
Preparation method:
Step S1, weighs Methacrylamide, maleimide, polyvinyl alcohol, aluminium hydroxide, Zinc fluosilicate, activated carbon fibre
Dimension, kieselguhr, sodium cocoyl glycinate, sodium tripolyphosphate and sodium hexameta phosphate；
Step S2, uses wet ball-milling method by said components mix homogeneously, is incubated 2 hours under the conditions of 105 DEG C, add silk egg
In vain, stir；
Step S3, heats at 205 DEG C, compressing, dries, to obtain final product.
Embodiment 7: comparative example, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 9:1
Parts by weight of raw materials compares:
Methacrylamide, 50 parts；Maleimide, 40 parts；Polyvinyl alcohol, 25 parts；Aluminium hydroxide, 13 parts；Fluorine silicon
Acid zinc, 7 parts；Activated carbon fiber, 12 parts；Kieselguhr, 20 parts；Fibroin, 3 parts；Sodium cocoyl glycinate, 4 parts；
Sodium tripolyphosphate and sodium hexameta phosphate totally 8 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 9:1.
Preparation method:
Step S1, weighs Methacrylamide, maleimide, polyvinyl alcohol, aluminium hydroxide, Zinc fluosilicate, activated carbon fibre
Dimension, kieselguhr, sodium cocoyl glycinate, sodium tripolyphosphate and sodium hexameta phosphate；
Step S2, uses wet ball-milling method by said components mix homogeneously, is incubated 2 hours under the conditions of 105 DEG C, add silk egg
In vain, stir；
Step S3, heats at 205 DEG C, compressing, dries, to obtain final product.
Embodiment 8: effect example
The performance test results that embodiment 1～7 prepares environmental protection material for air purification is as shown in the table:
| Absorbance (24h) to the formaldehyde that concentration is 4ppm | |
| Embodiment 1 | 99.9% |
| Embodiment 4 | 99.6% |
| Embodiment 5 | 99.7% |
| Embodiment 6 | 72.4 |
| Embodiment 7 | 70.8 |
The effect of embodiment 2,3 is basically identical with embodiment 4,5.
The above results shows, the material for air purification that the present invention provides has the air cleaning performance of excellence, as a example by formaldehyde, right
The absorbance of formaldehyde nearly reaches 100%.This performance may have with sodium tripolyphosphate in raw material and sodium hexameta phosphate weight part ratio
Closing, when sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 6～8:1, clean-up effect is optimum.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit protection scope of the present invention with this.
It will be understood by those within the art that, technical scheme can be modified or equivalent, and not take off
Essence and protection domain from technical solution of the present invention.
Claims (5)
1. an environmental protection air cleaning new material, it is characterised in that be prepared from by the raw material of following weight portion: metering system
Amide, 45～55 parts；Maleimide, 35～45 parts；Polyvinyl alcohol, 20～30 parts；Aluminium hydroxide, 12～14 parts；Fluorine silicon
Acid zinc, 6～8 parts；Activated carbon fiber, 10～14 parts；Kieselguhr, 15～25 parts；Fibroin, 2～4 parts；Cocos nucifera oil acyl glycine
Sodium, 3～5 parts；Sodium tripolyphosphate and sodium hexameta phosphate totally 7～9 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 6～8:1.
Environmental protection air cleaning new material the most according to claim 1, it is characterised in that by the raw material system of following weight portion
For forming: Methacrylamide, 50 parts；Maleimide, 40 parts；Polyvinyl alcohol, 25 parts；Aluminium hydroxide, 13 parts；
Zinc fluosilicate, 7 parts；Activated carbon fiber, 12 parts；Kieselguhr, 20 parts；Fibroin, 3 parts；Sodium cocoyl glycinate, 4
Part；Sodium tripolyphosphate and sodium hexameta phosphate totally 8 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 7:1.
Environmental protection air cleaning new material the most according to claim 1, it is characterised in that by the raw material system of following weight portion
For forming: Methacrylamide, 45 parts；Maleimide, 35 parts；Polyvinyl alcohol, 20 parts；Aluminium hydroxide, 12 parts；
Zinc fluosilicate, 6 parts；Activated carbon fiber, 10 parts；Kieselguhr, 15 parts；Fibroin, 2 parts；Sodium cocoyl glycinate, 3
Part；Sodium tripolyphosphate and sodium hexameta phosphate totally 7 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 6:1.
Environmental protection air cleaning new material the most according to claim 1, it is characterised in that by the raw material system of following weight portion
For forming: Methacrylamide, 55 parts；Maleimide, 45 parts；Polyvinyl alcohol, 30 parts；Aluminium hydroxide, 14 parts；
Zinc fluosilicate, 8 parts；Activated carbon fiber, 14 parts；Kieselguhr, 25 parts；Fibroin, 4 parts；Sodium cocoyl glycinate, 5
Part；Sodium tripolyphosphate and sodium hexameta phosphate totally 9 parts, sodium tripolyphosphate and sodium hexameta phosphate weight part ratio are 8:1.
5. the preparation method of the arbitrary described environmental protection air cleaning new material of Claims 1 to 4, it is characterised in that comprise the steps:
Step S1, weighs Methacrylamide, maleimide, polyvinyl alcohol, aluminium hydroxide, Zinc fluosilicate, activated carbon fibre
Dimension, kieselguhr, sodium cocoyl glycinate, sodium tripolyphosphate and sodium hexameta phosphate；
Step S2, uses wet ball-milling method by said components mix homogeneously, is incubated 2 hours under the conditions of 100～110 DEG C, add
Fibroin, stirs；
Step S3, heats at 200～210 DEG C, compressing, dries, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610393944.9A CN105854525A (en) | 2016-06-03 | 2016-06-03 | Novel environment-friendly air purifying material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610393944.9A CN105854525A (en) | 2016-06-03 | 2016-06-03 | Novel environment-friendly air purifying material and preparation method thereof |
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| CN105854525A true CN105854525A (en) | 2016-08-17 |
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| CN201610393944.9A Pending CN105854525A (en) | 2016-06-03 | 2016-06-03 | Novel environment-friendly air purifying material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108187469A (en) * | 2017-12-01 | 2018-06-22 | 杭州凯博特环保科技开发有限公司 | The formaldehyde scavenger of environmental type |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130309927A1 (en) * | 2012-05-18 | 2013-11-21 | Juzer Jangbarwala | Composite Porous Fibrous Dehumidifying Material |
| CN104017542A (en) * | 2014-05-20 | 2014-09-03 | 兰州旭照生物科技有限责任公司 | Environment-friendly type dust capturing agent |
| CN104707581A (en) * | 2015-03-13 | 2015-06-17 | 苏州能华节能环保科技有限公司 | Environment-protecting air purification material and preparation method thereof |
| CN105001578A (en) * | 2015-07-27 | 2015-10-28 | 合肥忠豪新材料有限公司 | Green and environment-friendly porous material and preparation method thereof |
-
2016
- 2016-06-03 CN CN201610393944.9A patent/CN105854525A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130309927A1 (en) * | 2012-05-18 | 2013-11-21 | Juzer Jangbarwala | Composite Porous Fibrous Dehumidifying Material |
| CN104017542A (en) * | 2014-05-20 | 2014-09-03 | 兰州旭照生物科技有限责任公司 | Environment-friendly type dust capturing agent |
| CN104707581A (en) * | 2015-03-13 | 2015-06-17 | 苏州能华节能环保科技有限公司 | Environment-protecting air purification material and preparation method thereof |
| CN105001578A (en) * | 2015-07-27 | 2015-10-28 | 合肥忠豪新材料有限公司 | Green and environment-friendly porous material and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108187469A (en) * | 2017-12-01 | 2018-06-22 | 杭州凯博特环保科技开发有限公司 | The formaldehyde scavenger of environmental type |
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Application publication date: 20160817 |
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