CN104707288A - Negative ion activated liquid and preparation method thereof - Google Patents

Negative ion activated liquid and preparation method thereof Download PDF

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Publication number
CN104707288A
CN104707288A CN201510135456.3A CN201510135456A CN104707288A CN 104707288 A CN104707288 A CN 104707288A CN 201510135456 A CN201510135456 A CN 201510135456A CN 104707288 A CN104707288 A CN 104707288A
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China
Prior art keywords
nano
active liquid
tourmaline powder
stone flour
anion active
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Pending
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CN201510135456.3A
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Chinese (zh)
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耿建平
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Individual
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/14Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/22Ionisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/44Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/58Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/406Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/91Bacteria; Microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation

Abstract

The invention discloses a negative ion activated liquid and a preparation method thereof, and aims to solve the problems that in the prior art a scavenging agent has toxicity self, is poor in toxic gas removal effect, cannot kill viruses or mold and is insufficient in smell removal property, and solves the problems of the prior art. The negative ion activated liquid comprises the following components in percentage by weight: 2-10% of nano radiobarite powder, 2-8% of nano titanium dioxide, 1-5% of nano tourmaline powder and 85-94% of pure water, wherein the sum of the weight percentages of the components is 100%. By adopting the technical scheme, the problems in the prior art can be solved.

Description

A kind of anion active liquid and preparation method thereof
Technical field
The present invention relates to field of Environment Protection, be specifically related to a kind of anion active liquid and preparation method thereof.
Technical field
the material of a large amount of toxic gases, particularly formaldehyde, TOVC and the serious harm such as amine, benzene homologues health generally can be produced after home improvement.This just make people need after having fitted up house ventilate just can move in for a long time, even and if ventilate can not avoid for a long time still remaining noxious material in house.In prior art, the general formaldehyde scavenger that adopts carries out the clear of toxic gas to the house after finishing, but general formaldehyde scavenger exists self also with certain toxicity, and can not well killing pathogenic bacteria and mould, and does not possess the ability of removal peculiar smell.
Summary of the invention
The invention provides a kind of anion active liquid and preparation method thereof, have self be not with toxicity, remove toxic gas effective, can killing pathogenic bacteria and mould, the advantage of peculiar smell can also be removed simultaneously, solve the problem of prior art.
A kind of anion active liquid, comprising: percentage by weight be 2 ~ 10% nanometer Peitou stone flour, the nano titanium oxide of 2% ~ 8%, the nano-tourmaline powder of 1% ~ 5% and 85 ~ 94% water, wherein, above-mentioned each weight percentages of components sum is 100%.
Particularly, the specification of described nanometer Peitou stone flour, nano titanium oxide and nano-tourmaline powder is 10 ~ 30 nanometers.
More specifically, described water is pure water.
Particularly, the pH value scope of anion active liquid is 5 ~ 8.
Preferably, a kind of anion active liquid, comprise percentage by weight be 4% nanometer Peitou stone flour, the nano titanium oxide of 4%, the nano-tourmaline powder of 2% and 90% pure water.
The preparation method of above-mentioned a kind of anion active liquid is:
(1) respectively Peitou stone flour, titanium dioxide and tourmaline powder are ground by nano-colloid grinder;
(2) according to above-mentioned steps, nano-colloid grinder grinding 10 ~ 24 hours, reaches 10 ~ 30 nanometers;
(3) by specification in step (2) at the Peitou stone flour of 10 ~ 30 nanometers, titanium dioxide, tourmaline powder and pure water according to above-mentioned formulation ratio;
(4) adjust pH value, make pH value scope between 5 ~ 8;
(5) be heated to 30 ~ 80 degrees Celsius and stir, obtained described anion active liquid.
Described nanometer Peitou stone flour anion releasing, it is more stable that described nano titanium oxide makes the anion of nanometer Peitou stone flour discharge, and tourmaline powder has higher anion generation and far infrared transmissivity.
The mechanism of action of the present invention is: after anion is combined with bacterium, makes bacterium produce the change of structure or the transfer of energy, causes bacterial death, final settlement ground.
Using method of the present invention: namely spray in house, or be sprayed on metope.
The present invention compared with prior art, has the following advantages:
(1) anion active liquid of the present invention all can discharge natural anion under the effect of natural daylight and light, release far infrared, the effect having killing pathogenic bacteria and purify air, the pollutants such as effective degradation of formaldehyde, benzene homologues, ammonia, TOVC.
(2) the present invention can effective degradation of contaminant, makes indoor negative ion concentration reach 1000 ~ 3000 every square centimeter.
(3) the present invention is in mechanism, and anion itself can not change and consume, and under the irradiation of light evaporated product function continuously, there is action time permanent and continuable advantage.
(4) the present invention is harmless, and the product that the degraded of pollutant is final is carbon dioxide, water and other innocuous substances, can not produce secondary pollution, and the toxin discharged by fungi decomposes harmless treatment.
(5) through the present invention spray process metope, light irradiate under there is Superhydrophilic and good self-cleaning function.
Detailed description of the invention
The object of the invention is to the defect overcoming prior art, a kind of anion active liquid and preparation method thereof is provided, below in conjunction with embodiment, the present invention is described in further detail.
A kind of anion active liquid, comprising percentage by weight is the Peitou stone flour of 2 ~ 10%, titanium dioxide, the tourmaline powder of 1% ~ 5%, the pure water of 85 ~ 94% of 2% ~ 8%.Wherein, above-mentioned each weight percentages of components sum is 100%.Wherein, the specification of Peitou stone flour, titanium dioxide and tourmaline powder is all in 10 ~ 30 nanometer range.
A kind of anion active liquid, its preparation method is as follows:
(1) respectively Peitou stone flour, titanium dioxide and tourmaline powder are ground by nano-colloid grinder;
(2) according to above-mentioned steps, nano-colloid grinder grinding 10 ~ 24 hours, reaches 10 ~ 30 nanometers;
(3) according to step (2), get grinding after percentage by weight be 2 ~ 10% Peitou stone flour, the titanium dioxide of 2 ~ 8%, the tourmaline powder of 1 ~ 5% and 85 ~ 94% pure water carry out proportioning;
(4) adjust PH to refer to, make pH value scope between 5 ~ 8;
(5) be heated to 30 ~ 80 degrees Celsius and stir, obtained described anion active liquid.
Embodiment 1
A kind of anion active liquid, comprise percentage by weight be 2% Peitou stone flour, the titanium dioxide of 2%, the tourmaline powder of 2% and 94% pure water.Wherein, above-mentioned Peitou stone flour, titanium dioxide and tourmaline powder are all in 10 ~ 30 nanometer range.
Embodiment 2
A kind of anion active liquid, comprise percentage by weight be 10% Peitou stone flour, the titanium dioxide of 4%, the tourmaline powder of 1% and 85% pure water.Wherein, above-mentioned Peitou stone flour, titanium dioxide and tourmaline powder are all in 10 ~ 30 nanometer range.
Embodiment 3
A kind of anion active liquid, comprise percentage by weight be 2% Peitou stone flour, the titanium dioxide of 8%, the tourmaline powder of 5% and 85% pure water.Wherein, above-mentioned Peitou stone flour, titanium dioxide and tourmaline powder are all in 10 ~ 30 nanometer range.
Embodiment 4
A kind of anion active liquid, comprise percentage by weight be 4% Peitou stone flour, the titanium dioxide of 4%, the tourmaline powder of 2% and 90% pure water.Wherein, above-mentioned Peitou stone flour, titanium dioxide and tourmaline powder are all in 10 ~ 30 nanometer range.
Embodiment 5
A kind of anion active liquid, comprise percentage by weight be 7% Peitou stone flour, the titanium dioxide of 3%, the tourmaline powder of 1% and 89% pure water.Wherein, above-mentioned Peitou stone flour, titanium dioxide and tourmaline powder are all in 10 ~ 30 nanometer range.
Embodiment 6
A kind of anion active liquid, comprise percentage by weight be 3% Peitou stone flour, the titanium dioxide of 3%, the tourmaline powder of 3% and 91% pure water.Wherein, above-mentioned Peitou stone flour, titanium dioxide and tourmaline powder are all in 10 ~ 30 nanometer range.
Embodiment 7
A kind of anion active liquid, comprise percentage by weight be 5% Peitou stone flour, the titanium dioxide of 6%, the tourmaline powder of 4% and 85% pure water.Wherein, above-mentioned Peitou stone flour, titanium dioxide and tourmaline powder are all in 10 ~ 30 nanometer range.
Embodiment 8
A kind of anion active liquid, comprise percentage by weight be 6% Peitou stone flour, the titanium dioxide of 4%, the tourmaline powder of 3% and 87% pure water.Wherein, above-mentioned Peitou stone flour, titanium dioxide and tourmaline powder are all in 10 ~ 30 nanometer range.
According to above-described embodiment, formula carries out testing drawn data:
1. in 9 closed glass casees, inject a certain amount of formaldehyde, put into sample and a common formaldehyde scavenger sample of embodiment 1 ~ 8 respectively, draw concentration of formaldehyde variable quantity:
Initial concentration of formaldehyde Concentration of formaldehyde after injection sample 3h Concentration of formaldehyde after injection sample 6h Concentration of formaldehyde after injection sample 12h
Embodiment 1 0.03mg/ml 0.12mg/ml 0.09mg/ml 0.05mg/ml
Embodiment 2 0.3mg/ml 0.13mg/ml 0.07mg/ml 0.04mg/ml
Embodiment 3 0.3mg/ml 0.12mg/ml 0.06mg/ml 0.04mg/ml
Embodiment 4 0.3mg/ml 0.09mg/ml 0.03mg/ml 0.02mg/ml
Embodiment 5 0.3mg/ml 0.11mg/ml 0.07mg/ml 0.03mg/ml
Embodiment 6 0.3mg/ml 0.14mg/ml 0.10mg/ml 0.06mg/ml
Embodiment 7 0.3mg/ml 0.10mg/ml 0.06mg/ml 0.04mg/ml
Embodiment 8 0.3mg/ml 0.12mg/ml 0.06mg/ml 0.03mg/ml
Formaldehyde scavenger 0.3mg/ml 0.18mg/ml 0.12mg/ml 0.09mg/ml
2. the sample of embodiment 1 ~ 8 being sprayed on respectively 8 specifications is on the paper of 20cm*30cm, puts into determination experiment case negative ion concentration after the experimental box 24h of 8 60L respectively:
Negative ion concentration (individual/cubic centimetre) after 24h
Embodiment 1 1800
Embodiment 2 2200
Embodiment 3 2300
Embodiment 4 2800
Embodiment 5 2300
Embodiment 6 1500
Embodiment 7 2400
Embodiment 8 2500
Content of the present invention is not limited to cited by embodiment, and the conversion of those of ordinary skill in the art by reading description of the present invention to any equivalence that technical solution of the present invention is taked, is claim of the present invention and contains.

Claims (7)

1. an anion active liquid, is characterized in that, comprise percentage by weight be 2 ~ 10% Peitou stone flour, the titanium dioxide of 2% ~ 8%, the tourmaline powder of 1% ~ 5% and 85 ~ 94% water, wherein, above-mentioned each weight percentages of components sum is 100%.
2. a kind of anion active liquid according to claim 1, is characterized in that, described Peitou stone flour is nanometer Peitou stone flour, and described titanium dioxide is nano titanium oxide, and described tourmaline powder is nano-tourmaline powder.
3. according to a kind of anion active liquid that claim 2 is stated, it is characterized in that, the specification of described nanometer Peitou stone flour, nano titanium oxide and nano-tourmaline powder is 10 ~ 30 nanometers.
4. a kind of anion active liquid according to any one of claim 1 ~ 3, is characterized in that, described water is pure water.
5. a kind of anion active liquid according to any one of claim 1 ~ 3, is characterized in that, the pH value scope of anion active liquid is 5 ~ 8.
6. a kind of anion active liquid according to claim 4, is characterized in that, comprise percentage by weight be 4% nanometer Peitou stone flour, the nano titanium oxide of 4%, the nano-tourmaline powder of 2% and 90% pure water.
7. a preparation method for anion active liquid, is characterized in that, step is as follows:
(1) respectively Peitou stone flour, titanium dioxide and tourmaline powder are ground by nano-colloid grinder;
(2) according to above-mentioned steps, nano-colloid grinder grinding 10 ~ 24 hours, reaches 10 ~ 30 nanometers;
(3) according to step (2), get grinding after percentage by weight be 2 ~ 10% Peitou stone flour, the titanium dioxide of 2 ~ 8%, the tourmaline powder of 1 ~ 5% and 85 ~ 94% pure water carry out proportioning;
(4) adjust pH value, make pH value scope between 5 ~ 8;
(5) be heated to 30 ~ 80 degrees Celsius and stir, obtained described anion active liquid.
CN201510135456.3A 2015-03-26 2015-03-26 Negative ion activated liquid and preparation method thereof Pending CN104707288A (en)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107433124A (en) * 2017-09-22 2017-12-05 太仓弘杉环保科技有限公司 A kind of anion biomass aldehyde remover
CN108559343A (en) * 2018-05-10 2018-09-21 重庆交通大学 Antibacterial environment protection coating and preparation method thereof
CN108912747A (en) * 2017-04-18 2018-11-30 吴瑛 For glass or the anion coating of rupture pressure disc and preparation method thereof
CN110523264A (en) * 2018-01-11 2019-12-03 广州市纳能环保技术开发有限公司 A kind of spray and preparation method thereof increasing indoor negative ion concentration

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1478755A (en) * 2003-06-24 2004-03-03 北京天之岩健康科技有限公司 Negative ion air purifying material and its preparation method
CN1861705A (en) * 2006-06-13 2006-11-15 上海弘康科技发展有限公司 Multifunctional environment protection health novel paint additive and preparation process thereof
CN101569756A (en) * 2008-05-03 2009-11-04 郭柯鸣 Pioneering catalyst (air comprehensive improver) and production method thereof
CN102702834A (en) * 2012-01-12 2012-10-03 上海韬鸿化工科技有限公司 Healthy anion coating
CN103468042A (en) * 2013-09-29 2013-12-25 杨奠基 Interior wall latex paint with anion releasing function, far infrared function and formaldehyde removing function and preparing method thereof
CN103933590A (en) * 2013-01-17 2014-07-23 陕西百业腾达实业有限责任公司 Fluctuant anion mineral powder and manufacturing method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1478755A (en) * 2003-06-24 2004-03-03 北京天之岩健康科技有限公司 Negative ion air purifying material and its preparation method
CN1861705A (en) * 2006-06-13 2006-11-15 上海弘康科技发展有限公司 Multifunctional environment protection health novel paint additive and preparation process thereof
CN101569756A (en) * 2008-05-03 2009-11-04 郭柯鸣 Pioneering catalyst (air comprehensive improver) and production method thereof
CN102702834A (en) * 2012-01-12 2012-10-03 上海韬鸿化工科技有限公司 Healthy anion coating
CN103933590A (en) * 2013-01-17 2014-07-23 陕西百业腾达实业有限责任公司 Fluctuant anion mineral powder and manufacturing method thereof
CN103468042A (en) * 2013-09-29 2013-12-25 杨奠基 Interior wall latex paint with anion releasing function, far infrared function and formaldehyde removing function and preparing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108912747A (en) * 2017-04-18 2018-11-30 吴瑛 For glass or the anion coating of rupture pressure disc and preparation method thereof
CN107433124A (en) * 2017-09-22 2017-12-05 太仓弘杉环保科技有限公司 A kind of anion biomass aldehyde remover
CN110523264A (en) * 2018-01-11 2019-12-03 广州市纳能环保技术开发有限公司 A kind of spray and preparation method thereof increasing indoor negative ion concentration
CN108559343A (en) * 2018-05-10 2018-09-21 重庆交通大学 Antibacterial environment protection coating and preparation method thereof

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