CN105838947B - Ultra-high strength wear-resisting aluminum alloy material and production process thereof - Google Patents

Ultra-high strength wear-resisting aluminum alloy material and production process thereof Download PDF

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Publication number
CN105838947B
CN105838947B CN201610383637.2A CN201610383637A CN105838947B CN 105838947 B CN105838947 B CN 105838947B CN 201610383637 A CN201610383637 A CN 201610383637A CN 105838947 B CN105838947 B CN 105838947B
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aluminium
aluminum alloy
alloy material
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ultra
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CN105838947A (en
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薛元良
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Shandong Kaiyi New Materials Technology Co.,Ltd.
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/10Alloys based on aluminium with zinc as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/002Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working by rapid cooling or quenching; cooling agents used therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/053Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with zinc as the next major constituent

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Gears, Cams (AREA)
  • Conductive Materials (AREA)

Abstract

The invention discloses an ultra-high strength wear-resisting aluminum alloy material and a production process thereof. The ultra-high strength wear-resisting aluminum alloy material is formed by smelting aluminum, copper, magnesium, zinc, neodymium, zirconium, nickel and titanium. The aluminum alloy material comprises, by weight, 0-0.7% of Si, 0-0.5% of Fe, 1.6%-2.9% of Cu, 0.1%-0.3% of Mn, 1.8%-2.9% of Mg, 0.05%-0.20% of Zr, 7.0%-13.5% of Zn, 0.01%-0.07% of Ti, 0.2%-1.3% of Nd and the balance Al. The ultra-high strength wear-resisting aluminum alloy material has the advantages of being low in weight, high in strength, good in wear-resisting property and low in cost, can be widely used for manufacturing transmission synchronizing tooth rings and other automobile parts, and meanwhile can be applied to the fields of aviation, aerospace, unmanned aerial vehicles, autonomous underwater vehicles and the like.

Description

A kind of anti-wear-resistant aluminium alloy material of superhigh intensity and its production technology
Technical field
The present invention relates to a kind of anti-wear-resistant aluminium alloy material of superhigh intensity, concretely relate to a kind of superhigh intensity resist it is resistance to The aluminium alloy for speed changer synchronizing tooth ring of mill, while being also applied for superhigh intensity, the field of the aluminum alloy materials of lightweight.Example Such as:Aeronautics and Astronautics, unmanned plane, underwater vehicle etc..
Background technology
It is well known that at present speed changer synchronizing tooth ring great majority are manufactured using copper alloy, Chinese only this project purposes is annual Copper material is consumed just up to more than 50,000 tons.Minority adopts steel making.But this steel is also easy to produce gluing when rubbing with steel, so using It is limited.There is presently no suitable aluminum alloy materials manufacture speed changer synchronizing tooth ring.Main cause is the intensity of existing aluminium alloy It is difficult to reach the requirement of manufacture speed changer synchronizing tooth ring with wearability.Will if satisfaction manufacture speed changer synchronizing tooth ring can be developed The aluminium alloy asked, is certain to be pursued and welcome by market.Because aluminium is lightweight, cost is calculated by volume than copper alloy cost It is low by more than 60%, economic benefit and market prospects it is very good.
The content of the invention
It is an object of the invention to provide a kind of anti-wear-resistant aluminium alloy material of superhigh intensity and its production technology, can have simultaneously Superhigh intensity and anti-wear satisfaction manufacture the needs of speed changer synchronizing tooth ring.
In order to solve above-mentioned technical problem, inventor is eventually found by test of many times repetition test, trial-production, screening Solve the technical scheme of above-mentioned technical problem.
The present invention is achieved by the following technical solutions:A kind of anti-wear-resistant aluminium alloy material of superhigh intensity, its component Percentage by weight is:Si≤0.7%;Fe≤0.5%;Cu1.6~2.9%;Mn0.1~0.3%;Mg1.8~2.9%; Zr0.05~0.20%;Zn7.0~13.5%;Ti0.01~0.07%;Nd0.2~1.3%;Remaining is aluminium.MAT'L mark: 7Y69。
Compared with prior art, the invention has the beneficial effects as follows:The anti-wear-resistant aluminum alloy of superhigh intensity has lightweight, intensity High, anti-wear-resisting advantage, can be widely used for manufacturing speed changer synchronizing tooth ring and other auto parts and components.With very good Jing Ji benefit and social benefit.Also being provided to Aeronautics and Astronautics, unmanned plane and underwater vehicle etc. simultaneously needs to use superelevation strong Degree, and and need light-weighted field to apply.
Specific embodiment
The present invention is described in further detail with reference to specific embodiment:
The present invention uses wrought aluminium alloy chemical composition standard GB/T/T3190 and Cast aluminium alloy ingot country mark In quasi- GB/T8733 without formula, the anti-wear-resistant aluminum alloy of superhigh intensity of the present invention is by aluminium, copper, magnesium, zinc, neodymium, zirconium, nickel, titanium Element melting is made, and is carried out on aluminum alloy smelting furnace and casting unit.
1. first melting is carried out in aluminum alloy smelting furnace;
2. at a temperature of 710 DEG C -800 DEG C, aluminium ingot 76.5~the 85.7%, (copper of electrolytic copper plate 1.6~2.9% are initially charged Can also be in the form of aluminum bronze intermediary alloy), add zirconium 0.05~0.20%, after carry out melting;
3. temperature is risen to into 750 DEG C -810 DEG C after aluminium, copper, zirconium all dissolve, add magnesium 1.8~2.9% and zinc 7.0 ~13.5%, then carry out melting;
4. after aluminium, copper, zirconium, magnesium, zinc all melt and is interposed between together, titanium is added when temperature is risen to into 780 DEG C -830 DEG C 0.01~0.07% and neodymium 0.2~1.3%, after carry out melting;
5. treat that various composition is substantially dissolved in together, degasification deslagging refining is then carried out again;
6. by it is molten every aluminium alloy round casting rod or square ingot casting are cast on casting unit;
If being 7. cast into the aluminium that circle casting rod is just crushed to round casting rod manufacture speed changer synchronizing tooth ring using extruder Alloy pipe stock or bar stock.Need the sheet material of thickness same for manufacturing speed changer if the side's of being cast into ingot casting is just rolled into using milling train Step ring gear.
8. ingot casting is squeezed into after pipe, rod or sheet material carries out Quenching Treatment, and quenching is carried out in glowing furnace, and hardening heat is 455 DEG C -515 DEG C, the cool time is 3-5 hours, and the time uses cold water chilling to rear;
9. the material after Quenching Treatment is carried out again Ageing Treatment, timeliness is carried out in aging furnace, and aging temp is 120 DEG C -180 DEG C, aging time is 26-30 hours, and aging time is to rear material along with the furnace cooling.
The anti-wear-resistant aluminum alloy 7Y69 of superhigh intensity of the present invention may be cast processing, then extrude, forge and press, rolling and be processed into manufacture The blank pipe fitting of synchro converter ring, forging-ring or sheet material, then forged and machining is manufactured into synchro converter ring.
7Y69 tensile strength Jing after T6 process is more than 730MPa, and yield strength is more than 610MPa.(according to existing seamless aluminium tubing GB GB/T437.1-2000, tensile strength maximum is 7075T6:Its tensile strength is 560MPa to the maximum, and yield strength is maximum Be 7075T6:Its yield strength is 505MPa to the maximum.Existing aluminium bar GB GB/T3191-1998, tensile strength it is maximum be 7A09T6:Its tensile strength is 530MPa to the maximum, and yield strength maximum is 7A09T6:Its yield strength is 400MPa to the maximum), In sum, the above compares the advance for sufficing to show that 7Y69 aluminium alloys.
The preferably feasible embodiment of the above-mentioned only present invention, the non-therefore limitation scope of the present invention, according to above-described embodiment Made various modifications are applied mechanically equal here and are remembered within scheme protection domain.

Claims (1)

1. a kind of anti-wear-resistant aluminium alloy material of superhigh intensity, is characterized in that:The percentage by weight of aluminum alloy materials component is:Si≤ 0.7%;Fe≤0.5%;Cu 1.6~2.9%;Mn 0.1~0.3%;Mg 1.8~2.9%;Zr 0.05~0.20%;Zn 13.5%;Ti 0.01~0.07%; Nd 0.2~1.3%;Remaining is aluminium;
Production technology is as follows:
(1)Carry out melting in aluminum alloy smelting furnace first;
(2)At a temperature of 710 DEG C -800 DEG C, aluminium ingot 76.5~85.7% is initially charged, electrolytic copper plate 1.6~2.9% adds zirconium 0.05~0.20%, after carry out melting;
(3)Temperature is risen to into 750 DEG C -810 DEG C after aluminium, copper, zirconium all dissolve, magnesium 1.8~2.9% and zinc 13.5% is added, Melting is carried out again;
(4)After aluminium, copper, zirconium, magnesium, zinc all it is molten be interposed between together after, add when temperature is risen to into 780 DEG C -830 DEG C titanium 0.01~ 0.07% and neodymium 0.2~1.3%, after carry out melting;
(5)Treat that various composition is substantially dissolved in together, carry out degasification deslagging refining;
(6)By it is molten every aluminium alloy round casting rod or square ingot casting are cast on casting unit;
(7)Ingot casting is squeezed into after pipe, rod or sheet material carries out Quenching Treatment, and quenching is carried out in glowing furnace, and hardening heat is 455 DEG C -515 DEG C, the cool time is 3-5 hours, and the time uses cold water chilling to rear;
(8)Material after Quenching Treatment is carried out again Ageing Treatment, timeliness is carried out in aging furnace, aging temp be 120 DEG C- 180 DEG C, aging time is 26-30 hours, and aging time is to rear material along with the furnace cooling.
CN201610383637.2A 2016-06-02 2016-06-02 Ultra-high strength wear-resisting aluminum alloy material and production process thereof Active CN105838947B (en)

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CN108300915B (en) * 2018-01-24 2019-12-31 中南大学 Al-Zn-Mg-Cu aviation aluminum alloy and preparation method thereof
CN109622652A (en) * 2018-12-25 2019-04-16 安徽宏宇铝业有限公司 A kind of wear-resisting Extrusion Process of Aluminum Alloy Profile processing unit (plant)
CN111959608B (en) * 2020-08-14 2021-06-29 福建祥鑫股份有限公司 Aluminum alloy light truck crossbeam and preparation method thereof

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JPH0794698B2 (en) * 1990-05-18 1995-10-11 昭和アルミニウム株式会社 High strength aluminum alloy with excellent resistance to stress corrosion cracking
FR2838136B1 (en) * 2002-04-05 2005-01-28 Pechiney Rhenalu ALLOY PRODUCTS A1-Zn-Mg-Cu HAS COMPROMISED STATISTICAL CHARACTERISTICS / DAMAGE TOLERANCE IMPROVED
CN100590215C (en) * 2007-06-12 2010-02-17 中南大学 Neodymium or dysprosium containing anti-recrystallizing corrosion resistant aluminum alloy
CN105154729B (en) * 2015-09-29 2017-04-12 济南大学 Cast aluminum-zinc-magnesium-copper-tantalum alloy and manufacturing method thereof

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