CN103103414B - A kind of chromaking is processed the smelting preparation method of aluminium alloy extrusions - Google Patents

A kind of chromaking is processed the smelting preparation method of aluminium alloy extrusions Download PDF

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CN103103414B
CN103103414B CN201210530770.8A CN201210530770A CN103103414B CN 103103414 B CN103103414 B CN 103103414B CN 201210530770 A CN201210530770 A CN 201210530770A CN 103103414 B CN103103414 B CN 103103414B
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aluminium alloy
aluminium
melt
chromaking
alloy extrusions
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CN103103414A (en
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夏坤财
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Foshan juchuang home furnishing Co., Ltd
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Wuhu Hengkun Auto Parts Co Ltd
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Abstract

The invention discloses a kind of chromaking and process the smelting preparation method of aluminium alloy extrusions, include following operating procedure: (1) configuration aluminium alloy melt: by following raw materials in part by weight: 55-60? 6063 aluminium ingots, discarded aluminum products, 5-10 chromium carbide, the 5-7 glass dregs powder of 30-40 carry out proportioning, above-mentioned raw materials is added to smelting furnace, be warming up to furnace charge and start to soften while staying, sprinkle one deck coverture to molten surface and cover; After furnace charge melts completely, should suitably stir melt, so that temperature uniformity everywhere in molten bath adds magnesium ingot in the most backward melt; In feed proportioning of the present invention, add aluminium scrap material, be conducive to aluminium section bar stable performance, reduced the possibility that occurs not having the Effect of Materials aluminium section bar quality detecting when aluminium liquid is smelted; Aluminium alloy section surface is carried out to chromaking processing, improved the resistance to corrosion of aluminium alloy section surface oxide-film and the adhesion of aluminium alloy extrusions and coating.

Description

A kind of chromaking is processed the smelting preparation method of aluminium alloy extrusions
Technical field
The present invention relates to a kind of chromaking and process the smelting preparation method of aluminium alloy extrusions, belong to aluminum alloy materials process technologyField.
Background technology
Aluminium alloy is a most widely used class non-ferrous metal structural material in industry, at Aeronautics and Astronautics, automobile, machineIn tool manufacture, boats and ships, widely apply. Along with the develop rapidly of science and technology and industrial economy in recent years, rightThe demand of Welded structural member is increasing, makes the Research on Weldability of aluminium alloy also thereupon deeply. Aluminium alloyExtensive use promoted the development of aluminum alloy solder technology, aluminium alloy has been expanded again in the development of solder technology simultaneouslyApplication, therefore the solder technology of aluminium alloy is just becoming one of focus of research. Aluminium-plastic panel is by process tableFace processes and uses 3003 alumals, 5005 aluminium-magnesium alloy sheets of coating baking vanish as surface, and PE plastics are doneFor sandwich layer, macromolecule felted-membrane processes through series of process the new material being composited. Of the prior artAluminium alloy extrusions often there will be impurity content large in fusion process, the shortcomings such as whole complex technical process.
Summary of the invention
The melting preparation that provides a kind of chromaking to process aluminium alloy extrusions is provided for the deficiencies in the prior artMethod, the combination property of raising aluminium alloy extrusions.
The technical solution used in the present invention is as follows:
Chromaking is processed a smelting preparation method for aluminium alloy extrusions, it is characterized in that, includes following operating procedure:
(1) configuration aluminium alloy melt: by following raw materials in part by weight: 5052 aluminium ingot 55-65 parts, discarded aluminumProduct 32-42 part, boron carbide 5-10 part, nano ceramic powder 5-10 part are carried out proportioning, and above-mentioned raw materials is addedSmelting furnace, is warming up to furnace charge and starts to soften while staying, sprinkles one deck coverture cover to molten surface; Work as furnace chargeAfter fusing, should suitably stir melt completely, so that temperature uniformity everywhere in molten bath adds in the most backward meltEnter magnesium ingot; Controlling the quality percentage composition of each element in melt is: 0.18≤Si≤0.25%, 1.2≤Mg≤2.8%、0.12≤P≤0.20%、Sn0.20~0.30、0.20≤Fe≤0.42%、0.06≤Cu≤0.10%、0.06≤Mn≤0.12%, 0.05≤V≤0.15, Zn≤0.10%, other elements totals≤0.15, surplus areAl;
(2) refining: utilize refining agent to carry out refining treatment to aluminium alloy melt, when aluminium alloy melt is through refining placeReason, and claw after surface scum, melt can be infused into standing furnace, aluminium alloy melt rises after entering standing furnaceTemperature, to 700-750 DEG C of maintenance 20-30min, then utilizes argon gas by the hydrogen in aluminium alloy melt and fine impurities bandTo surface, thereby reduce the hydrogen content in aluminium liquid; Add 20-30Kg sodium removing agent by aluminium alloy melt per ton again,Described sodium removing agent is made up of following parts by weight of component: potassium chloride 50-60 part, magnesium chloride 30-40 part, sixChlorination two carbon 2-10 parts make aluminum alloy round casting rod after casting in standing furnace again;
(3) after the sawing of heat-treatable aluminum alloy circle casting rod, carry out homogenizing annealing processing, in inert gas, first heat upAt 300-320 DEG C, insulation 2-3 hour, a 70-90 per hour DEG C intensification is heated to be incubated 6-8 at 520-550 DEG CHour, then put into 300-320 DEG C of No. 200 solvent naphthas with oily slow cooling, then a 60-80 per hour DEG C intensification addsHeat is to 360-380 DEG C, and degree of insulation 5-6 hour; Be cooled to again at 150-180 DEG C and be incubated 3-4 hour;
(4) aluminum alloy round casting rod is heated to 450-500 DEG C by extrusion modling, then utilizes extruder to heatCircle casting rod extrusion molding from mould, extrusion die temperature 240-260 DEG C, extrusion speed 7-8 m/min; WindCold mould material surface temperature, after 100-130 DEG C, is put into 2-5 DEG C of water-based quenching liquid and is carried out Quenching Treatment 5-7 minute;The last aluminium alloy extrusions having pushed that takes out from water carries out normal temperature alignment processing, at 120-130 DEG C, is incubated 3-5Hour;
Aluminium alloy extrusions, after alignment is processed, is quenched to aluminium alloy extrusions, hardening heat 400-500 DEG C,The type of cooling is chosen as high wind and coordinates water smoke quench cooled, ensures to obtain high oversaturated solid solution in matrix;
(6) after extruding finishes, within 8 hours, aluminium alloy extrusions is carried out to Ageing Treatment, aging temp is165-185 DEG C, temperature retention time is 6-8h;
Section bar after Ageing Treatment is carried out to subzero treatment, and liquid nitrogen temperature is-125~-150 DEG C, subzero treatment timeBetween be 2-5 hour, the isothermal time in liquid nitrogen is: the cross-sectional area of section bar is multiplied by 2~3min/mm2, darkThe section bar that after cold treatment, temperature has been gone back up to room temperature is put into the boiling water of 100 DEG C and is heated 60-80 minute;
(8) chromaking is processed aluminium alloy extrusions through degreasing agent cleaning, the processing of chromaking agent chromaking.
The fineness of described boron carbide is 5-8 μ m.
Described heat treatment, carries out homogenizing annealing processing after aluminum alloy round ingot sawing, in inert gas, be first warming up toAt 300 DEG C, be incubated 2.5 hours, 80 DEG C of intensifications per hour are heated to be incubated 7 hours at 530 DEG C, then putIn entering in 300 DEG C of No. 200 solvent naphthas, with oily slow cooling, then 70 DEG C of intensifications per hour are heated to 370 DEG C, and insulationSpend 5.5 hours; Be cooled to again at 170 DEG C and be incubated 3.5 hours.
In feed proportioning of the present invention, add aluminium scrap material, because aluminium scrap material is through primary smelting, its stable components,Be conducive to aluminium section bar stable performance therefore increase aluminium scrap material in the present invention's formula, reduced when aluminium liquid is smelted and occurred notThere is the possibility of the Effect of Materials aluminium section bar quality of detection; The steps such as annealing in process, Quenching Treatment, alignment processing,Increase the uniformity of interior tissue and the refinement of crystal grain of aluminum, greatly improved the quality of aluminium alloy extrusionsWith processing characteristics; Aluminium alloy section surface is carried out to chromaking processing, improved aluminium alloy section surface oxide-filmThe adhesion of resistance to corrosion and aluminium alloy extrusions and coating.
Detailed description of the invention
Below in conjunction with executing example, the invention will be further described, but be not limited to the following example.
Chromaking is processed a smelting preparation method for aluminium alloy extrusions, includes following operating procedure:
(1) configuration aluminium alloy melt:
Press row weight portion (kilogram) raw material: 55 part of 5052 aluminium ingot, 32 parts of discarded aluminum products, 5 parts of boron carbides,5 parts of nano ceramic powders carry out proportioning, and the fineness of boron carbide is 5-8 μ m, and above-mentioned raw materials is added to smelting furnace,Be warming up to furnace charge and start to soften while staying, sprinkle one deck coverture to molten surface and cover; When furnace charge melts completelyAfter, should suitably stir melt, so that temperature uniformity everywhere in molten bath adds magnesium ingot in the most backward melt;Controlling the quality percentage composition of each element in melt is: 0.18%≤Si≤0.25%, 1.2%≤Mg≤2.8%,0.12%≤P≤0.20%、Sn0.20~0.30%、0.20%≤Fe≤0.42%、0.06%≤Cu≤0.10%、0.06%≤Mn≤0.12%, 0.05%≤V≤0.15, Zn≤0.10%, other elements add up to≤0.15, more thanAmount is Al;
(2) refining: utilize refining agent to carry out refining treatment to aluminium alloy melt, when aluminium alloy melt is through refining placeReason, and claw after surface scum, melt can be infused into standing furnace, aluminium alloy melt rises after entering standing furnaceTemperature, to 700-750 DEG C of maintenance 20-30min, then utilizes argon gas by the hydrogen in aluminium alloy melt and fine impurities bandTo surface, thereby reduce the hydrogen content in aluminium liquid; Add 30Kg sodium removing agent by aluminium alloy melt per ton again, instituteThe sodium removing agent of stating by following weight portion (kilogram) component mix form: potassium chloride 50, magnesium chloride 40, chlordeneChange two carbon 2, in standing furnace, after casting, make again aluminum alloy round casting rod;
(3) heat treatment
After the sawing of aluminum alloy round casting rod, carry out homogenizing annealing processing, in inert gas, be first warming up at 300 DEG C, insulation2.5 hours, 80 DEG C of intensifications per hour were heated to be incubated 7 hours at 530 DEG C, then put into 300 DEG C No. 200 moltenIn in agent oil with oily slow cooling to room temperature, then 70 DEG C of intensifications per hour are heated to 370 DEG C, and degree of insulation 5.5 hours;Be cooled to again at 170 DEG C and be incubated 3.5 hours;
(4) extrusion modling
Aluminum alloy round casting rod is heated to 450-500 DEG C, then utilize extruder by the round casting rod heating from mouldExtrusion molding, extrusion die temperature 240-260 DEG C, extrusion speed 7-8 m/min; Air-cooled section bar surface temperatureAfter 100-130 DEG C, put into 2-5 DEG C of water-based quenching liquid and carry out Quenching Treatment 5-7 minute; Finally from water, getThe aluminium alloy extrusions that goes out to have pushed carries out normal temperature alignment processing, at 120-130 DEG C, is incubated 3-5 hour;
(5) to aluminium alloy extrusions through alignment process after, aluminium alloy extrusions is quenched, hardening heat400-500 DEG C, the type of cooling is chosen as high wind and coordinates water smoke quench cooled, ensures to obtain high satiety in matrixWith solid solution;
(6) after extruding finishes, within 8 hours, aluminium alloy extrusions is carried out to Ageing Treatment, aging temp is165-185 DEG C, temperature retention time is 6-8h;
(7) section bar after Ageing Treatment is carried out to subzero treatment, liquid nitrogen temperature is-125~-150 DEG C, subzero treatmentTime be 2-5 hour, the isothermal time in liquid nitrogen is: the cross-sectional area of section bar is multiplied by 2~3min/mm2,The section bar that after subzero treatment, temperature has been gone back up to room temperature is put into the boiling water of 100 DEG C and is heated 60-80 minute;
(8) chromaking processing
Aluminium alloy extrusions is through degreasing agent cleaning, the processing of chromaking agent chromaking.
After testing, product chemical composition is: Si0.267%, Mg2.823%, Fe0.414%, Cu0.0604%, Mn0.0586%, Cr0.312%, Zn0.0856%, other elements add up to 0.121%, all the other are Al; Mechanical propertyFor: tensile strength is 314MPa, and yield strength is 263MPa, and percentage elongation is 16.8%; Surface property is:The local thickness 25 μ m of single-piece, sand trail barasion coefficient 559g/ μ m, drop alkali test 136s.

Claims (3)

1. chromaking is processed a smelting preparation method for aluminium alloy extrusions, it is characterized in that, includes following operating procedure:
(1) configuration aluminium alloy melt: by following raw materials in part by weight: 5052 aluminium ingot 55-65 parts, discarded aluminum products 32-42 part, boron carbide 5-10 part, nano ceramic powder 5-10 part are carried out proportioning, above-mentioned raw materials is added to smelting furnace, be warming up to furnace charge and start to soften while staying, sprinkle one deck coverture to molten surface and cover; After furnace charge melts completely, should suitably stir melt, so that temperature uniformity everywhere in molten bath adds magnesium ingot in the most backward melt; The quality percentage composition of controlling each element in melt is :≤Si≤0.25,1.2≤Mg≤2.8,0.12≤P≤0.20, Sn0.20~0.30,0.20≤Fe≤0.42,0.06≤Cu≤0.10,0.06≤Mn≤0.12,0.05≤V≤0.15, Zn≤0.10, other elements totals≤0.15, surplus are Al;
(2) refining: utilize refining agent to carry out refining treatment to aluminium alloy melt, when aluminium alloy melt is through refining treatment, and claw after surface scum, melt can be infused into standing furnace, aluminium alloy melt is warming up to 700-750 DEG C of maintenance 20-30min after entering standing furnace, then utilize argon gas to take the hydrogen in aluminium alloy melt and fine impurities to surface, thereby reduce the hydrogen content in aluminium liquid; Add 20-30Kg sodium removing agent by aluminium alloy melt per ton again, described sodium removing agent is made up of following parts by weight of component: potassium chloride 50-60 part, magnesium chloride 30-40 part, chlordeneization two carbon 2-10 parts make aluminum alloy round casting rod after casting in standing furnace again;
(3) after the sawing of heat-treatable aluminum alloy circle casting rod, carry out homogenizing annealing processing, in inert gas, be first warming up at 300-320 DEG C, insulation 2-3 hour, a 70-90 per hour DEG C intensification is heated to be incubated 6-8 hour at 520-550 DEG C, then put into 300-320 DEG C of No. 200 solvent naphthas with oily slow cooling, a 60-80 per hour DEG C intensification is heated to 360-380 DEG C again, and degree of insulation 5-6 hour; Be cooled to again at 150-180 DEG C and be incubated 3-4 hour;
(4) aluminum alloy round casting rod is heated to 450-500 DEG C by extrusion modling, then utilizes extruder by the round casting rod extrusion molding from mould heating, extrusion die temperature 240-260 DEG C, extrusion speed 7-8 m/min; Air-cooled section bar surface temperature, after 100-130 DEG C, is put into 2-5 DEG C of water-based quenching liquid and is carried out Quenching Treatment 5-7 minute; The last aluminium alloy extrusions having pushed that takes out from water carries out normal temperature alignment processing, at 120-130 DEG C, is incubated 3-5 hour;
(5) to aluminium alloy extrusions after alignment is processed, aluminium alloy extrusions is quenched, hardening heat 400-500 DEG C, the type of cooling is chosen as high wind and coordinates water smoke quench cooled, ensures to obtain high oversaturated solid solution in matrix;
(6) after extruding finishes, within 8 hours, aluminium alloy extrusions is carried out to Ageing Treatment, aging temp is 165-185 DEG C, and temperature retention time is 6-8h;
(7) section bar after Ageing Treatment is carried out to subzero treatment, liquid nitrogen temperature is-125~-150 DEG C, the time of subzero treatment is 2-5 hour, isothermal time in liquid nitrogen is: the cross-sectional area of section bar is multiplied by 2~3min/mm2, and the section bar that after subzero treatment, temperature has been gone back up to room temperature is put into the boiling water of 100 DEG C and heated 60-80 minute;
(8) chromaking is processed aluminium alloy extrusions through degreasing agent cleaning, the processing of chromaking agent chromaking.
2. a kind of chromaking according to claim 1 is processed the smelting preparation method of aluminium alloy extrusions, it is characterized in that, the fineness of described boron carbide is 5-8 μ m.
3. a kind of chromaking according to claim 1 is processed the smelting preparation method of aluminium alloy extrusions, it is characterized in that, described heat treatment, after the sawing of aluminum alloy round casting rod, carry out homogenizing annealing processing, in inert gas, be first warming up at 300 DEG C, be incubated 2.5 hours, 80 DEG C of intensifications per hour are heated to be incubated 7 hours at 530 DEG C, in 300 DEG C of No. 200 solvent naphthas, with oily slow cooling, then 70 DEG C of intensifications per hour are heated to 370 DEG C, and degree of insulation 5.5 hours; Be cooled to again at 170 DEG C and be incubated 3.5 hours.
CN201210530770.8A 2012-12-11 2012-12-11 A kind of chromaking is processed the smelting preparation method of aluminium alloy extrusions Expired - Fee Related CN103103414B (en)

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