CN105837881A - Transparent surface sealing wax for art painting - Google Patents
Transparent surface sealing wax for art painting Download PDFInfo
- Publication number
- CN105837881A CN105837881A CN201610299978.1A CN201610299978A CN105837881A CN 105837881 A CN105837881 A CN 105837881A CN 201610299978 A CN201610299978 A CN 201610299978A CN 105837881 A CN105837881 A CN 105837881A
- Authority
- CN
- China
- Prior art keywords
- parts
- transparent surface
- art painting
- surface sealing
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention discloses transparent surface sealing wax for art painting. The sealing wax is prepared from butadiene styrene rubber, polyethylene glycol, polyisobutene, ceramic powder, paraffin oil, adhesive, dimethicone, polyurethane, trimethylolpropane, sulfonated oil, stearic acid, antioxidant and styrenated phenol. The transparent surface sealing wax for art painting is excellent in durability, corrosion resistance and oxidation resistance, long in service life, and not prone to abrasion or fracture in use. The components of the sealing wax are matched scientifically and reasonably, the preparing method is safe and simple, and the sealing wax is suitable for large-scale industrial popularization.
Description
Technical field
The present invention relates to sealing field, be specifically related to a kind of Transparent surface sealing adhesive for art painting.
Background technology
Sealing is that one is filled in binding site, is used for preventing liquid from leaking, and reaches to seal, fill out
Fill in the liquid with liner effect and pasty masses.According to different mode classifications, can be divided into again
Multiclass: as divided according to contained dominant chemical, resinae, rubber-like, mixing can be divided into
High score subclass and natural polymer subclass；Can be divided into by range of application: heat resistant type, cold resisting type, resistance to
Die mould, water-resistant type and corrosion resistant type；It is divided into structure class and non-structural class by intensity；By solidification spy
Property be divided into solidification glue, uncured sealing and anaerobic sealing etc..In order to ensure sealing function,
General sealing should possess following key property: good pointing storage stability, nontoxic or low
Toxicity, liquidproof, gas or other media permeabilitys, do not peel off, weatherability, not efflorescence,
Cracking, dismission or excess shrinkage.
Transparent surface sealing adhesive for art painting on market is main former material with common rubber at present
Material, does not fully takes into account it in formula design process and uses medium and working condition, causes existing
Some transparent area sealings are the most remote at aspects such as persistency, corrosion-resistant, resistance to oxidation, service lifes
Far from satisfied use requirement, therefore finding a kind of Transparent surface sealing adhesive for art painting is to have very much
Necessary.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of Transparent surface sealing adhesive for art painting,
Make produced sealing have persistency long, corrosion-resistant, resistance to oxidation, service life length spy
Point.
For realizing object above, the present invention is achieved by the following technical programs:
The invention provides a kind of Transparent surface sealing adhesive for art painting, former by following parts by weight
Material is prepared from: butadiene-styrene rubber: 30-70 part, Polyethylene Glycol: 12-40 part, polyisobutylene 12
-14 parts, ceramic 5-15 part, paraffin oil 1-8 part, adhesive 1-8 part, dimethicone
1-5 part, polyurethane 1-8 part, trimethylolpropane: 0.05-0.2 part, sulfonated oil: 6-15 part,
Stearic acid: 1-5 part, antioxidant: 2-5 part, styrenated phenol: 1-4.5 part.
Preferably, the raw material of following parts by weight it is prepared from: butadiene-styrene rubber: 35-68 part,
Polyethylene Glycol: 16-33 part, polyisobutylene: 18-33 part, ceramic 6-12 part, paraffin oil
4-6 part, adhesive 2-6 part, dimethicone 2-3 part, polyurethane 2-6 part, trihydroxy methyl
Propane: 0.08-0.15 part, sulfonated oil: 7-13 part, stearic acid: 2-4 part, antioxidant: 2-
5 parts, styrenated phenol: 2-4 part.
Preferably, the raw material of following parts by weight it is prepared from: butadiene-styrene rubber: 36 parts, poly-
Ethylene glycol: 16 parts, polyisobutylene: 18 parts, ceramic 6 parts, paraffin oil 4 parts, gluing
Agent 3 parts, dimethicone 3 parts, polyurethane 4 parts, trimethylolpropane: 0.1 part, sulfonation
Oil: 9 parts, stearic acid: 3 parts, antioxidant: 3 parts, styrenated phenol: 3 parts.
Preferably, the raw material of following parts by weight it is prepared from: butadiene-styrene rubber: 40 parts, poly-
Ethylene glycol: 20 parts, polyisobutylene: 22 parts, ceramic 8 parts, paraffin oil 5 parts, gluing
Agent 4 parts, dimethicone 3 parts, polyurethane 4 parts, trimethylolpropane: 0.1 part, sulfonation
Oil: 9 parts, stearic acid: 4 parts, antioxidant: 4 parts, styrenated phenol: 4 parts.
Preferably, the relative molecular mass of described Polyethylene Glycol is between 400-600.
Preferably, described antioxidant is tea polyphenols, tocopherol, flavonoid, butylhydroxy
Methoxybenzene, dibenzylatiooluene, the one of tert-butyl hydroquinone.
The method have the benefit that
Art painting sealing of the present invention uses butadiene-styrene rubber to be primary raw material, and butadiene-styrene rubber has
Wear-resisting, cold-resistant, heat is low, contractility is low, color and luster is good, ash is few, purity is high and sulfuration
The advantages such as speed is fast, can preferably protect art painting works, be not allowed to by the condition of environment
Damaged；Polyethylene Glycol has good water solublity, lubricity, moisture retention, a dispersibility, and with
Many organic matter components have good intermiscibility；Polyisobutylene adds in sealing as plasticizer,
Can improve the resistance to ag(e)ing of sealing under high temperature, weatherability, resist bending breaking property, ozone resistants,
Reduce its absorption to water and the infiltration to gas；It is steady that dimethicone has excellent antioxidation
Qualitative, heat decomposition temperature is high, the advantage that evaporation loss is little, by increasing capacitance it is possible to increase art painting sealing
Non-oxidizability；Ceramic is a kind of lightweight non-metallic multifunctional material, and main component is Si
O2 and Al2O3, chemical stability is good, plasticity is good, heat resisting temperature is high, density is little, can carry
The resistance to oxidation of high art painting sealing, corrosion resistance；Trimethylolpropane is efficient as one
Heat stabilizer, the heat resistance of sealing can be strengthened so that it is in high temperature environments character be difficult to send out
Raw change, the present invention uses styrenated phenol as age resistor, can prevent the fast of sealing entirety
Speed is aging, and has a good protective action to hot oxygen, weather, light flexure etc. are aging, and
And make that synthesized sealing is the most easy to change, do not pollute.The present invention by the scientific matching to raw material,
Making produced sealing not only persistency good, oxidative resistance is also very good, in use its property
The biggest change can will not occur, not easily cause abrasion and rupture, service life is long, and preparation method is easy
In operation, with low cost, it is suitable for industrially large-scale promotion.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below will knot
Close embodiments of the invention, the technical scheme in the embodiment of the present invention is carried out clearly and completely
Describe.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creation
The every other embodiment obtained under property work premise, broadly falls into the scope of protection of the invention.
Embodiment 1:
A kind of Transparent surface sealing adhesive for art painting, is prepared from by the raw material of following parts by weight:
Butadiene-styrene rubber: 36 parts, Polyethylene Glycol: 16 parts, polyisobutylene: 18 parts, ceramic: 6
Part, paraffin oil: 4 parts, adhesive: 3 parts, dimethicone: 3 parts, polyurethane: 4 parts,
Trimethylolpropane: 0.1 part, sulfonated oil: 9 parts, stearic acid: 3 parts, antioxidant: 3
Part, styrenated phenol: 3 parts；
Wherein the relative molecular mass of Polyethylene Glycol is between 400-600, and antioxidant is that tea is many
Phenol, tocopherol, flavonoid, Butylated hydroxyanisole, dibenzylatiooluene, the tert-butyl group pair
The one of Benzodiazepines.
Embodiment 2:
A kind of Transparent surface sealing adhesive for art painting, is prepared from by the raw material of following parts by weight:
Butadiene-styrene rubber: 36 parts, Polyethylene Glycol: 20 parts, polyisobutylene: 18 parts, ceramic: 6-
12 parts, paraffin oil: 4 parts, adhesive 3 parts, dimethicone: 3 parts, polyurethane: 4
Part, trimethylolpropane: 0.1 part, sulfonated oil: 9 parts, stearic acid: 3 parts, antioxidant:
3 parts, styrenated phenol: 3 parts；
Wherein the relative molecular mass of Polyethylene Glycol is between 400-600, and antioxidant is that tea is many
Phenol, tocopherol, flavonoid, Butylated hydroxyanisole, dibenzylatiooluene, the tert-butyl group pair
The one of Benzodiazepines.
Embodiment 3:
A kind of Transparent surface sealing adhesive for art painting, is prepared from by the raw material of following parts by weight:
Butadiene-styrene rubber: 40 parts, Polyethylene Glycol: 18 parts, polyisobutylene: 20 parts, ceramic: 1
0 part, ceramic: 8 parts, paraffin oil: 5 parts, adhesive: 4 parts, dimethicone: 3
Part, polyurethane: 4 parts, trimethylolpropane: 0.08 part, sulfonated oil: 8 parts, stearic acid:
4 parts, antioxidant: 4 parts, styrenated phenol: 3 parts；
Wherein the relative molecular mass of Polyethylene Glycol is between 400-600, and antioxidant is that tea is many
Phenol, tocopherol, flavonoid, Butylated hydroxyanisole, dibenzylatiooluene, the tert-butyl group pair
The one of Benzodiazepines.
Embodiment 4:
A kind of Transparent surface sealing adhesive for art painting, is prepared from by the raw material of following parts by weight:
Butadiene-styrene rubber: 50 parts, Polyethylene Glycol: 30 parts, polyisobutylene: 20 parts, ceramic: 8
Part, paraffin oil: 5 parts, adhesive: 3 parts, dimethicone: 2 parts, polyurethane: 4 parts,
Trimethylolpropane: 0.08 part, sulfonated oil: 10 parts, stearic acid: 4 parts, antioxidant: 5
Part, styrenated phenol: 4 parts；
Wherein the relative molecular mass of Polyethylene Glycol is between 400-600, and antioxidant is that tea is many
Phenol, tocopherol, flavonoid, Butylated hydroxyanisole, dibenzylatiooluene, the tert-butyl group pair
The one of Benzodiazepines.
Embodiment 5:
A kind of Transparent surface sealing adhesive for art painting, is prepared from by the raw material of following parts by weight:
Butadiene-styrene rubber: 60 parts, Polyethylene Glycol: 33 parts, polyisobutylene: 30 parts, ceramic: 8
Part, paraffin oil: 4 parts, adhesive: 3 parts, dimethicone: 2 parts, polyurethane: 3 parts,
Trimethylolpropane: 0.01 part, sulfonated oil: 8 parts, stearic acid: 2 parts, antioxidant: 2
Part, styrenated phenol: 2 parts；
Wherein the relative molecular mass of Polyethylene Glycol is between 400-600, and antioxidant is that tea is many
Phenol, tocopherol, flavonoid, Butylated hydroxyanisole, dibenzylatiooluene, the tert-butyl group pair
The one of Benzodiazepines.
Embodiment 6:
A kind of Transparent surface sealing adhesive for art painting, is prepared from by the raw material of following parts by weight:
Butadiene-styrene rubber: 38 parts, Polyethylene Glycol: 8 parts, polyisobutylene: 20 parts, ceramic: 8
Part, paraffin oil: 6 parts, adhesive: 4 parts, dimethicone: 3 parts, polyurethane: 4 parts,
Trimethylolpropane: 0.01 part, sulfonated oil: 9 parts, stearic acid: 4 parts, antioxidant: 3
Part, styrenated phenol: 3 parts；
Wherein the relative molecular mass of Polyethylene Glycol is between 400-600, and antioxidant is that tea is many
Phenol, tocopherol, flavonoid, Butylated hydroxyanisole, dibenzylatiooluene, the tert-butyl group pair
The one of Benzodiazepines.
Above example only in order to technical scheme to be described, is not intended to limit；Although
With reference to previous embodiment, the present invention is described in detail, those of ordinary skill in the art
It is understood that the technical scheme described in foregoing embodiments still can be modified by it,
Or wherein portion of techniques feature is carried out equivalent；And these amendments or replacement, not
The essence making appropriate technical solution departs from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (6)
1. a Transparent surface sealing adhesive for art painting, it is characterised in that by following parts by weight
Raw material is prepared from: butadiene-styrene rubber: 30-70 part, Polyethylene Glycol: 12-40 part, polyisobutylene
12-14 part, ceramic 5-15 part, paraffin oil 1-8 part, adhesive 1-8 part, dimethyl-silicon
Oil 1-5 part, polyurethane 1-8 part, trimethylolpropane: 0.05-0.2 part, sulfonated oil: 6-15
Part, stearic acid: 1-5 part, antioxidant: 2-5 part, styrenated phenol: 1-4.5 part.
2. Transparent surface sealing adhesive for art painting as claimed in claim 1, it is characterised in that by
The raw material of following parts by weight is prepared from: butadiene-styrene rubber: 35-68 part, Polyethylene Glycol: 16-33
Part, polyisobutylene: 18-33 part, ceramic 6-12 part, paraffin oil 4-6 part, adhesive
2-6 part, dimethicone 2-3 part, polyurethane 2-6 part, trimethylolpropane: 0.08-0.15
Part, sulfonated oil: 7-13 part, stearic acid: 2-4 part, antioxidant: 2-5 part, styrol
Phenol: 2-4 part.
3. Transparent surface sealing adhesive for art painting as claimed in claim 2, it is characterised in that by
The raw material of following parts by weight is prepared from: butadiene-styrene rubber: 36 parts, Polyethylene Glycol: 16 parts,
Polyisobutylene: 18 parts, ceramic 6 parts, paraffin oil 4 parts, adhesive 3 parts, dimethyl
Silicone oil 3 parts, polyurethane 4 parts, trimethylolpropane: 0.1 part, sulfonated oil: 9 parts, tristearin
Acid: 3 parts, antioxidant: 3 parts, styrenated phenol: 3 parts.
4. Transparent surface sealing adhesive for art painting as claimed in claim 2, it is characterised in that by
The raw material of following parts by weight is prepared from: butadiene-styrene rubber: 40 parts, Polyethylene Glycol: 20 parts,
Polyisobutylene: 22 parts, ceramic 8 parts, paraffin oil 5 parts, adhesive 4 parts, dimethyl
Silicone oil 3 parts, polyurethane 4 parts, trimethylolpropane: 0.1 part, sulfonated oil: 9 parts, tristearin
Acid: 4 parts, antioxidant: 4 parts, styrenated phenol: 4 parts.
5. Transparent surface sealing adhesive for art painting as claimed in claim 1, it is characterised in that institute
The relative molecular mass of the Polyethylene Glycol stated is between 400-600.
6. Transparent surface sealing adhesive for art painting as claimed in claim 1, it is characterised in that institute
The antioxidant stated is tea polyphenols, tocopherol, flavonoid, Butylated hydroxyanisole, dibutyl
Hydroxy-methylbenzene, the one of tert-butyl hydroquinone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610299978.1A CN105837881A (en) | 2016-05-05 | 2016-05-05 | Transparent surface sealing wax for art painting |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610299978.1A CN105837881A (en) | 2016-05-05 | 2016-05-05 | Transparent surface sealing wax for art painting |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105837881A true CN105837881A (en) | 2016-08-10 |
Family
ID=56591072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610299978.1A Pending CN105837881A (en) | 2016-05-05 | 2016-05-05 | Transparent surface sealing wax for art painting |
Country Status (1)
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| CN (1) | CN105837881A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3959206A (en) * | 1974-10-21 | 1976-05-25 | The Southland Corporation | High molecular weight butadiene-styrene latex can end sealant composition |
| CN103992529A (en) * | 2014-04-29 | 2014-08-20 | 天长永泰密封材料有限公司 | Nitrile butadiene rubber sealant |
| CN104292547A (en) * | 2014-09-25 | 2015-01-21 | 青岛美嘉隆包装机械有限公司 | Antiaging seal rubber ring |
| CN104327334A (en) * | 2014-11-06 | 2015-02-04 | 苏州佰格斯电子科技有限公司 | Anti-aging antiwear sealant |
-
2016
- 2016-05-05 CN CN201610299978.1A patent/CN105837881A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3959206A (en) * | 1974-10-21 | 1976-05-25 | The Southland Corporation | High molecular weight butadiene-styrene latex can end sealant composition |
| CN103992529A (en) * | 2014-04-29 | 2014-08-20 | 天长永泰密封材料有限公司 | Nitrile butadiene rubber sealant |
| CN104292547A (en) * | 2014-09-25 | 2015-01-21 | 青岛美嘉隆包装机械有限公司 | Antiaging seal rubber ring |
| CN104327334A (en) * | 2014-11-06 | 2015-02-04 | 苏州佰格斯电子科技有限公司 | Anti-aging antiwear sealant |
Non-Patent Citations (2)
| Title |
|---|
| 梁星宇: "《丁基橡胶应用技术》", 31 March 2004, 化学工业出版社 * |
| 王先会: "《润滑油脂生产原料和设备实用手册》", 31 March 2007, 中国石化出版社 * |
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| PB01 | Publication | ||
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Application publication date: 20160810 |