CN105836747B - 一种球形活性炭及其制备方法 - Google Patents

一种球形活性炭及其制备方法 Download PDF

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CN105836747B
CN105836747B CN201610159771.4A CN201610159771A CN105836747B CN 105836747 B CN105836747 B CN 105836747B CN 201610159771 A CN201610159771 A CN 201610159771A CN 105836747 B CN105836747 B CN 105836747B
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activated charcoal
spherical activated
spherical
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organic bond
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CN105836747A (zh
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江金寿
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Shaowu Tongxia Trade Co.,Ltd.
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Shaowu Jintai Activated Carbon Co Ltd
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Abstract

本发明公开了一种球形活性炭及其制备方法,将粉状活性炭与有机粘合剂进行粘合成球形后,放大孔径,增强吸附脱色效果。通过上述方式,本发明能够增强吸附脱色效果,避免二次污染,且再生性强。

Description

一种球形活性炭及其制备方法
技术领域
本发明涉及环保技术领域,尤其是涉及一种球形活性炭及其制备方法。
背景技术
活性炭又称活性炭黑。是黑色粉末状或块状、颗粒状、蜂窝状的无定形炭,也有排列规整的晶体炭。活性炭中除炭元素外,还包含两类掺和物:一类是化学结合的元素,主要是氧和氢,这些元素是由于未完全炭化而残留在炭中,或者在活化过程中,外来的非炭元素与活性炭表面化学结合,如用水蒸气活化时,活性炭表面被氧化或水蒸气氧化;另一类掺和物是灰分,它是活性炭的无机部分;灰分在活性炭中易降低活性炭的质量品质。
活性炭广泛用于石化、化工、食品制药及电力行业,如在火力发电厂、大型炼钢厂、石化炼油厂以及垃圾发电中,活性炭均发挥了不可替代的作用。居民生活中,活性炭可用于城市污水处理、饮用水及工业用水过滤处理等。在实际中,应用较广的是粉状活性炭及柱状活性炭,其中粉状活性炭使用时会造成二次污染、且其强度低、耐用性差、甚至会堵塞管道出入口等,在用于成品净化时,还会粘在成品上,不易分离;而柱状活性炭通常呈块状,粉磨后,其强度将会显著降低,往往达不到理想的效果,而且使用的时间短,会堵塞管口,用后还会造成第二次污染。
发明内容
本发明所要解决的技术问题是:提供一种球形活性炭,提高强度、耐用性长,避免二次污染。
为了解决上述技术问题,本发明采用的技术方案为:提供一种球形活性炭,所述球形活性炭通过有机粘合剂及粉状活性炭粘合而成。
为解决上述问题,本发明还提供一种球形活性炭的制备方法,所述球形活性炭通过有机粘合剂及粉状活性炭粘合而成。
本发明的有益效果在于:区别于现有技术,本发明通过将粉状活性炭与有机粘合剂进行粘合成球形后,放大孔径,增强吸附脱色效果。
具体实施方式
为详细说明本发明的技术内容、所实现目的及效果,以下结合实施方式予以说明。
本发明最关键的构思在于:将粉状活性炭与有机粘合剂进行粘合成球形后,放大孔径,增强吸附脱色效果和强度。
本发明提供一种球形活性炭,所述球形活性炭通过有机粘合剂及粉状活性炭粘合而成。
具体地,所述有机粘合剂包括:
甲基纤维素,含量占球形活性炭的5%~10%;
竹油,含量占球形活性炭的10%;
地瓜粉,含量占球形活性炭的5%~15%;
海藻泥,含量占球形活性炭的15%;
泡花碱,含量占球形活性炭的5%。
其中球形活性炭是通过将有机粘合剂及粉状活性炭粘合成球形,再经炭化、活化后而成。
具体地,可通过粘合剂混合粉状活性炭,再整体混合,形成球形,通过炭化、活化、出料、筛选及质检等工序后,即可包装入库。
为了在使用中实现更好的脱色效果,所述球形活性炭通过蒸汽放大孔径。
本发明所述的球形活性炭可用于冶炼行业脱硫脱氯、净水行业中进行污水处理净化,或在火力发电厂、大型炼钢厂、石化炼油厂及垃圾发电的工作流程中进行脱硫脱氯,效果显著,而且不会造成二次污染,并可再生。
对应地,本发明还提供一种球形活性炭的制备方法,所述球形活性炭通过有机粘合剂及粉状活性炭粘合而成。
具体地,所述有机粘合剂包括:
甲基纤维素,含量占球形活性炭的5%~10%;
竹油,含量占球形活性炭的10%;
地瓜粉,含量占球形活性炭的5%~15%;
海藻泥,含量占球形活性炭的15%;
泡花碱,含量占球形活性炭的5%。
其中球形活性炭是通过将有机粘合剂及粉状活性炭粘合成球形,再经炭化、活化后而成。
为了在使用中实现更好的脱色效果,所述球形活性炭通过蒸汽放大孔径
本发明所述的球形活性炭可用于冶炼行业脱硫脱氯、净水行业中进行污水处理净化,或在火力发电厂、大型炼钢厂、石化炼油厂及垃圾发电的工作流程中进行脱硫脱氯,效果显著,而且不会造成二次污染,并可再生。
以上所述仅为本发明的实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书内容所作的等同变换,或直接或间接运用在相关的技术领域,均同理包括在本发明的专利保护范围内。

Claims (2)

1.一种球形活性炭,其特征在于,所述球形活性炭是通过有机粘合剂及粉状活性炭粘合成球形,再经炭化、活化后而成;所述球形活性炭通过蒸汽放大孔径;
所述有机粘合剂包括:
甲基纤维素,含量占球形活性炭的5%~10%;
竹油,含量占球形活性炭的10%;
地瓜粉,含量占球形活性炭的5%~15%;
海藻泥,含量占球形活性炭的15%;
泡花碱,含量占球形活性炭的5%。
2.一种球形活性炭的制备方法,其特征在于,有机粘合剂及粉状活性炭粘合形成球形活性炭;其中球形活性炭是通过将有机粘合剂及粉状活性炭粘合成球形,再经炭化、活化后而成;所述球形活性炭通过蒸汽放大孔径;所述有机粘合剂包括:
甲基纤维素,含量占球形活性炭的5%~10%;
竹油,含量占球形活性炭的10%;
地瓜粉,含量占球形活性炭的5%~15%;
海藻泥,含量占球形活性炭的15%;
泡花碱,含量占球形活性炭的5%。
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CN110075791A (zh) * 2019-04-04 2019-08-02 河南嘉利美环保材料有限公司 一种复合球形活性炭净化颗粒及其制备方法

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3351071A (en) * 1964-12-23 1967-11-07 Fmc Corp Carbon filter material and process for preparing it
CN1188074A (zh) * 1997-01-17 1998-07-22 中国科学院山西煤炭化学研究所 一种球状活性炭的制备方法
CN101972630A (zh) * 2010-11-12 2011-02-16 丽水市禾子净化设备有限公司 蜂窝型净化活性炭的制造方法
CN102218297A (zh) * 2011-04-28 2011-10-19 孔亦周 一种无需不熔处理工艺的沥青基球形活性炭的制备方法
CN102259853A (zh) * 2011-06-15 2011-11-30 李钱胜 球形活性炭的制备方法及盘式造球机
CN102641721A (zh) * 2012-04-10 2012-08-22 郭伟 复合球形活性炭吸附剂
CN103350997A (zh) * 2013-07-04 2013-10-16 陕西煤业化工技术研究院有限责任公司 一种粉煤热解焦粉制备活性炭的工艺方法
CN105148843A (zh) * 2015-09-28 2015-12-16 清华大学深圳研究生院 一种活性炭颗粒及其制备方法及碳罐
CN105289489A (zh) * 2015-11-02 2016-02-03 中国矿业大学 一种粉末活性炭物理法再生工艺

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55113608A (en) * 1979-02-20 1980-09-02 Kureha Chem Ind Co Ltd Manufacture of spherical carbon or spherical activated carbon
CN85102191A (zh) * 1985-04-01 1986-08-06 中国科学院成都有机化学研究所 微球形活性炭及制备方法
CN104692377B (zh) * 2015-02-09 2016-08-17 江西能欣生物科技有限公司 一种木质柱状活性炭生产工艺
CN104891492A (zh) * 2015-06-15 2015-09-09 威海文隆电池有限公司 中等孔径活性炭的制备方法

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3351071A (en) * 1964-12-23 1967-11-07 Fmc Corp Carbon filter material and process for preparing it
CN1188074A (zh) * 1997-01-17 1998-07-22 中国科学院山西煤炭化学研究所 一种球状活性炭的制备方法
CN101972630A (zh) * 2010-11-12 2011-02-16 丽水市禾子净化设备有限公司 蜂窝型净化活性炭的制造方法
CN102218297A (zh) * 2011-04-28 2011-10-19 孔亦周 一种无需不熔处理工艺的沥青基球形活性炭的制备方法
CN102259853A (zh) * 2011-06-15 2011-11-30 李钱胜 球形活性炭的制备方法及盘式造球机
CN102641721A (zh) * 2012-04-10 2012-08-22 郭伟 复合球形活性炭吸附剂
CN103350997A (zh) * 2013-07-04 2013-10-16 陕西煤业化工技术研究院有限责任公司 一种粉煤热解焦粉制备活性炭的工艺方法
CN105148843A (zh) * 2015-09-28 2015-12-16 清华大学深圳研究生院 一种活性炭颗粒及其制备方法及碳罐
CN105289489A (zh) * 2015-11-02 2016-02-03 中国矿业大学 一种粉末活性炭物理法再生工艺

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