CN105820667A - Child toy surface paint and preparation method thereof - Google Patents

Child toy surface paint and preparation method thereof Download PDF

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Publication number
CN105820667A
CN105820667A CN201610304344.0A CN201610304344A CN105820667A CN 105820667 A CN105820667 A CN 105820667A CN 201610304344 A CN201610304344 A CN 201610304344A CN 105820667 A CN105820667 A CN 105820667A
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China
Prior art keywords
agent
parts
acid
container
taeniam
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Pending
Application number
CN201610304344.0A
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Chinese (zh)
Inventor
费邦忠
周正华
郭庆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI HUAHUI PLASTIC TECHNOLOGY Co Ltd
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ANHUI HUAHUI PLASTIC TECHNOLOGY Co Ltd
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Priority to CN201610304344.0A priority Critical patent/CN105820667A/en
Publication of CN105820667A publication Critical patent/CN105820667A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D105/00Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides child toy surface paint and a preparation method thereof. The paint is mainly prepared from dibutyl phthalate, a TGIC curing agent, edetic acid, borax, an ammonium polyphosphate temperature-resistant auxiliary, an acidic oxidant, a sand ripple agent, sulfamic acid, dispersing agent NNO, asbestos powder, nano silicon dioxide, chlorinated rubber, ammonium chloride, talcum powder, barium sulfate, an anti-settling agent, a defoaming agent, pigment, leucoxene powder, bamboo shoots, water, fructus mume, radix astragali, poria cocos, fritillaria, fructus aurantii, radix angelica sinensis, an aqueous solution of alkyl polyglycoside, sodium alkyl benzene sulfonate, nipagin, sodium silicate, lemon essence, ethyl alcohol, isopropanol, dichloromethane, trichloromethane, propylene dichloride, phenol, formic acid, hydrofluoric acid and paraffin. The paint prepared through the method is free of peculiar smell, the formaldehyde content is far lower than that in national standards, the paint releases unique fragrance, is suitable for being used on household appliances and furniture and is high in high temperature resistance and cold resistance, and defects of existing paint are effectively overcome.

Description

Toy for children surface coating and preparation method thereof
Technical field:
The present invention designs a kind of chemistry painting industry and preparation method thereof, is specifically related to toy for children surface coating and preparation method thereof.
Background technology:
On market, dragons and fishes jumbled together for existing coating, protects the coating time of occurrence length especially of household electrical appliances long afterwards, it is impossible to reach antiseptic property, cold-proof on household electrical appliances furniture, in order to meet the market demand, is badly in need of a kind of preferably coating of research and development.
Summary of the invention:
The technical problem to be solved is to overcome the defect of prior art, it is provided that a kind of field soybean plantation herbicide and preparation method thereof in early days.
The technical problem to be solved realizes by the following technical solutions.
Toy for children surface coating, it is characterised in that: mainly it is composed of the following components in parts by weight:
nullDibutyl phthalate: 10-15 part,TGIC firming agent: 2-3 part,Ethylenediaminetetraacetic acid: 1-2 part,Borax: 3-5 part,APP heatproof auxiliary agent: 1-2 part,Acidic oxidation agent: 5-6 part,Sand streak agent: 7-9 part,Sulfamic acid: 1-2 part,Sodium metnylene bis-naphthalene sulfonate: 3-5 part,Flake asbestos: 3-5 part,Nano silicon: 10-12 part,Chlorinated rubber: 16-18 part,Ammonium chloride: 2-5 part,Pulvis Talci: 6-9 part,Barium sulfate: 3-6 part,Anti-settling agent: 1-2 part,Defoamer: 1-2 part,Pigment: 10-12 part,Titanium stone white lead: 30-35 part,Caulis Bambusae In Taeniam: 60-70 part,Water: 1000-1100 part,Fructus Mume: 10-15 part,The Radix Astragali: 10-15 part,Poria: 10-15 part,Bulbus Fritillariae Uninbracteatae: 10-15 part,Fructus Aurantii: 10-15 part,Radix Angelicae Sinensis: 10-15 part,The aqueous solution of alkyl polyglycoside: 2-5 part,Sodium alkyl benzene sulfonate: 3-5 part,Nipagin ester: 1-2 part,Sodium silicate: 3-5 part,Fructus Citri Limoniae essence: 1-2 part,Ethanol: 10-35 part,Isopropanol 35-60 part,Dichloromethane: 10-15 part,Chloroform: 1-2 part,Dichloropropane 5-10 part,Phenol: 2-5 part,Formic acid: 1-2 part,Fluohydric acid.: 2-5 part,Paraffin: 1-2 part.
Mainly comprise the steps that
1) cut into slices after Caulis Bambusae In Taeniam being cleaned, be immersed in evaporated milk, treat that evaporated milk is absorbed totally by Caulis Bambusae In Taeniam, take Semen arachidis hypogaeae, grinds, be sprinkled upon on Caulis Bambusae In Taeniam;
2) being ground by nano silicon, milling time is 60min, and grinding rate is 600 turns/min, puts in reactor;
3) taking chlorinated rubber, ammonium chloride, Pulvis Talci, barium sulfate, anti-settling agent, defoamer, pigment, titanium stone white lead, Caulis Bambusae In Taeniam, mixing adds in reactor;
4) take in Fructus Mume, the Radix Astragali, Poria, Bulbus Fritillariae Uninbracteatae, Fructus Aurantii, Radix Angelicae Sinensis grinds addition alembic, add the water of 75%, distillation, collect distilled water;
5) distilled water is added in reactor, filter with the detailed catalogue filter screen of 300 mesh, filter out thicker granule, pulverize;
6) first the water of 15% is heated to 66-71 DEG C, is then respectively adding sodium alkyl benzene sulfonate, Nipagin ester, the aqueous solution of alkyl polyglycoside, Fructus Citri Limoniae essence, sodium silicate, stirs, cooling, homogenizing, after being cooled to room temperature, add isopropanol, mixing;
7) injecting in container A by dichloromethane, inject chloroform the most again in container A, the chlorohydrocarbon of composition mixing is standby;Paraffin, phenol being put into after another container B is heated to 30-40 DEG C, add dichloropropane, stirring is all;Material in container B is put in the container A filling chlorohydrocarbon, in container A, add formic acid, Fluohydric acid. the most again, stir by mechanical air;
8) by step 6) and step 7) gained mixture is in step 5) granular powder mixing;
9) take dibutyl phthalate, TGIC firming agent, ethylenediaminetetraacetic acid, Borax, APP heatproof auxiliary agent, acidic oxidation agent, sand streak agent, sulfamic acid, sodium metnylene bis-naphthalene sulfonate, flake asbestos simultaneously, grinding, the water adding 10% adds hot mixing;
10) finally by step 9) gained mixture addition step 8) in, stirring obtains coating.
The invention has the beneficial effects as follows: coating prepared by this law, free from extraneous odour, content of formaldehyde is far below national standard, discharges a kind of exclusive fragrance simultaneously, it is adaptable to use on family's household electrical appliances and furniture, high temperature resistant, and cold tolerance is high, effectively solves the deficiency of existing coating.
Detailed description of the invention:
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below in conjunction with specific embodiment, the present invention is expanded on further.
Specific embodiment 1: toy for children surface coating, is mainly composed of the following components in parts by weight:
nullDibutyl phthalate: 10 parts,TGIC firming agent: 2 parts,Ethylenediaminetetraacetic acid: 1 part,Borax: 3 parts,APP heatproof auxiliary agent: 1 part,Acidic oxidation agent: 5 parts,Sand streak agent: 7 parts,Sulfamic acid: 1 part,Sodium metnylene bis-naphthalene sulfonate: 3 parts,Flake asbestos: 3 parts,Nano silicon: 10 parts,Chlorinated rubber: 16 parts,Ammonium chloride: 2 parts,Pulvis Talci: 6 parts,Barium sulfate: 3 parts,Anti-settling agent: 1 part,Defoamer: 1 part,Pigment: 10 parts,Titanium stone white lead: 30 parts,Caulis Bambusae In Taeniam: 60 parts,Water: 1000 parts,Fructus Mume: 10 parts,The Radix Astragali: 10 parts,Poria: 10 parts,Bulbus Fritillariae Uninbracteatae: 10 parts,Fructus Aurantii: 10 parts,Radix Angelicae Sinensis: 10 parts,The aqueous solution of alkyl polyglycoside: 2 parts,Sodium alkyl benzene sulfonate: 3 parts,Nipagin ester: 1 part,Sodium silicate: 3 parts,Fructus Citri Limoniae essence: 1 part,Ethanol: 10 parts,Isopropanol 35 parts,Dichloromethane: 10 parts,Chloroform: 1 part,Dichloropropane 5 parts,Phenol: 2 parts,Formic acid: 1 part,Fluohydric acid.: 2 parts,Paraffin: 1 part.
Specific embodiment 2: toy for children surface coating, is mainly composed of the following components in parts by weight:
nullDibutyl phthalate: 15 parts,TGIC firming agent: 3 parts,Ethylenediaminetetraacetic acid: 2 parts,Borax: 5 parts,APP heatproof auxiliary agent: 2 parts,Acidic oxidation agent: 6 parts,Sand streak agent: 9 parts,Sulfamic acid: 2 parts,Sodium metnylene bis-naphthalene sulfonate: 5 parts,Flake asbestos: 5 parts,Nano silicon: 12 parts,Chlorinated rubber: 18 parts,Ammonium chloride: 5 parts,Pulvis Talci: 9 parts,Barium sulfate: 6 parts,Anti-settling agent: 2 parts,Defoamer: 2 parts,Pigment: 12 parts,Titanium stone white lead: 35 parts,Caulis Bambusae In Taeniam: 70 parts,Water: 1100 parts,Fructus Mume: 15 parts,The Radix Astragali: 15 parts,Poria: 15 parts,Bulbus Fritillariae Uninbracteatae: 15 parts,Fructus Aurantii: 15 parts,Radix Angelicae Sinensis: 15 parts,The aqueous solution of alkyl polyglycoside: 5 parts,Sodium alkyl benzene sulfonate: 5 parts,Nipagin ester: 2 parts,Sodium silicate: 5 parts,Fructus Citri Limoniae essence: 2 parts,Ethanol: 35 parts,Isopropanol 60 parts,Dichloromethane: 15 parts,Chloroform: 2 parts,Dichloropropane 10 parts,Phenol: 5 parts,Formic acid: 2 parts,Fluohydric acid.: 5 parts,Paraffin: 2 parts.
Mainly comprise the steps that
1) cut into slices after Caulis Bambusae In Taeniam being cleaned, be immersed in evaporated milk, treat that evaporated milk is absorbed totally by Caulis Bambusae In Taeniam, take Semen arachidis hypogaeae, grinds, be sprinkled upon on Caulis Bambusae In Taeniam;
2) being ground by nano silicon, milling time is 60min, and grinding rate is 600 turns/min, puts in reactor;
3) taking chlorinated rubber, ammonium chloride, Pulvis Talci, barium sulfate, anti-settling agent, defoamer, pigment, titanium stone white lead, Caulis Bambusae In Taeniam, mixing adds in reactor;
4) take in Fructus Mume, the Radix Astragali, Poria, Bulbus Fritillariae Uninbracteatae, Fructus Aurantii, Radix Angelicae Sinensis grinds addition alembic, add the water of 60%, distillation, collect distilled water;
5) distilled water of 75% is added in reactor, filter with the detailed catalogue filter screen of 300 mesh, filter out thicker granule, pulverize;
6) first the water of 15% is heated to 66-71 DEG C, is then respectively adding sodium alkyl benzene sulfonate, Nipagin ester, the aqueous solution of alkyl polyglycoside, Fructus Citri Limoniae essence, sodium silicate, stirs, cooling, homogenizing, after being cooled to room temperature, add isopropanol, mixing;
7) injecting in container A by dichloromethane, inject chloroform the most again in container A, the chlorohydrocarbon of composition mixing is standby;Paraffin, phenol being put into after another container B is heated to 30-40 DEG C, add dichloropropane, stirring is all;Material in container B is put in the container A filling chlorohydrocarbon, in container A, add formic acid, Fluohydric acid. the most again, stir by mechanical air;
8) by step 6) and step 7) gained mixture is in step 5) granular powder mixing;
9) take dibutyl phthalate, TGIC firming agent, ethylenediaminetetraacetic acid, Borax, APP heatproof auxiliary agent, acidic oxidation agent, sand streak agent, sulfamic acid, sodium metnylene bis-naphthalene sulfonate, flake asbestos simultaneously, grinding, the water adding 10% adds hot mixing;
10) finally by step 9) gained mixture addition step 8) in, stirring obtains coating.
The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described.Skilled person will appreciate that of the industry; the present invention is not restricted to the described embodiments; the principle that the present invention is simply described described in above-described embodiment and description; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements both fall within scope of the claimed invention.Claimed scope is defined by appending claims and equivalent thereof.

Claims (2)

1. toy for children surface coating, it is characterised in that: mainly it is composed of the following components in parts by weight:
nullDibutyl phthalate: 10-15 part,TGIC firming agent: 2-3 part,Ethylenediaminetetraacetic acid: 1-2 part,Borax: 3-5 part,APP heatproof auxiliary agent: 1-2 part,Acidic oxidation agent: 5-6 part,Sand streak agent: 7-9 part,Sulfamic acid: 1-2 part,Sodium metnylene bis-naphthalene sulfonate: 3-5 part,Flake asbestos: 3-5 part,Nano silicon: 10-12 part,Chlorinated rubber: 16-18 part,Ammonium chloride: 2-5 part,Pulvis Talci: 6-9 part,Barium sulfate: 3-6 part,Anti-settling agent: 1-2 part,Defoamer: 1-2 part,Pigment: 10-12 part,Titanium stone white lead: 30-35 part,Caulis Bambusae In Taeniam: 60-70 part,Water: 1000-1100 part,Fructus Mume: 10-15 part,The Radix Astragali: 10-15 part,Poria: 10-15 part,Bulbus Fritillariae Uninbracteatae: 10-15 part,Fructus Aurantii: 10-15 part,Radix Angelicae Sinensis: 10-15 part,The aqueous solution of alkyl polyglycoside: 2-5 part,Sodium alkyl benzene sulfonate: 3-5 part,Nipagin ester: 1-2 part,Sodium silicate: 3-5 part,Fructus Citri Limoniae essence: 1-2 part,Ethanol: 10-35 part,Isopropanol 35-60 part,Dichloromethane: 10-15 part,Chloroform: 1-2 part,Dichloropropane 5-10 part,Phenol: 2-5 part,Formic acid: 1-2 part,Fluohydric acid.: 2-5 part,Paraffin: 1-2 part.
2. according to the toy for children surface coating described in claim 1, it is characterised in that: mainly comprise the steps that
1) cut into slices after Caulis Bambusae In Taeniam being cleaned, be immersed in evaporated milk, treat that evaporated milk is absorbed totally by Caulis Bambusae In Taeniam, take Semen arachidis hypogaeae, grinds, be sprinkled upon on Caulis Bambusae In Taeniam;
2) being ground by nano silicon, milling time is 60min, and grinding rate is 600 turns/min, puts in reactor;
3) taking chlorinated rubber, ammonium chloride, Pulvis Talci, barium sulfate, anti-settling agent, defoamer, pigment, titanium stone white lead, Caulis Bambusae In Taeniam, mixing adds in reactor;
4) take in Fructus Mume, the Radix Astragali, Poria, Bulbus Fritillariae Uninbracteatae, Fructus Aurantii, Radix Angelicae Sinensis grinds addition alembic, add the water of 75%, distillation, collect distilled water;
5) distilled water is added in reactor, filter with the detailed catalogue filter screen of 300 mesh, filter out thicker granule, pulverize;
6) first the water of 15% is heated to 66-71 DEG C, is then respectively adding sodium alkyl benzene sulfonate, Nipagin ester, the aqueous solution of alkyl polyglycoside, Fructus Citri Limoniae essence, sodium silicate, stirs, cooling, homogenizing, after being cooled to room temperature, add isopropanol, mixing;
7) injecting in container A by dichloromethane, inject chloroform the most again in container A, the chlorohydrocarbon of composition mixing is standby;Paraffin, phenol being put into after another container B is heated to 30-40 DEG C, add dichloropropane, stirring is all;Material in container B is put in the container A filling chlorohydrocarbon, in container A, add formic acid, Fluohydric acid. the most again, stir by mechanical air;
8) by step 6) and step 7) gained mixture is in step 5) granular powder mixing;
9) take dibutyl phthalate, TGIC firming agent, ethylenediaminetetraacetic acid, Borax, APP heatproof auxiliary agent, acidic oxidation agent, sand streak agent, sulfamic acid, sodium metnylene bis-naphthalene sulfonate, flake asbestos simultaneously, grinding, the water adding 10% adds hot mixing;
10) finally by step 9) gained mixture addition step 8) in, stirring obtains coating.
CN201610304344.0A 2016-05-06 2016-05-06 Child toy surface paint and preparation method thereof Pending CN105820667A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610304344.0A CN105820667A (en) 2016-05-06 2016-05-06 Child toy surface paint and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610304344.0A CN105820667A (en) 2016-05-06 2016-05-06 Child toy surface paint and preparation method thereof

Publications (1)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1300241A (en) * 1999-03-11 2001-06-20 伊利诺斯·吉玛工具工程公司 Power coating device
CN1492007A (en) * 2002-10-22 2004-04-28 李宏钊 Paint remover and preparing method
CN1827758A (en) * 2006-02-13 2006-09-06 史秀宁 Cleaning liquid and its application in cleaning household electrical appliance
CN102533459A (en) * 2010-12-31 2012-07-04 宋国新 Cleaning agent for descaling water tank of automobile
CN103965752A (en) * 2014-05-06 2014-08-06 张家港江南粉末涂料有限公司 High-temperature-resistant powder coating with good gloss-retention performance and production method thereof
CN104387877A (en) * 2014-11-06 2015-03-04 浙江兄弟路标涂料有限公司 Color steel tile paint

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1300241A (en) * 1999-03-11 2001-06-20 伊利诺斯·吉玛工具工程公司 Power coating device
CN1492007A (en) * 2002-10-22 2004-04-28 李宏钊 Paint remover and preparing method
CN1827758A (en) * 2006-02-13 2006-09-06 史秀宁 Cleaning liquid and its application in cleaning household electrical appliance
CN102533459A (en) * 2010-12-31 2012-07-04 宋国新 Cleaning agent for descaling water tank of automobile
CN103965752A (en) * 2014-05-06 2014-08-06 张家港江南粉末涂料有限公司 High-temperature-resistant powder coating with good gloss-retention performance and production method thereof
CN104387877A (en) * 2014-11-06 2015-03-04 浙江兄弟路标涂料有限公司 Color steel tile paint

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Application publication date: 20160803