CN105803318A - High-temperature-resistant austenitic stainless steel for furnace pipe - Google Patents

High-temperature-resistant austenitic stainless steel for furnace pipe Download PDF

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Publication number
CN105803318A
CN105803318A CN201610354857.2A CN201610354857A CN105803318A CN 105803318 A CN105803318 A CN 105803318A CN 201610354857 A CN201610354857 A CN 201610354857A CN 105803318 A CN105803318 A CN 105803318A
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stainless steel
temperature
austenitic stainless
high temperature
steel
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颜海涛
杨振
申鹏
李�杰
杨赛
刘晓亚
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East Special Steel Co Ltd Of Zhen Shi Group
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East Special Steel Co Ltd Of Zhen Shi Group
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/52Manufacture of steel in electric furnaces
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • C22C33/06Making ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

The invention relates to high-temperature-resistant austenitic stainless steel for a furnace pipe. The high-temperature-resistant austenitic stainless steel comprises the following components in percentage by mass: 24-26% of Cr, 19-21% of Ni, 0.3-0.8% of Si, 0.02-0.06% of C, 1.0-1.5% of Mn, 1.5-2.5% of W, less than or equal to 0.2% of N, less than or equal to 0.04% of P, less than or equal to 0.03% of S and the balance of Fe. According to the high-temperature-resistant austenitic stainless steel, high-temperature creep resistance and oxidation resistance which are better than those of 310 heat-resistant stainless steel are provided; and the high-temperature-resistant austenitic stainless steel can be used for a longer time at a temperature above 1000 DEG C.

Description

A kind of high temperature resistant flue austenitic stainless steel
Technical field
The present invention relates to a kind of high temperature resistant flue austenitic stainless steel.
Background technology
nullConsteel electric steelmaking process is a kind of new Electric Furnace Steelmaking carried out the nineties in 20th century,This electric furnace has continuous charging、Continuously pre-heating、Continuous melting、The feature of melting continuously,It is short that it has smelting cycle、Smelting energy consumption is low、Noise is little、The advantages such as cost of investment is low,It is a kind of electric furnace smelting advanced technology with stronger vitality and competitiveness in field of steel-making,But adopt Consteel electric furnace smelting high temperature resistant flue austenitic stainless steel this nickelic、High chromium and tungstenic mother liquor of stainless steel are but without precedent,The present invention can not only adopt the high temperature resistant flue austenitic stainless steel mother solution of Consteel electric furnace smelting by adjusting process parameter,And power consumption can be reduced、Shorten smelting cycle,P content can drop to less than 0.01% simultaneously,Greatly improve economic benefit.
Austenite series stainless steel is Fe~Cr~Ni series or Fe~Cr~Mn series.All there is stable excellent mechanical property from low temperature to high temperature.Carry out solutionizing heat treatment ametaboly point 920~1150 DEG C of temperature, rely on and be rapidly cool-off to become the nonmagnetic austenite structure with excellent decay resistance.Austenite series stainless steel is compared with martensite, ferrite series stainless steel, little etc. because being rich in extensibility and yield ratio (yield strength/tensile strength), so its processability is very superior.But its hardening property is big.Recently, utilize processing temperature dexterously, by the drop-down plutonic merit of situation in uniform temperature of the ultra-deep drawing that can not carry out in the past.
Austenite heat-resistance stainless steel is widely applied in boiler and flue, such as the steam boiler of thermal power generation, steamturbine industrial furnace and jet engine etc..They all at high temperature work, and bear various load, and they also contact with high-temperature steam, High Temperature Gas in addition, and surface is susceptible to high-temperature oxydation.310/310S is chromium nickle type austenitic stainless steel, owing to the addition of the chromium nickel than 304 higher amounts, and at high temperature can the generation of effective control oxide so that it is there is better high-temperature oxidation resistance and creep strength at higher temperature.The maximum operating temperature of 310S is up to 1200 DEG C, can at 1100 DEG C continuous firing, generally the hot environment below 1100 DEG C uses, but using the time short in hot environment, neoteric a kind of high temperature resistant flue austenitic stainless steel has higher high temperature endurance performance and pyro-oxidation resistance.
Hot properties: more than 500 DEG C, the intensity of other steel grades can sharply decline, and austenite series stainless steel still has higher intensity.Especially because it has good oxidative resistance, so being applicable to various worst hot cases.Because austenite series stainless steel is face-centered cubic lattice, significantly more superior than the ferrite series stainless steel of body-centered cubic lattic elevated temperature strength more than 600 DEG C.
Low-temperature characteristics: ordinary steel (ferritic steel) is a kind of high-strength material, but in low temperature, because its intensity and toughness all weaken, and be restricted on using.Martensite series, ferrite series and austenite series stainless steel, each superior characteristic is possessed respectively in room temperature and hot environment, but in low temperature environment, martensite series stainless steel and ferrite series stainless steel, the same with ordinary steel, cryogenic property is not good, and austenite series stainless steel, it is widely used because possessing excellent low-temperature characteristics.
300 series austenitic rustless steels (such as 304,316,317 etc.) are widely used in the fields such as oil, chemical industry, aerospace and the energy owing to all having good plasticity and toughness, cold and hot working performance and resistance to local corrosion performance under high temperature and extremely low temperature.Along with existingizationization development, many working condition requirements at high temperature have higher-strength and the special steel of good chemical, typical high temperature resistant stainless steel such as 06Cr25Ni20(310S) it is grow up by improving Cr, Ni content and improving stainless high temperature oxidation resistance simultaneously.
At present, stainless steel enterprises headed by Taiyuan Iron and Steel Co. and Baosteel production development all 310S heat-resistance stainless steel at home, to use in annealing furnace equipment, but 310S is primarily present and has the drawback that service life is short, for this situation, by the design of reasonable science and experimentation, the special austenitic stainless steel strand being used exclusively in high temperature flue can be outputed.The present invention by improving the content of chromium, nickel, reasonably add tungsten alloy metallic element, and strict control other alloying element contents, can make its material can life-time service in high temperature flue, save Master Cost for downstream client and increase economic efficiency.By novelty assessment report, paper and patent for the special austenitic stainless steel technical elements of high temperature resistant flue have not been reported, and processing technology and this patent require also there is basic difference.
Publication number is the preparation method that the Chinese patent of CN102373379A discloses a kind of resistance to chemical attack martensitic stain less steel, and it counts by weight percentage, and ingredient is as follows: C:0.002~0.01%;Si:0.15~0.45%;Mn:0.3~1.5%;P :≤0.02%;S :≤0.005%;Cr:16~17.8%;Ni:2.5~5.0%;V:0.03%~0.15%;Mo:1.5~0.30%;O≤0.005%.This rustless steel has high temperature resistant and wear-resisting advantage, but does not reach the instructions for use of high temperature flue.
The Chinese patent that publication number is CN102260826A discloses a kind of high temperature resistant martensitic stain less steel and manufacture method thereof, and it counts by weight percentage, and ingredient is as follows: C:0.11~0.15%;Si :≤0.1%;Mn:0.5~0.8%;P :≤0.01%;S :≤0.005%;Cr:9.8~11.5%;Ni:0.6~0.8%;V:0.13%~0.23%;Al≤0.01%;Nb:0.09~0.15%;W:0.25~0.4%;N:0.05~0.08%;Mo:1.00~1.30%;O≤0.005%.This rustless steel has high temperature resistant and low temperature intensity advantages of higher, but does not reach high temperature resistant creep and the resistance to oxidation instructions for use of high temperature flue.
Summary of the invention
It is an object of the invention to overcome above shortcomings in prior art, and a kind of high temperature resistant flue austenitic stainless steel is provided, this steel grade can improve better high temperature resistant croop property and antioxygenic property than 310S heat-resistance stainless steel, it is possible to longer 1000 DEG C of times used above.
This invention address that the problems referred to above be the technical scheme is that a kind of high temperature resistant flue austenitic stainless steel, it is characterized in that: consist of by mass percentage: Cr:24~26%, Ni:19~21%, Si:0.3~0.8%, C:0.02~0.06%, Mn:1.0~1.5%, W:1.5~2.5%, N≤0.2%, P≤0.04%, S≤0.03%, surplus is Fe.
Chromium nickel equivalent ratio of the present invention controls between 0.9~1.1.
The present invention consists of by mass percentage: C:0.025%, Cr:24.5%, Si:0.45%, Ni:20.1%, Mn:1.5%, W:2.01, N:0.08%, P:0.018%, S:0.0005%, and surplus is Fe.
The present invention consists of by mass percentage: Cr:25%, Ni:201%, Si:0.55%, C:0.045%, Mn:1.25%, W:2.0%, N:0.1%, P:0.02%, S:0.015%, and surplus is Fe.
A kind of processing technology of high temperature resistant flue austenite stainless steel plate base, it is characterised in that: step is as follows:
One, Consteel smelting mother liquor of stainless steel from electric furnace, mother solution goes out composition of steel and consists of by mass percentage: C > 1.0%;Si < 1.0%;Cr≤2%;Ni:25~35%;P < 0.01%;W:3~5%, surplus is Fe;Tapping temperature controls at 1580~1630 DEG C;
Two, intermediate frequency furnace smelting high carbon ferrochrome is adopted;
Three, it is blended into AOD furnace after Consteel electric furnace mother solution and intermediate frequency furnace high carbon ferro-chrome molten steel being blent to smelt, after smelting, tapping temperature controls between 1550~1630 DEG C, then being blended into LF stove carry out refine and add microalloy element, rustless steel liquation composition is finally adjusted to the composition of above-mentioned high temperature resistant flue austenitic stainless steel;The qualified rear bull ladle of composition, temperature is to continuous casting platform, and LF stove bull ladle temperature controls between 1500~1520 DEG C, then passes through conticaster and this rustless steel liquation is casting continuously to form thickness 160~220mm slab.
Intermediate frequency furnace high carbon ferro-chrome molten steel chrome content of the present invention is more than 50%.
In step one of the present invention, mother solution goes out composition of steel and consists of by mass percentage: C:1.9%, Si:0.3%, P:0.005%, Cr:1.25%, W:4.1%, Ni:30%, and surplus is Fe.
In step one of the present invention, Consteel electric furnace steel tapping temperature is 1595 DEG C.
In step one of the present invention, AOD furnace tapping temperature is 1570 DEG C.
The present invention compared with prior art, has the following advantages and effect:
1, Consteel electric furnace has the feature of continuous charging, continuously pre-heating, continuous melting, melting continuously, it has, and smelting cycle is short, smelt the advantages such as energy consumption is low, noise is little, cost of investment is low, and it is a kind of electric furnace smelting advanced technology with stronger vitality and competitiveness in field of steel-making, but adopt this chromium nickelic, high of Consteel electric furnace smelting high temperature resistant flue austenitic stainless steel and tungstenic mother liquor of stainless steel but without precedent, and when smelting this chromium nickelic, high and tungstenic mother liquor of stainless steel, phosphorus content is controlled below 0.01 still extremely difficult.
Metallurgical characteristics according to Consteel, the present invention can not only adopt the high temperature resistant flue austenitic stainless steel mother solution of Consteel electric furnace smelting by adjusting process parameter, and can reduce power consumption, shorten smelting cycle, and phosphorus content controls below 0.01%.
2, Cr ferrite former, improve the corrosion resistance of material, carry heavy alloyed intensity and pyro-oxidation resistance, the content suitably controlling Cr element is conducive to controlling chromium nickel equivalent ratio, and then be conducive to controlling the hot-workability of this two phase stainless steel, in the present invention, the content of chromium controls at 24%≤Cr≤26%, preferentially selects 24%≤Cr≤25%.
Ni is austenite former, austenite can be reduced expanded range to low-temperature space by nickel, nickel can improve toughness and ductility, make it easier to processing, manufacture and welding, strengthen antiacid corrosion, keep the ability of passivating film and the resistance to corrosion in corrosive medium, as preferentially selecting 20%≤nickel≤21%.
C is austenite former, replaces nickel to a certain extent, promotes austenite stable austenite, when carbon content is too high, to generate chromium carbide, stainless corrosion resistance and toughness deterioration with chromium, in order to ensure stainless corrosion resistance, general control is at 0.02-0.06%, it is preferable that select 0.02-0.03%.
Si is ferrite former and plays and stablize ferritic effect, also functions to deoxidation additive, improves welding mobility, has and increases trend that mesophase spherule precipitates out and reduce N concentration, preferentially select 0.3%≤Si≤0.60% when silicone content is too high.
Mn is the effect of austenite former and stable austenite, nickel can be replaced to a certain extent, obtain austenite structure, improve nitrogen solid solubility simultaneously, and then improve the content of nitrogen, too high manganese is unfavorable to the corrosion-resistant shape of material, and promotes the formation of metal phase, affects impact flexibility and decay resistance.Fe content preferentially selects 1.0%≤Mn≤1.3%.
W is ferrite former, and can improve elevated temperature strength and high temperature resistant croop property, but too much adds membership and cause the precipitation of brittlement phase, as preferably 1.5%≤W≤2.0%.
N is stable austenite element, improves the corrosion resistance of steel, improves the intensity of steel.Improving the welding performance of material, but cross high nitrogen-containing and reduce the hot-workability of material, too low nitrogen content can reduce again the content of chromium, and the decay resistance of material is unfavorable, preferentially controls at N≤0.1%.
P is harmful element, is segregated in crystal boundary or phase boundary, and corrosion resistance and hot-working character to material are unfavorable, it is preferable that control below 0.02%.
S is harmful element, easily forms Manganese monosulfide. reduce the hot-workability of material with manganese, and calcium forms calcium sulfide, and corrosion resistance is harmful to, and priority acccess control is below 0.001%.
Detailed description of the invention
The present invention is described in further detail by the examples below, and following example are explanation of the invention and the invention is not limited in following example.
High temperature resistant flue austenitic stainless steel described in the embodiment of the present invention consists of by mass percentage: Cr:24~26%, Ni:19~21%, Si:0.3~0.8%, C:0.02~0.06%, Mn:1.0~1.5%, W:1.5~2.5%, N≤0.2%, P≤0.04%, S≤0.03%, surplus is Fe;Chromium nickel equivalent ratio controls between 0.9~1.1.
The processing technology of above-mentioned high temperature resistant flue austenite stainless steel plate base is: adopt Consteel smelting mother liquor of stainless steel from electric furnace, then blend to AOD furnace with the mother liquor of stainless steel of intermediate frequency furnace, decarburization, desulfurization, composition adjustment is carried out by controlling AOD furnace, microalloy composition adjustment and microalloy interpolation and temperature control is being carried out to LF stove, hanging ladle after qualified and carry out slab production to continuous casting, namely processing technology is: (Consteel+ intermediate frequency furnace) → AOD → LF → continuous casting.
Specifically comprise the following steps that
One, Consteel smelting mother liquor of stainless steel from electric furnace, mother solution goes out composition of steel and consists of by mass percentage: C > 1.0%;Si < 1.0%;Cr≤2%;Ni:25~35%;P < 0.01%;W:3~5%, surplus is Fe;Tapping temperature controls at 1580~1630 DEG C;
Two, adopt intermediate frequency furnace smelting high carbon ferrochrome, and control intermediate frequency furnace high carbon ferro-chrome molten steel chrome content more than 50%.The chrome content of indication is the mass percent of chromium herein.
Three, it is blended into AOD furnace after Consteel electric furnace mother solution and intermediate frequency furnace high carbon ferro-chrome molten steel being blent to smelt, after smelting, tapping temperature controls between 1550~1630 DEG C, then being blended into LF stove carry out refine and add microalloy element, rustless steel liquation composition is finally adjusted to the composition of above-mentioned high temperature resistant flue austenitic stainless steel;The qualified rear bull ladle of composition, temperature is to continuous casting platform, and LF stove bull ladle temperature controls between 1500~1520 DEG C, then passes through conticaster and this high temperature resistant flue austenite stainless molten steel is casting continuously to form thickness 160~220mm slab.
Embodiment:
One, Consteel smelting mother liquor of stainless steel from electric furnace, mother solution goes out composition of steel and consists of by mass percentage: C:1.9%, Si:0.3%, P:0.005%, Cr:1.25%, W:4.1, Ni:30%, and surplus is Fe;Tapping temperature is 1595 DEG C.
Two, Consteel mother solution qualified for composition and the successively tapping of intermediate frequency furnace high carbon ferro-chrome molten steel being mixed in duckbilled bag, be blended in AOD furnace again and carry out oxygen decarburization, nitrogen flushing after mixing, reduction period adds aluminum deep deoxidation and composition adjustment, and tapping temperature is 1570 DEG C;It is blended into LF stove after composition is qualified and carries out refine and microalloy addition, rustless steel liquation composition is finally adjusted to by mass percentage: C:0.025%, Cr:24.5%, Si:0.45%, Ni:20.1%, Mn:1.5%, W:2.01, N:0.08%, P:0.018%, S:0.0005%, and surplus is Fe;By conticaster, this rustless steel liquation being casting continuously to form thickness is 198mm strand.
12 embodiments (A1~A12) of the high temperature resistant flue austenitic stainless steel described in the embodiment of the present invention are mass percent in each component of Table 1().
Table 1.
In addition, it should be noted that the above-mentioned embodiment of the present invention is only for clearly demonstrating example of the present invention explanation, and it is not the restriction to embodiments of the present invention, specific embodiment described in this specification, the shape of its parts and components, be named title etc. can be different.For those of ordinary skill in the field, other multi-form change and variations can also be made on the basis of the above description.Here cannot all of embodiment be given exhaustive.Every belong to apparent change that technical scheme amplified out or the variation row still in protection scope of the present invention.

Claims (4)

1. a high temperature resistant flue austenitic stainless steel, it is characterised in that: consist of by mass percentage: Cr:24~26%, Ni:19~21%, Si:0.3~0.8%, C:0.02~0.06%, Mn:1.0~1.5%, W:1.5~2.5%, N≤0.2%, P≤0.04%, S≤0.03%, surplus is Fe.
2. high temperature resistant flue austenitic stainless steel according to claim 1, it is characterised in that: described chromium nickel equivalent ratio controls between 0.9~1.1.
3. high temperature resistant flue austenitic stainless steel according to claim 1 and 2, it is characterized in that: consist of by mass percentage: C:0.025%, Cr:24.5%, Si:0.45%, Ni:20.1%, Mn:1.5%, W:2.01, N:0.08%, P:0.018%, S:0.0005%, surplus is Fe.
4. high temperature resistant flue austenitic stainless steel according to claim 1 and 2, it is characterised in that: consist of by mass percentage: Cr:25%, Ni:201%, Si:0.55%, C:0.045%, Mn:1.25%, W:2.0%, N:0.1%, P:0.02%, S:0.015%, surplus is Fe.
CN201610354857.2A 2015-12-25 2016-05-26 High-temperature-resistant austenitic stainless steel for furnace pipe Pending CN105803318A (en)

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Publication number Priority date Publication date Assignee Title
CN107398681A (en) * 2017-03-17 2017-11-28 温州市建庆实业公司 A kind of high temperature resistant, erosion-resisting Compressor Air Exhaust Valve Plate and its preparation technology
CN109207852A (en) * 2018-09-29 2019-01-15 江阴祥瑞不锈钢精线有限公司 A kind of high temperature mesh belt stainless steel wire and its manufacturing method
CN113584401A (en) * 2021-08-03 2021-11-02 山东盛阳金属科技股份有限公司 310S heat-resistant steel hot continuous rolling plate coil and processing technology thereof

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