CN105794791A - Bactericidal composition containing isopyrazam and zoxamide and application of bactericidal composition - Google Patents
Bactericidal composition containing isopyrazam and zoxamide and application of bactericidal composition Download PDFInfo
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- CN105794791A CN105794791A CN201610268129.XA CN201610268129A CN105794791A CN 105794791 A CN105794791 A CN 105794791A CN 201610268129 A CN201610268129 A CN 201610268129A CN 105794791 A CN105794791 A CN 105794791A
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- zoxamide
- isopyrazam
- bactericidal composition
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
Abstract
The invention discloses a bactericidal composition containing isopyrazam and zoxamide and application of the bactericidal composition. The bactericidal composition takes the isopyrazam and the zoxamide as main effective components, wherein the mass ratio of the isopyrazam to the zoxamide is (1 to 70):(1 to 50). The bactericidal composition can be applied to control on cereal, fruit tree and vegetable diseases, has a higher synergetic effect, and is high in sterilizing speed and long in lasting period; the insecticide resistance of germs is overcome and delayed; the application cost is reduced; the control effect of the bactericidal composition is remarkably superior to that of a single agent of the isopyrazam or the zoxamide. The bactericidal composition disclosed by the invention can be used for controlling fungi diseases on crops, and particularly can be used for controlling fungi diseases such as powdery mildew of cucumber, tomato late blight, cucumber disease and downy mildew of grape; the control effect of the bactericidal composition is remarkably superior to that of the single agent.
Description
Technical field:
The present invention relates to a kind of bactericidal composition and application thereof, especially a kind of with isopyrazam and zoxamide be main active bactericidal composition and application.
Background technology
Isopyrazam (Isopyrazam), molecular formula: C20H23F2N3O, chemical name: 3-difluoromethyl-1-methyl-N-[1,2,3 ,-tetrahydrochysene=9-(1-Methylethyl)-Isosorbide-5-Nitrae-methanonaphthalen-5-base]-1H-pyrazole-4-carboxamide.
Isopyrazam is pyrazoles antibacterial, is the systemic fungicide that has concurrently of a kind of novel spectrum, protection and therapeutic activity.
Zoxamide (Zoxamide), molecular formula: C14H16Cl3NO2, structural formula:
The mechanism of action of zoxamide is very unique in Oomycete antibacterial, and it suppresses sclerotium to divide by combination and the breaking of microtubule cytoskeleton of tubulin β-subunit.Zoxamide do not affect travelling spore in travelling, sporangiocyst formed or sprout.Along with caryocinetic first circulation of bacterium, the elongation of germ tube is suppressed, thus stoping disease mattress to penetrate host plant.Controlling object is mainly used in preventing and treating ovum mattress guiding principle disease such as Rhizoma Solani tuber osi and tomato late blight, cucumber downy mildew and downy mildew of garpe etc.；Downy mildew of garpe there is specially good effect.
The industrial crops cultivated areas such as the difficulty of prevention and cure of current phytopathogen is increasing, on the one hand, along with the change of pattern of farming, melon fruits and vegetables progressively expand, and disease occurrence degree, occur quantity all to increase, and in preventing and treating, difficulty strengthens；On the other hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality, and control of plant disease is faced with significant challenge.
Summary of the invention:
It is an object of the invention to provide a kind of applied widely, plant bactericidal composition containing isopyrazam Yu zoxamide that cost is low, effective for above-mentioned technical problem.
It is a still further object of the present invention to provide this bactericidal composition and cause the application on fungal disease at preventing and treating plant epiphyte, particularly in the purposes prevented and treated on the fungal diseases such as powdery mildew of cucumber, tomato late blight, Fructus Cucumidis sativi, downy mildew of garpe.
It is an object of the invention to be achieved through the following technical solutions:
A kind of bactericidal composition containing isopyrazam and zoxamide, this bactericidal composition is with isopyrazam and zoxamide for principle active component, wherein isopyrazam is 1～70:1～50 with the mass ratio of zoxamide, and wherein in bactericidal composition, active ingredient is present in compositions with enhancing effective amount.
Described bactericidal composition, wherein isopyrazam is preferably 1～50:1～30 with the mass ratio of zoxamide, more preferably 1～20:1～10, it is most preferred that the mass ratio of isopyrazam and zoxamide is 1～5:1～10.The preferred mass proportioning of isopyrazam and zoxamide can also be: 70:1,50:1,30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50.
In the compositions of the present invention, the weight/mass percentage composition accounting for compositions both isopyrazam and zoxamide is 2～80%, it is preferable that 5～70%.
Described bactericidal composition, any one dosage form being wherein re-dubbed on pesticide with isopyrazam and zoxamide for principle active component and known auxiliary agent and excipient to allow.These known auxiliary agents, excipient has dispersant, diffusant, defoamer, wetting agent, disintegrating agent etc., calcium dodecyl benzene sulfonate can be adopted, alkylphenol polyoxyethylene, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products thereof, aliphatic amine polyoxyethylene ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, TWEEN Series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, one or more combinations in quaternary etc., excipient includes Ketohexamethylene, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
The application on preparation preventing and treating fungal diseases of plants medicine of the above-mentioned bactericidal composition.Particularly in preventing and treating Cereal, fruit tree, vegetable crop disease aspect application there is remarkable result.
Above-mentioned application, described fungal diseases of plants is at least one in powdery mildew of cucumber, tomato late blight, Fructus Cucumidis sativi, downy mildew of garpe.
The feature of bactericidal composition of the present invention:
1, isopyrazam used by the present invention and zoxamide, the mechanism of action is different, and mutual mixture will not produce low touching, can Synergistic, reduce dosage, reduce cost.
2, the present composition scope of application increases, it is adaptable to preventing and treating the refractory fungal disease of Cereal, fruit tree, vegetable, particularly preventing and treating powdery mildew of cucumber, tomato late blight, Fructus Cucumidis sativi, downy mildew of garpe etc. all has significant effect.Ascomycetes, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease are had good prevention effect by bactericidal composition of the present invention；And suppress the drug-fast generation to unitary agent (isopyrazam and zoxamide are arbitrary) of insect or fungus.Bactericidal composition of the present invention can produce higher synergistic function, and the consumption of the independent reactive compound of amount ratio of this mixture is substantially reduced, and namely the activity of mixture is more than the activity of independent component.
Compared with prior art beneficial effects of the present invention: (1) is compared with single dose, the said composition antagonism fungal disease such as fungal disease such as powdery mildew of cucumber, tomato late blight, Fructus Cucumidis sativi, downy mildew of garpe has obvious synergistic function, overcome and delayed Drug resistance, expanding prevention is composed, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative routine and the pesticide being easily generated resistance；(4) compared with single dose, produce and use cost reduces；(5) suppressing the drug-fast generation of fungus, its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is conventional method, and " % " of the present invention is mass percent.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure the different agents EC to bacterial strain50Value, adopts co-toxicity coefficient computational methods, calculates the co-toxicity coefficient (CTC) of mixture, it is determined that mixture building performance, and circular is as follows:
In mixture, a certain single dose (is generally selected EC for standard agent50Junior), it is calculated:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × A single dose the toxicity index of proportion+B single dose × B single dose proportion in mixture in mixture of theoretical toxicity index=A single dose
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theory toxicity index × 100
When co-toxicity coefficient classification: CTC is more than 120, mixture has synergetic, is antagonism when CTC is less than 80, and CTC is summation action between 80-120.
According to effective ingredient isopyrazam (A): zoxamide (B) quality proportioning is: 80:1,70:1,50:1,30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50,1:60 test, measure its co-toxicity coefficient to Plasmopara viticola (Plasmoparaviticola (Berk.dtCurtis) Berl.EtdeToni).
Table 1: the isopyrazam+zoxamide different ratio indoor biometrics result to downy mildew of garpe
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 13.16% isopyrazam EC | Y=4.615+2.031X | 1.548 | - |
| 24% zoxamide SC | Y=4.009+1.247X | 6.235 | - |
| A:B=80:1 | Y=3.180+2.237X | 6.509 | 96.69 |
| A:B=70:1 | Y=3.541+2.365X | 4.140 | 152.20 |
| A:B=50:1 | Y=1.996+4.512X | 4.633 | 136.59 |
| A:B=30:1 | Y=4.609+0.725X | 3.464 | 184.45 |
| A:B=20:1 | Y=4.304+1.201X | 3.801 | 170.12 |
| A:B=10:1 | Y=3.395+2.547X | 4.266 | 156.89 |
| A:B=5:1 | Y=4.209+1.236X | 4.366 | 163.25 |
| A:B=2.5:1 | Y=2.435+4.210X | 4.067 | 195.24 |
| A:B=1:1 | Y=4.747+0.365X | 4.943 | 202.10 |
| A:B=1:2 | Y=2.380+2.980X | 7.569 | 165.12 |
| A:B=1:4 | Y=3.652+1.352X | 9.932 | 157.48 |
| A:B=1:6 | Y=4.591+0.356X | 14.080 | 124.51 |
| A:B=1:10 | Y=1.752+3200X | 10.354 | 190.20 |
| A:B=1:20 | Y=3.182+1.457X | 17.679 | 124.15 |
| A:B=1:30 | Y=2.182+2.302X | 16.750 | 136.59 |
| A:B=1:50 | Y=3.575+1.245X | 13.941 | 170.04 |
| A:B=1:60 | Y=0.639+3.332X | 20.369 | 117.46 |
Field control effectiveness test:
The pesticidal preparations prepared with above-described embodiment prevents and treats downy mildew of garpe test.
1, test processes: this test medicine consumption sets three concentration for the treatment of respectively according to the difference of each composition, and comparison medicament is pesticide single dose 13.16% isopyrazam EC and 24% zoxamide SC and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, repeat 3 times；Investigation drug effect method after investigating before dispenser and preventing and treating is: randomization 5 point in test treatment region, carries out severity Scaling according to country's field test relevant criterion, calculates preventive effect.Result of the test is in Table 2:
Table 2 field test effect
By indoor biometrics and field efficacy it is shown that isopyrazam and zoxamide compositions have obvious synergistic function, the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, has using value in agricultural is applied.
Two kinds of reactive compounds can be processed into any one dosage form of permission, with specific embodiment, the preparation that two kinds of effective ingredient are processed into is described below, but the preparation that these two kinds of active component can be processed is not limited only to set forth below.
Embodiment 1:15% isopyrazam zoxamide wettable powder (1:2)
By isopyrazam 5g, zoxamide 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 15% isopyrazam zoxamide wettable powder.
Embodiment 2:15% isopyrazam zoxamide wettable powder (1:4)
By isopyrazam 3g, zoxamide 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 15% isopyrazam zoxamide wettable powder.
Embodiment 3:14% isopyrazam zoxamide wettable powder (1:6)
By isopyrazam 2g, zoxamide 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 14% isopyrazam zoxamide wettable powder.
Embodiment 4:20% isopyrazam zoxamide suspending agent (1:1)
Weigh 10g isopyrazam, 10g zoxamide, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredient percent under the effect of sand mill is 20% isopyrazam zoxamide suspending agent.
Embodiment 5:55% isopyrazam zoxamide aqueous emulsion (1:10)
Weigh 5g isopyrazam, 50g zoxamide, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into the mixing of mixing kettle high speed, and making effective Ingredient percent is 55% isopyrazam zoxamide aqueous emulsion.Embodiment 6:42% isopyrazam zoxamide cream (1:20)
Weighing 2g isopyrazam, 40g zoxamide, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 42% isopyrazam zoxamide cream.
Embodiment 7:70% isopyrazam zoxamide cream (2.5:1)
Weighing 50g isopyrazam, 20g zoxamide, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor oil polyoxyethylene ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 70% isopyrazam zoxamide cream.
Embodiment 8:18% isopyrazam zoxamide water dispersion granule (5:1)
Weigh 15g isopyrazam, 3g zoxamide, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, kieselguhr 28g complements to 100g, and by water dispersible granular agent method, above raw material is formed with effect Ingredient percent is 17% isopyrazam zoxamide water dispersion granule.
Embodiment 9:11% isopyrazam zoxamide cream (10:1)
Weighing 10g isopyrazam, 1g zoxamide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 11% isopyrazam zoxamide cream.
Embodiment 10:31.5% isopyrazam zoxamide microemulsion (20:1)
Weigh 30g isopyrazam, 1.5g zoxamide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.The method that above raw material is prepared microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 31.5% isopyrazam zoxamide microemulsion.
Embodiment 11:31% isopyrazam zoxamide cream (30:1)
Weighing 30g isopyrazam, 1g zoxamide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 31% isopyrazam zoxamide cream.
Embodiment 12:51% isopyrazam zoxamide suspending agent (50:1)
Weigh 50g isopyrazam, 1g zoxamide, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredient percent under the effect of sand mill is 51% isopyrazam zoxamide suspending agent.
Embodiment 13:32% isopyrazam zoxamide microemulsion (1:15)
Weigh 2g isopyrazam, 30g zoxamide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.The method that above raw material is prepared microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 32% isopyrazam zoxamide microemulsion.
Embodiment 14:6% isopyrazam zoxamide aqueous emulsion (1:5)
Weigh 1g isopyrazam, 5g zoxamide, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, add water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into the mixing of mixing kettle high speed, and making effective Ingredient percent is 6% isopyrazam zoxamide aqueous emulsion.
Embodiment 15:62% isopyrazam zoxamide microemulsion (1:30)
Weigh 2g isopyrazam, 60g zoxamide, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.The method that above raw material is prepared microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 62% isopyrazam zoxamide microemulsion.
Embodiment 16:51% isopyrazam zoxamide suspending agent (1:50)
Weigh 1g isopyrazam, 50g zoxamide, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, xanthan gum 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complementing to 100g with water, making effective Ingredient percent under the effect of sand mill is 51% isopyrazam zoxamide suspending agent.
Embodiment 17:7% isopyrazam zoxamide water dispersion granule (1:2.5)
Weigh 2g isopyrazam, 5g zoxamide, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, and by water dispersible granular agent method, above raw material is formed with effect Ingredient percent is 7% isopyrazam zoxamide water dispersion granule.
Claims (10)
1. the bactericidal composition containing isopyrazam and zoxamide, it is characterised in that this bactericidal composition is with isopyrazam and zoxamide for principle active component, and wherein isopyrazam is 1～70:1～50 with the mass ratio of zoxamide.
2. bactericidal composition according to claim 1, it is characterised in that the mass ratio of described isopyrazam and zoxamide is 1～50:1～30.
3. bactericidal composition according to claim 2, it is characterised in that the mass ratio of described isopyrazam and zoxamide is 1～20:1～10.
4. bactericidal composition according to claim 3, it is characterised in that the mass ratio of described isopyrazam and zoxamide is 1～5:1～10.
5. bactericidal composition according to claim 1, it is characterised in that it is 2-80% that both described isopyrazam and zoxamide account for the weight/mass percentage composition of compositions.
6. bactericidal composition according to claim 5, it is characterised in that it is 5-70% that both described isopyrazam and zoxamide account for the weight/mass percentage composition of compositions.
7. bactericidal composition according to claim 1, it is characterised in that any one dosage form being configured on pesticide with isopyrazam and zoxamide for principle active component and insecticides adjuvant, excipient to allow.
8. bactericidal composition according to claim 7, it is characterised in that described dosage form is cream, suspending agent, aqueous emulsion, wettable powder or water dispersion granule.
9. the application on preparation preventing and treating fungal diseases of plants medicine of the bactericidal composition described in claim 1.
10. application according to claim 9, it is characterised in that described fungal diseases of plants is at least one in powdery mildew of cucumber, tomato late blight, Fructus Cucumidis sativi, downy mildew of garpe.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109221121A (en) * | 2018-09-25 | 2019-01-18 | 广东广康生化科技股份有限公司 | A kind of bactericidal composition and application thereof containing zoxamide and fluopyram |
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|---|---|---|---|---|
| CN101035432A (en) * | 2004-10-08 | 2007-09-12 | 辛根塔参与股份公司 | Fungicidal compositions |
| CN101677558A (en) * | 2007-04-25 | 2010-03-24 | 先正达参股股份有限公司 | fungicidal compositions |
| EP2366289A1 (en) * | 2010-03-18 | 2011-09-21 | Basf Se | Synergistic fungicidal mixtures |
-
2016
- 2016-04-26 CN CN201610268129.XA patent/CN105794791A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101035432A (en) * | 2004-10-08 | 2007-09-12 | 辛根塔参与股份公司 | Fungicidal compositions |
| CN101677558A (en) * | 2007-04-25 | 2010-03-24 | 先正达参股股份有限公司 | fungicidal compositions |
| EP2366289A1 (en) * | 2010-03-18 | 2011-09-21 | Basf Se | Synergistic fungicidal mixtures |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109221121A (en) * | 2018-09-25 | 2019-01-18 | 广东广康生化科技股份有限公司 | A kind of bactericidal composition and application thereof containing zoxamide and fluopyram |
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Application publication date: 20160727 |