CN105780047A - Efficient safe electrolytic bath - Google Patents

Efficient safe electrolytic bath Download PDF

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Publication number
CN105780047A
CN105780047A CN201410831109.XA CN201410831109A CN105780047A CN 105780047 A CN105780047 A CN 105780047A CN 201410831109 A CN201410831109 A CN 201410831109A CN 105780047 A CN105780047 A CN 105780047A
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CN
China
Prior art keywords
plate
temperature sensor
electrolytic bath
electrolysis bath
highly effective
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Pending
Application number
CN201410831109.XA
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Chinese (zh)
Inventor
黄婉雅
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Foshan Baohang Machinery Equipment Industry Intellectual Property Services Co Ltd
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Foshan Baohang Machinery Equipment Industry Intellectual Property Services Co Ltd
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Priority to CN201410831109.XA priority Critical patent/CN105780047A/en
Publication of CN105780047A publication Critical patent/CN105780047A/en
Pending legal-status Critical Current

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Abstract

The invention discloses an efficient safe electrolytic bath. The efficient safe electrolytic bath comprises a cylindrical insulation electrolytic bath shell, a circular-ring-shaped anode plate and a cylindrical cathode plate. The cathode plate is located in the anode plate. An electric conductive circular cover plate is arranged at the top in the electrolytic bath shell, and an electric conductive circular bottom plate is arranged at the bottom in the electrolytic bath shell. The cathode plate and the cover plate are connected into a whole, and the anode plate and the bottom plate are connected into a whole. The electrolytic bath shell is further connected with a temperature control device. The cover plate and the bottom plate are connected with a first power source and a second power source correspondingly. The first power source and the second power source are connected in parallel. The space between the anode plate and the cathode plate is filled with particle electrodes. Ionic membranes are further arranged between the cathode plate and the anode plate. The efficient safe electrolytic bath has the advantages of being capable of increasing the electrolytic speed, improving the electrolytic rate, controlling the temperature in the electrolytic bath and preventing the voltage swing phenomenon, and further has the advantages of being simple in structure, easy to manufacture and convenient to carry.

Description

A kind of electrolysis bath of highly effective and safe
Technical field
The present invention relates to a kind of electrolysis bath, particularly relate to the electrolysis bath of a kind of highly effective and safe.
Technical background
Traditional electrolytic cell equipment is simple two-dimensional flat plate electric pole type, equipment body is made up of vertical placement, opposing parallel, interlaced yin, yang pole plate, auxiliary is with power supply, yin, yang pole plate can be the metallic plate of unlike material, the equipment of ion-exchange membrane electrolyzer also exists that area ratio is little, space-time treating capacity is few, current efficiency is low, energy consumption is big, high cost shortcoming, and production efficiency is not high.
Multidimension electrode is to pass the granule electrode filling bulk material composition between two-dimensional electrode, and the area ratio that three-diemsnional electrode electro-catalysis processes is greatly increased, and interparticle distance is little, thus mass transfer in liquid phase efficiency is high.But it is slower for the electrolyte velocity processing high concentration that existing three-dimensional catalytic processes equipment.
Ion-exchange membrane electrolyzer be at present in chlorine industry for producing the equipment of the main use of alkali liquor, hydrogen and chlorine.Ion-exchange membrane electrolyzer of the prior art, generally comprise electrolytic cell body and groove lid, minus plate, positive plate and ionic membrane that described electrolysis bath matches, described cell body is provided with electrolyte import and export, described electrolytic bath lid is provided with gas outlet, described minus plate and positive plate opposing parallel be located in electrolysis bath, described ionic membrane is located between yin, yang pole plate and described electrolysis bath is divided into two parts, is all filled with granule electrode between described minus plate and ionic membrane, positive plate and ionic membrane.This electrolysis bath can accelerate electrolytic efficiency to a certain extent, but the variations in temperature that this structure is in electrolytic process is very big, there is voltage swing phenomenon;And this electrolysis bath is unfavorable for transport.
Summary of the invention
The technical problem to be solved in the present invention is to control the voltage stabilization in electrolysis bath, thus improving electrolyzing rate;In order to overcome this problem to provide the electrolysis bath of a kind of highly effective and safe.
For solving above-mentioned technical problem, the electrolysis bath of a kind of highly effective and safe of the present invention, including the electrolytic cell housing of insulation;Also including annular positive plate and cylindrical female pole plate, described minus plate is in described positive plate;The top of described electrolytic bath shell intracoelomic cavity is provided with the cover plate that can conduct electricity, and is provided with the base plate of conduction bottom it;Described minus plate is connected with described cover plate, and described positive plate is connected with described base plate;Described cover plate and described base plate electrically connect with the first power supply and second source respectively, and described first power supply and described second source are parallel relationship;It is filled with granule electrode between described positive plate and described minus plate;It is also provided with ionic membrane between described minus plate and described positive plate;Described cover plate top is provided with passage, and described passage connects with gas collection capsule.
Further, described electrolytic cell housing being also connected with attemperating unit, attemperating unit is made up of the first temperature sensor and the second temperature sensor, current control module and heater;Described first temperature sensor and the second described temperature sensor are respectively provided with and electrically connect with described minus plate and positive plate;Described current control module electrically connects with the first temperature sensor and the second temperature sensor;Described heater is connected with current control module.
Further, described current control module is made up of microprocessor and second source;Described microprocessor electrically connects with second source;Described microprocessor described heater respectively, described first temperature sensor and described second temperature sensor electrical connection.
Further, described heater is heating wire.
Further, the top center position of described electrolytic cell housing has a manhole, and the rotating shaft being provided with motor is connected with described cover plate by this through hole.
Further, the top position of described electrolytic cell housing has two screwed holes, the suspension ring screwed hole being bolted to electrolytic cell housing by connecting.
After adopting said structure, the electrolysis bath of a kind of highly effective and safe of the present invention, it has quickening electrolysis speed, improves electrolyzing rate;Control temperature in electrolysis bath, it is prevented that the generation of voltage swing phenomenon;This invention also has simple in construction, it is easy to manufacture, it is simple to the advantage of carrying.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is further detailed explanation:
Fig. 1 is the structural representation of one embodiment of the invention.
In figure: 1 is electrolytic cell housing, 2 is cover plate, and 3 is base plate, 4 is motor, and 5 is second source, and 6 is the first power supply, 7 is microprocessor, and 8 is positive plate, and 9 is minus plate, 10 is ionic membrane, and 11 is heater, and 12 is the second temperature sensor, 13 is the first temperature sensor, 14 is suspension ring, and 15 is bolt, and 16 is granule electrode.
Detailed description of the invention
As it is shown in figure 1, the electrolysis bath of a kind of highly effective and safe, including cylindrical insulation electrolytic slot shell 1, annular positive plate 8 and cylindrical female pole plate 9;Described minus plate 9 is in positive plate 8;The described top in electrolytic cell housing 1 is provided with the circular cover 2 of conduction, is provided with the circular bottom plate 3 of conduction bottom it;Minus plate 8 is connected with cover plate 2, and positive plate 9 is connected with base plate 3;Described electrolytic cell housing 1 is also connected with attemperating unit;Described cover plate 2 is connected with the first power supply 6 and second source 5 respectively with described base plate 3, and described first power supply and described second source are parallel relationship, facilitate unified management;It is filled with granule electrode 16 between described positive plate 8 and described minus plate 9;It is also provided with ionic membrane 10 between described minus plate 9 and described positive plate 8.The present invention together constitutes multidimension electrode response system by minus plate 9 and positive plate 8 and the granule electrode 16 being supported with catalytic specie coating that is filled between pole plate.It is energized to minus plate 9 and positive plate 8 respectively through the first power supply 6 and second source 5 during work, makes solution generation cell reaction, allow ion produced by electrolysis be attached on ionic membrane 10, and this structure can be greatly improved electrolyzing rate.
Described cover plate 2 top is provided with passage, and described passage connects with gas collection capsule;Passage and gas collection bag apparatus are set, collect in time in electrolytic process, it is possible to create gas, alleviate the pressure in described electrolytic bath shell body, it is ensured that the safety of use.
Described attemperating unit is to be made up of the first temperature sensor 13 and the second temperature sensor 12, second source 5, microprocessor 7 and heater 11;The first described temperature sensor 13 and the second described temperature sensor 12 are separately positioned on minus plate 9 and positive plate 8;Described microprocessor 7 passes through to electrically connect with second source 5;Described microprocessor 7 is respectively adopted electrically connects with heater the 11, first temperature sensor 13 and the second temperature sensor 12;Described heater 11 is heating wire.This structure measures, by the first temperature sensor 13 and the second temperature sensor 12, the temperature being positioned on positive plate 8 and minus plate 9 respectively, and the numerical value of temperature is passed to microprocessor 7, microprocessor 7 contrasts both temperature, electric current can be passed to heating wire when difference is excessive, the temperature difference of positive plate 8 and minus plate 9 is stable to make heating wire works ensure, thus the temperature controlled in electrolysis bath, it is prevented that the generation of voltage swing phenomenon.
Having through hole on described cover plate 2, the rotation axle that motor 4 connects is connected with cover plate 2 by this through hole;The rotation axle connected by motor 4 during work drives cover plate 2 to rotate, so that minus plate 9 also rotates.This structure can not only accelerate electrolytic speed, and the temperature that the first temperature sensor 13 is surveyed can be made more accurate.
The top position of described electrolytic cell housing 1 has two screwed holes, and suspension ring 14 are fixed on the screwed hole of electrolytic cell housing 1 by the bolt 15 connected;The screw thread of the screw thread of bolt 15 and described screwed hole is mutually.This structure is in order to convenient, electrolysis bath to be carried, and can be sling electrolysis bath by suspension ring 14;And the present invention also has simple in construction, easily fabricated, electrolyzing rate advantages of higher.
The know-why of the present invention is described above in association with specific embodiment.These descriptions are intended merely to explanation principles of the invention, and can not be construed to limiting the scope of the invention by any way.Based on explanation herein, those skilled in the art need not pay performing creative labour can associate other detailed description of the invention of the present invention, and these modes fall within protection scope of the present invention.

Claims (6)

1. an electrolysis bath for highly effective and safe, including the electrolytic cell housing of insulation, it is characterised in that: also including annular positive plate and cylindrical female pole plate, described minus plate is in described positive plate;The top of described electrolytic bath shell intracoelomic cavity is provided with the cover plate that can conduct electricity, and is provided with the base plate of conduction bottom it;Described minus plate is connected with described cover plate, and described positive plate is connected with described base plate;Described cover plate and described base plate electrically connect with the first power supply and second source respectively, and described first power supply and described second source are parallel relationship;It is filled with granule electrode between described positive plate and described minus plate;It is also provided with ionic membrane between described minus plate and described positive plate;
Described cover plate top is provided with passage, and described passage connects with gas collection capsule.
2. the electrolysis bath of a kind of highly effective and safe according to claim 1, it is characterised in that: being also connected with attemperating unit on described electrolytic cell housing, attemperating unit is made up of the first temperature sensor and the second temperature sensor, current control module and heater;Described first temperature sensor and the second described temperature sensor are respectively provided with and electrically connect with described minus plate and positive plate;Described current control module electrically connects with the first temperature sensor and the second temperature sensor;Described heater is connected with current control module.
3. the electrolysis bath of a kind of highly effective and safe according to claim 2, it is characterised in that: described current control module is made up of microprocessor and second source;Described microprocessor electrically connects with second source;Described microprocessor described heater respectively, described first temperature sensor and described second temperature sensor electrical connection.
4. the electrolysis bath of a kind of highly effective and safe according to claim 2, it is characterised in that: described heater is heating wire.
5. the electrolysis bath of a kind of highly effective and safe according to claim 1, it is characterised in that: the top center position of described electrolytic cell housing has a manhole, and the rotating shaft being provided with motor is connected with described cover plate by this through hole.
6. the electrolysis bath of a kind of highly effective and safe according to claim 1, it is characterised in that: the top position of described electrolytic cell housing has two screwed holes, the suspension ring screwed hole being bolted to electrolytic cell housing by connecting.
CN201410831109.XA 2014-12-25 2014-12-25 Efficient safe electrolytic bath Pending CN105780047A (en)

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Application Number Priority Date Filing Date Title
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CN105780047A true CN105780047A (en) 2016-07-20

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108570689A (en) * 2018-04-24 2018-09-25 大连交通大学 Electrolysis prepares the device and method of chlorine dioxide
CN109750315A (en) * 2017-11-07 2019-05-14 丹阳市日晟工业设备有限公司 High-effect ionic membrane electrolysis cells
CN115613064A (en) * 2022-10-26 2023-01-17 五华县百洁灵科技有限公司 High-efficiency electrolysis device adopting multi-channel ionic membrane

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1331251A (en) * 1970-12-22 1973-09-26 Cjb Developments Ltd Electrochemical processes
CN1425079A (en) * 2000-04-19 2003-06-18 阿姆基纳股份公司 Electrolytic cell and method for electrolysis
CN101624228A (en) * 2009-08-06 2010-01-13 浙江工业大学 Pipe-type packed bed electrolyzing device and method for treating organic wastewater
CN101949041A (en) * 2010-10-08 2011-01-19 褚礼政 Voltage swing-eliminating electrolytic cell
CN101956217A (en) * 2010-10-08 2011-01-26 褚礼政 Temperature equalizing electrolysis bath
CN103103559A (en) * 2012-12-13 2013-05-15 苏州新区化工节能设备厂 Ionic membrane electrolytic bath
CN103114300A (en) * 2012-12-13 2013-05-22 苏州新区化工节能设备厂 Single-anode double-cathode ion-exchange membrane electrolytic unit cell
CN104030412A (en) * 2014-06-30 2014-09-10 杨小佳 Three-dimensional electrocoagulation device for deep treatment of fluorine-containing wastewater

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1331251A (en) * 1970-12-22 1973-09-26 Cjb Developments Ltd Electrochemical processes
CN1425079A (en) * 2000-04-19 2003-06-18 阿姆基纳股份公司 Electrolytic cell and method for electrolysis
CN101624228A (en) * 2009-08-06 2010-01-13 浙江工业大学 Pipe-type packed bed electrolyzing device and method for treating organic wastewater
CN101949041A (en) * 2010-10-08 2011-01-19 褚礼政 Voltage swing-eliminating electrolytic cell
CN101956217A (en) * 2010-10-08 2011-01-26 褚礼政 Temperature equalizing electrolysis bath
CN103103559A (en) * 2012-12-13 2013-05-15 苏州新区化工节能设备厂 Ionic membrane electrolytic bath
CN103114300A (en) * 2012-12-13 2013-05-22 苏州新区化工节能设备厂 Single-anode double-cathode ion-exchange membrane electrolytic unit cell
CN104030412A (en) * 2014-06-30 2014-09-10 杨小佳 Three-dimensional electrocoagulation device for deep treatment of fluorine-containing wastewater

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109750315A (en) * 2017-11-07 2019-05-14 丹阳市日晟工业设备有限公司 High-effect ionic membrane electrolysis cells
CN108570689A (en) * 2018-04-24 2018-09-25 大连交通大学 Electrolysis prepares the device and method of chlorine dioxide
CN115613064A (en) * 2022-10-26 2023-01-17 五华县百洁灵科技有限公司 High-efficiency electrolysis device adopting multi-channel ionic membrane

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Application publication date: 20160720