CN103103559A - Ionic membrane electrolytic bath - Google Patents

Ionic membrane electrolytic bath Download PDF

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Publication number
CN103103559A
CN103103559A CN2012105385336A CN201210538533A CN103103559A CN 103103559 A CN103103559 A CN 103103559A CN 2012105385336 A CN2012105385336 A CN 2012105385336A CN 201210538533 A CN201210538533 A CN 201210538533A CN 103103559 A CN103103559 A CN 103103559A
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CN
China
Prior art keywords
electrode
ionic membrane
electrolyzer
electrolytic bath
ion
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012105385336A
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Chinese (zh)
Inventor
黄东
包金祥
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Suzhou New District Chemical Equipment Plant
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Suzhou New District Chemical Equipment Plant
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou New District Chemical Equipment Plant filed Critical Suzhou New District Chemical Equipment Plant
Priority to CN2012105385336A priority Critical patent/CN103103559A/en
Publication of CN103103559A publication Critical patent/CN103103559A/en
Pending legal-status Critical Current

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Abstract

The invention relates to an ionic membrane electrolytic bath which comprises an electrolytic bath body, a bath cover matched with the electrolytic bath, a cathode net, an anode net and an ionic membrane. The electrolytic bath is provided with an electrolyte inlet and an electrolyte outlet, the bath cover of the electrolytic bath is provided with air outlets, the cathode net and the anode net are arranged in the electrolytic bath relatively in parallel, the ionic membrane is arranged between the cathode net and the anode net, and separates the electrolytic bath into two parts, particle electrodes are respectively filled between the cathode net and the ionic membrane as well as between the anode net and the ionic membrane. A cathode plate, an anode plate and the particle electrodes form a multidimensional electrode reaction system, wherein a catalytic material coating is loaded on the particle electrodes which are filled between the anode and cathode plates, and the electrolytic efficiency is greatly improved.

Description

Ion-exchange membrane electrolyzer
Technical field
The present invention relates to a kind of ion-exchange membrane electrolyzer, be specifically related to a kind of ion-exchange membrane electrolyzer that is filled with granule electrode.
Background technology
Ion-exchange membrane electrolyzer be at present in chlorine industry for the production of the equipment of the main use of alkali lye, hydrogen and chlorine.
Traditional electrolytic cell equipment is simple two-dimensional flat plate electric pole type, equipment body is made of vertical placement, opposing parallel, interlaced yin, yang pole plate, auxiliary with power supply, the yin, yang pole plate can be the metal sheet of unlike material, the equipment of ion-exchange membrane electrolyzer exists that Area Ratio is little, the space-time treatment capacity is few, current efficiency is low, energy consumption is large, the high cost shortcoming, and production efficiency is not high.
Multidimension electrode is the granule electrode of filling the granulated material formation between two-dimensional electrode passing, and the Area Ratio that the three-diemsnional electrode electrocatalysis is processed increases greatly, and spacing of particle is little, thereby mass transfer in liquid phase efficient is high.But existing three-dimensional catalytic treatment equipment is slower for the electrolytic solution speed of processing high density.
Summary of the invention
The technical problem to be solved in the present invention is: propose a kind of ion-exchange membrane electrolyzer high to the high salt concentration water treatment efficiency.
The present invention is that the technical scheme that solves the problems of the technologies described above proposition is: a kind of ion-exchange membrane electrolyzer, the groove lid, cathode screen, anode network and the ionic membrane that comprise electrolytic cell body, match with described electrolyzer, described cell body is provided with the electrolytic solution import and export, described electrolytic bath covers and is provided with the air outlet, being located in electrolyzer of described cathode screen and anode network opposing parallel, described ionic membrane is located between the yin, yang polar net and with described electrolyzer and is divided into two portions, all is filled with granule electrode between described cathode screen and ionic membrane, anode network and ionic membrane.
The invention has the beneficial effects as follows:
Yin, yang pole plate of the present invention and the granule electrode that is filled between pole plate have consisted of the multidimension electrode reactive system jointly, have greatly improved electrolytic efficiency.
Having improved of technique scheme:
Further improving of granule electrode had: by load by the ceramic particle of catalytic specie coating, uncoated ceramic particle and gac by volume 2:2:1 evenly mix the Bipolar Micro-Electrode electrode that forms.
More abundant for electrolysis, the Bipolar Micro-Electrode electrode of filling between negative plate, positive plate has vesicular structure, and the particle diameter of Bipolar Micro-Electrode electrode is the 3-5 millimeter.
To further improving of technical scheme in the present invention be: it is complex metal oxides tindioxide, antimonous oxide and Manganse Dioxide that load has the catalytic specie of the ceramic particle institute load of catalytic specie coating.
Description of drawings
Below in conjunction with accompanying drawing, the ion-exchange membrane electrolyzer that is filled with granule electrode in the present invention is described further.
Fig. 1 is the structural representation of embodiment intermediate ion membrane electrolyser.
Embodiment
Embodiment
According to shown in Figure 1, the ion-exchange membrane electrolyzer in the present invention, the groove lid 2, cathode screen 3, anode network 4 and the ionic membrane 5 that comprise electrolytic cell body 1, match with electrolyzer.
Wherein, cell body 1 is provided with electrolytic solution import and export 6,7, and electrolytic bath lid 2 is provided with air outlet 8.
Wherein, being located in electrolyzer of cathode screen 3 and anode network 4 opposing parallel, ionic membrane 5 is located between yin, yang polar net 3,4 and with electrolyzer and is divided into two portions, all is filled with granule electrode 9 between cathode screen 3 and ionic membrane 5, anode network 4 and ionic membrane 5.
Granule electrode 9 by load by the ceramic particle of catalytic specie coating, uncoated ceramic particle and gac by volume 2:2:1 evenly mix the Bipolar Micro-Electrode electrode that forms.The Bipolar Micro-Electrode electrode has vesicular structure, and the particle diameter of Bipolar Micro-Electrode electrode is the 3-5 millimeter.It is complex metal oxides tindioxide, antimonous oxide and Manganse Dioxide that load has the catalytic specie of the ceramic particle institute load of catalytic specie coating.
The above-described embodiment that is not limited to of the present invention, all employings are equal to replaces the technical scheme that forms, and all drops in the protection domain of requirement of the present invention.

Claims (4)

1. ion-exchange membrane electrolyzer, the groove lid, cathode screen, anode network and the ionic membrane that comprise electrolytic cell body, match with described electrolyzer, described cell body is provided with the electrolytic solution import and export, described electrolytic bath covers and is provided with the air outlet, being located in electrolyzer of described cathode screen and anode network opposing parallel, described ionic membrane is located between the yin, yang polar net and with described electrolyzer and is divided into two portions, it is characterized in that: all be filled with granule electrode between described cathode screen and ionic membrane, anode network and ionic membrane.
2. ion-exchange membrane electrolyzer according to claim 1 is characterized in that: described granule electrode by load by the ceramic particle of catalytic specie coating, uncoated ceramic particle and gac by volume 2:2:1 evenly mix the Bipolar Micro-Electrode electrode that forms.
3. ion-exchange membrane electrolyzer according to claim 2, it is characterized in that: the Bipolar Micro-Electrode electrode of filling between negative plate, positive plate has vesicular structure, and the particle diameter of Bipolar Micro-Electrode electrode is the 3-5 millimeter.
4. ion-exchange membrane electrolyzer according to claim 2 is characterized in that: it is complex metal oxides tindioxide, antimonous oxide and Manganse Dioxide that load has the catalytic specie of the ceramic particle institute load of catalytic specie coating.
CN2012105385336A 2012-12-13 2012-12-13 Ionic membrane electrolytic bath Pending CN103103559A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012105385336A CN103103559A (en) 2012-12-13 2012-12-13 Ionic membrane electrolytic bath

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012105385336A CN103103559A (en) 2012-12-13 2012-12-13 Ionic membrane electrolytic bath

Publications (1)

Publication Number Publication Date
CN103103559A true CN103103559A (en) 2013-05-15

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CN (1) CN103103559A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105780047A (en) * 2014-12-25 2016-07-20 佛山市宝航机械装备行业知识产权服务有限公司 Efficient safe electrolytic bath
WO2016141768A1 (en) * 2015-03-09 2016-09-15 罗民雄 Electrode mainly prepared from ceramic material and applicable to water electrolysis device
CN109750315A (en) * 2017-11-07 2019-05-14 丹阳市日晟工业设备有限公司 High-effect ionic membrane electrolysis cells

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2459329Y (en) * 2000-12-14 2001-11-14 深圳市柯雷恩环境科技有限公司 Anion membrane electrolytic bath
CN201325897Y (en) * 2008-11-18 2009-10-14 南京赛佳环保科技有限责任公司 Waste water treatment equipment of multi-dimensional electrode electrical catalytic reactor of horizontal electrode plate
CN203065587U (en) * 2012-12-13 2013-07-17 苏州新区化工节能设备厂 Ion-exchange membrane electrolytic bath

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2459329Y (en) * 2000-12-14 2001-11-14 深圳市柯雷恩环境科技有限公司 Anion membrane electrolytic bath
CN201325897Y (en) * 2008-11-18 2009-10-14 南京赛佳环保科技有限责任公司 Waste water treatment equipment of multi-dimensional electrode electrical catalytic reactor of horizontal electrode plate
CN203065587U (en) * 2012-12-13 2013-07-17 苏州新区化工节能设备厂 Ion-exchange membrane electrolytic bath

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105780047A (en) * 2014-12-25 2016-07-20 佛山市宝航机械装备行业知识产权服务有限公司 Efficient safe electrolytic bath
WO2016141768A1 (en) * 2015-03-09 2016-09-15 罗民雄 Electrode mainly prepared from ceramic material and applicable to water electrolysis device
CN109750315A (en) * 2017-11-07 2019-05-14 丹阳市日晟工业设备有限公司 High-effect ionic membrane electrolysis cells

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Application publication date: 20130515