CN105552256B - Generate electricity bottle and its power generation bottle cap - Google Patents
Generate electricity bottle and its power generation bottle cap Download PDFInfo
- Publication number
- CN105552256B CN105552256B CN201510969278.4A CN201510969278A CN105552256B CN 105552256 B CN105552256 B CN 105552256B CN 201510969278 A CN201510969278 A CN 201510969278A CN 105552256 B CN105552256 B CN 105552256B
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- Prior art keywords
- lid
- power generation
- bottle
- bottle cap
- electrode
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/147—Lids or covers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/02—Details
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/30—Deferred-action cells
Abstract
A kind of power generation bottle cap, including lid, interval and electrode；The lid is placed on after corresponding bottle body to the nearly intracorporal side of bottle is defined as the inside of the lid, the other side is defined as outside, then the interval extends on the inside of the lid, at least part of the electrode is located at the inside of the lid and is separated from each other by the interval, insulating materials is divided into described to be made, the electrode includes at least one cathode and at least one anode, and the cathode and the anode are in series or in parallel with each other；A kind of power generation bottle, including body, the body are equipped with electrolyte solution, the electrode and the electrolyte solution contacts.Power generation bottle provided by the invention and its power generation bottle cap facilitate production, easy to carry, effectively avoid self discharge, can also cooperate the body of common mineral water bottle to use by further designing, very convenient.
Description
Technical field
The present invention relates to battery more particularly to a kind of power generation bottle and its power generation bottle caps.
Background technique
Chemical cell is largely used in daily life at present.In chemical cell, it is to lean on that chemical energy, which is directly translated into electric energy,
Inside battery is spontaneous aoxidized, restored etc. chemical reactions as a result, this reaction carries out on two electrodes respectively.Cathode is living
Property substance be made of the relatively negative and stable in the electrolyte reducing agent of current potential, such as zinc, cadmium, lead active metal and hydrogen or hydrocarbonization
Close object etc..Positive active material is by current potential calibration and oxidant stable in the electrolyte forms, such as manganese dioxide, titanium dioxide
The metal oxides such as lead, nickel oxide, oxygen or air, halogen and its esters, oxyacid and its esters etc..Electrolyte be then have it is good
The material of good ionic conductivity, such as aqueous solution of acid, alkali, salt, organic or inorganic non-aqueous solution, fuse salt or solid electrolyte
Deng.
When external circuit disconnects, although there is potential difference (open-circuit voltage) between the two poles of the earth, there is no electric current, storage is in the battery
Chemical energy and be not converted into electric energy；When external circuit closure, there is electric current to flow through dispatch from foreign news agency under the action of two difference in Electrode Potential
Road.Simultaneously in inside battery, due to being not present free electron in electrolyte, the transmitting of charge it is inevitable with the two poles of the earth active material with
The material transport of the oxidation of electrolyte interface or reduction reaction and reactant and reaction product.The biography of charge in the electrolyte
Passing will also be completed by the migration of ion.Therefore, the normal charge transfer of inside battery and substance transmittance process are to guarantee normally
Export the necessary condition of electric energy.
Usually used chemical cell is that factory can be used, that is, container, electrolyte solution, electrode are just pressed one when producing
Fixed method is combined.Such battery has the characteristic of self discharge, and electricity can decline after placing a period of time, and be equipped with
Electrolyte solution keeps battery itself heavier.
It is easy to carry if a kind of assemblnig battery can be developed, the problem of self discharge is avoided without electrolyte, and can
Electrolyte solution is prepared at any time as needed, then should be had broad application prospects.
Summary of the invention
To achieve the above object, the present invention provides a kind of power generation bottle and its power generation bottle caps.
Specifically, the present invention provides a kind of power generation bottle caps, including lid, interval and electrode；The lid is placed on
The nearly intracorporal side of bottle is defined as the inside of the lid after corresponding bottle body, the other side is defined as outside, then the interval is prolonged
It stretching on the inside of the lid, at least part of the electrode is located at the inside of the lid and is separated from each other by the interval,
Insulating materials is divided into described to be made；The electrode includes at least one cathode and at least one anode, the cathode and described
Anode is in series or in parallel with each other.
Further, the power generation bottle cap further includes the conducting wire across the lid, and the electrode is fully located at the lid
The inside of body is simultaneously connected with the conducting wire.Electrode, which is set to completely on the inside of lid, connects it completely with electrolyte solution at work
Touching, utilization rate are high.
Further, the electrode is embedded in the lid, is located at the part on the outside of the lid for connecting external electrical
Road.
Further, the anode is aluminium, zinc, magnesium or other active high metallic elements and its alloy.More active gold
Category is easy to lose electronics in chemical reaction, is suitable as the anode i.e. material of battery cathode.
Preferably, the anode is made of aluminium, zinc, magnesium or its alloy.
Further, the metal (such as copper metal) that the cathode is graphite, active carbon is low with other metal actives mixes
Object is closed to be made.
Preferably, the cathode is the mixture of graphite and active carbon.Absorbent charcoal material is suitable for absorption air or pure oxygen, will
Oxygen therein is as cathode, the i.e. active material of the anode of battery；Graphitic conductive is good.
Preferably, the lid is equipped with the internal screw thread for connecting common mineral water bottle bottleneck.
The present invention also provides a kind of power generation bottles for being connected with above-mentioned power generation bottle cap, including body, and the body is equipped with electricity
Solve matter solid bag.Electrolyte solid bag is packed by porous material, such as filter paper, silk or non-woven fabrics, built-in powdered electrolyte
Solid, so that solid powder will not disperse everywhere because of carrying.The electrolyte solid bag can provide together with power generation bottle cap, necessary
When vacuum packaging to completely cut off external environment, enabling each section especially electrolyte before filling the water is dry and undergoes no deterioration, can
With long-term preservation.
Further, the electrolyte solid bag is equipped with sodium hydroxide, sodium chloride, potassium hydroxide or solid potassium chloride.
Power generation bottle provided by the invention and its power generation bottle cap are easy to produce, light-weight easy to carry, just prepare when needed
Electrolyte solution and the problem of come into operation, effectively prevent self discharge；Under special circumstances, as long as being prepared using the water obtained
Electrolyte solution can produce electricl energy, and have no particular/special requirement to water quality, convenient to use under severe conditions；Especially generate electricity bottle
The body of the common mineral water bottle of Gai Keyu is used cooperatively, very convenient.
It is described further below with reference to technical effect of the attached drawing to design of the invention, specific structure and generation, with
It is fully understood from the purpose of the present invention, feature and effect.
Detailed description of the invention
Fig. 1 is the present invention a kind of lid and interval structural schematic diagram of the bottle cap that generates electricity；
Fig. 2 is the structural schematic diagram of the power generation bottle cap on lid in Fig. 1 after connection electrode；
Fig. 3 is a kind of general structure schematic diagram for the bottle cap that generates electricity of the present invention；
Fig. 4 is a kind of power generation Bottle cap structure schematic diagram for having internal screw thread, may connect to common mineral water bottle body；
Fig. 5 is a kind of configuration schematic diagram for the bottle cap that generates electricity of the present invention, wherein increasing flow compared with the bottle cap that generates electricity in Fig. 4
Regulating valve；
In Fig. 1-Fig. 5,1- lid, 11- aperture, 2- interval, 21- outer cylinder, 3- electrode, 31- cathode, 32- anode, 33- electricity
Pole line, 4- conducting wire, 5- flow control valve, 51- valve block, 52- valve body.
Specific embodiment
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end
Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached
The embodiment of figure description is exemplary, it is intended to is used to explain the present invention, and is not considered as limiting the invention.
In the description of the present invention, it is to be understood that, term " center ", " longitudinal direction ", " transverse direction ", " length ", " width ",
" thickness ", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom" "inner", "outside", " up time
The orientation or positional relationship of the instructions such as needle ", " counterclockwise " is to be based on the orientation or positional relationship shown in the drawings, and is merely for convenience of
The description present invention and simplified description, rather than the device or element of indication or suggestion meaning must have a particular orientation, with spy
Fixed orientation construction and operation, therefore be not considered as limiting the invention.
In addition, term " first ", " second " are used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance
Or implicitly indicate the quantity of indicated technical characteristic.Define " first " as a result, the feature of " second " can be expressed or
Implicitly include one or more of the features.In the description of the present invention, the meaning of " plurality " is two or more,
Unless otherwise specifically defined.
In the present invention unless specifically defined or limited otherwise, term " installation ", " connected ", " connection ", " fixation " etc.
Term shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected；It can be machine
Tool connection, is also possible to be electrically connected；It can be directly connected, two members can also be can be indirectly connected through an intermediary
Connection inside part.For the ordinary skill in the art, above-mentioned term can be understood in this hair as the case may be
Concrete meaning in bright.
In the present invention unless specifically defined or limited otherwise, fisrt feature second feature "upper" or "lower"
It may include that the first and second features directly contact, also may include that the first and second features are not direct contacts but pass through it
Between other characterisation contact.Moreover, fisrt feature includes the first spy above the second feature " above ", " above " and " above "
Sign is right above second feature and oblique upper, or is merely representative of first feature horizontal height higher than second feature.Fisrt feature exists
Second feature " under ", " lower section " and " following " include fisrt feature right above second feature and oblique upper, or be merely representative of
First feature horizontal height is less than second feature.
Embodiment one
It is a kind of main body of bottle cap that generates electricity as shown in Figure 1, wherein lid 1 and interval 2 are integrally formed by insulating materials, lid
1 is slightly flat column, and section is that the interval 2 of cross shape extends one side, forms four separations.At wherein adjacent two
Lid 1 in separation is equipped with the aperture 11 of perforation.
Electrode 3, respectively cathode 31 and anode 32 are placed in four be separated by interval 2 separate.31 material of cathode
For the mixture of graphite and active carbon, 32 material of anode is zinc.Cathode 31, anode 32 are respectively separated setting, and sequentially use electrode
The connection conducting of line 33.Absorbent charcoal material is suitable for absorption air, (is positive oxygen therein as cathode for battery
Pole) active material；Graphitic conductive is good.
Fig. 3 is the structural schematic diagram for the power generation bottle cap that assembly is completed, and conducting wire 4 passes through aperture 11, will not pass through directly a little
It hits connected a pair of of the cathode 31 of line 33 and anode 32 connects, anode of the conducting wire being connected with cathode 31 as battery, with anode
Cathode of the 32 connected conducting wires as battery.It is sealed between conducting wire 4 and aperture 11.
Electrolyte solid bag is put into the bottle matched with lid 1, it is solid that solid bag is provided with powdered sodium hydroxide
Body.Sodium hydrate solid dissolves after injecting suitable quantity of water, forms electrolyte solution, covers lid 1, and reversing bottle body makes cathode 31 and sun
And electrolyte solution contacts, then electrolyte solution and each electrode together form zinc-air battery, the change of reaction at this time for pole 32
It is as follows to learn equation:
Cathode: Zn+2OH-=ZnO+H2O+2e-
Anode: 0.5O2+H2O+2e-=2OH-
Overall reaction: 2Zn+O2=2ZnO
It can be seen that electrolyte will not consume, the material of anode 32 becomes oxide and is lost.When anode material is complete
After full failure, lid 1 is extracted, disconnects relevant electrode connecting line 33, replacing the anode material of loss and covering back lid 1 can restore
The power supply capacity of battery.
In some cases, to provide continuous electric energy supply, can just set bottle body and be filled to electrolyte can contact electrode
3, the lid 1 of interval corresponding with cathode 31 opens up venthole, so that the cathode 31 of active carbon material touches air, thus
Oxygen needed for continuously obtaining.But the upright of body need to be kept when use, electrolyte solution is avoided to be flowed out by venthole.
It does not need venthole can be closed when continuous use, can still reverse body use at this time.
The design of this example uses when being suitable for urgent, only need to put into electrolyte in bottle and the water of acquisition is added, to water
Matter is without particular/special requirement, particularly suitable for electricity is promptly taken in field work.
Embodiment two
The present embodiment is similar with embodiment one, and difference is, the interval 2 of star section is changed to simple plate,
Its two sides is only distributed cathode 31 and anode 32 each one respectively, and cathode is changed to carbon-point, and electrolyte is changed to ammonium chloride, sodium chloride and chlorination
The aqueous solution of potassium, and cathode 31 and anode 32 are embedded in lid 1.
Due in the lid 1, the electrode 3 in this example be it is disposable, power generation bottle cap is abandoned after, working principle
Similar common dry cell.
The design of this example uses when being suitable for urgent, only need to put into electrolyte in bottle and the water of acquisition is added, to water
Matter is without particular/special requirement, particularly suitable for electricity is promptly taken in field work.
Embodiment three
The present embodiment is similar with embodiment one.In upper example cathode 31 and anode 32 respectively there are two, be equivalent to two groups of electricity
Pond series-fed, output voltage are the superposition of two groups of batteries.Interval 2 is changed to hexagon setting in this example, forms six points
Every.Compartment of terrain is discharged into three cathodes 31 and three anodes 32 in six separations, and sequentially with three groups two one group of electrode connecting line
Cathode 31 and anode 32 are connected, then three groups of electrodes are in parallel, to form the parallel output of three electromotive force, increases output electricity
Stream.
Being arranged for electrode is not limited in parallel and serial, can also need to carry out mixed connection according to current or voltage, with full
Sufficient particular demands.
In some cases, to provide continuous electric energy supply, can just set bottle body and be filled to electrolyte can contact electrode
3, the lid 1 of interval corresponding with cathode 31 opens up venthole, so that the cathode 31 of active carbon material touches air, thus
Oxygen needed for continuously obtaining.But the upright of body need to be kept when use, electrolyte solution is avoided to be flowed out by venthole.
It does not need venthole can be closed when continuous use, can still reverse body use at this time.
The design of this example uses when being suitable for urgent, only need to put into electrolyte in bottle and the water of acquisition is added, to water
Matter is without particular/special requirement, particularly suitable for electricity is promptly taken in field work.
Example IV
Power generation bottle cap schematic diagram such as Fig. 4 of the present embodiment, eliminates electrode 3 and is not shown, for illustrating lid 1 and interval
2 positional relationship.Interval 2 is similar with embodiment one to have divided four intervals.The quantity at interval can also carry out accordingly as needed
Change.
The bottleneck size of common mineral water bottle and screw thread setting are roughly the same.1 shape size of lid is similar to common mine
The setting of spring bottle, the protrusion of interval 2 extend its inside.The inner surface of lid 1 is provided with the interior spiral shell for cooperating common mineral water bottle
Line, for lid 1 to be screwed to the bottleneck with mineral water bottle.
Specific embodiment is similar with embodiment one, and difference is that anode 32 is changed to aluminium alloy, and lid 1 not compresses
In bottleneck, but it is tightened in mineral water bottle bottleneck, so that cathode 31 and anode 32 and electrolyte solution contacts.Aluminium (Al) exists
Reaction equation in alkaline electrolyte solution is as follows:
Cathode: 2Al+6OH-=Al2O3+3H2O+6e-
Anode: 0.5O2+H2O+2e-=2OH-
Overall reaction: 4Al+3O2=2Al2O3
It can be seen that electrolyte will not consume, the material of anode 32 becomes oxide and is lost.When anode material is complete
After full failure, lid 1 is extracted, disconnects relevant electrode connecting line 33, replacing the anode material of loss and covering back lid 1 can restore
The power supply capacity of battery.
In some cases, to provide continuous electric energy supply, can just set bottle body and be filled to electrolyte can contact electrode
3, the lid 1 of interval corresponding with cathode 31 opens up venthole, so that the cathode 31 of active carbon material touches air, thus
Oxygen needed for continuously obtaining.But the upright of body need to be kept when use, electrolyte solution is avoided to be flowed out by venthole.
It does not need venthole can be closed when continuous use, can still reverse body use at this time.
The design of this example uses when being suitable for urgent, only need to put into electrolyte in bottle and the water of acquisition is added, to water
Matter is without particular/special requirement, particularly suitable for electricity is promptly taken in field work.
Embodiment five
The present embodiment is similar with example IV, and is not shown in order to make it easy to understand, omitting electrode.The power generation of this example
Bottle cap structure explosive view is as shown in Figure 5.Difference with example IV is, 1 inside of lid is also connected with outer cylinder 21, outer cylinder 21 will in
In the inner every 2 packages, an opening is only stayed.
Flow control valve 5 is stamped in 21 end of outer cylinder, and flow control valve 5 includes valve block 51 and valve body 52.Valve body 52 is sheathed on
The outside of 21 end of outer cylinder, and valve block 51 is accompanied between outer cylinder 21 and valve body 52.Valve block 51 and valve body 52 have it is matching,
Homogeneous phase is every the aperture being staggered.Aperture is sector in this example.Adjustable openings are mutually rotated between valve block 51 and valve body 52
Be staggered angle, and then adjusts electrolyte solution in electrolyte solution and 21 inside cavity of outer cylinder of this bottle cap when in use in bottle
Exchange rate to adjust the reaction rate of electrode, and then adjusts the rate of electric energy production.
The aperture of valve block 51 and valve body 52 may be alternatively provided as arbitrary shape in other embodiments, can be staggered and realize flow tune
Section.
In some cases, to provide continuous electric energy supply, can just set bottle body and be filled to electrolyte can contact electrode
3, the lid 1 of interval corresponding with cathode 31 opens up venthole, so that the cathode 31 of active carbon material touches air, thus
Oxygen needed for continuously obtaining.But the upright of body need to be kept when use, electrolyte solution is avoided to be flowed out by venthole.
It does not need venthole can be closed when continuous use, can still reverse body use at this time.
The design of this example uses when being suitable for urgent, only need to put into electrolyte in bottle and the water of acquisition is added, to water
Matter is without particular/special requirement, particularly suitable for electricity is promptly taken in field work.
The preferred embodiment of the present invention has been described in detail above.It should be appreciated that those skilled in the art without
It needs creative work according to the present invention can conceive and makes many modifications and variations.Therefore, all technologies in the art
Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea
Technical solution, all should be within the scope of protection determined by the claims.
Claims (9)
1. a kind of power generation bottle cap, which is characterized in that including lid, interval and electrode；After the lid is placed on corresponding bottle body
The nearly intracorporal side of bottle is defined as the inside of the lid, the other side is defined as outside, then the interval extends the lid
Inside, at least part of the electrode are located at the inside of the lid and are separated from each other by the interval, it is described in be divided into absolutely
Edge material is made；The electrode includes at least one cathode and at least one anode, and the cathode and the anode are serially connected
Or it is in parallel；Further include cylinder, the cylinder has first end, and the first end is fixedly connected on the lid, and will be described in
Every forming hemi-closure space with the electrodes surrounding.
2. power generation bottle cap according to claim 1, which is characterized in that further include the conducting wire across the lid, the electricity
Pole is fully located at the inside of the lid and is connected with the conducting wire.
3. power generation bottle cap according to claim 1, which is characterized in that the electrode is embedded in the lid, is located at described
Part on the outside of lid is for connecting external circuit.
4. power generation bottle cap according to claim 1, which is characterized in that the anode is made of aluminium, zinc, magnesium or its alloy.
5. power generation bottle cap according to claim 4, which is characterized in that the cathode is the mixture of graphite and active carbon.
6. power generation bottle cap according to claim 1, which is characterized in that the cylinder further includes second end, the second end
It is stamped flow control valve, the flow control valve is used to adjust in cylinder and the exchange velocity of the outer electrolyte solution of cylinder, thus
Adjust the reaction rate of the anode.
7. power generation bottle cap according to claim 1-6, which is characterized in that the lid is equipped with common for connecting
The internal screw thread of mineral water bottle bottleneck.
8. a kind of power generation bottle for being connected with power generation bottle cap according to claim 1-7, which is characterized in that including bottle
Body, the body are equipped with electrolyte solid bag.
9. power generation bottle according to claim 8, which is characterized in that the electrolyte solid bag is equipped with sodium hydroxide, chlorination
Sodium, potassium hydroxide or solid potassium chloride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510969278.4A CN105552256B (en) | 2015-12-21 | 2015-12-21 | Generate electricity bottle and its power generation bottle cap |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510969278.4A CN105552256B (en) | 2015-12-21 | 2015-12-21 | Generate electricity bottle and its power generation bottle cap |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105552256A CN105552256A (en) | 2016-05-04 |
| CN105552256B true CN105552256B (en) | 2019-01-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510969278.4A Active CN105552256B (en) | 2015-12-21 | 2015-12-21 | Generate electricity bottle and its power generation bottle cap |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112459835A (en) * | 2020-11-24 | 2021-03-09 | 中国地质大学（武汉） | Device for preventing crystal blockage of tunnel drainage system in karst area |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101752518A (en) * | 2009-12-30 | 2010-06-23 | 江苏春兰清洁能源研究院有限公司 | Integral upper cover assembly of battery |
| CN202454649U (en) * | 2011-12-26 | 2012-09-26 | 中国电子科技集团公司第十八研究所 | Battery cover for thermal battery |
-
2015
- 2015-12-21 CN CN201510969278.4A patent/CN105552256B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101752518A (en) * | 2009-12-30 | 2010-06-23 | 江苏春兰清洁能源研究院有限公司 | Integral upper cover assembly of battery |
| CN202454649U (en) * | 2011-12-26 | 2012-09-26 | 中国电子科技集团公司第十八研究所 | Battery cover for thermal battery |
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| CN105552256A (en) | 2016-05-04 |
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