CN105778785A - Energy-saving environment-friendly glue and preparation method thereof - Google Patents
Energy-saving environment-friendly glue and preparation method thereof Download PDFInfo
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- CN105778785A CN105778785A CN201610376850.0A CN201610376850A CN105778785A CN 105778785 A CN105778785 A CN 105778785A CN 201610376850 A CN201610376850 A CN 201610376850A CN 105778785 A CN105778785 A CN 105778785A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses energy-saving environment-friendly glue and a preparation method thereof. The glue is prepared from, by weight, 13-17 parts of n-butyl acrylate, 14-18 parts of acrylic acid, 10-14 parts of polyvinyl acetate, 8-12 parts of methyl methacrylate, 3-4 parts of Tween-80, 0.5-1 part of diisopropyl peroxydicarbonate, 5-10 parts of ethyl alcohol, 30-40 parts of deionized water, 6-12 parts of japonica rice starch, 3-5 parts of graphene oxide quantum dots and 0.3-0.5 part of a silane coupling agent. The energy-saving environment-friendly glue does not release formaldehyde and other harmful matter harmful to human bodies in use, no harmful solvents are used in the preparation process, and the glue is safe and environmentally friendly and has good adhesion, heat resistance and mechanical performance. Besides, operation is easy, raw material sources are wide, the process procedure is short, production conditions are mild, cost and energy consumption are low, and industrial production is easy.
Description
Technical field
The invention belongs to adhesive preparation field, be specifically related to a kind of energy-conserving and environment-protective glue and preparation method thereof.
Background technology
Currently used adhesive is of a great variety, but in preparation process, major part all with the addition of one or more of the poisonous and harmful substances such as formaldehyde, dichloroethanes, dichloromethane, carbon tetrachloride, acetone, butanone, toluene, dimethylbenzene, these harmful substances not only can be to environmental concerns, also skin, mucosa etc. can be caused to damage, healthy to human body causes great threat simultaneously.Therefore, invent a kind of energy-conservation and environmental protection adhesive to be necessary to meet actual production and life requirement.
Summary of the invention
Present invention aims to prior art not enough, it is provided that a kind of energy-conserving and environment-protective glue and preparation method thereof.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of energy-conserving and environment-protective glue, counts by weight, and its raw material consists of:
N-butyl acrylate: 13 ~ 17 parts；
Acrylic acid: 14 ~ 18 parts；
Polyvinyl acetate: 10 ~ 14 parts；
Methyl methacrylate: 8 ~ 12 parts；
Polyoxyethylenesorbitan sorbitan monooleate: 3 ~ 4 parts；
Di-isopropyl peroxydicarbonate: 0.5 ~ 1 part；
Ethanol: 5-10 part；
Deionized water: 30-40 part；
Semen oryzae sativae starch: 6 ~ 12 parts；
Graphene oxide quantum dot: 3 ~ 5 parts；
Silane coupler: 0.3 ~ 0.5 part.
The lateral dimension of described graphene oxide quantum dot is 1 ~ 100nm.
The preparation method of a kind of energy-conserving and environment-protective glue as above, specifically includes following steps:
(1) n-butyl acrylate, polyvinyl acetate, acrylic acid, methyl methacrylate are mixed with ethanol, add di-isopropyl peroxydicarbonate, be sufficiently mixed at 50-60 DEG C uniformly；
(2) in step (1) gained solution, polyoxyethylenesorbitan sorbitan monooleate and deionized water, stirring and emulsifying are added；
(3) stir at addition Semen oryzae sativae starch, graphene oxide quantum dot and silane coupler are at 60-70 DEG C in step (2) gained emulsion, be cooled to room temperature, prepare described energy-conserving and environment-protective glue.
The beneficial effects of the present invention is:
(1) the energy-conserving and environment-protective glue that prepared by the present invention in use will not discharge the harmful substances such as harmful formaldehyde, and does not the most use any hazardous solvent in preparation process, therefore safety and environmental protection, applied range；
(2) formula of the present invention adds graphene oxide quantum dot, graphene oxide quantum dot be smaller in size than 100nm, have good water solublity, abundant chemical group (hydroxyl, carboxyl, epoxy resin-matrix etc.) is available for chemical modification and functionalization, can crosslink with the hydroxyl etc. in latex and be polymerized, form macromole, thus improve the cohesiveness between glue-line, thermostability and shear strength, macroscopically show as significantly improving of adhesive property and mechanical performance；
(3) preparation method of the present invention is simple to operate, and raw material sources are extensive, and technological process is short, and working condition is gentle, and production cost is low, and energy consumption is low, it is easy to industrialized production.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited only to these embodiments.
Embodiment 1
A kind of energy-conserving and environment-protective glue, counts by weight, and its raw material consists of:
N-butyl acrylate: 17 parts；
Acrylic acid: 18 parts；
Polyvinyl acetate: 14 parts；
Methyl methacrylate: 12 parts；
Polyoxyethylenesorbitan sorbitan monooleate: 4 parts；
Di-isopropyl peroxydicarbonate: 1 part；
Ethanol: 10 parts；
Deionized water: 40 parts；
Semen oryzae sativae starch: 12 parts；
Graphene oxide quantum dot: 5 parts；
Silane coupler: 0.5 part.
The lateral dimension of described graphene oxide quantum dot is 1 ~ 100nm.
The preparation method of a kind of energy-conserving and environment-protective glue as above, specifically includes following steps:
(1) n-butyl acrylate, polyvinyl acetate, acrylic acid, methyl methacrylate are mixed with ethanol, add di-isopropyl peroxydicarbonate, be sufficiently mixed at 60 DEG C uniformly；
(2) in step (1) gained solution, polyoxyethylenesorbitan sorbitan monooleate and deionized water, stirring and emulsifying are added；
(3) in step (2) gained emulsion, add Semen oryzae sativae starch, graphene oxide quantum dot and silane coupler to stir at 70 DEG C, be cooled to room temperature, prepare described energy-conserving and environment-protective glue.
Embodiment 2
A kind of energy-conserving and environment-protective glue, counts by weight, and its raw material consists of:
N-butyl acrylate: 13 parts；
Acrylic acid: 14 parts；
Polyvinyl acetate: 10 parts；
Methyl methacrylate: 8 parts；
Polyoxyethylenesorbitan sorbitan monooleate: 3 parts；
Di-isopropyl peroxydicarbonate: 0.5 part；
Ethanol: 5 parts；
Deionized water: 30 parts；
Semen oryzae sativae starch: 6 parts；
Graphene oxide quantum dot: 3 parts；
Silane coupler: 0.3 part.
The lateral dimension of described graphene oxide quantum dot is 1 ~ 100nm.
The preparation method of a kind of energy-conserving and environment-protective glue as above, specifically includes following steps:
(1) n-butyl acrylate, polyvinyl acetate, acrylic acid, methyl methacrylate are mixed with ethanol, add di-isopropyl peroxydicarbonate, be sufficiently mixed at 50 DEG C uniformly；
(2) in step (1) gained solution, polyoxyethylenesorbitan sorbitan monooleate and deionized water, stirring and emulsifying are added；
(3) in step (2) gained emulsion, add Semen oryzae sativae starch, graphene oxide quantum dot and silane coupler to stir at 60 DEG C, be cooled to room temperature, prepare described energy-conserving and environment-protective glue.
Embodiment 3
A kind of energy-conserving and environment-protective glue, counts by weight, and its raw material consists of:
N-butyl acrylate: 15 parts；
Acrylic acid: 16 parts；
Polyvinyl acetate: 12 parts；
Methyl methacrylate: 10 parts；
Polyoxyethylenesorbitan sorbitan monooleate: 3.5 parts；
Di-isopropyl peroxydicarbonate: 0.6 part；
Ethanol: 8 parts；
Deionized water: 35 parts；
Semen oryzae sativae starch: 9 parts；
Graphene oxide quantum dot: 4 parts；
Silane coupler: 0.4 part.
The lateral dimension of described graphene oxide quantum dot is 1 ~ 100nm.
The preparation method of a kind of energy-conserving and environment-protective glue as above, specifically includes following steps:
(1) n-butyl acrylate, polyvinyl acetate, acrylic acid, methyl methacrylate are mixed with ethanol, add di-isopropyl peroxydicarbonate, be sufficiently mixed at 55 DEG C uniformly；
(2) in step (1) gained solution, polyoxyethylenesorbitan sorbitan monooleate and deionized water, stirring and emulsifying are added；
(3) in step (2) gained emulsion, add Semen oryzae sativae starch, graphene oxide quantum dot and silane coupler to stir at 65 DEG C, be cooled to room temperature, prepare described energy-conserving and environment-protective glue.
The foregoing is only presently preferred embodiments of the present invention, all impartial changes done according to scope of the present invention patent and modification, all should belong to the covering scope of the present invention.
Claims (3)
1. an energy-conserving and environment-protective glue, it is characterised in that: counting by weight, the raw material of described environment-friendlyadhesive adhesive consists of:
N-butyl acrylate: 13 ~ 17 parts；
Acrylic acid: 14 ~ 18 parts；
Polyvinyl acetate: 10 ~ 14 parts；
Methyl methacrylate: 8 ~ 12 parts；
Polyoxyethylenesorbitan sorbitan monooleate: 3 ~ 4 parts；
Di-isopropyl peroxydicarbonate: 0.5 ~ 1 part；
Ethanol: 5-10 part；
Deionized water: 30-40 part；
Semen oryzae sativae starch: 6 ~ 12 parts；
Graphene oxide quantum dot: 3 ~ 5 parts；
Silane coupler: 0.3 ~ 0.5 part.
A kind of energy-conserving and environment-protective glue the most according to claim 1, it is characterised in that: the lateral dimension of described graphene oxide quantum dot is 1 ~ 100nm.
3. the method preparing a kind of energy-conserving and environment-protective glue as claimed in claim 1, it is characterised in that: specifically include following steps:
(1) n-butyl acrylate, polyvinyl acetate, acrylic acid, methyl methacrylate are mixed with ethanol, add di-isopropyl peroxydicarbonate, be sufficiently mixed at 50-60 DEG C uniformly；
(2) in step (1) gained solution, polyoxyethylenesorbitan sorbitan monooleate and deionized water, stirring and emulsifying are added；
(3) stir at addition Semen oryzae sativae starch, graphene oxide quantum dot and silane coupler are at 60-70 DEG C in step (2) gained emulsion, be cooled to room temperature, prepare described energy-conserving and environment-protective glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610376850.0A CN105778785A (en) | 2016-06-01 | 2016-06-01 | Energy-saving environment-friendly glue and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610376850.0A CN105778785A (en) | 2016-06-01 | 2016-06-01 | Energy-saving environment-friendly glue and preparation method thereof |
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| CN105778785A true CN105778785A (en) | 2016-07-20 |
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| CN201610376850.0A Pending CN105778785A (en) | 2016-06-01 | 2016-06-01 | Energy-saving environment-friendly glue and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106381104A (en) * | 2016-10-20 | 2017-02-08 | 北京林业大学 | Water-based adhesive and preparation method thereof |
| CN109321144A (en) * | 2018-09-29 | 2019-02-12 | 安徽兆拓新能源科技有限公司 | A kind of preparation method of green wallpaper adhesive |
| CN110734716A (en) * | 2019-08-26 | 2020-01-31 | 揭阳市汉和新材料有限公司 | domestic white latex formula and its process |
| CN112143429A (en) * | 2020-10-16 | 2020-12-29 | 冯国旭 | Environment-friendly structural adhesive and preparation method thereof |
Citations (3)
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| CN102603957A (en) * | 2012-02-29 | 2012-07-25 | 长兴化学工业(中国)有限公司 | Water-based adhesive component and preparation method of water-based pressure sensitive adhesive formed by water-based adhesive component |
| CN103554346A (en) * | 2013-10-14 | 2014-02-05 | 陕西科技大学 | Method for preparing pigment printing binder from oxidized graphene modified polyacrylate |
| CN105542685A (en) * | 2016-02-03 | 2016-05-04 | 京东方科技集团股份有限公司 | Frame sealing adhesive, liquid crystal panel, liquid crystal display device and preparation method thereof |
-
2016
- 2016-06-01 CN CN201610376850.0A patent/CN105778785A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102603957A (en) * | 2012-02-29 | 2012-07-25 | 长兴化学工业(中国)有限公司 | Water-based adhesive component and preparation method of water-based pressure sensitive adhesive formed by water-based adhesive component |
| CN103554346A (en) * | 2013-10-14 | 2014-02-05 | 陕西科技大学 | Method for preparing pigment printing binder from oxidized graphene modified polyacrylate |
| CN105542685A (en) * | 2016-02-03 | 2016-05-04 | 京东方科技集团股份有限公司 | Frame sealing adhesive, liquid crystal panel, liquid crystal display device and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 胡长伟: "《纳米材料的生态毒性效应与环境释放风险》", 28 February 2015, 山东人民出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106381104A (en) * | 2016-10-20 | 2017-02-08 | 北京林业大学 | Water-based adhesive and preparation method thereof |
| CN109321144A (en) * | 2018-09-29 | 2019-02-12 | 安徽兆拓新能源科技有限公司 | A kind of preparation method of green wallpaper adhesive |
| CN110734716A (en) * | 2019-08-26 | 2020-01-31 | 揭阳市汉和新材料有限公司 | domestic white latex formula and its process |
| CN112143429A (en) * | 2020-10-16 | 2020-12-29 | 冯国旭 | Environment-friendly structural adhesive and preparation method thereof |
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Application publication date: 20160720 |
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