CN103524667A - Water-based pressure-sensitive adhesive for polyethylene protection film and polyethylene protection film and preparation method thereof - Google Patents
Water-based pressure-sensitive adhesive for polyethylene protection film and polyethylene protection film and preparation method thereof Download PDFInfo
- Publication number
- CN103524667A CN103524667A CN201310486265.2A CN201310486265A CN103524667A CN 103524667 A CN103524667 A CN 103524667A CN 201310486265 A CN201310486265 A CN 201310486265A CN 103524667 A CN103524667 A CN 103524667A
- Authority
- CN
- China
- Prior art keywords
- sensitive adhesive
- water
- protective film
- pressure sensitive
- polyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a water-based pressure-sensitive adhesive for a polyethylene protection film and a polyethylene protection film thereof. The water-based pressure-sensitive adhesive comprises the following components in percentage by weight: 48.0-50.0% of polymerization monomer, 0.2-0.4% of initiator, 0.4-0.6% of emulsifier, 0.05-0.08% of buffer agent, 0.4-1.0% of neutralizer and 48.0-50.0% of deionized water. The water-based pressure-sensitive adhesive and the polyethylene protection film prepared from the same, disclosed by the invention, have excellent yellowing resistance.
Description
Technical field
The present invention relates to pressure sensitive adhesive and applied protective membrane thereof for a kind of protective membrane, particularly relate to a kind of Water-based pressure-sensitive adhesive of polyethylene protective film and applied polyethylene protective film thereof.
Background technology
Protective membrane is a kind of surface protection for the protection of commodity surface, wrapping material; be attached to the surface of the commodity such as metal, glass, plastics, furniture, instrument, electronic product; make it in manufacture, transportation, secondary processing, storage and use procedure, protect surface; avoid commodity to be subject to polluting, scratch and slowing down commodity surface oxidation; thereby the visual appearance of improving product, facilitates materials processing.
Protective membrane is comprised of substrate layer and pressure-sensitive adhesive layer, conventionally on membranaceous base material, is coated with the pressure-sensitive adhesive of emulsion state or solution state, except after desolventizing, makes protective membrane.Conventional protective membrane base material has polyethylene film, polypropylene film etc., and pressure sensitive adhesive is generally solvent type polyacrylate pressure sensitive adhesive, therefore, has in process of production a large amount of volatile organic compoundss to discharge, and causes environmental pollution.For this reason, people develop water polyacrylic acid pressure sensitive adhesive, replace organic solvent, to reduce environmental pollution with the aqueous solution.Yet, compare with solvent pressure-sensitive adhesive, there is the defects such as the transparency is poor, color jaundice in existing water-borne pressure sensitive adhesive, and this is because its emulsifying agent pyrolytic decomposition containing causes.
Summary of the invention
Based on this, being necessary, for the existing problem of existing water-borne pressure sensitive adhesive, provides a kind of Water-based pressure-sensitive adhesive of polyethylene protective film of high transparent.
Another object of the present invention is, a kind of polyethylene protective film of high-clarity is provided.
A further object of the present invention is, the preparation method of described Water-based pressure-sensitive adhesive of polyethylene protective film and polyethylene protective film thereof is provided.
, comprise by weight percentage following component:
Described polymerization single polymerization monomer comprises following component by weight percentage:
Acrylate soft monomer 90%～95%,
Acrylate hard monomer 2%～5%,
Cross-linking monomer 3%～5%.
Therein in an embodiment, described acrylate soft monomer is selected from one or more the combination in ethyl propenoate, Isooctyl acrylate monomer, butyl acrylate or lauryl acrylate.The effect of this acrylate soft monomer is for pressure sensitive adhesive provides tack, if its consumption very little, the tack of pressure sensitive adhesive is poor; If its consumption is too large, cause the force of cohesion of pressure sensitive adhesive poor, easily there is degumming phenomenon.
Therein in an embodiment, described acrylate hard monomer is selected from one or more the combination in methyl acrylate, vinyl acetate, methyl methacrylate or vinylbenzene.The effect of this acrylate hard monomer is for pressure sensitive adhesive provides force of cohesion, if its consumption very little, the force of cohesion of pressure sensitive adhesive is inadequate; If its consumption is too large, cause the tack of pressure sensitive adhesive poor.
Therein in an embodiment, described cross-linking monomer is selected from one or more the combination in vinylformic acid, methacrylic acid, toxilic acid, Hydroxyethyl acrylate, hydroxyethyl methylacrylate or Propylene glycol monoacrylate.The effect of this cross-linking monomer is to provide reactive behavior and crosslinked group for pressure sensitive adhesive.If its consumption very little, the degree of crosslinking of pressure sensitive adhesive is inadequate, causes coming unstuck; If its consumption is too large, be cross-linked excessively, cause the tack degradation of pressure sensitive adhesive.
In an embodiment, described initiator is ammonium persulphate therein.The effect of this initiator is for polyreaction provides free radical, if its consumption very little, polyreaction is incomplete; If its consumption is too large, polyreaction is too violent, causes the force of cohesion of pressure sensitive adhesive to reduce.
Therein in an embodiment, described emulsifying agent is selected from one or both the combination in allyloxy aliphatic alcohol polyethenoxy base ether, allyloxy Nonyl pheno base ether ammonium sulfate.Allyloxy aliphatic alcohol polyethenoxy base ether and allyloxy Nonyl pheno base ether ammonium sulfate, for reactive emulsifier, in its chemical structure, contain high hydrophilic radical and lipophilic group, make it have good emulsifying performance, in addition, in its structure, contain the two keys of C=C that can participate in polyreaction, by polyreaction, with covalent linkage form, be grafted on pressure sensitive adhesive, thereby can avoid residual because of emulsifying agent, in hot environment, issue the phenomenon that solution estranged produces xanthochromia.
In an embodiment, described buffer reagent is sodium bicarbonate therein.In polyreaction, decomposition of initiator, the pH value of reaction system can reduce gradually, when pH < 4, can cause the easy breakdown of emulsion of emulsifying agent, by adding appropriate sodium bicarbonate as buffer reagent, the pH value that can regulate reaction system, makes it to maintain between pH4～5, thereby improves the stability of reaction system.
In an embodiment, described neutralizing agent is the ammoniacal liquor of mass concentration 25%～28% therein.Add appropriate ammoniacal liquor as neutralizing agent, for the pH value of pressure sensitive adhesive is adjusted to pH7～8, and pressure sensitive adhesive under this pH value, its Painting effect is best.
The preparation method of Water-based pressure-sensitive adhesive of polyethylene protective film of the present invention, comprises the following steps:
1) by formula, take respectively each component;
2) preparation initiator solution: by 2%～5% deionized water dissolving for 30%～40% initiator, make initial initiator solution; By 10%～15% deionized water dissolving for 60%～70% initiator, make reaction initiator solution;
3) pre-emulsification: 30%～40% deionized water, emulsifying agent are added in emulsifying kettle, add polymerization single polymerization monomer after stirring, continue to stir, make pre-emulsion;
4) 40%～50% deionized water is added in reactor, under stirring, add buffer reagent;
5) reactor is warming up to 80 ℃～82 ℃, adds 1%～2% pre-emulsion, after stirring, add initial initiator solution, react 20～30 minutes, then drip remaining pre-emulsion and reaction initiator solution simultaneously;
6) reactor is warming up to 85 ℃～92 ℃ after dropwising, insulation reaction 1～2 hour, is then cooled to below 60 ℃, adds neutralizing agent that pH value is adjusted to pH7～8, after stirring, filters, and is cooled to room temperature, makes described water-borne pressure sensitive adhesive.
, by water-borne pressure sensitive adhesive of the present invention, after crosslinking curing, be coated on polyethylene film and be prepared from.
The preparation method of polyethylene protective film of the present invention, comprises the following steps:
A) in water-borne pressure sensitive adhesive of the present invention, add linking agent, stir, make water-borne pressure sensitive adhesive coating fluid;
B) by steps A) the water-borne pressure sensitive adhesive coating fluid that makes, be coated on polyethylene film, make described polyethylene protective film.
In an embodiment, described linking agent is aziridine therein, and the consumption of linking agent is 0.3%～0.8% of water-borne pressure sensitive adhesive weight.This aziridine crosslinker can improve the force of cohesion of pressure sensitive adhesive, forms reticulated structure in pressure sensitive adhesive, and the cross-linking density of pressure sensitive adhesive is increased, thereby significantly promotes the performances such as tack, weathering resistance and temperature tolerance of pressure sensitive adhesive.
In an embodiment, described polyethylene film is through corona treatment therein, and the glue spread of described water-borne pressure sensitive adhesive coating fluid is 10g/m
2～12g/m
2.
Water-borne pressure sensitive adhesive of the present invention and prepared polyethylene protective film thereof have excellent anti-yellowing property; because described water-borne pressure sensitive adhesive adopts reactive emulsifier; in its chemical structure, contain high hydrophilic radical and lipophilic group; make it have good emulsifying performance; in addition; in its structure, contain the two keys of C=C that can participate in polyreaction; can with covalent linkage form, be grafted on pressure sensitive adhesive by polyreaction; thereby can avoid residual because of emulsifying agent, in hot environment, issue the phenomenon that solution estranged produces xanthochromia.Use this reactive emulsifier also to have the following advantages: (1) makes pressure sensitive adhesive increase in the stability of the aspects such as high shear force, freeze thawing, ionogen; (2) pressure sensitive adhesive is had significantly promotes at aspects such as water tolerance, glossiness, film-forming propertiess.Pressure sensitive adhesive of the present invention also has and the advantage such as does not come unstuck, does not haze, easily peels off.
The preparation method of Water-based pressure-sensitive adhesive of polyethylene protective film of the present invention, has reacting balance, is easy to control, and transformation efficiency advantages of higher.
Embodiment
Embodiment mono-:
1, prepare Water-based pressure-sensitive adhesive of polyethylene protective film
1) by following formula, take each component:
2) preparation initiator solution: by 1Kg ammonium persulphate 10Kg deionized water dissolving, make initial initiator solution; By 1.5Kg ammonium persulphate 60Kg deionized water dissolving, make reaction initiator solution;
3) pre-emulsification: 200Kg deionized water, 4Kg allyloxy aliphatic alcohol polyethenoxy base ether are added in emulsifying kettle, stir after 20 minutes and add polymerization single polymerization monomer, continue to stir 30 minutes, make pre-emulsion 692.5Kg;
4) 230Kg deionized water is added in reactor, under stirring, add 0.5Kg sodium bicarbonate;
5) reactor is warming up to 80 ℃～82 ℃, adds 10Kg pre-emulsion, stir after 3 minutes and add initial initiator solution, react 20～30 minutes, then drip remaining pre-emulsion and reaction initiator solution simultaneously, within 3～3.5 hours, drip off;
6) reactor is warming up to 85 ℃～92 ℃ after dropwising, insulation reaction 1～2 hour, is then cooled to below 60 ℃, adds 4.5Kg ammoniacal liquor, and pH value is adjusted to pH7～8, stirs after 15 minutes and filters, and is cooled to room temperature, makes described water-borne pressure sensitive adhesive.
2, prepare polyethylene protective film
1) according to following formula, take each component:
Water-borne pressure sensitive adhesive 10Kg,
Aziridine 60g.
2) aziridine is added in water-borne pressure sensitive adhesive and stirred, make water-borne pressure sensitive adhesive coating fluid;
3) on coating machine, with spread 10g～12g/m
2anilox roll, by step 2) to be uniformly coated on the thickness of crossing through corona treatment be on the cellothene of 45 μ m for the water-borne pressure sensitive adhesive coating fluid that makes, makes described polyethylene protective film.
Embodiment bis-:
1, prepare Water-based pressure-sensitive adhesive of polyethylene protective film
1) by following formula, take each component:
2) preparation initiator solution: by 1Kg ammonium persulphate 10Kg deionized water dissolving, make initial initiator solution; By 1.5Kg ammonium persulphate 60Kg deionized water dissolving, make reaction initiator solution;
3) pre-emulsification: 200Kg deionized water, 4.5Kg allyloxy Nonyl pheno base ether ammonium sulfate are added in emulsifying kettle, stir after 20 minutes and add polymerization single polymerization monomer, continue to stir 30 minutes, make pre-emulsion 692.4Kg;
4) 230Kg deionized water is added in reactor, under stirring, add 0.6Kg sodium bicarbonate;
5) reactor is warming up to 80 ℃～82 ℃, adds 10Kg pre-emulsion, stir after 3 minutes and add initial initiator solution, react 20～30 minutes, then drip remaining pre-emulsion and reaction initiator solution simultaneously, within 3～3.5 hours, drip off;
6) reactor is warming up to 85 ℃～92 ℃ after dropwising, insulation reaction 1～2 hour, is then cooled to below 60 ℃, adds 4.5Kg ammoniacal liquor, and pH value is adjusted to pH7～8, stirs after 15 minutes and filters, and is cooled to room temperature, makes described water-borne pressure sensitive adhesive.
2, prepare polyethylene protective film
1) according to following formula, take each component:
Water-borne pressure sensitive adhesive 10Kg,
Aziridine 50g.
2) aziridine is added in water-borne pressure sensitive adhesive and stirred, make water-borne pressure sensitive adhesive coating fluid;
3) on coating machine, with spread 10g～12g/m
2anilox roll, by step 2) to be uniformly coated on the thickness of crossing through corona treatment be on the cellothene of 45 μ m for the water-borne pressure sensitive adhesive coating fluid that makes, makes described polyethylene protective film.
Embodiment tri-:
1, prepare Water-based pressure-sensitive adhesive of polyethylene protective film
1) by following formula, take each component:
2) preparation initiator solution: by 1Kg ammonium persulphate 10Kg deionized water dissolving, make initial initiator solution; By 1.5Kg ammonium persulphate 60Kg deionized water dissolving, make reaction initiator solution;
3) pre-emulsification: 200Kg deionized water, 3Kg allyloxy aliphatic alcohol polyethenoxy base ether, 1Kg allyloxy Nonyl pheno base ether ammonium sulfate are added in emulsifying kettle, stir and add polymerization single polymerization monomer after 20 minutes, continue to stir 30 minutes, make pre-emulsion 688Kg;
4) 230Kg deionized water is added in reactor, under stirring, add 0.5Kg sodium bicarbonate;
5) reactor is warming up to 80 ℃～82 ℃, adds 10Kg pre-emulsion, stir after 3 minutes and add initial initiator solution, react 20～30 minutes, then drip remaining pre-emulsion and reaction initiator solution simultaneously, within 3～3.5 hours, drip off;
6) reactor is warming up to 85 ℃～92 ℃ after dropwising, insulation reaction 1～2 hour, is then cooled to below 60 ℃, adds 9Kg ammoniacal liquor, and pH value is adjusted to pH7～8, stirs after 15 minutes and filters, and is cooled to room temperature, makes described water-borne pressure sensitive adhesive.
2, prepare polyethylene protective film
1) according to following formula, take each component:
Water-borne pressure sensitive adhesive 10Kg,
Aziridine 40g.
2) aziridine is added in water-borne pressure sensitive adhesive and stirred, make water-borne pressure sensitive adhesive coating fluid;
3) on coating machine, with spread 10g～12g/m
2anilox roll, by step 2) to be uniformly coated on the thickness of crossing through corona treatment be on the cellothene of 45 μ m for the water-borne pressure sensitive adhesive coating fluid that makes, makes described polyethylene protective film.
Embodiment tetra-: performance test
1, testing method
1) 180 ° of stripping strengths: according to GB/T2792-1998, test with electronic tensile machine.
2) ageing-resistant test: the polyethylene protective film making is attached on stainless steel mirror board, is placed in baking oven and carries out weathering test.At the appointed time with temperature under, if occur, haze, degumming phenomenon, show that ageing-resistant performance is defective.
3) resistance to xanthochromia test: the polyethylene protective film making is placed in to baking oven and carries out non-yellowing test.At the appointed time with temperature under, if compare and occur yellowing phenomenon with before test, show that anti-yellowing property is defective.
2, test result
Above-mentioned experimental result shows, polyethylene protective film of the present invention has good ageing-resistant, anti-yellowing property, and has good stripping strength.
The above embodiment has only expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (10)
1. a Water-based pressure-sensitive adhesive of polyethylene protective film, comprises following component by weight percentage:
Wherein, described polymerization single polymerization monomer comprises following component by weight percentage:
Acrylate soft monomer 90%～95%,
Acrylate hard monomer 2%～5%,
Cross-linking monomer 3%～5%.
2. Water-based pressure-sensitive adhesive of polyethylene protective film according to claim 1, is characterized in that: described acrylate soft monomer is selected from one or more the combination in ethyl propenoate, Isooctyl acrylate monomer, butyl acrylate or lauryl acrylate; Described acrylate hard monomer is selected from one or more the combination in methyl acrylate, vinyl acetate, methyl methacrylate or vinylbenzene; Described cross-linking monomer is selected from one or more the combination in vinylformic acid, methacrylic acid, toxilic acid, Hydroxyethyl acrylate, hydroxyethyl methylacrylate or Propylene glycol monoacrylate.
3. Water-based pressure-sensitive adhesive of polyethylene protective film according to claim 1, is characterized in that: described emulsifying agent is selected from one or both the combination in allyloxy aliphatic alcohol polyethenoxy base ether, allyloxy Nonyl pheno base ether ammonium sulfate.
4. Water-based pressure-sensitive adhesive of polyethylene protective film according to claim 1, is characterized in that: described initiator is ammonium persulphate.
5. according to the Water-based pressure-sensitive adhesive of polyethylene protective film described in one of them of claim 1 to 4, it is characterized in that: described buffer reagent is sodium bicarbonate; Described neutralizing agent is that mass concentration is 25%～28% ammoniacal liquor.
6. the preparation method of Water-based pressure-sensitive adhesive of polyethylene protective film claimed in claim 1, comprises the following steps:
1) by formula, take respectively each component;
2) preparation initiator solution: by 2%～5% deionized water dissolving for 30%～40% initiator, make initial initiator solution; By 10%～15% deionized water dissolving for 60%～70% initiator, make reaction initiator solution;
3) pre-emulsification: 30%～40% deionized water, emulsifying agent are added in emulsifying kettle, add polymerization single polymerization monomer after stirring, continue to stir, make pre-emulsion;
4) 40%～50% deionized water is added in reactor, under stirring, add buffer reagent;
5) reactor is warming up to 80 ℃～82 ℃, adds 1%～2% pre-emulsion, after stirring, add initial initiator solution, react 20～30 minutes, then drip remaining pre-emulsion and reaction initiator solution simultaneously;
6) reactor is warming up to 85 ℃～92 ℃ after dropwising, insulation reaction 1～2 hour, is then cooled to below 60 ℃, adds neutralizing agent that pH value is adjusted to pH7～8, after stirring, filters, and is cooled to room temperature, makes described water-borne pressure sensitive adhesive.
7. a polyethylene protective film, is coated on polyethylene film and is prepared from by Water-based pressure-sensitive adhesive of polyethylene protective film claimed in claim 1 after crosslinking curing.
8. the preparation method of polyethylene protective film claimed in claim 7, comprises the following steps:
A) in water-borne pressure sensitive adhesive claimed in claim 1, add linking agent, stir, make water-borne pressure sensitive adhesive coating fluid;
B) by steps A) the water-borne pressure sensitive adhesive coating fluid that makes, be coated on polyethylene film, make described polyethylene protective film.
9. preparation method according to claim 8, is characterized in that: described linking agent is aziridine, and the consumption of linking agent is 0.3%～0.8% of water-borne pressure sensitive adhesive weight.
10. preparation method according to claim 8, is characterized in that: described polyethylene film is through corona treatment, and the glue spread of described water-borne pressure sensitive adhesive coating fluid is 10g/m
2～12g/m
2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310486265.2A CN103524667A (en) | 2013-10-16 | 2013-10-16 | Water-based pressure-sensitive adhesive for polyethylene protection film and polyethylene protection film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310486265.2A CN103524667A (en) | 2013-10-16 | 2013-10-16 | Water-based pressure-sensitive adhesive for polyethylene protection film and polyethylene protection film and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103524667A true CN103524667A (en) | 2014-01-22 |
Family
ID=49927054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310486265.2A Pending CN103524667A (en) | 2013-10-16 | 2013-10-16 | Water-based pressure-sensitive adhesive for polyethylene protection film and polyethylene protection film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103524667A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104710951A (en) * | 2015-04-08 | 2015-06-17 | 潍坊胜达科技股份有限公司 | High-temperature-resistance and unimpressed pressure sensitive adhesive (PSA) for polyethylene protective film, preparation method thereof and prepared polyethylene protective film |
| CN105219311A (en) * | 2014-06-10 | 2016-01-06 | 湖北航天化学技术研究所 | A kind of preparation of water soluble acrylic acid ester pressure-sensitive and application thereof |
| CN105884964A (en) * | 2016-05-12 | 2016-08-24 | 上海保立佳新材料有限公司 | Emulsion pressure sensitive adhesive for anti-yellowing surface protective film and preparation method thereof |
| CN106147635A (en) * | 2015-03-31 | 2016-11-23 | 常熟市新明宇塑胶有限公司 | A kind of antioxidation environmental protection type protecting film and preparation technology thereof |
| CN106147634A (en) * | 2015-03-30 | 2016-11-23 | 常熟市新明宇塑胶有限公司 | A kind of three-layer co-extruded blown film glued membrane and preparation technology thereof |
| CN106281138A (en) * | 2016-08-08 | 2017-01-04 | 澳新粘胶科技(湖北)有限公司 | A kind of environment friendly pressure sensitive stick |
| CN107459941A (en) * | 2017-09-04 | 2017-12-12 | 安徽明讯新材料科技股份有限公司 | A kind of water-soluble glue-type touch screen environmental protection protective film and preparation method thereof |
| CN110041859A (en) * | 2019-03-20 | 2019-07-23 | 广东银洋环保新材料有限公司 | Without base stock CPP cold lamination film water-borne pressure sensitive adhesive and preparation method thereof and cold lamination film |
| CN111040182A (en) * | 2019-12-27 | 2020-04-21 | 无锡达美新材料有限公司 | Functional master batch for high-surface-energy polyethylene protective film and preparation method thereof |
| CN111057484A (en) * | 2019-12-05 | 2020-04-24 | 江苏晶华新材料科技有限公司 | Waterproof prime coat latex for paper base and preparation method thereof |
| CN111234727A (en) * | 2020-03-30 | 2020-06-05 | 上海保立佳新材料有限公司 | Waterborne environmental protection acrylic emulsion pressure sensitive adhesive protection film |
| CN111285962A (en) * | 2020-03-30 | 2020-06-16 | 上海保立佳新材料有限公司 | Water-based environment-friendly acrylic emulsion pressure-sensitive adhesive for protective film and preparation method thereof |
| CN113462312A (en) * | 2021-08-06 | 2021-10-01 | 江苏国胶新材料有限公司 | Water-based pressure-sensitive adhesive for polyethylene protective film and preparation device thereof |
| WO2021197056A1 (en) * | 2020-03-30 | 2021-10-07 | 上海保立佳新材料有限公司 | Medium viscosity protective film emulsion and preparation method therefor |
| CN115011290A (en) * | 2022-07-08 | 2022-09-06 | 上海晶华胶粘新材料股份有限公司 | Water-acrylic emulsion pressure-sensitive adhesive for high-viscosity PE protective film, preparation method and PE protective film |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974299A (en) * | 2010-10-11 | 2011-02-16 | 新丰杰力电工材料有限公司 | High temperature-resistant polyacrylate pressure-sensitive adhesive emulsion and preparation method and application thereof |
| CN102019737A (en) * | 2010-09-30 | 2011-04-20 | 南亚塑胶工业股份有限公司 | Aqueous thermally-foamed gluing adhesive plate |
-
2013
- 2013-10-16 CN CN201310486265.2A patent/CN103524667A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102019737A (en) * | 2010-09-30 | 2011-04-20 | 南亚塑胶工业股份有限公司 | Aqueous thermally-foamed gluing adhesive plate |
| CN101974299A (en) * | 2010-10-11 | 2011-02-16 | 新丰杰力电工材料有限公司 | High temperature-resistant polyacrylate pressure-sensitive adhesive emulsion and preparation method and application thereof |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105219311A (en) * | 2014-06-10 | 2016-01-06 | 湖北航天化学技术研究所 | A kind of preparation of water soluble acrylic acid ester pressure-sensitive and application thereof |
| CN105219311B (en) * | 2014-06-10 | 2017-11-17 | 湖北航天化学技术研究所 | A kind of preparation and its application of water soluble acrylic acid ester pressure-sensitive |
| CN106147634A (en) * | 2015-03-30 | 2016-11-23 | 常熟市新明宇塑胶有限公司 | A kind of three-layer co-extruded blown film glued membrane and preparation technology thereof |
| CN106147635A (en) * | 2015-03-31 | 2016-11-23 | 常熟市新明宇塑胶有限公司 | A kind of antioxidation environmental protection type protecting film and preparation technology thereof |
| CN104710951A (en) * | 2015-04-08 | 2015-06-17 | 潍坊胜达科技股份有限公司 | High-temperature-resistance and unimpressed pressure sensitive adhesive (PSA) for polyethylene protective film, preparation method thereof and prepared polyethylene protective film |
| CN105884964A (en) * | 2016-05-12 | 2016-08-24 | 上海保立佳新材料有限公司 | Emulsion pressure sensitive adhesive for anti-yellowing surface protective film and preparation method thereof |
| CN106281138A (en) * | 2016-08-08 | 2017-01-04 | 澳新粘胶科技(湖北)有限公司 | A kind of environment friendly pressure sensitive stick |
| CN107459941A (en) * | 2017-09-04 | 2017-12-12 | 安徽明讯新材料科技股份有限公司 | A kind of water-soluble glue-type touch screen environmental protection protective film and preparation method thereof |
| CN110041859A (en) * | 2019-03-20 | 2019-07-23 | 广东银洋环保新材料有限公司 | Without base stock CPP cold lamination film water-borne pressure sensitive adhesive and preparation method thereof and cold lamination film |
| CN111057484A (en) * | 2019-12-05 | 2020-04-24 | 江苏晶华新材料科技有限公司 | Waterproof prime coat latex for paper base and preparation method thereof |
| CN111040182A (en) * | 2019-12-27 | 2020-04-21 | 无锡达美新材料有限公司 | Functional master batch for high-surface-energy polyethylene protective film and preparation method thereof |
| CN111234727A (en) * | 2020-03-30 | 2020-06-05 | 上海保立佳新材料有限公司 | Waterborne environmental protection acrylic emulsion pressure sensitive adhesive protection film |
| CN111285962A (en) * | 2020-03-30 | 2020-06-16 | 上海保立佳新材料有限公司 | Water-based environment-friendly acrylic emulsion pressure-sensitive adhesive for protective film and preparation method thereof |
| WO2021197056A1 (en) * | 2020-03-30 | 2021-10-07 | 上海保立佳新材料有限公司 | Medium viscosity protective film emulsion and preparation method therefor |
| CN113462312A (en) * | 2021-08-06 | 2021-10-01 | 江苏国胶新材料有限公司 | Water-based pressure-sensitive adhesive for polyethylene protective film and preparation device thereof |
| CN115011290A (en) * | 2022-07-08 | 2022-09-06 | 上海晶华胶粘新材料股份有限公司 | Water-acrylic emulsion pressure-sensitive adhesive for high-viscosity PE protective film, preparation method and PE protective film |
| CN115011290B (en) * | 2022-07-08 | 2023-11-24 | 上海晶华胶粘新材料股份有限公司 | Water acrylic emulsion pressure-sensitive adhesive for high-viscosity PE protective film, preparation method and PE protective film |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103524667A (en) | Water-based pressure-sensitive adhesive for polyethylene protection film and polyethylene protection film and preparation method thereof | |
| CN107602760B (en) | Polyacrylate emulsion pressure-sensitive adhesive for electronic protective film, and preparation method and application thereof | |
| CN104277172B (en) | Water-based waterproof acrylate emulsion and preparation method thereof | |
| JP6463737B2 (en) | Production of pressure-sensitive adhesive dispersions by multi-stage emulsion polymerization for the application of protective films | |
| CN102260478B (en) | Pressure-sensitive adhesive for PET protective film and preparation method thereof | |
| EP3916064B1 (en) | Uv-crosslinked hot-melt pressure-sensitive adhesive used for polyvinyl-chloride insulated adhesive tape | |
| CN102504717B (en) | Adhesive tape for bonding low-surface-energy material and preparation method thereof | |
| CN102260472B (en) | High-strength repeelable pressure-sensitive adhesive for window film and preparation method thereof | |
| CN104449485B (en) | A kind of preparation method of reflective membrane emulsion-type polyacrylate pressure-sensitive | |
| CN102260477A (en) | Pressure-sensitive adhesive for biaxially-oriented polypropylene (BOPP) protective film and preparation method thereof | |
| CN102492379A (en) | Fog-resistant aqueous pressure-sensitive adhesive and polyethylene protection film containing same | |
| CN103074011B (en) | Single-component water-borne pressure sensitive adhesive for sun-proof and heat-insulating film | |
| CN105237675A (en) | Polyacrylic woodware emulsion with core-shell bi-crosslinking structure and preparation method thereof | |
| CN102504733A (en) | Water-blush-resistant fluoride and siloxane modified waterborne pressure-sensitive adhesive and polyethylene protective film | |
| CN103059235B (en) | Epoxy modified water-soluble acrylic resin, and preparation method and application thereof | |
| CN103980414A (en) | Polyacrylate pressure-sensitive adhesive emulsion for polyethylene protection film and preparation method thereof | |
| CN102351979A (en) | Acrylic resin coating liquid for alumite coloring layer and preparation method thereof | |
| CN103952105A (en) | Fluorosilicone modified aqueous pressure-sensitive adhesive used for polyethylene protection film, and preparation method thereof | |
| CN105408437B (en) | Pressure-sensitive adhesive agent dispersion for protective film is prepared by multistage emulsion polymerization | |
| CN108485565A (en) | A kind of UV photocurings are suitable for the water-fast multi-functional pressure sensitive adhesive in dry/wet interface, preparation method and pressure sensitive adhesive adhesive tape | |
| CN103694403A (en) | Preparation method of self-crosslinking polyester film primer acrylic ester emulsion | |
| CN103524666B (en) | Silk screen printing use pressure sensitive adhesive and preparation method thereof | |
| CN113913134B (en) | Adhesive for battery cell protective film, protective film prepared from adhesive and application of protective film | |
| CN107418351B (en) | A kind of one-component water solubility release-free electrochemical aluminum paint and preparation method thereof | |
| CN103724521A (en) | Preparation method of single-component polyacrylate pressure-sensitive adhesive for optical protective film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140122 |