CN106281138A - A kind of environment friendly pressure sensitive stick - Google Patents
A kind of environment friendly pressure sensitive stick Download PDFInfo
- Publication number
- CN106281138A CN106281138A CN201610642894.3A CN201610642894A CN106281138A CN 106281138 A CN106281138 A CN 106281138A CN 201610642894 A CN201610642894 A CN 201610642894A CN 106281138 A CN106281138 A CN 106281138A
- Authority
- CN
- China
- Prior art keywords
- monomer
- pressure sensitive
- environment friendly
- methyl
- friendly pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention discloses a kind of environment friendly pressure sensitive stick, emulsion polymer and water cross-linking agent mix at normal temperatures with mass ratio 1 (0.1 5%) and form, its system of described emulsion polymer includes water, monomer, surfactant, buffer agent etc..Described monomer includes that the carboxylic acid monomer as comonomer and at least one second monoene are good for formula unsaturated monomer, described carboxylic acid monomer is selectable acrylic acid, methacrylic acid, itaconic acid and maleic anhydride etc., and described second monoene is good for that formula unsaturated monomer is selectable (methyl) acrylic acid methyl ester., (methyl) butyl acrylate, (methyl) 2-(Acryloyloxy)ethanol, vinyl acetate, styrene etc..The preferred polyfunctional isocyanate compound of described water cross-linking agent.The present invention can according to gummed tape, cover the demand that protection adhesive tape uses and adjust its initial bonding strength, 180 ° of peeling force intensity, cohesivenesss, and not cull under using in certain temperature range, effect is good.
Description
[technical field]
The present invention relates to adhesive tape field of adhesive technology, particularly to a kind of environment friendly pressure sensitive stick.
[background technology]
Pressure-sensitive adhesive i.e. pressure sensibility adhesive, is commonly called as again adhesive sticker, is called for short pressure sensitive adhesive, and pressure sensitive adhesive goods include pressure
Sensitive adhesive tape, pressure-sensitive adhesive label paper, pressure sensitive film three major types, apply relatively broad.The pressure sensitive adhesive of industrial use is mainly by four
Big class: solvent pressure-sensitive adhesive, emulsion-type pressure-sensitive, thermotropic pressure sensitive glue and ray curing pressure sensitive adhesive, pressure sensitive adhesive is polymerized by it
Thing is divided into the emulsion based pressure sensitive such as rubber-like pressure sensitive adhesive, polyacrylate pressure sensitive adhesive, polyvingl ether resin class, polyisobutylene class
Glue is in occupation of absolute advantages status.Wherein pressure-sensitive polyacrylate emulsion glue stick is with low cost, safe, simple to operate, in recent years
Be rapidly developed, but the defect existed to be initial bonding strength, 180 ° of peeling force intensity, cohesiveness three power more difficult in response to actual demand
Reach balance, water-fast, weatherability is poor.
[summary of the invention]
In view of this, for overcoming the deficiencies in the prior art, the present invention provides a kind of environment friendly pressure sensitive stick, can be according to bag
Dress adhesive tape, cover the demand that protection adhesive tape uses and adjust its initial bonding strength, 180 ° of peeling force intensity, cohesiveness at uniform temperature model
Enclose under interior use not cull.
For achieving the above object, technical scheme is as follows:
A kind of environment friendly pressure sensitive stick, by emulsion polymer with water cross-linking agent with mass ratio 1 (0.1-5%) often
Mixing composition under temperature, its system of described emulsion polymer includes water, monomer, surfactant, buffer agent, wherein water account for 40～
55%, described monomer includes that the carboxylic acid monomer as comonomer and at least one second monoene are good for formula unsaturated monomer, described
It is 40～55% that second monoene is good for formula unsaturated monomer accounting, and described carboxylic acid monomer is selectable to be had: acrylic acid, metering system
Acid, itaconic acid or maleic anhydride, described second monoene is good for that formula unsaturated monomer is selectable to be had: (methyl) acrylic acid methyl ester., (first
Base) ethyl acrylate, (methyl) butyl acrylate, (methyl) 2-(Acryloyloxy)ethanol, (methyl) acrylic acid-2-ethyl caproite, second
Acid ethylene or styrene；
Described water cross-linking agent is selectable to be had: multifunctional melamine compound, polycarbodiimide, multifunctional epoxide chemical combination
Thing, aziridine, polyfunctional isocyanate compound, metallic-ion crosslinking agent.
It is also preferred that the left described carboxylic acid monomer is preferably (methyl) acrylic acid.
Add " methyl " before described acrylic acid and represent acrylic acid and methacrylic acid respectively, add before other each term herein
" methyl " the most by that analogy.
Described second monoene is good for formula unsaturated monomer and is preferably acrylic composition.
Described water cross-linking agent is preferably polyfunctional isocyanate compound, and usage amount is described emulsion polymer quality
0.1-5%.
Further, described emulsion polymer also includes organic or inorganic pigment, conven-tional adjuvants, such as plasticizer, antifreezing agent, profit
Humectant, defoamer, heat stabilizer, dispersant, absorbent, preservative etc..
The polymerization of its system of emulsion polymer of the present invention is as follows:
First use conventional surfactants such as anion or nonionic emulsifier (quality accounting 0.1-0.3%) stirring, will
Water, monomer dispersion become little oil droplet, add initiator such as tert-butyl hydroperoxide or ammonium persulfate concentrations 0.01～0.75% it
Between；The most heated described decomposition of initiator produces free radical, and trigger monomer is polymerized, and in reaction, pH value can be gradually lowered, and adds slow
Electuary such as sodium bicarbonate, makes pH value maintain between 4-5.
Further, described monomer feed postition has two kinds, and one is to add with monomer emulsions form after all monomer pre-emulsifications
Enter；Two is that mix monomer adds with net phase form.
Described mixing speed is suitable with paddle shape and reactor size, preferably 3～8 tons reactors, the stirrings of anchor formula
Machine, speed 60～80r/min.
The heating and temperature control during polymerization of above-mentioned monomer, at 80～90 DEG C, needs heating before reaction.Because being exothermic reaction
Need to cool down and circulate to keep suitable temperature, reaction temperature preferably 80～85 DEG C.
PH value: in polymerization process, pH value slant acidity, prevention monomer hydrolysis, after being polymerized, pH value be preferably 6～10 it
Between, generally use ammonia regulation.The appropriate viscosity of above-mentioned emulsion polymer is between 50～150cps.
The invention has the beneficial effects as follows, make simple, low cost, nuisanceless, can according to gummed tape, cover protection adhesive tape
Use demand adjust its initial bonding strength, 180 ° of peeling force intensity, cohesivenesss and reach balance, and in certain temperature range use
Under not cull.
[detailed description of the invention]
Below in conjunction with embodiment, technical scheme is clearly and completely described, it is clear that described reality
Executing example is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area is general
The every other embodiment that logical technical staff is obtained under not making creative work premise, broadly falls into present invention protection
Scope.
A kind of environment friendly pressure sensitive stick, by emulsion polymer with water cross-linking agent with mass ratio 1 1.2% at normal temperatures
Mixing composition, its system of described emulsion polymer includes water, monomer, surfactant, buffer agent, and wherein water accounts for 40～55%,
Described monomer includes that the carboxylic acid monomer as comonomer and at least one second monoene are good for formula unsaturated monomer, and described second is single
It is 40～55% that alkene is good for formula unsaturated monomer accounting.
The polymerization of described emulsion polymer is as follows:
First use conventional surfactants such as anion or nonionic emulsifier (quality accounting 0.1-0.3%) stirring, will
Water, monomer dispersion become little oil droplet, add initiator such as tert-butyl hydroperoxide or ammonium persulfate concentrations 0.01～0.75% it
Between；The most heated described decomposition of initiator produces free radical, and trigger monomer is polymerized, and in reaction, pH value can be gradually lowered, and adds slow
Electuary such as sodium bicarbonate, makes pH value maintain between 4-5.
The heating and temperature control during polymerization of above-mentioned monomer, at 80～90 DEG C, needs heating before reaction.Because being exothermic reaction
Need to cool down and circulate to keep suitable temperature, reaction temperature preferably 80～85 DEG C.
PH value: in polymerization process, pH value slant acidity, prevention monomer hydrolysis, after being polymerized, pH value be preferably 6～10 it
Between, generally use ammonia regulation.The appropriate viscosity of above-mentioned emulsion polymer is between 50～150cps.
Embodiment:
Component proportion is divided into A, B, C tri-class in this embodiment, and the carboxylic acid monomer that A class emulsion polymer compositions selects is third
Olefin(e) acid, as the second monoene of copolymerization be good for that formula unsaturated monomer selects for butyl acrylate, acrylic acid-2-ethyl caproite and third
Olefin(e) acid hydroxyl ethyl ester；The carboxylic acid monomer that B class emulsion polymer compositions selects is acrylic acid and methacrylic acid, the second monoene of selection
Strong formula unsaturated monomer is butyl acrylate and 2-(Acryloyloxy)ethanol；The carboxylic acid monomer that C class emulsion polymer compositions selects is third
Olefin(e) acid, the second monoene of selection is good for formula unsaturated monomer butyl acrylate and vinyl acetate.
A, B, C tri-the water cross-linking agent of class component all select polyisocyanates, be equivalent to emulsion polymer 1.2% with quality
Add mixing at normal temperatures, hang with bar immediately and be applied in BOPP film make, below for form contrast signal:
Note: physical property detection method: with reference to GB GB/T22378-2008
More than it is embodied as case it can be seen that the finished product the most not cull made of B class, C class component, compares A class
Preferably, the configuration of suitable monomer can make the emulsion polymer of different physical property keynote to composition, then is mixed proper ratio
Water cross-linking agent, can make be applicable to general gummed tape and cover protection adhesive tape emulsion-type polyacrylate pressure-sensitive glue
Agent, because of its use that water base making is simple, low cost, nuisanceless, can progressively replace solvent type polyacrylate pressure sensitive adhesive, meet not
The growth requirement come.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (9)
1. an environment friendly pressure sensitive stick, it is characterised in that by emulsion polymer with water cross-linking agent with mass ratio 1 (0.1-
5%) mixing composition at normal temperatures, its system of described emulsion polymer includes water, monomer, surfactant, buffer agent, Qi Zhongshui
Accounting for 40～55%, described monomer includes that the carboxylic acid monomer as comonomer and at least one second monoene are good for formula unsaturation list
Body, it is 40～55% that described second monoene is good for formula unsaturated monomer accounting, and described carboxylic acid monomer is selectable to be had: acrylic acid, first
Base acrylic acid, itaconic acid or maleic anhydride, described second monoene is good for that formula unsaturated monomer is selectable to be had: (methyl) acrylic acid first
Ester, (methyl) ethyl acrylate, (methyl) butyl acrylate, (methyl) 2-(Acryloyloxy)ethanol, (methyl) acrylic acid-2-ethyl are own
Ester, vinyl acetate or styrene；
Described water cross-linking agent is selectable to be had: multifunctional melamine compound, polycarbodiimide, polyfunctional epoxy compound,
Aziridine, polyfunctional isocyanate compound, metallic-ion crosslinking agent.
A kind of environment friendly pressure sensitive stick the most according to claim 1, it is characterised in that described carboxylic acid monomer is preferably
(methyl) acrylic acid.
A kind of environment friendly pressure sensitive stick the most according to claim 1, it is characterised in that described second monoene is good for formula insatiable hunger
It is preferably acrylic composition with monomer.
A kind of environment friendly pressure sensitive stick the most according to claim 1, it is characterised in that described water cross-linking agent is preferably
Polyfunctional isocyanate compound.
A kind of environment friendly pressure sensitive stick the most according to claim 1, it is characterised in that described emulsion polymer also includes
Organic or inorganic pigment, conven-tional adjuvants, such as plasticizer, antifreezing agent, wetting agent, defoamer or heat stabilizer, dispersant, absorption
Agent, preservative.
A kind of environment friendly pressure sensitive stick the most according to claim 1, it is characterised in that the polymerization of described emulsion polymer
Method is: first use conventional surfactants such as anion or nonionic emulsifier (quality accounting 0.1-0.3%) stirring, will
Water, monomer dispersion become little oil droplet, add initiator such as tert-butyl hydroperoxide or ammonium persulfate concentrations 0.01～0.75% it
Between；The most heated described decomposition of initiator produces free radical, and trigger monomer is polymerized, and in reaction, pH value can be gradually lowered, and adds slow
Electuary such as sodium bicarbonate, makes pH value maintain between 4-5.
A kind of environment friendly pressure sensitive stick the most according to claim 6, it is characterised in that the feed postition of described monomer has
Two kinds: one is will to add with monomer emulsions form after all monomer pre-emulsifications；Two is that mix monomer adds with net phase form.
A kind of environment friendly pressure sensitive stick the most according to claim 6, it is characterised in that described mixing speed and paddle
Shape and reactor size are suitable, preferably 3～8 tons reactors, anchor agitators, speed 60～80r/min.
A kind of environment friendly pressure sensitive stick the most according to claim 6, it is characterised in that the heating during polymerization of above-mentioned monomer
Temperature controls at 80～90 DEG C, needs heating before reaction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610642894.3A CN106281138A (en) | 2016-08-08 | 2016-08-08 | A kind of environment friendly pressure sensitive stick |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610642894.3A CN106281138A (en) | 2016-08-08 | 2016-08-08 | A kind of environment friendly pressure sensitive stick |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106281138A true CN106281138A (en) | 2017-01-04 |
Family
ID=57666297
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610642894.3A Pending CN106281138A (en) | 2016-08-08 | 2016-08-08 | A kind of environment friendly pressure sensitive stick |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106281138A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106995676A (en) * | 2017-04-10 | 2017-08-01 | 孙小力 | A kind of zero formaldehyde wood adhesive and preparation method thereof |
| CN108130007A (en) * | 2017-12-29 | 2018-06-08 | 浙江仁丰科技有限公司 | A kind of adhesive tape protective film and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070148444A1 (en) * | 2005-12-22 | 2007-06-28 | Nitto Denko Corporation | Removable water-dispersible acrylic adhesive compositiion and adhesive sheet |
| JP2011093956A (en) * | 2009-10-27 | 2011-05-12 | Lintec Corp | Water-dispersed acrylic pressure-sensitive adhesive composition, pressure-sensitive adhesive sheet, and method for producing the same |
| CN103467650A (en) * | 2013-09-18 | 2013-12-25 | 潍坊胜达塑胶有限公司 | Pressure-sensitive adhesive emulsion, preparation method and high-holding protective film prepared from pressure-sensitive adhesive emulsion |
| CN103524667A (en) * | 2013-10-16 | 2014-01-22 | 佛山市奥雅图胶粘实业有限公司 | Water-based pressure-sensitive adhesive for polyethylene protection film and polyethylene protection film and preparation method thereof |
| CN104710952A (en) * | 2015-04-08 | 2015-06-17 | 潍坊胜达科技股份有限公司 | Coating pressure sensitive adhesive for moisture-air permeable protective film, method for producing coating pressure sensitive adhesive and moisture-air permeable protective film made of pressure sensitive adhesive |
-
2016
- 2016-08-08 CN CN201610642894.3A patent/CN106281138A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070148444A1 (en) * | 2005-12-22 | 2007-06-28 | Nitto Denko Corporation | Removable water-dispersible acrylic adhesive compositiion and adhesive sheet |
| JP2011093956A (en) * | 2009-10-27 | 2011-05-12 | Lintec Corp | Water-dispersed acrylic pressure-sensitive adhesive composition, pressure-sensitive adhesive sheet, and method for producing the same |
| CN103467650A (en) * | 2013-09-18 | 2013-12-25 | 潍坊胜达塑胶有限公司 | Pressure-sensitive adhesive emulsion, preparation method and high-holding protective film prepared from pressure-sensitive adhesive emulsion |
| CN103524667A (en) * | 2013-10-16 | 2014-01-22 | 佛山市奥雅图胶粘实业有限公司 | Water-based pressure-sensitive adhesive for polyethylene protection film and polyethylene protection film and preparation method thereof |
| CN104710952A (en) * | 2015-04-08 | 2015-06-17 | 潍坊胜达科技股份有限公司 | Coating pressure sensitive adhesive for moisture-air permeable protective film, method for producing coating pressure sensitive adhesive and moisture-air permeable protective film made of pressure sensitive adhesive |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106995676A (en) * | 2017-04-10 | 2017-08-01 | 孙小力 | A kind of zero formaldehyde wood adhesive and preparation method thereof |
| CN108130007A (en) * | 2017-12-29 | 2018-06-08 | 浙江仁丰科技有限公司 | A kind of adhesive tape protective film and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104004477B (en) | A kind of room-temperature self crosslinking polyacrylate pressure-sensitive and preparation method thereof and application | |
| CN105463882B (en) | A kind of gold stamping slurry and preparation method thereof | |
| CN101864025B (en) | Preparation method of polyacrylate microgel emulsion and application thereof | |
| CN106832104A (en) | High temperature resistant aluminium foil polyacrylate pressure-sensitive emulsion and application thereof and preparation method | |
| KR20140030247A (en) | Water-based adhesive agent composition and method for producing same | |
| CN105838297A (en) | Method for preparing environment-friendly thermoplastic resin aqueous adhesive | |
| CN106833446A (en) | PP film gum Acrylate pressure-sensitive adhesive emulsions and application thereof and preparation method | |
| CN103320065A (en) | Emulsion pressure-sensitive adhesive for protecting adhesive tape and preparation method thereof | |
| KR20210063329A (en) | contact adhesive | |
| CN107189723A (en) | Waterborne dry-type laminated adhesive and preparation method thereof | |
| CN109517102A (en) | Vinyl acetate-ester-vinyl multi-copolymer emulsion and preparation method thereof | |
| CN102808360B (en) | Temperature-resistant water-based gloss oil for high-gloss paper products and preparation method of temperature-resistant water-based gloss oil | |
| CN111620983A (en) | Acrylate emulsion for moisture-resistant rubbing water-based ink and preparation method thereof | |
| CN105440982B (en) | Packing box used and wood-leather base material used environmentally-friendly aqueous binder | |
| CN108912262A (en) | A kind of water-borne pressure sensitive adhesive lotion and its synthetic method with double grains gauge structure | |
| CN106281138A (en) | A kind of environment friendly pressure sensitive stick | |
| CN103936916B (en) | PET film precoating heat is mounted aqueous binder emulsion and preparation method | |
| CN106189950B (en) | A kind of aqueous, environmental protective high intensity sticker adhesive and preparation method thereof | |
| CN103205173B (en) | Aqueous wallpaper printing medium and preparation method thereof | |
| CN106010380B (en) | A kind of method that pickering emulsion polymerizations prepare water-fast albefaction acrylic emulsion pressure sensitive adhesive | |
| TWI826368B (en) | Water-based pressure sensitive adhesive compositions and methods of making same | |
| CN107652771A (en) | A kind of online water-based base oil composition of high adhesion force and its manufacture method | |
| KR101349848B1 (en) | Method of producing high performance water-soluble acrylic adhesive compositon | |
| CN114044846A (en) | Preparation method of semi-oil semi-aqueous partial adhesive | |
| CN107090223A (en) | Rosin/styrene-acrylic composite emulsion and preparation method thereof, application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 431600 Beiqiao Industrial Park, Hanchuan economic and Technological Development Zone, Xiaogan, Hubei, China Applicant after: Hubei Huazhong Polytron Technologies Inc Address before: 431600 Beiqiao Industrial Park, Hanchuan economic and Technological Development Zone, Xiaogan, Hubei, China Applicant before: Aoxin Adhesive Science & Technology (Hubei) Co., Ltd. |
|
| COR | Change of bibliographic data | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170104 |
|
| RJ01 | Rejection of invention patent application after publication |