CN105754273B - 一种阻隔水汽的聚合纳米薄膜及其制备方法 - Google Patents

一种阻隔水汽的聚合纳米薄膜及其制备方法 Download PDF

Info

Publication number
CN105754273B
CN105754273B CN201610139436.8A CN201610139436A CN105754273B CN 105754273 B CN105754273 B CN 105754273B CN 201610139436 A CN201610139436 A CN 201610139436A CN 105754273 B CN105754273 B CN 105754273B
Authority
CN
China
Prior art keywords
parts
polymer
nanometer film
preparation
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201610139436.8A
Other languages
English (en)
Other versions
CN105754273A (zh
Inventor
朱晓玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Great Rich Technology Co Ltd
Original Assignee
ANHUI JDPV NEW MATERIAL TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI JDPV NEW MATERIAL TECHNOLOGY Co Ltd filed Critical ANHUI JDPV NEW MATERIAL TECHNOLOGY Co Ltd
Priority to CN201610139436.8A priority Critical patent/CN105754273B/zh
Publication of CN105754273A publication Critical patent/CN105754273A/zh
Application granted granted Critical
Publication of CN105754273B publication Critical patent/CN105754273B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042—PV modules or arrays of single PV cells
    • H01L31/048—Encapsulation of modules
    • H01L31/049—Protective back sheets
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2455/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
    • C08J2455/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2477/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino carboxylic acids or of polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/008—Additives improving gas barrier properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/14—Gas barrier composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Electromagnetism (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种阻隔水汽的聚合纳米薄膜及其制备方法，该聚合纳米薄膜，按照质量份数计的原料包括：聚丙烯酸酯10‑25份、碳纳米管8‑28份、碳酸钙0.1‑2份、三元乙丙橡胶1‑8份、聚对苯二甲酸乙二酯10‑20份、纳米二氧化锆1‑5份、丙烯腈‑丁二烯‑苯乙烯共聚物1‑8份、硅酮粉1‑5份、十二烷基氨基丙酸2‑12份、乙酸丁酯30‑60份、芳纶纤维1‑8份、碳化硅纤维1‑8份。本发明具有良好的水气阻隔性、耐候性及附着性，并且薄膜与封装材料之间的粘结强度高。本发明在制作工艺简单，成本较低。本发明的耐候层组合物具有较好的相容性，更有利于涂布生产。本发明的耐候层与基材表面具有较好的附着性，可避免在使用过程中耐候层发生脱落。

Description

一种阻隔水汽的聚合纳米薄膜及其制备方法
技术领域
本发明涉及太阳能电池技术领域，具体是一种阻隔水汽的聚合纳米薄膜及其制备方法。
背景技术
太阳能电池己经被大量的使用在各个技术领域。背膜是构成太阳能电池组件的重要组成部分，其在整个太阳能电池中主要起着绝缘和阻隔水气的作用，因此需要具备较好的水气阻隔性及绝缘性，这些性能主要是通过背膜中的基材达到的，但由于基材在使用过程中，尤其是在户外使用过程中，容易受到紫外线等的侵蚀造成老化，故需要采用具有耐候性的材料来保护基材，从而形成太阳能电池背膜。现有技术中，太阳能电池背膜的耐候层与基材的附着性较差，使用过程中容易发生脱落。同时，生产的背膜不仅需要挥发大量的溶剂，制备工艺复杂，成本较高，而且自身的层间粘合以及与薄膜的粘合效果都无法达到令人满意的程度，长期户外使用便会出现层间分脱的现象。
发明内容
本发明的目的在于提供一种具有良好的耐候性及附着性、阻隔水汽的聚合纳米薄膜及其制备方法，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：
一种阻隔水汽的聚合纳米薄膜，按照质量份数计的原料包括：聚丙烯酸酯10-25份、碳纳米管8-28份、碳酸钙0.1-2份、三元乙丙橡胶1-8份、聚对苯二甲酸乙二酯10-20份、纳米二氧化锆1-5份、丙烯腈-丁二烯-苯乙烯共聚物1-8份、硅酮粉1-5份、十二烷基氨基丙酸2-12份、乙酸丁酯30-60份、芳纶纤维1-8份、碳化硅纤维1-8份。
作为本发明进一步的方案：所述阻隔水汽的聚合纳米薄膜，按照质量份数计的原料包括：聚丙烯酸酯12-20份、碳纳米管10-25份、碳酸钙0.1-1份、三元乙丙橡胶2-6份、聚对苯二甲酸乙二酯12-18份、纳米二氧化锆2-3份、丙烯腈-丁二烯-苯乙烯共聚物2-6份、硅酮粉1-3份、十二烷基氨基丙酸4-10份、乙酸丁酯35-55份、芳纶纤维2-5份、碳化硅纤维2-5份。
作为本发明进一步的方案：所述阻隔水汽的聚合纳米薄膜，按照质量份数计的原料包括：聚丙烯酸酯14-18份、碳纳米管15-20份、碳酸钙0.1-1份、三元乙丙橡胶3-5份、聚对苯二甲酸乙二酯14-16份、纳米二氧化锆2-3份、丙烯腈-丁二烯-苯乙烯共聚物3-5份、硅酮粉2-3份、十二烷基氨基丙酸5-8份、乙酸丁酯40-50份、芳纶纤维3-4份、碳化硅纤维3-4份。
所述阻隔水汽的聚合纳米薄膜的制备方法，包括以下步骤:
1)在容器中加入十二烷基氨基丙酸，然后加入聚丙烯酸酯、碳纳米管、碳酸钙、三元乙丙橡胶与纳米二氧化锆，搅拌均匀，再加入乙酸丁酯，然后再逐步加入硅酮粉、芳纶纤维与碳化硅纤维，搅拌均匀后，得到耐候层组合物；
2)将耐候层组合物涂布于110-170μm厚的采用聚对苯二甲酸乙二酯与丙烯腈-丁二烯-苯乙烯共聚物制作的基材上，具体涂布过程如下：先将基材经放卷机放卷，然后自动上料，耐候层组合物在基材上涂布之后经过三段烘板箱烘烤，烘板箱温度分别设为120-125℃，100-108℃，80-90℃，烘道长度为10-25m，线速度为2-20m/min，再通过3-6kg/cm2的压力辊辊压，最后经收卷机收卷，即得聚合纳米薄膜。
作为本发明进一步的方案：步骤2)中采用聚碳酸酯制作的基材的厚度为120-150μm。
作为本发明进一步的方案：步骤2)中烘道长度为15-20m，线速度为5-15m/min。
作为本发明进一步的方案：步骤2)中压力辊辊压压力为4.5kg/cm2。
与现有技术相比，本发明的有益效果是：
本发明具有良好的水气阻隔性、耐候性及附着性，并且薄膜与封装材料之间的粘结强度高。本发明在制作工艺简单，成本较低。本发明的耐候层组合物具有较好的相容性，更有利于涂布生产。本发明的耐候层与基材表面具有较好的附着性，可避免在使用过程中耐候层发生脱落。
具体实施方式
下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1
本发明实施例中，一种阻隔水汽的聚合纳米薄膜，按照质量份数计的原料包括：聚丙烯酸酯10份、碳纳米管8份、碳酸钙0.1份、三元乙丙橡胶1份、聚对苯二甲酸乙二酯10份、纳米二氧化锆1份、丙烯腈-丁二烯-苯乙烯共聚物1份、硅酮粉1份、十二烷基氨基丙酸2份、乙酸丁酯30份、芳纶纤维1份、碳化硅纤维1份。
所述阻隔水汽的聚合纳米薄膜的制备方法，包括以下步骤:
1)在容器中加入十二烷基氨基丙酸，然后加入聚丙烯酸酯、碳纳米管、碳酸钙、三元乙丙橡胶与纳米二氧化锆，搅拌均匀，再加入乙酸丁酯，然后再逐步加入硅酮粉、芳纶纤维与碳化硅纤维，搅拌均匀后，得到耐候层组合物。
2)将耐候层组合物涂布于110μm厚的采用聚对苯二甲酸乙二酯与丙烯腈-丁二烯-苯乙烯共聚物制作的基材上，具体涂布过程如下：先将基材经放卷机放卷，然后自动上料，耐候层组合物在基材上涂布之后经过三段烘板箱烘烤，烘板箱温度分别设为120℃，100℃，80℃，烘道长度为10m，线速度为2m/min，再通过3kg/cm2的压力辊辊压，最后经收卷机收卷，即得聚合纳米薄膜。
实施例2
本发明实施例中，一种阻隔水汽的聚合纳米薄膜，按照质量份数计的原料包括：聚丙烯酸酯25份、碳纳米管28份、碳酸钙2份、三元乙丙橡胶8份、聚对苯二甲酸乙二酯20份、纳米二氧化锆5份、丙烯腈-丁二烯-苯乙烯共聚物8份、硅酮粉5份、十二烷基氨基丙酸12份、乙酸丁酯60份、芳纶纤维8份、碳化硅纤维8份。
所述阻隔水汽的聚合纳米薄膜的制备方法，包括以下步骤:
1)在容器中加入十二烷基氨基丙酸，然后加入聚丙烯酸酯、碳纳米管、碳酸钙、三元乙丙橡胶与纳米二氧化锆，搅拌均匀，再加入乙酸丁酯，然后再逐步加入硅酮粉、芳纶纤维与碳化硅纤维，搅拌均匀后，得到耐候层组合物。
2)将耐候层组合物涂布于170μm厚的采用聚对苯二甲酸乙二酯与丙烯腈-丁二烯-苯乙烯共聚物制作的基材上，具体涂布过程如下：先将基材经放卷机放卷，然后自动上料，耐候层组合物在基材上涂布之后经过三段烘板箱烘烤，烘板箱温度分别设为125℃，108℃，90℃，烘道长度为25m，线速度为20m/min，再通过6kg/cm2的压力辊辊压，最后经收卷机收卷，即得聚合纳米薄膜。
实施例3
本发明实施例中，一种阻隔水汽的聚合纳米薄膜，按照质量份数计的原料包括：聚丙烯酸酯12份、碳纳米管10份、碳酸钙0.1份、三元乙丙橡胶2份、聚对苯二甲酸乙二酯12份、纳米二氧化锆2份、丙烯腈-丁二烯-苯乙烯共聚物2份、硅酮粉1份、十二烷基氨基丙酸4份、乙酸丁酯35份、芳纶纤维2份、碳化硅纤维2份。
所述阻隔水汽的聚合纳米薄膜的制备方法，包括以下步骤:
1)在容器中加入十二烷基氨基丙酸，然后加入聚丙烯酸酯、碳纳米管、碳酸钙、三元乙丙橡胶与纳米二氧化锆，搅拌均匀，再加入乙酸丁酯，然后再逐步加入硅酮粉、芳纶纤维与碳化硅纤维，搅拌均匀后，得到耐候层组合物。
2)将耐候层组合物涂布于120μm厚的采用聚对苯二甲酸乙二酯与丙烯腈-丁二烯-苯乙烯共聚物制作的基材上，具体涂布过程如下：先将基材经放卷机放卷，然后自动上料，耐候层组合物在基材上涂布之后经过三段烘板箱烘烤，烘板箱温度分别设为120℃，100℃，80℃，烘道长度为15m，线速度为5m/min，再通过4.5kg/cm2的压力辊辊压，最后经收卷机收卷，即得聚合纳米薄膜。
实施例4
本发明实施例中，一种阻隔水汽的聚合纳米薄膜，按照质量份数计的原料包括：聚丙烯酸酯20份、碳纳米管25份、碳酸钙1份、三元乙丙橡胶6份、聚对苯二甲酸乙二酯18份、纳米二氧化锆3份、丙烯腈-丁二烯-苯乙烯共聚物6份、硅酮粉3份、十二烷基氨基丙酸10份、乙酸丁酯55份、芳纶纤维5份、碳化硅纤维5份。
所述阻隔水汽的聚合纳米薄膜的制备方法，包括以下步骤:
1)在容器中加入十二烷基氨基丙酸，然后加入聚丙烯酸酯、碳纳米管、碳酸钙、三元乙丙橡胶与纳米二氧化锆，搅拌均匀，再加入乙酸丁酯，然后再逐步加入硅酮粉、芳纶纤维与碳化硅纤维，搅拌均匀后，得到耐候层组合物。
2)将耐候层组合物涂布于150μm厚的采用聚对苯二甲酸乙二酯与丙烯腈-丁二烯-苯乙烯共聚物制作的基材上，具体涂布过程如下：先将基材经放卷机放卷，然后自动上料，耐候层组合物在基材上涂布之后经过三段烘板箱烘烤，烘板箱温度分别设为125℃，108℃，90℃，烘道长度为20m，线速度为15m/min，再通过4.5kg/cm2的压力辊辊压，最后经收卷机收卷，即得聚合纳米薄膜。
实施例5
本发明实施例中，一种阻隔水汽的聚合纳米薄膜，按照质量份数计的原料包括：聚丙烯酸酯14份、碳纳米管1份、碳酸钙0.1份、三元乙丙橡胶3份、聚对苯二甲酸乙二酯14份、纳米二氧化锆2份、丙烯腈-丁二烯-苯乙烯共聚物3份、硅酮粉2份、十二烷基氨基丙酸5份、乙酸丁酯40份、芳纶纤维3份、碳化硅纤维3份。
制备过程与实施例3一致。
实施例6
本发明实施例中，一种阻隔水汽的聚合纳米薄膜，按照质量份数计的原料包括：聚丙烯酸酯18份、碳纳米管20份、碳酸钙1份、三元乙丙橡胶5份、聚对苯二甲酸乙二酯16份、纳米二氧化锆3份、丙烯腈-丁二烯-苯乙烯共聚物5份、硅酮粉3份、十二烷基氨基丙酸8份、乙酸丁酯50份、芳纶纤维4份、碳化硅纤维4份。
制备过程与实施例3一致。
将上述实施例制备的聚合纳米薄膜应用于太阳能电池背膜并进行性能测试，试验如下：
一、水蒸气透过率试验
根据标准ASTM F 1249，采用TSY-W2水蒸气透过率测试仪对上述背膜的水蒸气透过率进行测试。
二、耐候性试验
根据标准ISO 4892-2，采用Q-sun氙灯型耐候试验机对上述背膜的耐候性进行测试。
三、附着力试验
根据标准GB/T 9286-1998，采用漆膜划格仪(昆山三诺仪器QFH漆膜划格仪，划格等级最高级为0级)对上述背膜的附着力进行测试。
四、粘结强度试验
粘结强度依据国家标准GB/T8808进行测试。
将试验一至四的试验数据进行统计，试验结果见表1。
表1
对于本领域技术人员而言，显然本发明不限于上述示范性实施例的细节，而且在不背离本发明的精神或基本特征的情况下，能够以其他的具体形式实现本发明。因此，无论从哪一点来看，均应将实施例看作是示范性的，而且是非限制性的，本发明的范围由所附权利要求而不是上述说明限定，因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。
此外，应当理解，虽然本说明书按照实施方式加以描述，但并非每个实施方式仅包含一个独立的技术方案，说明书的这种叙述方式仅仅是为清楚起见，本领域技术人员应当将说明书作为一个整体，各实施例中的技术方案也可以经适当组合，形成本领域技术人员可以理解的其他实施方式。

Claims (7)

1.一种阻隔水汽的聚合纳米薄膜，其特征在于，按照质量份数计的原料包括：聚丙烯酸酯10-25份、碳纳米管8-28份、碳酸钙0.1-2份、三元乙丙橡胶1-8份、聚对苯二甲酸乙二酯10-20份、纳米二氧化锆1-5份、丙烯腈-丁二烯-苯乙烯共聚物1-8份、硅酮粉1-5份、十二烷基氨基丙酸2-12份、乙酸丁酯30-60份、芳纶纤维1-8份、碳化硅纤维1-8份。
2.根据权利要求1所述的阻隔水汽的聚合纳米薄膜，其特征在于，按照质量份数计的原料包括：聚丙烯酸酯12-20份、碳纳米管10-25份、碳酸钙0.1-1份、三元乙丙橡胶2-6份、聚对苯二甲酸乙二酯12-18份、纳米二氧化锆2-3份、丙烯腈-丁二烯-苯乙烯共聚物2-6份、硅酮粉1-3份、十二烷基氨基丙酸4-10份、乙酸丁酯35-55份、芳纶纤维2-5份、碳化硅纤维2-5份。
3.根据权利要求2所述的阻隔水汽的聚合纳米薄膜，其特征在于，按照质量份数计的原料包括：聚丙烯酸酯14-18份、碳纳米管15-20份、碳酸钙0.1-1份、三元乙丙橡胶3-5份、聚对苯二甲酸乙二酯14-16份、纳米二氧化锆2-3份、丙烯腈-丁二烯-苯乙烯共聚物3-5份、硅酮粉2-3份、十二烷基氨基丙酸5-8份、乙酸丁酯40-50份、芳纶纤维3-4份、碳化硅纤维3-4份。
4.一种如权利要求1-3任一所述的阻隔水汽的聚合纳米薄膜的制备方法，其特征在于，包括以下步骤:
1)在容器中加入十二烷基氨基丙酸，然后加入聚丙烯酸酯、碳纳米管、碳酸钙、三元乙丙橡胶与纳米二氧化锆，搅拌均匀，再加入乙酸丁酯，然后再逐步加入硅酮粉、芳纶纤维与碳化硅纤维，搅拌均匀后，得到耐候层组合物；
2)将耐候层组合物涂布于110-170μm厚的采用聚对苯二甲酸乙二酯与丙烯腈-丁二烯-苯乙烯共聚物制作的基材上，具体涂布过程如下：先将基材经放卷机放卷，然后自动上料，耐候层组合物在基材上涂布之后经过三段烘板箱烘烤，烘板箱温度分别设为120-125℃，100-108℃，80-90℃，烘道长度为10-25m，线速度为2-20m/min，再通过3-6kg/cm2的压力辊辊压，最后经收卷机收卷，即得聚合纳米薄膜。
5.根据权利要求4所述的阻隔水汽的聚合纳米薄膜的制备方法，其特征在于，步骤2)中采用聚碳酸酯制作的基材的厚度为120-150μm。
6.根据权利要求4所述的阻隔水汽的聚合纳米薄膜的制备方法，其特征在于，步骤2)中烘道长度为15-20m，线速度为5-15m/min。
7.根据权利要求4所述的阻隔水汽的聚合纳米薄膜的制备方法，其特征在于，步骤2)中压力辊辊压压力为4.5kg/cm2。
CN201610139436.8A 2016-03-11 2016-03-11 一种阻隔水汽的聚合纳米薄膜及其制备方法 Active CN105754273B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610139436.8A CN105754273B (zh) 2016-03-11 2016-03-11 一种阻隔水汽的聚合纳米薄膜及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610139436.8A CN105754273B (zh) 2016-03-11 2016-03-11 一种阻隔水汽的聚合纳米薄膜及其制备方法

Publications (2)

Publication Number Publication Date
CN105754273A CN105754273A (zh) 2016-07-13
CN105754273B true CN105754273B (zh) 2018-04-20

Family

ID=56333008

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610139436.8A Active CN105754273B (zh) 2016-03-11 2016-03-11 一种阻隔水汽的聚合纳米薄膜及其制备方法

Country Status (1)

Country Link
CN (1) CN105754273B (zh)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10612492B2 (en) 2017-03-16 2020-04-07 Northrop Grumman Innovation Systems, Inc. Precursor compositions for an insulation, insulated rocket motors, and related methods
US20190120174A1 (en) * 2017-10-25 2019-04-25 Northrop Grumman Innovation Systems, Inc. Precursor compositions for an insulation, insulated rocket motors, and related methods
CN110591005B (zh) * 2019-09-20 2022-03-15 铁科创恒新材料科技有限公司 一种耐高温水汽封闭膜及其制备方法
CN115246746A (zh) * 2021-04-25 2022-10-28 中国科学院苏州纳米技术与纳米仿生研究所 轻柔层状碳膜及其制备方法与应用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101177514B (zh) * 2007-11-08 2010-06-09 中国乐凯胶片集团公司 一种太阳能电池背板及其制备方法
JP5906550B2 (ja) * 2011-07-28 2016-04-20 株式会社Moresco ハイバリア性を有する封止材
CN103214770B (zh) * 2013-04-22 2015-03-18 山东东岳高分子材料有限公司 一种太阳能电池封装膜及其制备方法

Also Published As

Publication number Publication date
CN105754273A (zh) 2016-07-13

Similar Documents

Publication Publication Date Title
CN105754273B (zh) 一种阻隔水汽的聚合纳米薄膜及其制备方法
CN104600230A (zh) 一种电池隔膜及其应用
CN104392845A (zh) 一种可拉伸的线状超级电容器和锂离子电池制备方法
CN104900833B (zh) 一种锂离子电池隔膜及其制备方法
CN107528038A (zh) 制备复合隔膜的混合浆料及复合隔膜的制备方法
TW201110381A (en) Protecting sheet for solar cell module
CN104057671A (zh) 抗静电离型膜及其制造方法
CN104022250B (zh) 一种锂离子电池隔膜及其制备方法
CN102166851B (zh) 一种太阳能电池背板及使用该背板的太阳能电池模块
CN106590459A (zh) 一种光伏组件电池片定位用耐高温胶带及其制备方法
CN106794689A (zh) 层叠体的制造方法
CN105070851B (zh) 一种聚合物锂离子电池包装高阻隔专用膜
CN105720125B (zh) 一种功能性多层复合光伏背板
CN106189921A (zh) 一种具有高粘结强度的poe封装胶膜用复合增粘剂及其应用
CN106671513B (zh) 云母带和制造云母带的方法
CN201756528U (zh) 一种聚酰亚胺薄膜压敏胶带
KR101520437B1 (ko) 도전성 점착 보호 필름
CN204111657U (zh) 一种抗紫外耐腐蚀胶带
JP6388026B2 (ja) 被覆リチウム−ニッケル複合酸化物粒子及び被覆リチウム−ニッケル複合酸化物粒子の製造方法
CN104393083A (zh) 一种太阳能电池背膜及其制备方法
CN207925194U (zh) 复合式云母带
CN207210313U (zh) 一种高性能阻燃保护膜胶带
CN104031572A (zh) 一种胶带及其制备方法
TW201243890A (en) Capacitance unit and stacked solid electrolytic capacitor
Zhao et al. Single‐Piece Membrane Supercapacitor with Exceptional Areal/Volumetric Capacitance via Double‐Face Print of Electrode/Electrolyte Active Ink

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information

Inventor after: Zhu Xiaoling

Inventor before: Tang Zhuoqun

CB03 Change of inventor or designer information
TA01 Transfer of patent application right

Effective date of registration: 20180319

Address after: 233400 Huaiyuan Economic Development Zone, Bengbu, Anhui

Applicant after: ANHUI JINDUI NEW MATERIAL TECHNOLOGY CO.,LTD.

Address before: 311813 Zhejiang city of Shaoxing province Zhuji city streets Jiyang new century garden harvest in the 13 room 103

Applicant before: Tang Zhuoqun

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20221024

Address after: No. 8, Changxing Road, Changjing Town, Jiangyin, Wuxi City, Jiangsu Province, 214400 (business site: No. 26, Tonggang Road, Changjing Town, Jiangyin)

Patentee after: JIANGYIN TONGLI OPTOELECTRONIC TECHNOLOGY Co.,Ltd.

Address before: 233400 Huaiyuan Economic Development Zone, Anhui, Bengbu

Patentee before: ANHUI JINDUI NEW MATERIAL TECHNOLOGY CO.,LTD.

TR01 Transfer of patent right