CN105746501B - Folium eucalypti oil assistant and preparation method thereof and fabric final finishing working solution - Google Patents
Folium eucalypti oil assistant and preparation method thereof and fabric final finishing working solution Download PDFInfo
- Publication number
- CN105746501B CN105746501B CN201610172779.4A CN201610172779A CN105746501B CN 105746501 B CN105746501 B CN 105746501B CN 201610172779 A CN201610172779 A CN 201610172779A CN 105746501 B CN105746501 B CN 105746501B
- Authority
- CN
- China
- Prior art keywords
- oil
- parts
- folium eucalypti
- added
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Textile Engineering (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Toxicology (AREA)
- Biotechnology (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Dispersion Chemistry (AREA)
- Botany (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention discloses a kind of folium eucalypti oil assistant and preparation method thereof and fabric final finishing working solution, and folium eucalypti oil assistant includes 5-20 parts of folium eucalypti oil microcapsule, 5-10 parts of eucalyptus oil, 1-20 parts of nonionic emulsifier, 5-10 parts of anion thickener, 5-10 parts of polyurethane binder and 30-50 parts of deionized water.The present invention uses emulsifying process, and eucalyptus oil is dissolved in emulsifier, and obtained auxiliary agent has good affinity and assimilation effect to face liber；Folium eucalypti oil microcapsule is added simultaneously in auxiliary agent, under the protection of cyst wall, the retention time of eucalyptus oil effective component increases, and functional effect extends, and is conducive to keep the optimal using effect of fabric；One or more essential oils can be added in emulsifier, the inoxidizability of essential oil itself can be improved, can also improve the storage stability of auxiliary agent, avoid for a long time as gravity and caused by layering；The production method of auxiliary agent of the present invention is simple and easy, easy to accomplish.
Description
Technical field
The present invention relates to a kind of auxiliary agents and preparation method thereof and fabric final finishing working solution more particularly to a kind of eucalyptus oil
Auxiliary agent and preparation method thereof and fabric final finishing working solution, belong to textile auxiliary agent and technical field of textile afterfinish.
Background technique
Textile is essential articles in people's daily life, however the fabric without the protection of any specific function holds
Vulnerable to the factors such as environment, artificial, become bacterium, the temperature with microorganism (such as acarid etc.) growth and breeding of human body symbiosis
Bed, in addition, also suffering from the long-term infringement of dermatophagoides pteronyssinus in nature etc., causes various allergic symptoms and disease.Mesh
Before, the safety problem of textile has become the hot spot of consumer's common concern, and the anti-mite equal functional requirements of antibacterial textile
It is more more and more urgent, therefore research and develop such textile and have a very important significance and be worth.
At present in the anti-mite field of antibacterial textile, the antibacterial agent of organic synthesis is mostly used greatly to realize the function of antibiosis anti-acarien
Effect, such as: quaternary ammonium compound, silver ion series antibacterial agent, macromolecular organic compound antibacterial agent, nitro compound, first
Aldehyde derivatives etc..But wherein most antibacterial agents can not only cause certain injury to human body, but also there are non-degradables, right
The problems such as environment impacts.Emphasis is transferred to natural Chinese herbal medicine and pure plant origin by some enterprises, colleges and universities in recent years
Substance research on, therefore study green, safety antibiosis anti-acarien auxiliary agent/will become exploitation hot spot.
Eucalyptus oil, main component are 1.8 Cineoles, and scientific name 1.3,3- trimethyl -2 oxa- ring [2.2,2] octane, is one
The pure natural plants essential oil of kind.It is known its in low concentration, have for bacterium, fungi, microorganism, mosquito etc. and repellent and go out
The effect killed, only 5% eucalyptus oil can reach 99.5% to the scattering ratio 30min of acarid, and belonging to has preferable anti-mite effect；
And it is smaller to human toxicity, not will cause secondary pollution, therefore have wide development prospect.But due to eucalyptus oil itself
With volatility, and light resistance and heat resistance are unstable, certain negative effect can be generated to its pharmacological action, if directly
It connects and uses on textile, the effect of its script is not only not achieved, but also can also affect on product quality.
Therefore, how effective exploitation and using eucalyptus oil and to be used on textile, become skill urgently to be resolved at present
Art problem.
Summary of the invention
Goal of the invention: the first object of the present invention be to provide a kind of anti-mite fungistatic effect is good, smell is small, it is not volatile and
Fast light hot stable folium eucalypti oil assistant；The second object of the present invention is to provide the preparation method of the folium eucalypti oil assistant；The present invention
Third purpose be to provide the fabric final finishing working solution containing the folium eucalypti oil assistant.
Technical solution: folium eucalypti oil assistant of the present invention includes following component: folium eucalypti oil microcapsule 5- by weight
20 parts, 5-10 parts of eucalyptus oil, 1-20 parts of nonionic emulsifier, 5-10 parts of anion thickener, polyurethane binder 5-10
Part and 30-50 parts of deionized water.
Wherein, which further includes 1-5 parts of eugenol, at least one in 1-5 parts of wormwood oil and 1-5 parts of cedar oil
Kind, uniform dissolution eucalyptus oil can be played the role of, if Multiple components are used together, synergistic effect can be played.
The HLB value of the nonionic emulsifier is 8.5-14.5, and emulsifying effectiveness is preferable.
Folium eucalypti oil assistant of the invention can also include 0.1-0.2 parts of Kathon preservative and organosilicon emulsion-type defoaming agent
0.01-0.02 parts, to improve the stability etc. of auxiliary agent.
The preparation method of folium eucalypti oil assistant of the present invention, includes the following steps:
(1) folium eucalypti oil microcapsule is made；
(2) eucalyptus oil is added in nonionic emulsifier by weight and carries out shearing dispersion, 1/3-2/3 amount is then added
Deionized water, obtain solution A；
(3) solution A is added in folium eucalypti oil microcapsule, stirs evenly to obtain solution B；
(4) anion thickener, polyurethane binder are added in remaining deionized water by weight, obtain solution C；
(5) oil assistant containing folium eucalypti is obtained after solution B and solution C being stirred evenly, stood.
Wherein, in step (2), at least one of eugenol, wormwood oil and cedar oil are mixed with eucalyptus oil by weight
It closes, is then added in nonionic emulsifier and carries out shearing dispersion.
In step (1), the folium eucalypti oil microcapsule is the aqueous solution that eucalyptus oil is added to Arabic gum and modification of chitosan
In, it stirs, is obtained by drying；Wherein, the mass fraction of the aqueous solution of Arabic gum and modification of chitosan be 3-5%, eucalyptus oil with
The mass ratio of the aqueous solution of Arabic gum and modification of chitosan is 1:4-10.
The modification of chitosan is at least one of chitosan hydrochloride, chitosan nitrate, Chitosan citrate.
In step (4), remaining go also is added in Kathon preservative and organosilicon emulsion-type defoaming agent together by weight
In ionized water, solution C is obtained.
The fabric final finishing working solution of the oil assistant of the present invention containing folium eucalypti, is added 5- in fabric final finishing working solution
The folium eucalypti oil assistant of 30g/L.
The utility model has the advantages that compared with prior art, the invention has the benefit that firstly, the present invention is incited somebody to action using emulsifying process
Eucalyptus oil is dissolved in emulsifier, and obtained auxiliary agent has good affinity and assimilation effect to face liber；Secondly, in auxiliary agent
Folium eucalypti oil microcapsule is added simultaneously, under the protection of cyst wall, the retention time of eucalyptus oil effective component increases, functional effect
Extend, is conducive to keep the optimal using effect of fabric；Then, one or more essential oils can be added in emulsifier, can be improved
The inoxidizability of essential oil itself can also improve the storage stability of auxiliary agent, avoid for a long time as gravity and caused by point
Layer；In addition, the production method of auxiliary agent of the present invention is simple and easy, it is easy to accomplish.
Specific embodiment:
Oil assistant containing folium eucalypti of the invention (similarly hereinafter) includes following component by weight: 5-20 parts of folium eucalypti oil microcapsule,
5-10 parts of eucalyptus oil, 1-20 parts of nonionic emulsifier, 5-10 parts of anionic thickener, 5-10 parts of polyurethane binder and go from
Sub- water 30-50 parts.
Wherein, folium eucalypti oil microcapsule is eucalyptus oil to be added in the aqueous solution of Arabic gum and modification of chitosan, and stirring is dried
It is dry to obtain.There is the protection of microcapsule wall material, the effective component in eucalyptus oil can effectively be maintained to be not easily susceptible to temperature or moisture
Influence is diffused into air, to guarantee the stability of its function.Wherein, modification of chitosan is chitosan hydrochloride, chitosan
At least one of nitrate, Chitosan citrate, smaller by modified molecular weight of chitosan, deacetylation is higher,
With good water solubility, advantageous colloid is formed, and improves microcapsules preparation efficiency.
In above-mentioned auxiliary agent, eucalyptus oil is made either after the emulsification treatment of nonionic emulsifier to cellulose fiber
Dimension or chemical fibre all have the lotion of affinity and energy uniform pickup, guarantee after arranging, fabric is not when by external force
Also suppression mite and antibacterial effect can be played.Above-mentioned nonionic emulsifier for example can be span 20 (to be had purchased from the outstanding chemical industry in Zibo sea
Limit company), polysorbate85 (be purchased from Zibo Hai Jie Chemical Co., Ltd.), alkyl phenol polyoxyethylene ether -4 is (purchased from the outstanding chemical industry in Zibo sea
Co., Ltd), fatty alcohol polyoxyethylene ether AEO-3, AEO-7 octyl phenol polyoxyethylene ether OP-4, OP-6 (be purchased from Hai'an petrochemical industry)
Deng.When selecting HLB value is the emulsifier of 8.5-14.5, emulsifying effectiveness is more；Requirements when RHLB is oil emulsion phase, when
When HLB=RHLB, effect is best, oil-in-water system (RHLB:8.0-18.0), the present invention in oily phase HLB 8.5-14.5 it
Between, optimal stability.
Anion thickener of the invention, which has, increases system viscosity effect, and while thickening power, guarantees
Product water solubility is not influenced, such as CMC can be selected.
Polyurethane binder of the invention has the function of improving auxiliary agent with fiber ining conjunction with, it is multiple wash after remain to and fiber
It is acted in conjunction with preferable, and good with adjuvant system compatibility, counter productive is not generated to auxiliary agent storage.
Present invention oil assistant containing folium eucalypti can also be including in eugenol 1-5 parts, 1-5 parts of wormwood oil and 1-5 parts of cedar oil
It is at least one.These essential oils can play the role of uniform dissolution eucalyptus oil, by repeatedly implementing comparison discovery, using a variety of pharmacology
Similar essential oil compounding, can effectively promote beneficial effect, to reach optimum efficiency, and it is that may be present to make up folk prescription essential oil
Some defects, such as volatility, smell, color；Using pure plant source essential oil, more artificial synthesized essential oil, there is nothing
Toxic side effect, it is safe and secure the advantages that.
Present invention oil assistant containing folium eucalypti can also include preservative 0.1-0.2 parts and defoaming agent 0.01-0.02 parts.Wherein,
Preservative can select Kathon preservative, and defoaming agent can be selected from organosilicon emulsion-type defoaming agent.Kathon broad-spectrum high efficacy superpower goes out
Bacterium and bacteriostasis efficacy, organosilicon emulsion-type defoaming agent, dosage is few, and effect is good, is suitble to textile auxiliary agent defoaming.
Embodiment 1
(1) folium eucalypti oil assistant raw material components
20 parts of folium eucalypti oil microcapsule, 10 parts of eucalyptus oil, 5 parts of fatty alcohol polyoxyethylene ether AEO-3, octylphenol polyethylene ethylene oxide
5 parts of ether OP-4,10 parts of alkyl phenol polyoxyethylene ether -4,10 parts of thickener CMC, 10 parts of polyurethane binder, deionized water 50
Part.
(2) folium eucalypti oil assistant preparation method
Step 1, eucalyptus oil is added to the Arabic gum and chitosan mixed nitrate aqueous solution that mass fraction is 3%
In, the mass ratio of eucalyptus oil and mixed aqueous solution is 1:4, the mass ratio of Arabic gum and chitosan nitrate in mixed aqueous solution
For 1:1.Abundant shear agitation obtains mixture, then uses spray-on process, and 140 DEG C are dried, and collection obtains folium eucalypti oil microcapsule
Powder；
Step 2, by 5 parts of eucalyptus oil, the span 20 mixed, polysorbate85, -4 mixture of alkyl phenol polyoxyethylene ether is added
In, emulsion dispersion is carried out using high-speed shearing machine, then shear time 30min is added the deionized water of 1/2 amount, continues to stir
30min obtains solution A；
Step 3, it takes eucalyptus oil microscapsule powder to be added in solution A, is uniformly mixing to obtain solution B；
Step 4, it by thickener CMC, polyurethane binder, is added in remaining deionized water and stirs 30min, obtain solution
C；
Step 5, solution B and solution C are stirred evenly, after standing to obtain the final product.
(3) the fabric final finishing working solution and method for sorting of the oil assistant containing folium eucalypti
By fabric by taking cotton C40*C40/144*76 as an example
Step 1, fabric final finishing working solution is prepared, wherein the oil assistant containing folium eucalypti of above-mentioned preparation is added, additive amount is
30g/L is added in forming machine material cylinder, stirs evenly；
Step 2,140 DEG C of forming machine temperature, setting time 60s, material treatment are completed.
Embodiment 2
(1) raw material components of oil assistant containing folium eucalypti
5 parts of folium eucalypti oil microcapsule, 5 parts of eucalyptus oil, 3 parts of span 20,3 parts of polysorbate85, alkyl phenol polyoxyethylene ether -4 4
Part, 5 parts of thickener CMC, 5 parts of polyurethane binder, 30 parts of deionized water, 0.1 part of preservative, 0.01 part of defoaming agent.
(2) preparation method of oil assistant containing folium eucalypti
Step 1, eucalyptus oil is added to the Arabic gum and chitosan hydrochloride mixed aqueous solution that mass fraction is 3%
In, the mass ratio of eucalyptus oil and mixed aqueous solution is 1:4, the mass ratio of Arabic gum and chitosan hydrochloride in mixed aqueous solution
For 1:1.Abundant shear agitation obtains mixture, then uses spray-on process, and 140 DEG C are dried, and collection obtains folium eucalypti oil microcapsule
Powder；
Step 2, by 5 parts of eucalyptus oil, the span 20 mixed, polysorbate85, -4 mixture of alkyl phenol polyoxyethylene ether is added
In, emulsion dispersion is carried out using high-speed shearing machine, then shear time 30min is added the deionized water of 1/2 amount, continues to stir
30min obtains solution A；
Step 3, it takes eucalyptus oil microscapsule powder to be added in solution A, is uniformly mixing to obtain solution B；
Step 4, it by thickener CMC, polyurethane binder, preservative, defoaming agent, is added in remaining deionized water and stirs
30min obtains solution C；
Step 5, solution B and solution C are stirred evenly, after standing to obtain the final product.
(3) the fabric final finishing working solution and method for sorting of the oil assistant containing folium eucalypti
Fabric is by taking cotton C60*C60/200*100 as an example
Step 1, fabric final finishing working solution is prepared, wherein the oil assistant containing folium eucalypti of above-mentioned preparation is added, additive amount is
10g/L is added in forming machine material cylinder, stirs evenly；
Step 2,150 DEG C of forming machine temperature, setting time 60s, material treatment are completed.
Embodiment 3
(1) raw material components of oil assistant containing folium eucalypti
Increase on the basis of embodiment 2: 5 parts of eugenol, 4 parts, 1 part of cedar oil of wormwood oil.
(2) preparation method of oil assistant containing folium eucalypti
It is same as Example 2, difference are as follows: add the compound oil of eugenol, wormwood oil and cedar oil modulation in step 2
Enter in eucalyptus oil and emulsifies jointly.
(3) the material treatment method of the oil assistant containing folium eucalypti
It is same as Example 2.
Reference examples 1
(1) raw material components of oil assistant containing folium eucalypti
5 parts of folium eucalypti oil microcapsule, 3 parts of span 20,3 parts of polysorbate85,4 parts of alkyl phenol polyoxyethylene ether -4, thickener
5 parts of CMC, 5 parts of polyurethane binder, 30 parts of deionized water, 0.1 part of preservative, 0.01 part of defoaming agent.
Above-mentioned raw materials and 2 raw material of embodiment are essentially identical, difference are as follows: be added without eucalyptus oil.
(2) preparation method of oil assistant containing folium eucalypti
Step 1, eucalyptus oil is added to the Arabic gum and chitosan hydrochloride mixed aqueous solution that mass fraction is 3%
In, the mass ratio of eucalyptus oil and mixed aqueous solution is 1:4, the mass ratio of Arabic gum and chitosan hydrochloride in mixed aqueous solution
For 1:1, abundant shear agitation obtains mixture, then uses spray-on process, and 140 DEG C are dried, and collection obtains folium eucalypti oil microcapsule
Powder；
Step 2, by 5 parts of folium eucalypti oil microcapsule made from step 1, it is poly- that the span 20, polysorbate85, alkyl phenol mixed is added
In -4 mixture of ethylene oxide ether, emulsion dispersion is carried out using high-speed shearing machine, then going for 1/2 amount is added in shear time 30min
Ionized water continues to stir 30min, obtains solution A；
Step 3, it takes eucalyptus oil microscapsule powder to be added in solution A, is uniformly mixing to obtain solution B；
Step 4, it by thickener CMC, polyurethane binder, preservative and defoaming agent, is added in remaining deionized water and stirs
30min is mixed, solution C is obtained；
Step 5, solution B is mixed with solution C, addition preservative, defoaming agent, after standing to obtain the final product.
(3) the material treatment method of the oil assistant containing folium eucalypti
It is consistent with embodiment 2.
Reference examples 2
(1) raw material components of oil assistant containing folium eucalypti
5 parts of eucalyptus oil, 3 parts of span 20,3 parts of polysorbate85,4 parts of alkyl phenol polyoxyethylene ether -4,5 parts of thickener CMC,
5 parts of polyurethane binder, 30 parts of deionized water, 0.1 part of preservative, 0.01 part of defoaming agent.
Above-mentioned raw materials and 2 raw material of embodiment are essentially identical, difference are as follows: are added without folium eucalypti oil microcapsule.
(2) preparation method of oil assistant containing folium eucalypti
Step 1, by 5 parts of eucalyptus oil, the span 20 mixed, polysorbate85, -4 mixture of alkyl phenol polyoxyethylene ether is added
In, emulsion dispersion is carried out using high-speed shearing machine, then shear time 30min is added the deionized water of 1/2 amount, continues to stir
30min obtains solution A；
Step 2,5 parts of thickener, 5 parts of adhesive, preservative and defoaming agent are added into solution A made from step 1, is added
30min is stirred in remaining deionized water, obtains solution B；
Step 3, preservative, defoaming agent will be added in solution B made from step 3, after standing to obtain the final product.
(3) the material treatment method of the oil assistant containing folium eucalypti
It is consistent with embodiment 2.
Reference examples 3
Difference with embodiment 3 is to be added without wormwood oil and cedar oil；
Other steps and component and process implementing method are constant.
Reference examples 4
Difference with embodiment 3 is 1 part of eugenol, 1 part, 1 part of cedar oil of wormwood oil；
Other steps and component and process implementing method are constant.
Reference examples 5
Difference with embodiment 3 is 6 parts of eugenol, 6 parts, 6 parts of cedar oil of wormwood oil；
Other steps and component and process implementing method are constant.
The performance comparison of 1 embodiment 1-3 of table, comparative example 1-2 folium eucalypti oil assistant
Note: biocidal property be prioritized to be divided into it is fine, good, general, poor and poor, similarly hereinafter.
As shown in Table 1:
Embodiment 1 is added without preservative and defoaming agent and essential oil, and foam easily occurs in finishing agent, and stability is poor, but antibacterial
Property and suppression mite rate it is preferable, can satisfy the whole of auxiliary agent of the present invention requires, but in bulk production production, foam meeting occurs in finishing agent
Extend the reaction time of finishing agent, the delay of bubble is also it is easier that cloth cover generates spot fault, and the poor finishing agent of stability is not
Energy long storage needs not being suitable for producing with using；
Eugenol, wormwood oil, cedar oil is added in embodiment 3 on the basis of embodiment 2, in emulsifier, improves suppression mite
Rate and biocidal property；
Reference examples 1 are added without eucalyptus oil, and directly test suppression mite rate and biocidal property are lower, but have after washing lower
Press down mite and biocidal property；Reference examples 2 are added without folium eucalypti oil microcapsule, and directly test has lower suppression mite rate and biocidal property, washing
Do not have suppression mite rate and biocidal property afterwards, comprehensive reference examples 1 illustrate influence of the addition of eucalyptus oil to antibacterial anti-mite more with reference examples 2
Greatly；
Reference examples 3 are added without wormwood oil and cedar oil, and pressing down mite rate and biocidal property compared to embodiment 3 has certain reduction, select
This three kinds of essential oil compounding effect of explanation is best, mutually has preferable dissolubility between the essential oil of compounding, can promote suppression mite suppression
Bacterium effect, and stability can be improved, make up the deficiency of single essential oil；
Reference examples 4 reduce the additive amount of eugenol, wormwood oil, cedar oil, press down mite rate compared to embodiment 3 and biocidal property drops
It is low；
Reference examples 5 increase the additive amount of eugenol, wormwood oil, cedar oil, press down mite rate compared to embodiment 3 and biocidal property drops
It is low, although this illustrates that the increase of auxiliary essential oil content can promote suppression mite and bacteriostasis efficacy is also broken if additive amount is excessive
Bad emulsification system causes to be layered.
Embodiment 4 studies influence of the addition number of eucalyptus oil and folium eucalypti oil microcapsule to additive performance effect
Four groups of parallel laboratory tests are designed, raw material components are substantially the same manner as Example 3 with preparation method, and difference is eucalyptus oil
With the addition number of folium eucalypti oil microcapsule, the additive performance compared, as shown in table 2.
The performance comparison of 2 embodiment of table, 4 folium eucalypti oil assistant
As shown in Table 2, it is less that 1 eucalyptus oil, eucalyptus oil microcapsule content are organized, so various functions can not be up to standard；Group 3,
Group 4 is all preferable in terms of anti-mite, fungistatic effect, but eucalyptus oil and folium eucalypti oil microcapsule dosage increase, and emulsification system is easily destroyed,
Cause product layering auxiliary agent shelf life not up to standard, stability is poor；Folium eucalypti oil microcapsule amount is larger in group 2, directly test suppression mite
Rate is not up to standard.
In conclusion the ratio range of eucalyptus oil disclosed by the invention and folium eucalypti oil microcapsule can obtain maximum beneficial effect
Fruit.
Claims (7)
1. a kind of folium eucalypti oil assistant, which is characterized in that by weight include following component: 5-20 parts of folium eucalypti oil microcapsule, eucalyptus
5-10 parts of leaf oil, 10-20 parts of nonionic emulsifier, 5-10 parts of anion thickener, 5-10 parts of polyurethane binder, go from
Sub- water 30-50 parts, 0.1-0.2 parts of Kathon preservative and 0.01-0.02 parts of organosilicon emulsion-type defoaming agent, wherein it is described it is non-from
The HLB value of subtype emulsifier is 8.5-14.5.
2. folium eucalypti oil assistant according to claim 1, it is characterised in that by weight further include 1-5 parts of eugenol, Chinese mugwort
1-5 parts and at least one of cedar oil 1-5 parts of careless oil.
3. the preparation method of folium eucalypti oil assistant according to claim 1, it is characterised in that include the following steps:
(1) folium eucalypti oil microcapsule is made；
(2) eucalyptus oil is added in nonionic emulsifier by weight and carries out shearing dispersion, going for 1/3-2/3 amount is then added
Ionized water obtains solution A；
(3) solution A is added in folium eucalypti oil microcapsule, stirs evenly to obtain solution B；
(4) anion thickener, polyurethane binder, Kathon preservative and organosilicon emulsion-type defoaming agent are added by weight
Enter in remaining deionized water, obtains solution C；
(5) oil assistant containing folium eucalypti is obtained after solution B and solution C being stirred evenly, stood.
4. the preparation method of folium eucalypti oil assistant according to claim 3, it is characterised in that: in step (2), by weight by fourth
At least one of fragrant phenol, wormwood oil and cedar oil are mixed with eucalyptus oil, are then added in nonionic emulsifier and are sheared
Dispersion.
5. the preparation method of folium eucalypti oil assistant according to claim 3, it is characterised in that: in step (1), the eucalyptus oil is micro-
Capsule is eucalyptus oil to be added in the aqueous solution of Arabic gum and modification of chitosan, stirs, is obtained by drying；Wherein, Arabic gum
Mass fraction with the aqueous solution of modification of chitosan is the aqueous solution of 3-5%, eucalyptus oil and Arabic gum and modification of chitosan
Mass ratio is 1:4-10.
6. the preparation method of folium eucalypti oil assistant according to claim 5, it is characterised in that: the modification of chitosan is chitosan
At least one of hydrochloride, chitosan nitrate, Chitosan citrate.
7. the fabric final finishing working solution of the oil assistant containing folium eucalypti described in claim 1, it is characterised in that: work in fabric final finishing
The folium eucalypti oil assistant of 5-30g/L is added in liquid.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610172779.4A CN105746501B (en) | 2016-03-24 | 2016-03-24 | Folium eucalypti oil assistant and preparation method thereof and fabric final finishing working solution |
| PCT/CN2016/079580 WO2017161613A1 (en) | 2016-03-24 | 2016-04-18 | Eucalyptus oil auxiliary agent, preparation method thereof, and fabric-finishing working solution |
| AU2016102391A AU2016102391A4 (en) | 2016-03-24 | 2016-04-18 | Eucalyptus oil auxiliary agent, preparation method thereof, and fabric-finishing working solution |
| AU2016399387A AU2016399387A1 (en) | 2016-03-24 | 2016-04-18 | Eucalyptus oil auxiliary agent, preparation method thereof, and fabric-finishing working solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610172779.4A CN105746501B (en) | 2016-03-24 | 2016-03-24 | Folium eucalypti oil assistant and preparation method thereof and fabric final finishing working solution |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105746501A CN105746501A (en) | 2016-07-13 |
| CN105746501B true CN105746501B (en) | 2019-02-01 |
Family
ID=56346406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610172779.4A Active CN105746501B (en) | 2016-03-24 | 2016-03-24 | Folium eucalypti oil assistant and preparation method thereof and fabric final finishing working solution |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN105746501B (en) |
| AU (2) | AU2016399387A1 (en) |
| WO (1) | WO2017161613A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107761398A (en) * | 2017-09-15 | 2018-03-06 | 南通香佳纺织科技有限公司 | A kind of anti-mite finishing agent of microcapsules textile and preparation method thereof |
| CN110846893A (en) * | 2019-11-28 | 2020-02-28 | 南京海派企业管理咨询有限公司 | Textile anti-mite agent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203293A (en) * | 1998-07-03 | 1998-12-30 | 王雪平 | Cold antibiotic fabric and making method thereof |
| CN103668945A (en) * | 2012-09-21 | 2014-03-26 | 青岛道合生物科技有限公司 | Anti-mite antibacterial agent special for textiles |
| CN104250927A (en) * | 2014-06-09 | 2014-12-31 | 浙江纺织服装科技有限公司 | Wrinkle resistant and shrink proof mugwort microcapsule finishing agent for fabric and preparation method thereof |
| CN104264473A (en) * | 2014-10-08 | 2015-01-07 | 苏州印丝特纺织数码科技有限公司 | Environmentally-friendly mosquito-repelling finishing agent |
| CN104975513A (en) * | 2015-05-29 | 2015-10-14 | 天津城建大学 | Efficient antibacterial chitosan essential oil microcapsule preparation method |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998030124A1 (en) * | 1997-01-09 | 1998-07-16 | Lice Busters International Pty | Insect repellent substrate for headwear |
| JP3955012B2 (en) * | 2003-11-26 | 2007-08-08 | 創研工業株式会社 | Indoor pest control agent |
| CN102405941A (en) * | 2011-08-10 | 2012-04-11 | 华南农业大学 | Isatis root oil microcapsule and functional fabric finishing agent |
| CN104532595A (en) * | 2014-12-15 | 2015-04-22 | 西安工程大学 | Mosquito-preventing and fly-repelling capsule finishing agent as well as preparation method and application thereof |
| CN105002625A (en) * | 2015-06-25 | 2015-10-28 | 张家港市华源染织有限公司 | Mosquito repelling fabric |
-
2016
- 2016-03-24 CN CN201610172779.4A patent/CN105746501B/en active Active
- 2016-04-18 AU AU2016399387A patent/AU2016399387A1/en active Pending
- 2016-04-18 AU AU2016102391A patent/AU2016102391A4/en not_active Expired
- 2016-04-18 WO PCT/CN2016/079580 patent/WO2017161613A1/en active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203293A (en) * | 1998-07-03 | 1998-12-30 | 王雪平 | Cold antibiotic fabric and making method thereof |
| CN103668945A (en) * | 2012-09-21 | 2014-03-26 | 青岛道合生物科技有限公司 | Anti-mite antibacterial agent special for textiles |
| CN104250927A (en) * | 2014-06-09 | 2014-12-31 | 浙江纺织服装科技有限公司 | Wrinkle resistant and shrink proof mugwort microcapsule finishing agent for fabric and preparation method thereof |
| CN104264473A (en) * | 2014-10-08 | 2015-01-07 | 苏州印丝特纺织数码科技有限公司 | Environmentally-friendly mosquito-repelling finishing agent |
| CN104975513A (en) * | 2015-05-29 | 2015-10-14 | 天津城建大学 | Efficient antibacterial chitosan essential oil microcapsule preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2016102391A4 (en) | 2019-05-16 |
| WO2017161613A1 (en) | 2017-09-28 |
| AU2016399387A1 (en) | 2018-10-04 |
| CN105746501A (en) | 2016-07-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105746501B (en) | Folium eucalypti oil assistant and preparation method thereof and fabric final finishing working solution | |
| CN106758221A (en) | A kind of spinning post-finishing microcapsules and its production and use | |
| CN103317566A (en) | Micro-emulsion-type wood and bamboo mould-proof agent, as well as preparation method and application thereof | |
| CN101357856B (en) | Zinc oxide suspending agent | |
| CN101690481B (en) | Spirodiclofen multiple emulsion and preparation method thereof | |
| WO2010129489A4 (en) | Method for treating fabrics | |
| CN110144734A (en) | A kind of mosquito repellent and sunscreen complex function microcapsules and preparation method thereof | |
| CN103168773A (en) | Water-suspension nano capsule and preparation method thereof | |
| KR20140103136A (en) | Microbicidal composition and method for preparing the same | |
| CN105442329A (en) | Care agent containing eucalyptus oilmicrocapsules and preparation method of care agent | |
| CN106497439A (en) | A kind of Natural plant environment-friendlyand glue and preparation method thereof | |
| CN106930102B (en) | A kind of camellia oil textile auxiliary agent and the preparation method and application thereof | |
| CN105794861A (en) | Pure natural plant essential oil mosquito repellent and preparation method thereof | |
| CN103563962A (en) | Insecticide composition containing propylene glycol alginate and anabasine | |
| CN102493272A (en) | ASA emulsion sizing agent and preparation method thereof | |
| CN103651403B (en) | A kind of Efficient insecticidal composition containing Spiromesifen | |
| CN105145619A (en) | Pyrethroid pesticide aqueous emulsion and preparation method thereof | |
| AT507049B1 (en) | MEANS FOR REDUCING THE FLAMMABILITY OF SUBSTANCES - UNIVERSAL FLAME PROTECTION AGENT | |
| CN101642094A (en) | Triadimefon pesticide microemulsion and preparation method thereof | |
| CN105696355A (en) | Cinnamon oil containing adjuvant for textiles and preparation method and application thereof | |
| CN103621524B (en) | Pesticide composition | |
| CN106390738A (en) | Photocatalyst formaldehyde removing spraying agent | |
| CN103907624A (en) | Pyriminostrobin-containing acaricidal composition | |
| CN103907623A (en) | Efficient acaricidal composition containing pyriminostrobin | |
| CN103621548B (en) | A kind of Pesticidal combination containing Spiromesifen and pyrethroid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |